CN104293248A - Modified adhesive - Google Patents
Modified adhesive Download PDFInfo
- Publication number
- CN104293248A CN104293248A CN201410533460.0A CN201410533460A CN104293248A CN 104293248 A CN104293248 A CN 104293248A CN 201410533460 A CN201410533460 A CN 201410533460A CN 104293248 A CN104293248 A CN 104293248A
- Authority
- CN
- China
- Prior art keywords
- parts
- sodium
- bamboo
- weight
- mixed solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000853 adhesive Substances 0.000 title abstract 5
- 230000001070 adhesive effect Effects 0.000 title abstract 5
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims abstract description 65
- 235000017491 Bambusa tulda Nutrition 0.000 claims abstract description 65
- 241001330002 Bambuseae Species 0.000 claims abstract description 65
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims abstract description 65
- 239000011425 bamboo Substances 0.000 claims abstract description 65
- 238000002360 preparation method Methods 0.000 claims abstract description 41
- XPFVYQJUAUNWIW-UHFFFAOYSA-N furfuryl alcohol Chemical compound OCC1=CC=CO1 XPFVYQJUAUNWIW-UHFFFAOYSA-N 0.000 claims abstract description 39
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 30
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000002994 raw material Substances 0.000 claims abstract description 22
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 21
- 239000000052 vinegar Substances 0.000 claims abstract description 20
- 235000021419 vinegar Nutrition 0.000 claims abstract description 20
- 238000002203 pretreatment Methods 0.000 claims abstract description 16
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 15
- 239000004342 Benzoyl peroxide Substances 0.000 claims abstract description 12
- 235000019400 benzoyl peroxide Nutrition 0.000 claims abstract description 12
- 230000004913 activation Effects 0.000 claims abstract description 11
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000003063 flame retardant Substances 0.000 claims abstract description 11
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims abstract description 9
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims abstract description 7
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 claims abstract description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 6
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 claims abstract description 6
- 235000013312 flour Nutrition 0.000 claims abstract description 6
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 6
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 6
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229920001084 poly(chloroprene) Polymers 0.000 claims abstract description 6
- 241000196324 Embryophyta Species 0.000 claims abstract description 5
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 70
- 229920003023 plastic Polymers 0.000 claims description 43
- 239000004033 plastic Substances 0.000 claims description 43
- 239000000178 monomer Substances 0.000 claims description 41
- 239000011259 mixed solution Substances 0.000 claims description 38
- 239000011230 binding agent Substances 0.000 claims description 36
- 229910001961 silver nitrate Inorganic materials 0.000 claims description 35
- 239000000203 mixture Substances 0.000 claims description 33
- 239000000243 solution Substances 0.000 claims description 32
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 27
- 239000000843 powder Substances 0.000 claims description 27
- 229910052709 silver Inorganic materials 0.000 claims description 27
- 239000004332 silver Substances 0.000 claims description 27
- 239000007864 aqueous solution Substances 0.000 claims description 24
- MOMKYJPSVWEWPM-UHFFFAOYSA-N 4-(chloromethyl)-2-(4-methylphenyl)-1,3-thiazole Chemical compound C1=CC(C)=CC=C1C1=NC(CCl)=CS1 MOMKYJPSVWEWPM-UHFFFAOYSA-N 0.000 claims description 23
- 229920000178 Acrylic resin Polymers 0.000 claims description 23
- 239000004925 Acrylic resin Substances 0.000 claims description 23
- 235000019983 sodium metaphosphate Nutrition 0.000 claims description 23
- 150000003983 crown ethers Chemical class 0.000 claims description 21
- 239000000839 emulsion Substances 0.000 claims description 21
- 239000003610 charcoal Substances 0.000 claims description 16
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 15
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical group [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 15
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 15
- 238000010792 warming Methods 0.000 claims description 15
- 239000003999 initiator Substances 0.000 claims description 14
- -1 polyoxyethylene octylphenol Polymers 0.000 claims description 13
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 claims description 12
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 12
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 12
- 238000001816 cooling Methods 0.000 claims description 12
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 claims description 12
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 11
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 11
- 229920002554 vinyl polymer Polymers 0.000 claims description 11
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 10
- 229920002125 Sokalan® Polymers 0.000 claims description 10
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 10
- 239000004584 polyacrylic acid Substances 0.000 claims description 10
- 229920002635 polyurethane Polymers 0.000 claims description 10
- 239000004814 polyurethane Substances 0.000 claims description 10
- 239000007787 solid Substances 0.000 claims description 10
- 239000004141 Sodium laurylsulphate Substances 0.000 claims description 9
- 238000001354 calcination Methods 0.000 claims description 9
- WVIIMZNLDWSIRH-UHFFFAOYSA-N cyclohexylcyclohexane Chemical group C1CCCCC1C1CCCCC1 WVIIMZNLDWSIRH-UHFFFAOYSA-N 0.000 claims description 8
- 239000008367 deionised water Substances 0.000 claims description 8
- RRAFCDWBNXTKKO-UHFFFAOYSA-N eugenol Chemical group COC1=CC(CC=C)=CC=C1O RRAFCDWBNXTKKO-UHFFFAOYSA-N 0.000 claims description 8
- 238000009413 insulation Methods 0.000 claims description 8
- 239000002245 particle Substances 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- 239000004359 castor oil Substances 0.000 claims description 6
- 239000003921 oil Substances 0.000 claims description 6
- 239000003352 sequestering agent Substances 0.000 claims description 6
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 6
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 6
- DAJSVUQLFFJUSX-UHFFFAOYSA-M sodium;dodecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCS([O-])(=O)=O DAJSVUQLFFJUSX-UHFFFAOYSA-M 0.000 claims description 6
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 5
- 239000004254 Ammonium phosphate Substances 0.000 claims description 5
- 229920000388 Polyphosphate Polymers 0.000 claims description 5
- 239000004743 Polypropylene Substances 0.000 claims description 5
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 5
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 5
- GTTSNKDQDACYLV-UHFFFAOYSA-N Trihydroxybutane Chemical compound CCCC(O)(O)O GTTSNKDQDACYLV-UHFFFAOYSA-N 0.000 claims description 5
- 238000013019 agitation Methods 0.000 claims description 5
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 5
- 229910000148 ammonium phosphate Inorganic materials 0.000 claims description 5
- 235000019289 ammonium phosphates Nutrition 0.000 claims description 5
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 5
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 5
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 5
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 5
- 239000004327 boric acid Substances 0.000 claims description 5
- 235000019438 castor oil Nutrition 0.000 claims description 5
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 claims description 5
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 5
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 5
- 239000008187 granular material Substances 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- CXHHBNMLPJOKQD-UHFFFAOYSA-M methyl carbonate Chemical compound COC([O-])=O CXHHBNMLPJOKQD-UHFFFAOYSA-M 0.000 claims description 5
- 230000007935 neutral effect Effects 0.000 claims description 5
- 229920001444 polymaleic acid Polymers 0.000 claims description 5
