CN107383964A - A kind of environmentally friendly anti-pollution type exterior wall latex paint - Google Patents
A kind of environmentally friendly anti-pollution type exterior wall latex paint Download PDFInfo
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- CN107383964A CN107383964A CN201710861056.XA CN201710861056A CN107383964A CN 107383964 A CN107383964 A CN 107383964A CN 201710861056 A CN201710861056 A CN 201710861056A CN 107383964 A CN107383964 A CN 107383964A
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- latex paint
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/022—Emulsions, e.g. oil in water
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1668—Vinyl-type polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Paints Or Removers (AREA)
Abstract
Environmentally friendly anti-pollution type exterior wall latex paint of the present invention, with organosilicon-modified acrylate emulsion primary raw material, good with compliance, high and low temperature resistance, surface energy is low, and water-fast and weather resistance is excellent；Using embedded nonionic emulsifier between ionic emulsifying agent, the distance of emulsion particle surface reaction emulsifying agent ionic bond can be widened, nonionic emulsifier electrostatic screen acts on, greatly reduce the electrostatic tension on emulsion particle surface, increase distribution of the reactive emulsifier on emulsion particle, so that emulsion paint stability is higher, surface tension is good；Oyster shell whiting can solve the problems, such as that shell spreads unchecked pollution of marine environment, it is also possible that the quality of emulsion paint is fine and smooth, enrich paint film, assign emulsion paint and be not easy precipitation and good brushability, porous also can help to adsorb the harmful substance such as formaldehyde in air and metal ion；Using deionized water as solvent, safety and environmental protection, volume is solid containing height, can increase film thickness, low VOC, adhesive force is strong, water resistance is excellent.
Description
Technical field
The present invention relates to a kind of exterior wall latex paint technical field, more particularly to a kind of environmentally friendly anti-pollution type exterior wall latex paint.
Background technology
Exterior wall latex paint is a kind of coating using macromolecule emulsion as film forming matter, and face is added by raw material of synthetic resin emulsion
A kind of water paint that material, filler and the configuration of various auxiliary agents form.Exterior wall latex paint major function is decoration and protection building
Face, make building appearance neat and artistic, so as to reach the purpose of beautifying urban environment, while protection skin can be played
Effect, extends its service life.
After emulsion paint construction terminates rear thing volatilization to be evaporated, the paint film for staying in building surface is only protection wall
Active ingredient, it is generally solid containing measurement with volume；Volume mostly be present and consolidate, attachment low containing weighing in exterior wall latex paint in the market
Indifferent, water-fast weatherability is poor, is chronically exposed in air easily and the problems such as peeling, cracking, discoloration, shedding occurs；Simultaneously
Also environment is polluted containing compositions such as formaldehyde or benzene solvents.
The content of the invention
To solve above-mentioned problem, it is an object of the invention to provide a kind of environmentally friendly anti-pollution type exterior wall latex paint and its
Preparation method.
To reach above-mentioned purpose, the technical scheme is that：
A kind of environmentally friendly anti-pollution type exterior wall latex paint, include the raw material components of following parts by weight：Organosilicon-modified acrylate
Emulsion 25-35 parts, fluorine-containing Si acrylate 3-5 parts, titanium dioxide 8-12 parts, shell Ultramicro-powder 15-25 parts, cellulose acetate 3-5
Part, compound emulsifying agent 0.5-0.8 parts, ceramic 2-4 parts, powdered whiting 6-10 parts, antiseptic 1-3 parts, mould inhibitor 3-5
Part, defoamer 1-2 parts, antifreezing agent 1-2 parts, deionized water 60-80 parts.
