CN107384053A - A kind of anti-soil water paint - Google Patents
A kind of anti-soil water paint Download PDFInfo
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- CN107384053A CN107384053A CN201710522366.9A CN201710522366A CN107384053A CN 107384053 A CN107384053 A CN 107384053A CN 201710522366 A CN201710522366 A CN 201710522366A CN 107384053 A CN107384053 A CN 107384053A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
- C09D5/028—Pigments; Filters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1668—Vinyl-type polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of anti-soil water paint, its raw material includes by weight：90 110 parts of film forming material, 48 parts of coalescents, 80 90 parts of inserts, 36 parts of glycerine, 5 10 parts of levelling agent, 48 parts of iron chloride, 48 parts, N of barium stearate, 12 parts of N dimethylethanolamines, 24 parts of silicone oil, 46 parts of lecithin, 60 90 parts of deionized water.Anti-soil water paint proposed by the present invention, mechanical property and heat-resisting, excellent anti-corrosion performance, antifouling property is outstanding, has heat-insulated, insulation effect, film is not easy to crack, and homogeneity is good, and weather resistance is good, and adhesive force is good, anti-zoned anti-wear performance is good, and cost is low, and pollution will not be brought to environment.
Description
Technical field
The present invention relates to technical field of aqueous paint, more particularly to a kind of anti-soil water paint.
Background technology
For water paint because it avoids using organic solvent, price is low, does not have volatile organic matter generation during use,
The characteristic such as will not damage to environment and people, obtain the favor of more and more researchers.However, its original of conventional water paint
Material dissolubility and poor dispersion, and contamination resistance to be present poor for coating material, the deficiencies of weatherability difference.
The content of the invention
Based on technical problem existing for background technology, the present invention proposes a kind of anti-soil water paint, mechanical property and resistance to
Heat, excellent anti-corrosion performance, antifouling property is outstanding, has heat-insulated, insulation effect, film is not easy to crack, and homogeneity is good, weatherability
Can be good, adhesive force is good, and anti-zoned anti-wear performance is good, and cost is low, and pollution will not be brought to environment.
A kind of anti-soil water paint proposed by the present invention, its raw material include by weight：Film forming material 90-110 parts, film forming
Auxiliary agent 4-8 parts, inserts 80-90 parts, glycerine 3-6 parts, levelling agent 5-10 parts, iron chloride 4-8 parts, barium stearate 4-8 parts, N, N-
Dimethylethanolamine 1-2 parts, silicone oil 2-4 parts, lecithin 4-6 parts, deionized water 60-90 parts.
Preferably, film forming material includes by weight：Fluorine carbon emulsion 60-80 parts, bisphenol f type epoxy resin 30-50 parts.
Preferably, inserts includes by weight：Medical stone compound 7-11 parts, sericite 10-20 parts, organobentonite
6-12 parts, charcoal mud acid 6-12 parts, zeolite powder 8-12 parts, powdered whiting 8-10 parts, titanium dioxide 4-8 parts, barium sulfate 6-14 parts.
Preferably, medical stone compound is prepared using following technique：By Butyl Phthalate, hydrochloric acid, absolute ethyl alcohol and stirring, add
VTES continues to stir, spray drying, adds medical stone, tourmaline, limonite, boccaro, water and mixes
Uniformly, calcine, crushing obtains medical stone compound.
Preferably, medical stone compound is prepared using following technique：By weight by 8-16 parts Butyl Phthalate, 40-60 parts
Concentration is 1.2-2.4mol/L hydrochloric acid, 70-90 part absolute ethyl alcohol and stirrings, adds 1-2 part VTESs and continues to stir
Mix, be spray-dried, add 6-12 parts medical stone, 4-8 parts tourmaline, 4-6 parts limonite, 4-8 parts boccaro, the mixing of 40-60 parts water
Stir, calcine, crushing obtains medical stone compound.
Preferably, medical stone compound is prepared using following technique：By weight by 8-16 parts Butyl Phthalate, 40-60 parts
Concentration is 1.2-2.4mol/L hydrochloric acid, 70-90 part absolute ethyl alcohol and stirring 4-8h, and whipping temp is 60-70 DEG C, adds 1-2 part second
Alkenyl triethoxysilane continues to stir 4-8h, spray drying, adds 6-12 parts medical stone, 4-8 parts tourmaline, 4-6 part wooden fishes
Stone, 4-8 parts boccaro, 40-60 part water are mixed evenly, and calcine 4-8h, and calcining heat is 900-1000 DEG C, and crushing obtains wheat meal
Stone compound.