- 239000001205 polyphosphate Substances 0.000 claims description 5
- 235000011176 polyphosphates Nutrition 0.000 claims description 5
- 229920001155 polypropylene Polymers 0.000 claims description 5
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 5
- 108010048734 sclerotin Proteins 0.000 claims description 5
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 5
- 239000004299 sodium benzoate Substances 0.000 claims description 5
- 235000010234 sodium benzoate Nutrition 0.000 claims description 5
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 5
- 239000001488 sodium phosphate Substances 0.000 claims description 5
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 5
- VKFFEYLSKIYTSJ-UHFFFAOYSA-N tetraazanium;phosphonato phosphate Chemical compound [NH4+].[NH4+].[NH4+].[NH4+].[O-]P([O-])(=O)OP([O-])([O-])=O VKFFEYLSKIYTSJ-UHFFFAOYSA-N 0.000 claims description 5
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 5
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 5
- 239000011787 zinc oxide Substances 0.000 claims description 5
- 235000014692 zinc oxide Nutrition 0.000 claims description 5
- JOLVYUIAMRUBRK-UHFFFAOYSA-N 11',12',14',15'-Tetradehydro(Z,Z-)-3-(8-Pentadecenyl)phenol Natural products OC1=CC=CC(CCCCCCCC=CCC=CCC=C)=C1 JOLVYUIAMRUBRK-UHFFFAOYSA-N 0.000 claims description 4
- YLKVIMNNMLKUGJ-UHFFFAOYSA-N 3-Delta8-pentadecenylphenol Natural products CCCCCCC=CCCCCCCCC1=CC=CC(O)=C1 YLKVIMNNMLKUGJ-UHFFFAOYSA-N 0.000 claims description 4
- JOLVYUIAMRUBRK-UTOQUPLUSA-N Cardanol Chemical compound OC1=CC=CC(CCCCCCC\C=C/C\C=C/CC=C)=C1 JOLVYUIAMRUBRK-UTOQUPLUSA-N 0.000 claims description 4
- FAYVLNWNMNHXGA-UHFFFAOYSA-N Cardanoldiene Natural products CCCC=CCC=CCCCCCCCC1=CC=CC(O)=C1 FAYVLNWNMNHXGA-UHFFFAOYSA-N 0.000 claims description 4
- NPBVQXIMTZKSBA-UHFFFAOYSA-N Chavibetol Natural products COC1=CC=C(CC=C)C=C1O NPBVQXIMTZKSBA-UHFFFAOYSA-N 0.000 claims description 4
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 claims description 4
- 239000005770 Eugenol Substances 0.000 claims description 4
- UVMRYBDEERADNV-UHFFFAOYSA-N Pseudoeugenol Natural products COC1=CC(C(C)=C)=CC=C1O UVMRYBDEERADNV-UHFFFAOYSA-N 0.000 claims description 4
- PTFIPECGHSYQNR-UHFFFAOYSA-N cardanol Natural products CCCCCCCCCCCCCCCC1=CC=CC(O)=C1 PTFIPECGHSYQNR-UHFFFAOYSA-N 0.000 claims description 4
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 claims description 4
- 229960002217 eugenol Drugs 0.000 claims description 4
- 238000005469 granulation Methods 0.000 claims description 4
- 230000003179 granulation Effects 0.000 claims description 4
- 150000002989 phenols Chemical class 0.000 claims description 4
- 239000002023 wood Substances 0.000 claims description 4
- 241000209140 Triticum Species 0.000 claims description 3
- 235000021307 Triticum Nutrition 0.000 claims description 3
- 240000008042 Zea mays Species 0.000 claims description 3
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims description 3
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims description 3
- 235000005822 corn Nutrition 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 239000002893 slag Substances 0.000 claims description 3
- 235000015099 wheat brans Nutrition 0.000 claims description 3
- 238000002485 combustion reaction Methods 0.000 claims 1
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 5
- 239000003054 catalyst Substances 0.000 abstract description 4
- 229920001971 elastomer Polymers 0.000 abstract 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 abstract 3
- 239000007788 liquid Substances 0.000 abstract 3
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 abstract 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract 1
- 235000013339 cereals Nutrition 0.000 abstract 1
- 239000002738 chelating agent Substances 0.000 abstract 1
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 abstract 1
- 238000005453 pelletization Methods 0.000 abstract 1
- 239000000835 fiber Substances 0.000 description 14
- 239000003643 water by type Substances 0.000 description 9
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 7
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 7
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 7
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 7
- 230000007613 environmental effect Effects 0.000 description 7
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 6
- 229940083025 silver preparation Drugs 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- DXPPIEDUBFUSEZ-UHFFFAOYSA-N 6-methylheptyl prop-2-enoate Chemical compound CC(C)CCCCCOC(=O)C=C DXPPIEDUBFUSEZ-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 230000003115 biocidal effect Effects 0.000 description 3
- 239000000084 colloidal system Substances 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 238000004945 emulsification Methods 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 238000009775 high-speed stirring Methods 0.000 description 3
- 125000005395 methacrylic acid group Chemical class 0.000 description 3
- 230000001681 protective effect Effects 0.000 description 3
- 238000010298 pulverizing process Methods 0.000 description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 238000006722 reduction reaction Methods 0.000 description 2
- 238000009987 spinning Methods 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 description 1
- RUMACXVDVNRZJZ-UHFFFAOYSA-N 2-methylpropyl 2-methylprop-2-enoate Chemical compound CC(C)COC(=O)C(C)=C RUMACXVDVNRZJZ-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- 229910052728 basic metal Inorganic materials 0.000 description 1
- 150000003818 basic metals Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000011491 glass wool Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- FSAJWMJJORKPKS-UHFFFAOYSA-N octadecyl prop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C=C FSAJWMJJORKPKS-UHFFFAOYSA-N 0.000 description 1
- 230000008447 perception Effects 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses an adhesive and particularly relates to a modified adhesive. The modified adhesive consists of the following raw materials in parts by weight: 70-95 parts of elastic rubber, 25-35 parts of phthalic anhydride, 7-11 parts of furfuryl alcohol extracted from natural plant, 10-12 parts of triethylene glycol, 15-18 parts of glutaric acid, 8-10 parts of butantriol, 5-7 parts of zinc oxide powder, 3-5 parts of magnesium oxide, 15-25 parts of chloroprene rubber, 2-3 parts of softening oil, 15-20 parts of dimethyl carbonate, 1-3 parts of benzoyl peroxide, 4-8 parts of ethyl acetate, 1-4 parts of an emulsifier, 20-30 parts of flour, 5*10<-5>-9*10<-5> parts of nano sliver, 1-3 parts of a flame retardant, 0.8-2.5 parts of a catalyst, 3-7 parts of a bamboo vinegar aqueous liquid, 6-13 parts of bamboo carbon powder with grain size of 0.01-0.06mm, wherein the bamboo vinegar aqueous liquid is a mixed liquid of bamboo vinegar, a chelating agent and water in a weight ratio of 1 to (0.1-0.2) to (60-100); the bamboo carbon powder is prepared by the steps such as raw material pre-treatment, primary carbon preparation, activation treatment and pelletizing; the elastic rubber comprises first elastic rubber and second elastic rubber mixed in a weight ratio of (1-3) to 1. The adhesive has good antibacterial activity, stability and adhesion property.
Description
Technical field
The present invention relates to a kind of binding agent, particularly relate to a kind of modified binder.
Background technology
Bamboo fibers in the market has following two classes: one is the regenerated fibre produced by bamboo pulp, is commonly referred to bamboo pulp fiber; Two is the fibers directly extracted from bamboo through special process, is called bamboo fiber.Because bamboo fiber has more superior performance in water absorbability, ventilation property, spinning property etc., therefore study spinning property bamboo fiber and there is obvious economic benefit and good social benefit.Although bamboo fiber products itself has certain biocidal property, but still can produce mildew after repeated use, affect perception and use.
It is multi-field that binding agent can be widely used in wood working, building decoration, fabric bonding etc., extensive market, but existing binding agent is mostly unavoidably containing objectionable impurities formaldehyde, and having free formaldehyde after using discharges, and environmental-protecting performance is to be improved.