Preferably, described organosilicon-modified acrylate emulsion preparation method be by ammonium persulfate be added to equipped with go from
In the initiator groove of sub- water, the initiator lysate that concentration is 2-3% is uniformly mixing to obtain；By methyl acrylate, acrylic acid second
Ester, GMA, octamethylcy-clotetrasiloxane (D4) are well mixed in groove is premixed and obtain polymerized monomer and mix
Close phase；Sodium dodecyl allyl base sodium succinate and deionized water are added in four-hole boiling flask, are heated to 60-80 DEG C, slowly drop
Add well mixed polymerized monomer mixed phase and 80% initiator lysate, time 1-2h, temperature maintains in course of reaction
60-80 DEG C, rotating speed maintains 200-300r/min；Insulation 1-2h is dripped, temperature is 60-80 DEG C, then is added dropwise remaining 20%
Initiator lysate, when system is cooled to 40 DEG C, adds sodium acid carbonate and adjust pH value and produce to 6-8；Described each component
The parts by weight of raw material are：Methyl acrylate 10-20 parts, ethyl acrylate 10-20 parts, GMA 1-2
Part, octamethylcy-clotetrasiloxane (D4) 5-10 parts, sodium dodecyl allyl base sodium succinate 4-8 parts, ammonium persulfate 0.1-1.0 parts,
Deionized water 60-80 parts.
Preferably, described titanium dioxide is rutile type titanium white.
Preferably, described shell superfine preparation method is to burn shell in 600-800 DEG C under atmosphere of inert gases
Ultramicro grinding to 325 mesh form after knot 1h.
Preferably, described compound emulsifying agent is nonionic fluorocarbon surfactant and dodecyl alcohol according to weight ratio
1-3:1 is combined.
Preferably, described ceramic is aluminium oxide ceramics micro mist, one kind in titanium dioxide ceramic micro mist or two
The arbitrary proportion mixture of kind.
Preferably, described antiseptic is inorganic antiseptic, including the mixing of one or both of silver orthophosphate, wolframic acid silver
Thing, and when being mixture, mixed weight ratio is 1:1.
Preferably, described mould inhibitor is mould inhibitor M-8.
Preferably, described defoamer is water-soluble silicon oils defoamer.
Preferably, described antifreezing agent is propane diols.
The beneficial effects of the present invention are：
A kind of environmentally friendly anti-pollution type exterior wall latex paint provided by the invention, it is mainly former with organosilicon-modified acrylate emulsion
Material, compliance, high and low temperature resistance with height are good, and surface energy is low, and water resistance and weather resistance are excellent；Compound emulsifying agent is adopted
With embedded nonionic emulsifier between ionic emulsifying agent, can widen emulsion particle surface reaction emulsifying agent ionic bond away from
From nonionic emulsifier electrostatic screen acts on, and greatly reduces the electrostatic tension on emulsion particle surface, increases reactive emulsifier
Distribution on emulsion particle so that emulsion paint stability is higher, and surface tension is good；The utilization of oyster shell whiting, can not only solve shell
Pollution of marine environment problem is spread unchecked, it is also possible that the quality of emulsion paint is fine and smooth, enriches paint film, emulsion paint is assigned and is not easy precipitation and good
Good brushability, porous also can help to adsorb the harmful substance such as formaldehyde in air and metal ion；The emulsion paint of the present invention uses
For deionized water as solvent, volume is solid containing height, can increase film thickness, low VOC, safety and environmental protection, adhesive force is strong, water resistance is excellent.
Embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, it is further detailed with reference to embodiments
Describe in detail bright.
Table 1 is the environmentally friendly anti-pollution type exterior wall latex paint constituent table described in the embodiment of the present invention；Table 2 is of the invention real
Apply the performance test of the environmentally friendly anti-pollution type exterior wall latex paint of example；Table 3 is organosilicon-modified acrylate emulsion of the present invention
Each component component list.
Latex paint ingredients (unit described in the embodiment of table 1.：Part)
The performance test results of table 2.