The present invention is compounded using fluorine carbon emulsion, bisphenol f type epoxy resin and medical stone compound, addition appropriate 2,2,4- tri-
Methyl isophthalic acid, 3- pentanediol mono isobutyrates are acted synergistically, and make after film-forming of the present invention mechanical property and heat-resisting, corrosion-resistant
Excellent performance, antifouling property are outstanding；And there is very strong parent with other raw materials after fluorine carbon emulsion, bisphenol f type epoxy resin compounding
And power, film is not easy to crack, and its heat-resisting and decay resistance further enhances, with sericite, zeolite powder, charcoal mud acid, barium sulfate,
Powdered whiting, medical stone compound, titanium dioxide, organobentonite coordinate, and can play good heat-insulated, insulation effect, heat-resisting
Performance further enhances.
In medical stone compound, in ethanol solution, Butyl Phthalate hydrolyzes generation nanometer titanium dioxide under the cooperation of hydrochloric acid
Titanium colloidal sol, and the alkoxy and vinyl on VTES can be sent out with the hydroxyl on nano titanic oxide sol surface
Raw condensation reaction, it is high with the compatibility of medical stone, tourmaline, limonite, boccaro, not only the bacterium in adsorbable air, virus,
The harmful substances such as chlorine, stink, and the performance with stronger cold-hot, the cracked phenomenon of process capable of reducing using, effectively
Aging is prevented, while other raw material can be promoted to be uniformly dispersed, makes coating homogeneity good, high mechanical strength, good impact resistance is resistance to
Time performance is good, and adhesive force is good, and anti-zoned anti-wear performance is good, and cost is low, and pollution will not be brought to environment.
Embodiment
Below, technical scheme is described in detail by specific embodiment.
Embodiment 1
A kind of anti-soil water paint proposed by the present invention, its raw material include by weight：90 parts of film forming material, coalescents
8 parts, 80 parts of inserts, 6 parts of glycerine, 5 parts of levelling agent, 8 parts of iron chloride, 4 parts, N of barium stearate, 2 parts of N- dimethylethanolamines, silicon
2 parts of oil, 6 parts of lecithin, 60 parts of deionized water.
Embodiment 2
A kind of anti-soil water paint proposed by the present invention, its raw material include by weight：110 parts of film forming material, film forming helps
4 parts of agent, 90 parts of inserts, 3 parts of glycerine, 10 parts of levelling agent, 4 parts of iron chloride, 8 parts, N of barium stearate, N- dimethylethanolamines 1
Part, 4 parts of silicone oil, 4 parts of lecithin, 90 parts of deionized water.
Film forming material includes by weight：60 parts of fluorine carbon emulsion, 50 parts of bisphenol f type epoxy resin.Inserts is by weight
Including：7 parts of medical stone compound, 20 parts of sericite, 6 parts of organobentonite, 12 parts of charcoal mud acid, 8 parts of zeolite powder, powdered whiting
10 parts, 4 parts of titanium dioxide, 14 parts of barium sulfate.
Medical stone compound is prepared using following technique：By Butyl Phthalate, hydrochloric acid, absolute ethyl alcohol and stirring, vinyl is added
Triethoxysilane continues to stir, spray drying, adds medical stone, tourmaline, limonite, boccaro, water and is mixed evenly, forges
Burn, crushing obtains medical stone compound.
Embodiment 3
A kind of anti-soil water paint proposed by the present invention, its raw material include by weight：95 parts of film forming material, coalescents
7 parts, 85 parts of inserts, 5 parts of glycerine, 6 parts of levelling agent, 7 parts of iron chloride, 5 parts, N of barium stearate, 1.8 parts of N- dimethylethanolamines,
2.5 parts of silicone oil, 5.5 parts of lecithin, 70 parts of deionized water.
Film forming material includes by weight：70 parts of fluorine carbon emulsion, 35 parts of bisphenol f type epoxy resin.Inserts is by weight
Including：10 parts of medical stone compound, 12 parts of sericite, 10 parts of organobentonite, 8 parts of charcoal mud acid, 11 parts of zeolite powder, heavy carbonic acid
9 parts of calcium, 7 parts of titanium dioxide, 8 parts of barium sulfate.