CN102690618B (2013-12-4) discloses a kind of preparation method of thermosetting acrylic resin binding agent, but this binding agent is mainly used in glass wool, is not suitable for bamboo fiber products.
Summary of the invention
The object of this invention is to provide a kind of biocidal property good, stability and dispersing property good, bond properties is good, the modified binder that is especially suitable for bamboo fiber products.
Above-mentioned technical purpose of the present invention is achieved by the following technical programs:
A kind of modified binder, it is made up of the raw material of following parts by weight:
Phthalic anhydride 25-35 part, the furfuryl alcohol 7-11 part of extracting from natural phant, triethylene glycol 10-12 part, pentanedioic acid 15-18 part, trihydroxybutane 8-10 part, zinc white 5-7 part, magnesium oxide 3-5 part, chloroprene rubber 15-25 part, elastic plastic 70-95 part, softening oil 2-3 part, methylcarbonate 15-20 part, benzoyl peroxide 1-3 part, vinyl acetic monomer 4-8 part, emulsifying agent 1-4 part, flour 20-30 part, nanometer silver 5 × 10
-5-9 × 10
-5part, fire retardant 1-3 part, catalyzer 0.8-2.5 part, 3-7 part bamboo vinegar aqueous solution, 6-13 part particle diameter are the bamboo charcoal powder of 0.01-0.06mm;
The described bamboo vinegar aqueous solution is the mixing solutions of the bamboo vinegar of weight ratio 1:0.1-0.2:60-100, sequestrant and water composition;
Described fire retardant is counted composed of the following components by weight: ammonium low polyphosphate 20 ~ 50 parts, 10 ~ 25 parts, ammonium phosphate, ammonium pyrophosphate 6 ~ 12 parts, 5 ~ 20 parts, ammonium sulfate, boric acid 5 ~ 10 parts, 10 ~ 25 parts, water;
Described bamboo charcoal powder obtains through raw material pre-treatment, primary carbon preparation, activation treatment and granulation step; The concrete preparation method of described bamboo charcoal powder is:
A. raw material pre-treatment: bamboo is sent in microwave vacuum tank, be evacuated to vacuum tightness for-0.02MPa ~-0.001MPa, then carry out microwave treatment, microwave frequency is 300MHz ~ 950MHz, and microwave treatment time is 1 ~ 3min;
B. primary carbon preparation: the bamboo through raw material pre-treatment gained is experienced successively drying, pre-charing, charing, calcining and cooling, control calcining and be incubated 40-80min with the ramp of 5-15 DEG C/min to 700-750 DEG C, and then be incubated 2-8h with the ramp of 5-15 DEG C/min to 1000-1500 DEG C, then 300-400 DEG C is cooled to the speed of 18-25 DEG C/min, cool to room temperature with the furnace again, obtain primary carbon;
C. then activation treatment: by gained primary carbon and 140-160g/L polymaleic acid and 40-70g/L inferior sodium phosphate mixed solution 1:3-4 mixing submergence 3-5h is in mass ratio neutral by washed with de-ionized water to pH value;
D. granulate;
Described emulsifying agent is one or more in polyoxyethylene octylphenol ether, sulfonated castor oil, sodium lauryl sulphate, Sodium dodecylbenzene sulfonate;
Described elastic plastic comprises the first elastic plastic and the second elastic plastic that mix by weight 1-3:1;
The solids content that described first elastic plastic comprises 10-35 part weight is the Emulsion acrylic resin of 60-75%, 10-15 part aqueous polyurethane, the acrylic resin powder of 5-8 part weight, the solids content of 2-6 part weight are the EVA emulsion of 20-35% and the Chlorinated Polypropylene III of 1-4 part weight;
The preparation method of described Emulsion acrylic resin is: the acrylate monomer mixed solution of preparation 80-110 part weight is stand-by, then the emulsifying agent of 5-7 part weight of several compositions in polyoxyethylene octylphenol ether, sulfonated castor oil, sodium lauryl sulphate, Sodium dodecylbenzene sulfonate, the sodium bicarbonate of 0.3-0.7 part weight and deionized water are joined in reactor, add the 1/3 acrylate monomer mixed solution prepared again wherein, be warming up to 50-90 DEG C, fully stir 20-40min; Be warming up to 60-100 DEG C, drip remaining 2/3 acrylate monomer mixed solution and ammonium persulfate solution initiator, time for adding controls, for 1-4h, to ensure that monomer drips prior to initiator solution; Dropwise rear insulation 1-4h, after cooling, regulate ph value of emulsion to about 7;
Described nanometer silver is prepared from according to following steps:
(1) sodium dodecyl sulfate solution, water polyacrylic acid and hydrazine hydrate solution are added in silver nitrate aqueous solution and obtain mixed solution, the mol ratio of described sodium laurylsulfonate and Silver Nitrate is 4-6:1; The mol ratio of described water polyacrylic acid and Silver Nitrate is 0.4-0.6:1; ; The mol ratio of described hydrazine hydrate and Silver Nitrate is 0.2-0.3:1;
(2) in described mixed solution, add crown ether and sodium-metaphosphate, the mol ratio of described crown ether and Silver Nitrate is 3-5:1; The mol ratio of described sodium-metaphosphate and Silver Nitrate is 0.8-1.3:1, and control ph is 8-9, obtains nanometer silver.
The per-cent that the present invention relates to, unless stated otherwise, all refers to mass percent.
Advantage of the present invention is:
1. contriver selects specific activation treatment to coordinate raw material pre-treatment and primary carbon preparation, obtains the bamboo charcoal powder with high bacteriostasis rate and antibacterial value; Meanwhile, bamboo charcoal powder, as the interpolation raw material of binding agent, can further improve again the biocidal property of binding agent, stability, dispersiveness and binding property;
Environmental protection binding agent composition of the present invention environmental protection, while the larger sticking power of imparting bamboo fiber products, can prevent binding agent from coming off, and increases bactericidal properties and the mildew resistance of bamboo fiber products;
2. the combination matching of nanometer silver, furfuryl alcohol, benzoyl peroxide and elastic plastic can improve some performance of binding agent, and makes it have very strong sterilizing ability, stability, dispersing property and bond properties simultaneously;
3. crown ether have hydrophobic external skeletal and hydrophilic can with the inner chamber of metal ion Cheng Jian, stable title complex can be formed with alkalimetal ion.Meanwhile, the present invention is engaged in follow-up reduction reaction and adds sodium-metaphosphate, makes on the one hand free in reaction system or exposed reduction negative ion have higher reactive behavior; Meanwhile, after basic metal and crown ether generation ligand complex, alkali metal cation is coated in inner chamber by crown ether, just pulls open the distance in nanometer silver system between positive and negative charge thus, make nanometer silver can stable dispersion in the aqueous solution, not easily reunite;
4., by each raw material of binding agent and the particular combination of nanometer silver, can not occur to reunite and particle growth in depositing, and can not be oxidized, stability and good dispersity.
As preferably, the sequestrant in the described bamboo vinegar aqueous solution is at least one in ethylenediamine tetraacetic acid (EDTA) or disodium edta.
As preferably, the preparation method of described second elastic plastic is: be that the polyvinyl alcohol water solution of 30-45% and the aqueous polyurethane aqueous solution of 5-10% are heated to 60-80 DEG C by mass concentration, be cooled to 30-50 DEG C and add acrylate 10-15%, then add potassium hydroxide 0.1-0.2% and be warming up to 100-110 DEG C, then the plant phenols 2-4% adding sclerotin albumen 5-8%, rosin fat 6-9%, extract from natural phant; React and be cooled to 45-55 DEG C in 3-5 hour, then add Sodium Benzoate 0.06-0.08%, ditertiary butyl peroxide 0.01-0.02% and vinyl acetic monomer 0.1-0.3%, stir 1-1.5 hour, cooling, obtained described second elastic plastic.