| Test event | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Drying time/h | 1.5 | 1.2 | 1.0 |
| Water resistance | 120h is without exception | 120h is without exception | 120h is without exception |
| Alkali resistance 48h | It is without exception | It is without exception | It is without exception |
| Abrasion resistance/time | ≥2000 | ≥2000 | ≥2000 |
| Low-temperature stability | Never degenerate | Never degenerate | Never degenerate |
Organosilicon-modified acrylate emulsion composition (the unit of table 3.：Part)
| Embodiment 1 | Embodiment 2 | Embodiment 3 | |
| Methyl acrylate | 10 | 20 | 15 |
| Ethyl acrylate | 1 | 20 | 15 |
| GMA | 1 | 2 | 1.5 |
| Octamethylcy-clotetrasiloxane (D4) | 5 | 10 | 8 |
| Sodium dodecyl allyl base sodium succinate | 4 | 8 | 6 |
| Ammonium persulfate | 0.1 | 1 | 0.5 |
| Deionized water | 60 | 80 | 70 |
Embodiment 1
Described organosilicon-modified acrylate emulsion preparation method is that ammonium persulfate is added to equipped with deionized water
In initiator groove, the initiator lysate that concentration is 2% is uniformly mixing to obtain；By methyl acrylate, ethyl acrylate, methyl-prop
Olefin(e) acid ethylene oxidic ester, octamethylcy-clotetrasiloxane (D4) are well mixed in groove is premixed and obtain polymerized monomer mixed phase；By ten
Dialkyl group allyl succinic acid sodium and deionized water are added in four-hole boiling flask, are heated to 60 DEG C, are slowly added dropwise well mixed
Polymerized monomer mixed phase and 80% initiator lysate, time 1h, temperature maintains 60 DEG C in course of reaction, and rotating speed maintains
200r/min；Insulation 1h is dripped, temperature is 60 DEG C, then remaining 20% initiator lysate is added dropwise, and the system for the treatment of is cooled to
At 40 DEG C, addition sodium acid carbonate regulation pH value to 6 produces.
Described titanium dioxide is rutile type titanium white.
Described shell superfine preparation method be by shell under atmosphere of inert gases in 600 DEG C sinter 1h after Ultramicro-powder
325 mesh are broken to form.
Described compound emulsifying agent is nonionic fluorocarbon surfactant and dodecyl alcohol according to weight ratio 1:1 is compound
Form.
Described ceramic is aluminium oxide ceramics micro mist, one or two kinds of any in titanium dioxide ceramic micro mist
Scalemic thereof.
Described antiseptic is inorganic antiseptic, including one or both of silver orthophosphate, wolframic acid silver mixture, and is mixed
During compound, mixed weight ratio is 1:1.
Described mould inhibitor is mould inhibitor M-8.
Described defoamer is water-soluble silicon oils defoamer.
Described antifreezing agent is propane diols.
Embodiment 2
Described organosilicon-modified acrylate emulsion preparation method is that ammonium persulfate is added to equipped with deionized water
In initiator groove, the initiator lysate that concentration is 3% is uniformly mixing to obtain；By methyl acrylate, ethyl acrylate, methyl-prop
Olefin(e) acid ethylene oxidic ester, octamethylcy-clotetrasiloxane (D4) are well mixed in groove is premixed and obtain polymerized monomer mixed phase；By ten
Dialkyl group allyl succinic acid sodium and deionized water are added in four-hole boiling flask, are heated to 80 DEG C, are slowly added dropwise well mixed
Polymerized monomer mixed phase and 80% initiator lysate, time 2h, temperature maintains 80 DEG C in course of reaction, and rotating speed maintains
300r/min；Insulation 2h is dripped, temperature is 80 DEG C, then remaining 20% initiator lysate is added dropwise, and the system for the treatment of is cooled to
At 40 DEG C, addition sodium acid carbonate regulation pH value to 8 produces.
Described titanium dioxide is rutile type titanium white.
Described shell superfine preparation method be by shell under atmosphere of inert gases in 800 DEG C sinter 1h after Ultramicro-powder
325 mesh are broken to form.
Described compound emulsifying agent is nonionic fluorocarbon surfactant and dodecyl alcohol according to weight ratio 3:1 is compound
Form.
Described ceramic is aluminium oxide ceramics micro mist, one or two kinds of any in titanium dioxide ceramic micro mist
Scalemic thereof.
Described antiseptic is inorganic antiseptic, including one or both of silver orthophosphate, wolframic acid silver mixture, and is mixed
During compound, mixed weight ratio is 1:1.
Described mould inhibitor is mould inhibitor M-8.
