CN107384247A - A kind of based Wood Adhesives based on esterification modification tapioca and preparation method thereof - Google Patents
A kind of based Wood Adhesives based on esterification modification tapioca and preparation method thereof Download PDFInfo
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- CN107384247A CN107384247A CN201710565766.8A CN201710565766A CN107384247A CN 107384247 A CN107384247 A CN 107384247A CN 201710565766 A CN201710565766 A CN 201710565766A CN 107384247 A CN107384247 A CN 107384247A
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- esterification modification
- tapioca
- wood adhesives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J103/00—Adhesives based on starch, amylose or amylopectin or on their derivatives or degradation products
- C09J103/04—Starch derivatives
- C09J103/06—Esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of based Wood Adhesives based on esterification modification tapioca and preparation method thereof, it is characterised in that mixes esterifying agent maleic anhydride, oxygen sodium oxide molybdena, is dissolved in distilled water, obtains A liquid;Tapioca is crushed, spraying treatment is carried out to it with A liquid, is well mixed, temperature reaction, filtering, alcohol are washed, and are dried in an oven, are obtained esterification modification tapioca;By poly-vinyl alcohol solution heating water bath, after adding borax soln to react, with urea, hydrogen peroxide, ferrous sulfate hybrid reaction, add tributyl phosphate, stir to obtain hydrophobically modified polyvinyl alcohol glue;Paraffin heating water bath is melted, adds polysorbate60, sorbester p18, stirs, methylate methyl acrylate, potassium peroxydisulfate, emulsion reaction, filters to obtain complex emulsions waterproofing agent;Esterification modification tapioca, hydrophobically modified polyvinyl alcohol glue, complex emulsions waterproofing agent are mixed with styrene-acrylic emulsion, initiator ammonium persulfate, stirs, standing and defoaming, obtains a kind of based Wood Adhesives.
Description
Technical field
The present invention relates to adhesive field, and in particular to a kind of based Wood Adhesives based on esterification modification tapioca and its
Preparation method.
Background technology
Coal ash fiber is flyash gets rid of the ultra-fine inorganic mineral fibres that a fiber-forming process produces by melting, at present
Research for coal ash fiber both at home and abroad and production are still at an early stage, most of research still rest on fiber copy paper with
And fiberboard preparation etc..
Wang Cheng is far away from its master thesis《The preparation and water resistance research of coal ash fiberboard》In, using wet method system
Plate technology utilization coal ash fiber prepares sheet material, and coal ash fiber is loosened except Slag treatment by water conservancy stirring means, ground
The factors such as adhesive polyethylene alcohol, coal ash fiber slurry agitation jitter time, coal ash fiber concentration, additive have been studied carefully to powder
The influence of coal ash fiberboard mechanical property, improved by modified coal ash fiber, modified adhesive and using waterproof coating
The water resistance of coal ash fiberboard.But combination property, water resistance deficiency be present.
The content of the invention
The present invention solves the technical problem of provide a kind of polyvinyl alcohol-paraffin wax emulsions composite modified water proof type powder
Coal ash fiberboard and preparation method thereof, the fiberboard prepared according to the technique possess good combination property and water resistance.