Second elastic plastic of the present invention not only environmental protection, water-fast, mildew-resistant, and bonding strength is high, with the first elastic plastic in proportion combination matching in environmental protection binding agent, give environmental protection binding agent of the present invention and there is better bactericidal properties, stability, dispersing property and bond properties.
As preferably, described Emulsion acrylic resin is synthesized as monomer and emulsifying agent, ammonium persulfate initiator, sodium bicarbonate and deionized water by any one or a few in any one or a few in methyl methacrylate, β-dimethyl-aminoethylmethacrylate, butyl methacrylate, butyl acrylate, Propenoic acid, 2-methyl, isobutyl ester, dodecylacrylate, octadecyl acrylate and methacrylic acid, vinylformic acid, acrylamide, vinyl cyanide, Methacrylamide, vinylbenzene.
As preferably, described mixed solution is heated to 45-55 DEG C add crown ether and sodium-metaphosphate in described mixed solution before by described step (2).
As preferably, described step (2) adds crown ether and sodium-metaphosphate post-heating to 70-85 DEG C in described mixed solution, Keep agitation 5-8min.
As preferably, described step (2) is carried out under microwave vacuum condition, and be specifically evacuated to vacuum tightness for-0.02MPa ~-0.001MPa, then carry out microwave treatment, microwave frequency is 100MHz ~ 230MHz, and microwave treatment time is 3 ~ 7s.
More preferably, described crown ether is bicyclohexane also-18-hat-6.
As preferably, the described furfuryl alcohol extracted from natural phant is selected from the furfuryl alcohol extracted from the wheat bran or bamboo wood chip of the core slag of corn cob, oat or wheat.
As preferably, the described plant phenols extracted from natural phant is Eugenol or cardanol.
More preferably, described catalyzer is sodium hydroxide.
In sum, the present invention has following beneficial effect:
1, environmental protection binding agent composition of the present invention environmental protection, while the larger sticking power of imparting bamboo fiber products, can prevent binding agent from coming off, and increases bactericidal properties and the mildew resistance of bamboo fiber products;
2, the combination matching of nanometer silver, furfuryl alcohol, benzoyl peroxide and elastic plastic can improve some performance of binding agent, and makes it have very strong sterilizing ability, stability, dispersing property and bond properties simultaneously;
3, by each raw material of binding agent and the particular combination of nanometer silver, can not occur to reunite and particle growth in depositing, and can not be oxidized, stability and good dispersity.
Embodiment
Embodiment one
The preparation of nanometer silver:
(1) sodium dodecyl sulfate solution, water polyacrylic acid and hydrazine hydrate solution are added in silver nitrate aqueous solution and obtain mixed solution, the mol ratio of sodium laurylsulfonate and Silver Nitrate is 4:1; The mol ratio of water polyacrylic acid and Silver Nitrate is 0.4:1; The mol ratio of hydrazine hydrate and Silver Nitrate is 0.2:1;
(2) in mixed solution, add bicyclohexane also-18-hat-6 and sodium-metaphosphate, bicyclohexane also-18-hat-6 is 3:1 with the mol ratio of Silver Nitrate; The mol ratio of sodium-metaphosphate and Silver Nitrate is 0.8:1, and control ph is 8-9, obtains nanometer silver.
The concrete preparation method of bamboo charcoal powder is:
A. raw material pre-treatment: bamboo is sent in microwave vacuum tank, be evacuated to vacuum tightness for-0.01MPa, then carry out microwave treatment, microwave frequency is 650MHz, and microwave treatment time is 2min;
B. primary carbon preparation: the bamboo through raw material pre-treatment gained is experienced successively drying, pre-charing, charing, calcining and cooling, controlling calcining with the ramp to 730 of 10 DEG C/min DEG C is incubated 50min, and then be incubated 6h with the ramp to 1300 of 8 DEG C/min DEG C, then 350 DEG C are cooled to the speed of 22 DEG C/min, cool to room temperature with the furnace again, obtain primary carbon;
C. then activation treatment: by gained primary carbon and 140-160g/L polymaleic acid and 60g/L inferior sodium phosphate mixed solution 1:3.5 mixing submergence 4h is in mass ratio neutral by washed with de-ionized water to pH value;
D. granulate.
The preparation method of the second elastic plastic is: be that the polyvinyl alcohol water solution of 30% and the aqueous polyurethane aqueous solution of 5% are heated to 60 DEG C by mass concentration, be cooled to 30 DEG C and add acrylate 10%, then add potassium hydroxide 0.1% and be warming up to 100 DEG C, then add sclerotin albumen 5%, rosin fat 6%, Eugenol 2%; React and be cooled to 45 DEG C in 3 hours, then add Sodium Benzoate 0.06%, ditertiary butyl peroxide 0.01% and vinyl acetic monomer 0.1%, stir 1 hour, cooling, obtained second elastic plastic.
The preparation of Emulsion acrylic resin:
4.63 parts of polyoxyethylene octylphenol ethers (OP-10), 1.67 parts of sodium lauryl sulphate, 0.6 part of sodium bicarbonate are dissolved in 70 parts of deionized waters, then add in reactor, are warming up to about 70 DEG C; Take 1.3 parts of methyl methacrylates, 2.14 parts of vinylbenzene, 50.9 parts of butyl acrylates, 29.08 parts of Isooctyl acrylate monomers, 2.45 parts of butyl methacrylate, 1.8 parts of vinyl cyanide, 0.8 part of vinylformic acid and 1.44 parts of methacrylic acids make mix monomer; 1/3 part of mix monomer is added in reactor, at 85 DEG C of pre-emulsification 30min; Then 0.45 part of initiator ammonium persulfate (APS) joined and make solution in 50 parts of deionized waters and drop to gradually in reactor, drip residual monomer, about 3h dropwises simultaneously, controls mix monomer and drips prior to initiator solution; After dropwising, after insulation 1h, namely can be made into stand-by emulsion;
The preparation of acrylic resin powder: 3 parts of BPO are dissolved in 13.3 parts of methyl methacrylates, 61 parts of vinylbenzene, 21.4 parts of n-butyl acrylates and 4.3 parts of acrylic acid mix monomers; The mix monomer being dissolved with initiator is joined and is dissolved with in 500 parts of deionized waters of 7.5 parts of protective colloids, high-speed stirring, in 30min, be warming up to 85 DEG C simultaneously; Product is collected after insulation reaction 4h; Product is dried after pulverizing, make acrylic resin powder with 200 eye mesh screens filtrations stand-by.
The solids content that first elastic plastic comprises 10 parts of weight is the Emulsion acrylic resin of 60-75%, 10 parts of aqueous polyurethanes, the acrylic resin powder of 5 parts of weight, the solids content of 2 parts of weight are the EVA emulsion of 20% and the Chlorinated Polypropylene III of 1 part of weight.
Fire retardant is counted composed of the following components by weight: ammonium low polyphosphate 20 parts, 10 parts, ammonium phosphate, ammonium pyrophosphate 6 parts, 5 parts, ammonium sulfate, boric acid 5 parts, 25 parts, water.