Medical stone compound is prepared using following technique：It is 1.2mol/L by weight by 8 parts of Butyl Phthalates, 60 parts of concentration
Hydrochloric acid, 90 parts of absolute ethyl alcohol and stirring 4h, whipping temp are 70 DEG C, add 1 part of VTES and continue to stir 8h, spray
Mist is dried, and is added 6 parts of medical stones, 8 parts of tourmaline, 4 parts of limonites, 8 parts of boccaros, 40 parts of water and is mixed evenly, calcines 8h, forge
It is 900 DEG C to burn temperature, and crushing obtains medical stone compound.
Embodiment 4
A kind of anti-soil water paint proposed by the present invention, its raw material include by weight：105 parts of film forming material, film forming helps
5 parts of agent, 88 parts of inserts, 4 parts of glycerine, 8 parts of levelling agent, 5 parts of iron chloride, 7 parts, N of barium stearate, N- dimethylethanolamines 1.2
Part, 3.5 parts of silicone oil, 4.5 parts of lecithin, 80 parts of deionized water.
Film forming material includes by weight：80 parts of fluorine carbon emulsion, 30 parts of bisphenol f type epoxy resin.Inserts is by weight
Including：Medical stone compound 11 part, 10 parts of sericite, 12 parts of organobentonite, 6 parts of charcoal mud acid, 12 parts of zeolite powder, heavy carbonic acid
8 parts of calcium, 8 parts of titanium dioxide, 6 parts of barium sulfate.
Medical stone compound is prepared using following technique：It is 1.8mol/ by weight by 12 parts of Butyl Phthalates, 50 parts of concentration
L hydrochloric acid, 80 parts of absolute ethyl alcohol and stirrings, add 1.2 parts of VTESs and continue to stir, be spray-dried, add 8 portions of wheats
Meal stone, 6 parts of tourmaline, 5 parts of limonites, 6 parts of boccaros, 50 parts of water are mixed evenly, and calcining, it is compound that crushing obtains medical stone
Thing.
Embodiment 5
A kind of anti-soil water paint proposed by the present invention, its raw material include by weight：100 parts of film forming material, film forming helps
6 parts of agent, 86 parts of inserts, 4.5 parts of glycerine, 7 parts of levelling agent, 6 parts of iron chloride, 6 parts, N of barium stearate, N- dimethylethanolamines
1.5 parts, 3 parts of silicone oil, 5 parts of lecithin, 75 parts of deionized water.
Film forming material includes by weight：65 parts of fluorine carbon emulsion, 45 parts of bisphenol f type epoxy resin.Inserts is by weight
Including：8 parts of medical stone compound, 18 parts of sericite, 8 parts of organobentonite, 10 parts of charcoal mud acid, 10 parts of zeolite powder, heavy carbonic acid
9.5 parts of calcium, 5 parts of titanium dioxide, 12 parts of barium sulfate.
Medical stone compound is prepared using following technique：It is 2.4mol/ by weight by 16 parts of Butyl Phthalates, 40 parts of concentration
L hydrochloric acid, 70 parts of absolute ethyl alcohol and stirring 8h, whipping temp are 60 DEG C, add 2 parts of VTESs and continue to stir 4h,
Spray drying, add 12 parts of medical stones, 4 parts of tourmaline, 6 parts of limonites, 4 parts of boccaros, 60 parts of water and be mixed evenly, calcine
4h, calcining heat are 1000 DEG C, and crushing obtains medical stone compound.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.
Claims (6)
1. a kind of anti-soil water paint, it is characterised in that its raw material includes by weight：Film forming material 90-110 parts, film forming help
Agent 4-8 parts, inserts 80-90 parts, glycerine 3-6 parts, levelling agent 5-10 parts, iron chloride 4-8 parts, barium stearate 4-8 parts, N, N- bis-
Methylethanolamine 1-2 parts, silicone oil 2-4 parts, lecithin 4-6 parts, deionized water 60-90 parts.
2. anti-soil water paint according to claim 1, it is characterised in that film forming material includes by weight：Fluorine carbon emulsion
60-80 parts, bisphenol f type epoxy resin 30-50 parts.