The technical problems to be solved by the invention are realized using following technical scheme:
A kind of preparation method of the based Wood Adhesives based on esterification modification tapioca, it is characterised in that carry out according to the following steps:
A. 4-7 parts by weight esterifying agents maleic anhydride, 1-2 parts by weight oxygen sodium oxide molybdena are mixed, 1:5-10 is dissolved in distilled water
In, obtain A liquid;20-30 parts by weight tapiocas are put into pulverizer and crushed, spraying treatment are carried out to it with A liquid, mixing is equal
Even, it is 5-10% to be put into 40-50 DEG C of baking oven and be dried to moisture, is warming up to 90-110 DEG C of reaction time 3-4h, is down to room temperature,
Filtering, alcohol are washed 3-5 times, are dried in 50-60 DEG C of baking oven, are crossed 80-100 mesh sieves, are obtained esterification modification tapioca;
B. by poly-vinyl alcohol solution heating water bath to 70-80 DEG C, lower addition 6-9 parts by weight borax solns are stirred, constant temperature stirring is anti-
After answering 1-2h, mix, stir with 3-5 parts by weight of urea, 1-2 parts by weight hydrogen peroxide, it is 5- to adjust pH with 1-2mol/L HCl
6, add 1-3 parts by weight of ferrous sulfate, be incubated 50-60 DEG C of stirring reaction 30-50min, 1-2 parts by weight of phosphoric acid tributyls are added dropwise, stir
Mix uniformly, be cooled to room temperature, adjust pH to obtain hydrophobically modified polyvinyl alcohol glue for neutrality;
C. by 6-10 parts by weight paraffin, heating water bath, stirring fusing are slow to add 2-3 parts by weight polysorbate60,1-2 at 85-95 DEG C
Parts by weight sorbester p18, stirs, and 1:3-5 adds distilled water, continues constant temperature stirring 1-2h, adds 5-8 weight parts of methacrylic acid first
Ester, 0.1-0.2 parts by weight potassium peroxydisulfates, 3-4h is reacted in 70-80 DEG C of stirring and emulsifying, room temperature is cooled to, with 100-200 eye mesh screens
Filtering and discharging, obtain complex emulsions waterproofing agent;
D. resulting material in a, b, c is mixed with 6-11 parts by weight styrene-acrylic emulsion, 1-2 parts by weight initiator potassium persulfates, room temperature
Under be sufficiently stirred, standing and defoaming, obtain a kind of based Wood Adhesives.
Wherein, poly-vinyl alcohol solution described in step b is to add distilled water into 50-60 weight account polyethylene alcohol, heating
1-2h is stirred to 90-100 DEG C of heating water bath, obtains the solution that mass fraction is 8-10%;Borax soln concentration is 3-5%.In step c
The emulsion reaction mixing speed is 1000-1100rpm.Styrene-acrylic emulsion solid content described in step d is 40-45%.
The present invention reaction mechanism and have the beneficial effect that:
With tapioca esterification occurs for maleic anhydride, tapioca particle is diminished, specific surface area increases, hydrophobicity
It can improve;With polyvinyl alcohol (PVA) for adhesive, nonhazardous, but its poor water resistance, first polyvinyl alcohol is changed with borax
Property, reaction is crosslinked between the two, improves PVA water resistance;Again with oxidant hydrogen peroxide, catalyst sulfuric acid ferrous iron, urea
Oxidative degradation and hydrophobically modified are carried out to it, to reduce the viscosity of glue, its solid content and water resistance is improved, it is good to obtain hydrophobic performance
And the PVA glues of good combination property, it is good to the hydrophobically modified effect of timber;Using sorbester p18 as emulsifying agent, using potassium peroxydisulfate to draw
Agent is sent out, using methyl methacrylate as monomer, emulsion polymerization is carried out with paraffin wax emulsions, obtains complex emulsions waterproofing agent, use it for
Improve the water imbibition and dimensional stability of timber.By modified PVA glue and modified starch, complex emulsions waterproofing agent, styrene-acrylic emulsion, draw
Hair agent potassium peroxydisulfate blending compounding obtains based Wood Adhesives.
Embodiment
In order that the technical means, the inventive features, the objects and the advantages of the present invention are easy to understand, tie below
Specific embodiment is closed, the present invention is expanded on further.