The composition and ratio of modified binder:
Phthalic anhydride 25 parts, the furfuryl alcohol 7 parts extracted from the core slag of corn cob, triethylene glycol 10 parts, pentanedioic acid 15 parts, trihydroxybutane 8 parts, zinc white 5 parts, 3 parts, magnesium oxide, chloroprene rubber 15 parts, elastic plastic 70 parts, softening oil 2 parts, methylcarbonate 15 parts, benzoyl peroxide 1 part, vinyl acetic monomer 4 parts, emulsifying agent 1 part, 20 parts, flour, nanometer silver 5 × 10
-5, fire retardant 3 parts, sodium hydroxide catalyst 1.5 parts, 5 parts of the bamboo vinegar aqueous solution, 8 parts of particle diameters are the bamboo charcoal powder of 0.01-0.06mm; The bamboo vinegar aqueous solution is the mixing solutions of the bamboo vinegar of weight ratio 1:0.15:80, disodium edta sequestrant and water composition.
Emulsifying agent is polyoxyethylene octylphenol ether;
Elastic plastic comprises the first elastic plastic and the second elastic plastic that mix by weight 1:1.
Embodiment two
The preparation of nanometer silver:
(1) sodium dodecyl sulfate solution, water polyacrylic acid and hydrazine hydrate solution are added in silver nitrate aqueous solution and obtain mixed solution, the mol ratio of sodium laurylsulfonate and Silver Nitrate is 6:1; The mol ratio of water polyacrylic acid and Silver Nitrate is 0.6:1; ; The mol ratio of hydrazine hydrate and Silver Nitrate is 0.3:1;
(2) in mixed solution, add bicyclohexane also-18-hat-6 and sodium-metaphosphate, bicyclohexane also-18-hat-6 is 5:1 with the mol ratio of Silver Nitrate; The mol ratio of sodium-metaphosphate and Silver Nitrate is 1.3:1, and control ph is 8-9, obtains nanometer silver.
The composition and ratio of modified binder:
Phthalic anhydride 35 parts, the furfuryl alcohol 11 parts, triethylene glycol 12 parts, pentanedioic acid 18 parts, trihydroxybutane 10 parts, zinc white 7 parts, 5 parts, magnesium oxide, chloroprene rubber 25 parts, elastic plastic 95 parts, softening oil 3 parts, methylcarbonate 20 parts, benzoyl peroxide 3 parts, vinyl acetic monomer 8 parts, emulsifying agent 4 parts, 30 parts, flour, the nanometer silver 5 × 10 that extract from the wheat bran of oat or wheat
-5-9 × 10
-5, fire retardant 1 part, sodium hydroxide catalyst 2.5 parts, 7 parts of the bamboo vinegar aqueous solution, 13 parts of particle diameters are the bamboo charcoal powder of 0.01-0.06mm; The bamboo vinegar aqueous solution is the mixing solutions of the bamboo vinegar of weight ratio 1:0.2:100, disodium edta sequestrant and water composition;
Described bamboo charcoal powder obtains through raw material pre-treatment, primary carbon preparation, activation treatment and granulation step; The concrete preparation method of bamboo charcoal powder is:
A. raw material pre-treatment: bamboo is sent in microwave vacuum tank, be evacuated to vacuum tightness for-0.001MPa, then carry out microwave treatment, microwave frequency is 950MHz, and microwave treatment time is 3min;
B. primary carbon preparation: the bamboo through raw material pre-treatment gained is experienced successively drying, pre-charing, charing, calcining and cooling, controlling calcining with the ramp to 750 of 15 DEG C/min DEG C is incubated 80min, and then be incubated 2-8h with the ramp to 1500 of 15 DEG C/min DEG C, then 400 DEG C are cooled to the speed of 25 DEG C/min, cool to room temperature with the furnace again, obtain primary carbon;
C. then activation treatment: by gained primary carbon and 160g/L polymaleic acid and 70g/L inferior sodium phosphate mixed solution 1:4 mixing submergence 5h is in mass ratio neutral by washed with de-ionized water to pH value;
D. granulate.
Fire retardant is counted composed of the following components by weight: ammonium low polyphosphate 50 parts, 25 parts, ammonium phosphate, ammonium pyrophosphate 12 parts, 20 parts, ammonium sulfate, boric acid 10 parts, 10 parts, water.
Emulsifying agent is sodium lauryl sulphate;
Elastic plastic comprises the first elastic plastic and the second elastic plastic that mix by weight 3:1;
The solids content that first elastic plastic comprises 35 parts of weight is the Emulsion acrylic resin of 75%, 15 parts of aqueous polyurethanes, the acrylic resin powder of 8 parts of weight, the solids content of 6 parts of weight are the EVA emulsion of 35% and the Chlorinated Polypropylene III of 4 parts of weight;
The preparation of Emulsion acrylic resin: 5.28 parts of sulfonated castor oils, 1.84 parts of sodium lauryl sulphate, 0.66 part of sodium bicarbonate are dissolved in 70 parts of deionized waters, then join in reactor, are warming up to about 70 DEG C; Take 6.12 parts of methyl methacrylates, 62.78 parts of butyl acrylates, 11.58 parts of vinylbenzene, 7.35 parts of butyl methacrylate, 0.88 part of vinylformic acid, 1.58 parts of methacrylic acids, 8.7 parts of Isooctyl acrylate monomers make mix monomer; 1/3 part of mix monomer is added in reactor, at 85 DEG C of pre-emulsification 30min; Then joined by 0.5 part of initiator A PS and make solution in 50 parts of deionized waters and drop to gradually in reactor, drip residual monomer, about 3h dropwises simultaneously, controls mix monomer and drips prior to initiator solution; After dropwising, after insulation 1h, namely can be made into stand-by emulsion;
The preparation of acrylic resin powder: 4 parts of BPO are dissolved in 15.96 parts of methyl methacrylates, 65 parts of vinylbenzene, 23.54 parts of n-butyl acrylates, 4.3 parts of acrylic acid mix monomers; The mix monomer being dissolved with initiator is joined and is dissolved with in 600 parts of deionized waters of 8 parts of protective colloids, high-speed stirring, in 30min, be warming up to 85 DEG C simultaneously; Product is collected after insulation reaction 4h; Product is dried after pulverizing, make acrylic resin powder with 200 eye mesh screens filtrations stand-by.The preparation method of the second elastic plastic is: be that the polyvinyl alcohol water solution of 38% and the aqueous polyurethane aqueous solution of 9% are heated to 80 DEG C by mass concentration, be cooled to 50 DEG C and add acrylate 15%, then add potassium hydroxide 0.2% and be warming up to 110 DEG C, then add sclerotin albumen 8%, rosin fat 9%, cardanol 2-4%; React and be cooled to 55 DEG C in 5 hours, then add Sodium Benzoate 0.08%, ditertiary butyl peroxide 0.02% and vinyl acetic monomer 0.3%, stir 1.5 hours, cooling, obtained second elastic plastic.
Embodiment three
The preparation of nanometer silver:
(1) sodium dodecyl sulfate solution, water polyacrylic acid and hydrazine hydrate solution are added in silver nitrate aqueous solution and obtain mixed solution, the mol ratio of sodium laurylsulfonate and Silver Nitrate is 5:1; The mol ratio of water polyacrylic acid and Silver Nitrate is 0.5:1; ; The mol ratio of hydrazine hydrate and Silver Nitrate is 0.25:1;
(2) in mixed solution, add bicyclohexane also-18-hat-6 and sodium-metaphosphate, bicyclohexane also-18-hat-6 is 4:1 with the mol ratio of Silver Nitrate; The mol ratio of sodium-metaphosphate and Silver Nitrate is 1:1, and control ph is 8-9, obtains nanometer silver.