3. anti-soil water paint according to claim 1, it is characterised in that inserts includes by weight：Medical stone is compound
Thing 7-11 parts, sericite 10-20 parts, organobentonite 6-12 parts, charcoal mud acid 6-12 parts, zeolite powder 8-12 parts, powdered whiting
8-10 parts, titanium dioxide 4-8 parts, barium sulfate 6-14 parts.
4. anti-soil water paint according to claim 3, it is characterised in that medical stone compound is prepared using following technique：
By Butyl Phthalate, hydrochloric acid, absolute ethyl alcohol and stirring, add VTES and continue to stir, be spray-dried, add wheat meal
Stone, tourmaline, limonite, boccaro, water are mixed evenly, and calcining, crushing obtains medical stone compound.
5. according to the anti-soil water paint of claim 3 or 4, it is characterised in that medical stone compound uses following technique system
It is standby：It is that 1.2-2.4mol/L hydrochloric acid, 70-90 part absolute ethyl alcohols stir by weight by 8-16 parts Butyl Phthalate, 40-60 parts concentration
Mix, add 1-2 part VTESs and continue to stir, be spray-dried, add 6-12 parts medical stones, 4-8 parts tourmaline,
4-6 parts limonite, 4-8 parts boccaro, 40-60 part water are mixed evenly, and calcining, crushing obtains medical stone compound.
6. according to any one of the claim 3-5 anti-soil water paints, it is characterised in that medical stone compound uses following work
It is prepared by skill：It is 1.2-2.4mol/L hydrochloric acid, 70-90 part absolute ethyl alcohols by weight by 8-16 parts Butyl Phthalate, 40-60 parts concentration
4-8h is stirred, whipping temp is 60-70 DEG C, adds 1-2 part VTESs and continues to stir 4-8h, is spray-dried,
Add 6-12 parts medical stone, 4-8 parts tourmaline, 4-6 parts limonite, 4-8 parts boccaro, 40-60 part water to be mixed evenly, calcine
4-8h, calcining heat are 900-1000 DEG C, and crushing obtains medical stone compound.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710522366.9A CN107384053A (en) | 2017-06-30 | 2017-06-30 | A kind of anti-soil water paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710522366.9A CN107384053A (en) | 2017-06-30 | 2017-06-30 | A kind of anti-soil water paint |
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| Publication Number | Publication Date |
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| CN107384053A true CN107384053A (en) | 2017-11-24 |
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| CN201710522366.9A Withdrawn CN107384053A (en) | 2017-06-30 | 2017-06-30 | A kind of anti-soil water paint |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101486867A (en) * | 2009-02-12 | 2009-07-22 | 张文磊 | Photo-catalytic coating |
| CN102031022A (en) * | 2010-10-27 | 2011-04-27 | 华南理工大学 | Method for modifying nano titanium dioxide sol by utilizing silane coupling agent |
| CN105176276A (en) * | 2015-08-31 | 2015-12-23 | 天长市银狐漆业有限公司 | Scrubbing-resistant and antifouling interior wall emulsion paint |
| CN105176232A (en) * | 2015-08-31 | 2015-12-23 | 天长市银狐漆业有限公司 | Weather-resistant and waterproof exterior wall emulsion paint |
| CN105602401A (en) * | 2016-01-08 | 2016-05-25 | 长沙民德消防工程涂料有限公司 | Water-based environment-friendly negative ion anticorrosive paint and preparation method thereof |
-
2017
- 2017-06-30 CN CN201710522366.9A patent/CN107384053A/en not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101486867A (en) * | 2009-02-12 | 2009-07-22 | 张文磊 | Photo-catalytic coating |
| CN102031022A (en) * | 2010-10-27 | 2011-04-27 | 华南理工大学 | Method for modifying nano titanium dioxide sol by utilizing silane coupling agent |
| CN105176276A (en) * | 2015-08-31 | 2015-12-23 | 天长市银狐漆业有限公司 | Scrubbing-resistant and antifouling interior wall emulsion paint |
| CN105176232A (en) * | 2015-08-31 | 2015-12-23 | 天长市银狐漆业有限公司 | Weather-resistant and waterproof exterior wall emulsion paint |
| CN105602401A (en) * | 2016-01-08 | 2016-05-25 | 长沙民德消防工程涂料有限公司 | Water-based environment-friendly negative ion anticorrosive paint and preparation method thereof |
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Application publication date: 20171124 |
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