Embodiment
A kind of preparation method of the based Wood Adhesives based on esterification modification tapioca, it is characterised in that according to the following steps
Carry out:
A. 4kg esterifying agents maleic anhydride, 1kg oxygen sodium oxide molybdena are mixed, 1:5 are dissolved in distilled water, obtain A liquid;By 20kg wood
Sweet potato starch is put into pulverizer and crushed, and spraying treatment is carried out to it with A liquid, is well mixed, is put into 40-50 DEG C of baking oven and is dried to water
It is 5-10% to divide content, is warming up to 90-110 DEG C of reaction time 3h, is down to room temperature, filtering, alcohol are washed 3 times, in 50-60 DEG C of baking oven
Drying, 80 mesh sieves are crossed, obtain esterification modification tapioca;
B. by poly-vinyl alcohol solution heating water bath to 70-80 DEG C, lower addition 6kg borax solns, constant temperature stirring reaction 1-2h are stirred
Afterwards, mix, stir with 3kg urea, 1kg hydrogen peroxide, it is 5-6 to adjust pH with 1mol/L HCl, adds 1kg ferrous sulfate, is incubated
50-60 DEG C of stirring reaction 40min, 1kg tributyl phosphates are added dropwise, stir, be cooled to room temperature, adjust pH to be obtained hydrophobic for neutrality
Modified polyvinylalcohol glue;
C. by 6kg paraffin, heating water bath, stirring fusing, slow plus 2kg polysorbate60s, 1kg sorbester p18s, stirring are equal at 85-95 DEG C
It is even, 1:5 add distilled water, continue constant temperature stirring 1h, add 5kg methyl methacrylates, 0.1kg potassium peroxydisulfates, in 70-80 DEG C of stirring
Emulsion reaction 3h, is cooled to room temperature, with 100 eye mesh screen filtering and dischargings, obtains complex emulsions waterproofing agent;
D. resulting material in a, b, c is mixed with 8kg styrene-acrylic emulsions, 1kg initiator potassium persulfates, be sufficiently stirred at room temperature, it is quiet
Deaeration is put, obtains a kind of based Wood Adhesives.
Wherein, poly-vinyl alcohol solution described in step b is to add distilled water into 50kg polyvinyl alcohol, is warming up to 90-100
DEG C heating water bath stirring 1h, obtains the solution that mass fraction is 10%;Borax soln concentration is 4%.Emulsion reaction stirs described in step c
It is 1000rpm to mix speed.Styrene-acrylic emulsion solid content described in step d is 45%.
Claims (5)
- A kind of 1. preparation method of the based Wood Adhesives based on esterification modification tapioca, it is characterised in that:Esterifying agent maleic anhydride, oxygen sodium oxide molybdena are mixed, is dissolved in distilled water, obtains A liquid;Tapioca is crushed, with A liquid Spraying treatment is carried out to it, temperature reaction, obtains esterification modification tapioca;By poly-vinyl alcohol solution heating water bath, add borax molten After liquid reaction, with urea, hydrogen peroxide, ferrous sulfate hybrid reaction, add tributyl phosphate, stir to obtain hydrophobically modified polyvinyl alcohol glue Liquid;Paraffin heating water bath is melted, adds polysorbate60, sorbester p18, stirs, methylate methyl acrylate, potassium peroxydisulfate, emulsification Reaction, filters to obtain complex emulsions waterproofing agent;Esterification modification tapioca, hydrophobically modified polyvinyl alcohol glue, complex emulsions are prevented Aqua mixes with styrene-acrylic emulsion, initiator ammonium persulfate, stirring, standing and defoaming, obtains a kind of based Wood Adhesives.