The composition and ratio of modified binder:
Phthalic anhydride 30 parts, the furfuryl alcohol 7-11 part extracted from bamboo wood chip, triethylene glycol 11 parts, pentanedioic acid 16 parts, trihydroxybutane 9 parts, zinc white 6 parts, 4 parts, magnesium oxide, chloroprene rubber 19 parts, elastic plastic 85 parts, softening oil 2.5 parts, methylcarbonate 18 parts, benzoyl peroxide 2 parts, vinyl acetic monomer 7 parts, emulsifying agent 3 parts, 27 parts, flour, nanometer silver 6 × 10
-5, sodium hydroxide catalyst 0.8 part, fire retardant 2 parts, 3 parts of the bamboo vinegar aqueous solution, 6 parts of particle diameters are the bamboo charcoal powder of 0.01-0.06mm; The bamboo vinegar aqueous solution is the mixing solutions of the bamboo vinegar of weight ratio 1:0.1:60, ethylenediamine tetraacetic acid (EDTA) and water composition;
Described bamboo charcoal powder obtains through raw material pre-treatment, primary carbon preparation, activation treatment and granulation step; The concrete preparation method of bamboo charcoal powder is:
A. raw material pre-treatment: bamboo is sent in microwave vacuum tank, be evacuated to vacuum tightness for-0.02MPa, then carry out microwave treatment, microwave frequency is 300MHz, and microwave treatment time is 1min;
B. primary carbon preparation: the bamboo through raw material pre-treatment gained is experienced successively drying, pre-charing, charing, calcining and cooling, controlling calcining with the ramp to 700 of 5 DEG C/min DEG C is incubated 40min, and then be incubated 2h with the ramp to 1000 of 5 DEG C/min DEG C, then 300 DEG C are cooled to the speed of 18 DEG C/min, cool to room temperature with the furnace again, obtain primary carbon;
C. then activation treatment: by gained primary carbon and 140g/L polymaleic acid and 40g/L inferior sodium phosphate mixed solution 1:3 mixing submergence 3h is in mass ratio neutral by washed with de-ionized water to pH value;
D. granulate.
Fire retardant is counted composed of the following components by weight: ammonium low polyphosphate 30 parts, 15 parts, ammonium phosphate, ammonium pyrophosphate 8 parts, 15 parts, ammonium sulfate, boric acid 8 parts, 18 parts, water.
Emulsifying agent is one or more in polyoxyethylene octylphenol ether, sulfonated castor oil, sodium lauryl sulphate, Sodium dodecylbenzene sulfonate;
Elastic plastic comprises the first elastic plastic and the second elastic plastic that mix by weight 2:1;
The solids content that first elastic plastic comprises 25 parts of weight is the Emulsion acrylic resin of 65%, 12 parts of aqueous polyurethanes, the acrylic resin powder of 7 parts of weight, the solids content of 5 parts of weight are the EVA emulsion of 28% and the Chlorinated Polypropylene III of 3 parts of weight;
The preparation of Emulsion acrylic resin: 4.5 parts of OP-10,1.62 parts of sodium lauryl sulphate, 0.55 part of sodium bicarbonate are dissolved in 70 parts of deionized waters, then join in reactor, are warming up to about 70 DEG C; Take 5.42 parts of methyl methacrylates, 54.79 parts of butyl acrylates, 10.11 parts of vinylbenzene, 6.55 parts of butyl methacrylate, 0.76 part of vinylformic acid, 1.41 parts of methacrylic acids, 7.83 parts of Isooctyl acrylate monomers make mix monomer; 1/3 part of mix monomer is added in reactor, at 85 DEG C of pre-emulsification 30min; Then joined by 0.42 part of initiator A PS and make solution in 50 parts of deionized waters and drop to gradually in reactor, drip residual monomer, about 3h dropwises simultaneously, controls mix monomer and drips prior to initiator solution; After dropwising, after insulation 1h, namely can be made into stand-by emulsion;
The preparation of acrylic resin powder: 2.7 parts of BPO are dissolved in 11.97 parts of methyl methacrylates, 57.95 parts of vinylbenzene, 19.26 parts of n-butyl acrylates, 4.1 parts of acrylic acid mix monomers; The mix monomer being dissolved with initiator is joined and is dissolved with in 420 parts of deionized waters of 6 parts of protective colloids, high-speed stirring, in 30min, be warming up to 85 DEG C simultaneously; Product is collected after insulation reaction 4h; Product is dried after pulverizing, make acrylic resin powder with 200 eye mesh screens filtrations stand-by;
The preparation method of the second elastic plastic is: be that the polyvinyl alcohol water solution of 35% and the aqueous polyurethane aqueous solution of 8% are heated to 69 DEG C by mass concentration, be cooled to 40 DEG C and add acrylate 13%, then add potassium hydroxide 0.15% and be warming up to 105 DEG C, then add sclerotin albumen 6%, rosin fat 8%, Eugenol or cardanol 3%; React and be cooled to 50 DEG C in 4 hours, then add Sodium Benzoate 0.07%, ditertiary butyl peroxide 0.015% and vinyl acetic monomer 0.2%, stir 1.2 hours, cooling, obtained second elastic plastic.
Embodiment four
With embodiment one, before adding crown ether and sodium-metaphosphate unlike nanometer silver preparation process (2) in mixed solution, mixed solution is heated to 45 DEG C; Crown ether and sodium-metaphosphate post-heating to 70 DEG C is added, Keep agitation 5min in mixed solution.Nanometer silver preparation process (2) is carried out under microwave vacuum condition, and be specifically evacuated to vacuum tightness for-0.02MPa, then carry out microwave treatment, microwave frequency is 100MHz, and microwave treatment time is 3s.
Embodiment five
With embodiment two, before adding crown ether and sodium-metaphosphate unlike nanometer silver preparation process (2) in mixed solution, mixed solution is heated to 55 DEG C; Crown ether and sodium-metaphosphate post-heating to 85 DEG C is added, Keep agitation 8min in mixed solution.Nanometer silver preparation process (2) is carried out under microwave vacuum condition, and be specifically evacuated to vacuum tightness for-0.001MPa, then carry out microwave treatment, microwave frequency is 230MHz, and microwave treatment time is 7s.
Embodiment six
With embodiment three, before adding crown ether and sodium-metaphosphate unlike nanometer silver preparation process (2) in mixed solution, mixed solution is heated to 48 DEG C; Crown ether and sodium-metaphosphate post-heating to 78 DEG C is added, Keep agitation 6min in mixed solution.Nanometer silver preparation process (2) is carried out under microwave vacuum condition, and be specifically evacuated to vacuum tightness for-0.01MPa, then carry out microwave treatment, microwave frequency is 180MHz, and microwave treatment time is 5s.
Comparative example one
With embodiment one, unlike the furfuryl alcohol extracted from natural phant 14 parts, triethylene glycol 13 parts, elastic plastic 60 parts, softening oil 4 parts, emulsifying agent 6 parts; Not containing benzoyl peroxide, vinyl acetic monomer;
Elastic plastic comprises the first elastic plastic and the second elastic plastic that mix by weight 4:1.
Comparative example two
With embodiment two, be prepared from according to following steps unlike nanometer silver:
(1) sodium dodecyl sulfate solution and hydrazine hydrate solution are added in silver nitrate aqueous solution and obtain mixed solution, the mol ratio of sodium laurylsulfonate and Silver Nitrate is 3:1; The mol ratio of described hydrazine hydrate and Silver Nitrate is 0.2:1;
(2) in mixed solution, add crown ether and sodium-metaphosphate, the mol ratio of described crown ether and Silver Nitrate is 6:1; The mol ratio of sodium-metaphosphate and Silver Nitrate is 0.8:1, and control ph is 8-9, obtains nanometer silver.
Embodiment 1-6 and comparative example are left standstill, observe the dispersion state of the nanometer silver of sizing agent system after 1 month and 6 months containing nanometer silver respectively, observations is in table 1.
The dispersion state of table 1 containing nanometer silver in the binder system of nanometer silver
The Binder Properties contrast of table 2 embodiment and comparative example
This specific embodiment is only explanation of the invention; it is not limitation of the present invention; those skilled in the art can make to the present embodiment the amendment not having creative contribution as required after reading this specification sheets, as long as but be all subject to the protection of patent law in right of the present invention.
Claims (10)
1. a modified binder, is characterized in that being made up of the raw material of following parts by weight:
Elastic plastic 70-95 part, phthalic anhydride 25-35 part, the furfuryl alcohol 7-11 part of extracting from natural phant, triethylene glycol 10-12 part, pentanedioic acid 15-18 part, trihydroxybutane 8-10 part, zinc white 5-7 part, magnesium oxide 3-5 part, chloroprene rubber 15-25 part, softening oil 2-3 part, methylcarbonate 15-20 part, benzoyl peroxide 1-3 part, vinyl acetic monomer 4-8 part, emulsifying agent 1-4 part, flour 20-30 part, nanometer silver 5 × 10
-5-9 × 10
-5part, fire retardant 1-3 part, catalyzer 0.8-2.5 part, 3-7 part bamboo vinegar aqueous solution, 6-13 part particle diameter are the bamboo charcoal powder of 0.01-0.06mm;
The described bamboo vinegar aqueous solution is the mixing solutions of the bamboo vinegar of weight ratio 1:0.1-0.2:60-100, sequestrant and water composition;
Described fire retardant is counted composed of the following components by weight: ammonium low polyphosphate 20 ~ 50 parts, 10 ~ 25 parts, ammonium phosphate, ammonium pyrophosphate 6 ~ 12 parts, 5 ~ 20 parts, ammonium sulfate, boric acid 5 ~ 10 parts, 10 ~ 25 parts, water;
Described bamboo charcoal powder obtains through raw material pre-treatment, primary carbon preparation, activation treatment and granulation step;
The concrete preparation method of described bamboo charcoal powder is:
A. raw material pre-treatment: bamboo is sent in microwave vacuum tank, be evacuated to vacuum tightness for-0.02MPa ~-0.001MPa, then carry out microwave treatment, microwave frequency is 300MHz ~ 950MHz, and microwave treatment time is 1 ~ 3min;
B. primary carbon preparation: the bamboo through raw material pre-treatment gained is experienced successively drying, pre-charing, charing, calcining and cooling, control combustion is incubated 40-80min with the ramp of 5-15 DEG C/min to 700-750 DEG C, and then be incubated 2-8h with the ramp of 5-15 DEG C/min to 1000-1500 DEG C, then 300-400 DEG C is cooled to the speed of 18-25 DEG C/min, cool to room temperature with the furnace again, obtain primary carbon;
C. then activation treatment: by gained primary carbon and 140-160g/L polymaleic acid and 40-70g/L inferior sodium phosphate mixed solution 1:3-4 mixing submergence 3-5h is in mass ratio neutral by washed with de-ionized water to pH value;
D. granulate;
Described emulsifying agent is one or more in polyoxyethylene octylphenol ether, sulfonated castor oil, sodium lauryl sulphate, Sodium dodecylbenzene sulfonate; Described elastic plastic comprises the first elastic plastic and the second elastic plastic that mix by weight 1-3:1;
The solids content that described first elastic plastic comprises 10-35 part weight is the Emulsion acrylic resin of 60-75%, 10-15 part aqueous polyurethane, the acrylic resin powder of 5-8 part weight, the solids content of 2-6 part weight are the EVA emulsion of 20-35% and the Chlorinated Polypropylene III of 1-4 part weight;
The preparation method of described Emulsion acrylic resin is: the acrylate monomer mixed solution of preparation 80-110 part weight is stand-by, then the emulsifying agent of 5-7 part weight of several compositions in polyoxyethylene octylphenol ether, sulfonated castor oil, sodium lauryl sulphate, Sodium dodecylbenzene sulfonate, the sodium bicarbonate of 0.3-0.7 part weight and deionized water are joined in reactor, add the 1/3 acrylate monomer mixed solution prepared again wherein, be warming up to 50-90 DEG C, fully stir 20-40min; Be warming up to 60-100 DEG C, drip remaining 2/3 acrylate monomer mixed solution and ammonium persulfate solution initiator, time for adding controls, for 1-4h, to ensure that monomer drips prior to initiator solution; Dropwise rear insulation 1-4h, after cooling, regulate ph value of emulsion to about 7;
Described nanometer silver is prepared from according to following steps:
(1) sodium dodecyl sulfate solution, water polyacrylic acid and hydrazine hydrate solution are added in silver nitrate aqueous solution and obtain mixed solution, the mol ratio of described sodium laurylsulfonate and Silver Nitrate is 4-6:1; The mol ratio of described water polyacrylic acid and Silver Nitrate is 0.4-0.6:1; ; The mol ratio of described hydrazine hydrate and Silver Nitrate is 0.2-0.3:1;
(2) in described mixed solution, add crown ether and sodium-metaphosphate, the mol ratio of described crown ether and Silver Nitrate is 3-5:1; The mol ratio of described sodium-metaphosphate and Silver Nitrate is 0.8-1.3:1, and control ph is 8-9, obtains nanometer silver.
2. a kind of modified binder according to claim 1, it is characterized in that: the preparation method of described second elastic plastic is: be that the polyvinyl alcohol water solution of 30-45% and the aqueous polyurethane aqueous solution of 5-10% are heated to 60-80 DEG C by mass concentration, be cooled to 30-50 DEG C and add acrylate 10-15%, then add potassium hydroxide 0.1-0.2% and be warming up to 100-110 DEG C, then the plant phenols 2-4% adding sclerotin albumen 5-8%, rosin fat 6-9%, extract from natural phant; React and be cooled to 45-55 DEG C in 3-5 hour, then add Sodium Benzoate 0.06-0.08%, ditertiary butyl peroxide 0.01-0.02% and vinyl acetic monomer 0.1-0.3%, stir 1-1.5 hour, cooling, obtained described second elastic plastic.
3. a kind of modified binder according to claim 2, is characterized in that: the sequestrant in the described bamboo vinegar aqueous solution is at least one in ethylenediamine tetraacetic acid (EDTA) or disodium edta.
4. a kind of modified binder according to claim 3, is characterized in that: the described furfuryl alcohol extracted from natural phant is selected from the furfuryl alcohol extracted from the wheat bran or bamboo wood chip of the core slag of corn cob, oat or wheat.
5. a kind of modified binder according to claim 4, is characterized in that: described mixed solution is heated to 45-55 DEG C add crown ether and sodium-metaphosphate in described mixed solution before by described step (2).
6. a kind of modified binder according to claim 5, is characterized in that: described step (2) adds crown ether and sodium-metaphosphate post-heating to 70-85 DEG C in described mixed solution, Keep agitation 5-8min.
7. a kind of modified binder according to claim 6, it is characterized in that: described step (2) is carried out under microwave vacuum condition, specifically be evacuated to vacuum tightness for-0.02MPa ~-0.001MPa, carry out microwave treatment again, microwave frequency is 100MHz ~ 230MHz, and microwave treatment time is 3 ~ 7s.
8. a kind of modified binder according to claim 7, is characterized in that: described crown ether is bicyclohexane also-18-hat-6.