- A kind of 2. preparation method of the based Wood Adhesives based on esterification modification tapioca, it is characterised in that:A. 4-7 parts by weight esterifying agents maleic anhydride, 1-2 parts by weight oxygen sodium oxide molybdena are mixed, 1:5-10 is dissolved in distilled water In, obtain A liquid;20-30 parts by weight tapiocas are put into pulverizer and crushed, spraying treatment are carried out to it with A liquid, mixing is equal Even, it is 5-10% to be put into 40-50 DEG C of baking oven and be dried to moisture, is warming up to 90-110 DEG C of reaction time 3-4h, is down to room temperature, Filtering, alcohol are washed 3-5 times, are dried in 50-60 DEG C of baking oven, are crossed 80-100 mesh sieves, are obtained esterification modification tapioca;B. by poly-vinyl alcohol solution heating water bath to 70-80 DEG C, lower addition 6-9 parts by weight borax solns are stirred, constant temperature stirring is anti- After answering 1-2h, mix, stir with 3-5 parts by weight of urea, 1-2 parts by weight hydrogen peroxide, it is 5- to adjust pH with 1-2mol/L HCl 6, add 1-3 parts by weight of ferrous sulfate, be incubated 50-60 DEG C of stirring reaction 30-50min, 1-2 parts by weight of phosphoric acid tributyls are added dropwise, stir Mix uniformly, be cooled to room temperature, adjust pH to obtain hydrophobically modified polyvinyl alcohol glue for neutrality;C. by 6-10 parts by weight paraffin, heating water bath, stirring fusing are slow to add 2-3 parts by weight polysorbate60,1-2 at 85-95 DEG C Parts by weight sorbester p18, stirs, and 1:3-5 adds distilled water, continues constant temperature stirring 1-2h, adds 5-8 weight parts of methacrylic acid first Ester, 0.1-0.2 parts by weight potassium peroxydisulfates, 3-4h is reacted in 70-80 DEG C of stirring and emulsifying, room temperature is cooled to, with 100-200 eye mesh screens Filtering and discharging, obtain complex emulsions waterproofing agent;D. resulting material in a, b, c is mixed with 6-11 parts by weight styrene-acrylic emulsion, 1-2 parts by weight initiator potassium persulfates, room temperature Under be sufficiently stirred, standing and defoaming, obtain a kind of based Wood Adhesives.
- 3. a kind of preparation method of based Wood Adhesives based on esterification modification tapioca according to claim 2, it is special Sign is that poly-vinyl alcohol solution described in step b is to add distilled water into 50-60 weight account polyethylene alcohol, is warming up to 90- 100 DEG C of heating water baths stir 1-2h, obtain the solution that mass fraction is 8-10%;Borax soln concentration is 3-5%.
- 4. a kind of preparation method of based Wood Adhesives based on esterification modification tapioca according to claim 2, it is special Sign is that emulsion reaction mixing speed described in step c is 1000-1100rpm.
- 5. a kind of preparation method of based Wood Adhesives based on esterification modification tapioca according to claim 2, it is special Sign is that styrene-acrylic emulsion solid content described in step d is 40-45%.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN115708788A (en) * | 2022-11-25 | 2023-02-24 | 上海绵花棠生物科技有限公司 | Cosmetic powder base solution and preparation method thereof |
Citations (2)
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CN105524575A (en) * | 2015-12-28 | 2016-04-27 | 常州思宇环保材料科技有限公司 | Preparation method of esterified lotus root starch/polyvinyl alcohol blend adhesive |
CN106753065A (en) * | 2016-12-30 | 2017-05-31 | 河南中包科技有限公司 | A kind of quickstick MR adhesive and its preparation method for corrugated board temperature production |
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2017
- 2017-07-12 CN CN201710565766.8A patent/CN107384247A/en active Pending
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CN105524575A (en) * | 2015-12-28 | 2016-04-27 | 常州思宇环保材料科技有限公司 | Preparation method of esterified lotus root starch/polyvinyl alcohol blend adhesive |
CN106753065A (en) * | 2016-12-30 | 2017-05-31 | 河南中包科技有限公司 | A kind of quickstick MR adhesive and its preparation method for corrugated board temperature production |
Non-Patent Citations (2)
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN115708788A (en) * | 2022-11-25 | 2023-02-24 | 上海绵花棠生物科技有限公司 | Cosmetic powder base solution and preparation method thereof |
CN115708788B (en) * | 2022-11-25 | 2024-01-30 | 上海绵花棠生物科技有限公司 | Make-up-holding foundation liquid and preparation method thereof |
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Application publication date: 20171124 |