9. a kind of modified binder according to claim 8, is characterized in that: the described plant phenols extracted from natural phant is Eugenol or cardanol.
10. a kind of modified binder according to claim 9, is characterized in that: described catalyzer is sodium hydroxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410533460.0A CN104293248B (en) | 2014-10-11 | 2014-10-11 | A kind of modified binder |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410533460.0A CN104293248B (en) | 2014-10-11 | 2014-10-11 | A kind of modified binder |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104293248A true CN104293248A (en) | 2015-01-21 |
| CN104293248B CN104293248B (en) | 2016-03-30 |
Family
ID=52313212
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410533460.0A Expired - Fee Related CN104293248B (en) | 2014-10-11 | 2014-10-11 | A kind of modified binder |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104293248B (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105542686A (en) * | 2016-02-17 | 2016-05-04 | 广西大学 | Environment-friendly high-strength binder and preparing method thereof |
| CN107286529A (en) * | 2017-08-02 | 2017-10-24 | 合肥安力电力工程有限公司 | A kind of cable jacket material and preparation method thereof |
| CN111480531A (en) * | 2020-05-26 | 2020-08-04 | 湖南省蔬菜研究所 | Method for relieving continuous cropping obstacle of watermelons |
| CN113717540A (en) * | 2021-07-26 | 2021-11-30 | 安徽大禹防水科技发展有限公司 | Thermoplastic polyolefin waterproof coiled material and preparation method thereof |
| CN113771395A (en) * | 2021-09-13 | 2021-12-10 | 福建鸿星尔克体育用品有限公司 | Preparation method of damping sole formed by CPU injection method |
| CN113969093A (en) * | 2021-11-05 | 2022-01-25 | 西咸新区雅舒美生物科技有限公司 | Antifouling antibacterial coating with high stability and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090023086A1 (en) * | 2007-07-19 | 2009-01-22 | Samsung Electronics Co., Ltd | Recording medium for electrophotographic printer |
| KR20090046029A (en) * | 2007-11-05 | 2009-05-11 | 재단법인서울대학교산학협력재단 | Orthodontic adhesive |
| CN103820056A (en) * | 2014-03-21 | 2014-05-28 | 德华兔宝宝装饰新材股份有限公司 | Nano-silver-containing adhesive and using method of adhesive in technical wood |
| CN103832205A (en) * | 2014-03-21 | 2014-06-04 | 德华兔宝宝装饰新材股份有限公司 | Nano silver decoration laminated board |
| CN103862988A (en) * | 2014-03-21 | 2014-06-18 | 德华兔宝宝装饰新材股份有限公司 | Mildew-resistant and antibacterial nano-silver decorative laminated board |
-
2014
- 2014-10-11 CN CN201410533460.0A patent/CN104293248B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090023086A1 (en) * | 2007-07-19 | 2009-01-22 | Samsung Electronics Co., Ltd | Recording medium for electrophotographic printer |
| KR20090046029A (en) * | 2007-11-05 | 2009-05-11 | 재단법인서울대학교산학협력재단 | Orthodontic adhesive |
| CN103820056A (en) * | 2014-03-21 | 2014-05-28 | 德华兔宝宝装饰新材股份有限公司 | Nano-silver-containing adhesive and using method of adhesive in technical wood |
| CN103832205A (en) * | 2014-03-21 | 2014-06-04 | 德华兔宝宝装饰新材股份有限公司 | Nano silver decoration laminated board |
| CN103862988A (en) * | 2014-03-21 | 2014-06-18 | 德华兔宝宝装饰新材股份有限公司 | Mildew-resistant and antibacterial nano-silver decorative laminated board |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105542686A (en) * | 2016-02-17 | 2016-05-04 | 广西大学 | Environment-friendly high-strength binder and preparing method thereof |
| CN107286529A (en) * | 2017-08-02 | 2017-10-24 | 合肥安力电力工程有限公司 | A kind of cable jacket material and preparation method thereof |
| CN111480531A (en) * | 2020-05-26 | 2020-08-04 | 湖南省蔬菜研究所 | Method for relieving continuous cropping obstacle of watermelons |
| CN113717540A (en) * | 2021-07-26 | 2021-11-30 | 安徽大禹防水科技发展有限公司 | Thermoplastic polyolefin waterproof coiled material and preparation method thereof |
| CN113717540B (en) * | 2021-07-26 | 2022-08-05 | 安徽大禹防水科技发展有限公司 | Thermoplastic polyolefin waterproof coiled material and preparation method thereof |
| CN113771395A (en) * | 2021-09-13 | 2021-12-10 | 福建鸿星尔克体育用品有限公司 | Preparation method of damping sole formed by CPU injection method |
| CN113969093A (en) * | 2021-11-05 | 2022-01-25 | 西咸新区雅舒美生物科技有限公司 | Antifouling antibacterial coating with high stability and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104293248B (en) | 2016-03-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104293248B (en) | A kind of modified binder | |
| CN104231980B (en) | A kind of preparation method of environmental protection binding agent | |
| CN104294402B (en) | The preparation method with bamboo charcoal fibre face fabric spins in a kind of family | |
| CN104264279B (en) | A kind of bamboo charcoal fibre face fabric spun for family | |
| CN104289205A (en) | Preparation method of charcoal particle drying agent | |
| CN103980432B (en) | Containing polycarboxylate water-reducer and its preparation method of modified soluble acrylate | |
| CN103524669B (en) | Acrylic ester emulsion and preparation method thereof | |
| CN104264443B (en) | The production method with health care bamboo fibre fabric is spun by a kind of family | |
| CN104497454A (en) | Polytetrafluoroethylene film for filtering air | |
| CN104263290B (en) | A kind of environmental protection binding agent for bamboo fiber products | |
| CN105732903A (en) | Method for preparing environment-friendly interior wall and exterior wall styrene-acrylic emulsion | |
| CN108729230A (en) | A kind of preparation method of bamboo fibre grid cloth | |
| CN104371606A (en) | Binder containing bamboo charcoal powder | |
| CN104258697B (en) | A kind of bamboo charcoal drier for Suitcases & Leatherware | |
| CN109293836A (en) | A kind of preparation method for the polysaccharose substance modifiers dispersants that performance is controllable | |
| CN102876266B (en) | Preparation method of environment-friendly adhesive for lithium ion battery | |
| CN105542686A (en) | Environment-friendly high-strength binder and preparing method thereof | |
| CN103897098B (en) | A kind of polyster fibre slurry and preparation method thereof | |
| CN103951790A (en) | Vinyl acetate emulsion and preparation process thereof | |
| CN102732075B (en) | Wood putty and preparation method thereof | |
| CN104358002A (en) | Preparation method for bamboo fiber mesh fabric | |
| CN102127273A (en) | Polrvinyl chloride heat-resistance modifier and preparation method thereof | |
| CN1122052C (en) | Synthesis of high-hydroscopicity resin | |
| CN104262547A (en) | Method for low-temperature synthesis of polycarboxylate water reducer by using isoamyl alcohol polyether | |
| CN103361005A (en) | Anti-attenuation acrylate binder for waterproof roll tire fabric and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20230718 Address after: 313000 Wujiatang, Maji Village, Tianhuangping Town, Anji County, Huzhou, Zhejiang Province Patentee after: Anji Bamboo Impression Home Furnishings Co.,Ltd. Address before: 313000 Wujiatang Anji Dengguan Bamboo and Wood Development Co., Ltd., Maji Village, Tianhuangping Town, Anji County, Huzhou, Zhejiang Province Patentee before: ANJI DENGGUAN BAMBOO & WOOD DEVELOP CO.,LTD. |
|
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160330 |