Described defoamer is water-soluble silicon oils defoamer.
Described antifreezing agent is propane diols.
Embodiment 3
Described organosilicon-modified acrylate emulsion preparation method is that ammonium persulfate is added to equipped with deionized water
In initiator groove, the initiator lysate that concentration is 2.5% is uniformly mixing to obtain；By methyl acrylate, ethyl acrylate, methyl
Glycidyl acrylate, octamethylcy-clotetrasiloxane (D4) are well mixed in groove is premixed and obtain polymerized monomer mixed phase；Will
Sodium dodecyl allyl base sodium succinate and deionized water are added in four-hole boiling flask, are heated to 70 DEG C, are slowly added dropwise well mixed
Polymerized monomer mixed phase and 80% initiator lysate, time 1.5h, temperature maintains 70 DEG C in course of reaction, rotating speed dimension
Hold in 250r/min；Insulation 1.5h is dripped, temperature is 70 DEG C, then remaining 20% initiator lysate is added dropwise, and treats system
When being cooled to 40 DEG C, addition sodium acid carbonate regulation pH value to 6-8 produces.
Described titanium dioxide is rutile type titanium white.
Described shell superfine preparation method be by shell under atmosphere of inert gases in 700 DEG C sinter 1h after Ultramicro-powder
325 mesh are broken to form.
Described compound emulsifying agent is nonionic fluorocarbon surfactant and dodecyl alcohol according to weight ratio 2:1 is compound
Form.
Described ceramic is aluminium oxide ceramics micro mist, one or two kinds of any in titanium dioxide ceramic micro mist
Scalemic thereof.
Described antiseptic is inorganic antiseptic, including one or both of silver orthophosphate, wolframic acid silver mixture, and is mixed
During compound, mixed weight ratio is 1:1.
Described mould inhibitor is mould inhibitor M-8.
Described defoamer is water-soluble silicon oils defoamer.
Described antifreezing agent is propane diols.
It should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted.Although with reference to compared with
The present invention is described in detail good embodiment, it will be understood by those within the art that, can be to the technology of invention
Scheme is modified or equivalent substitution, and without departing from the scope of technical solution of the present invention, it all should cover the power in the present invention
In sharp claimed range.
Claims (10)
1. a kind of environmentally friendly anti-pollution type exterior wall latex paint, it is characterised in that include the raw material components of following parts by weight：It is organic-silicon-modified
Acrylic acid ester emulsion 25-35 parts, fluorine-containing Si acrylate 3-5 parts, titanium dioxide 8-12 parts, shell Ultramicro-powder 15-25 parts, acetic acid are fine
Tie up plain 3-5 parts, compound emulsifying agent 0.5-0.8 parts, ceramic 2-4 parts, powdered whiting 6-10 parts, antiseptic 1-3 parts, mould proof
Agent 3-5 parts, defoamer 1-2 parts, antifreezing agent 1-2 parts, deionized water 60-80 parts.
2. a kind of environmentally friendly anti-pollution type exterior wall latex paint according to claim 1, it is characterised in that described is organic-silicon-modified
Acrylic acid ester emulsion preparation method is uniformly mixing to obtain dense for ammonium persulfate is added in the initiator groove equipped with deionized water
Spend the initiator lysate for 2-3%；By methyl acrylate, ethyl acrylate, GMA, prestox ring
Tetrasiloxane（D4）It is well mixed in groove is premixed and obtains polymerized monomer mixed phase；By sodium dodecyl allyl base sodium succinate and go
Ionized water is added in four-hole boiling flask, is heated to 60-80 DEG C, and well mixed polymerized monomer mixed phase and 80% is slowly added dropwise
Initiator lysate, time 1-2h, temperature maintains 60-80 DEG C in course of reaction, and rotating speed maintains 200-300r/min；It is added dropwise
Complete insulation 1-2h, temperature is 60-80 DEG C, then remaining 20% initiator lysate is added dropwise, and when system is cooled to 40 DEG C, is added
Enter sodium acid carbonate and adjust pH value and produce to 6-8；The parts by weight of described each component raw material are：Methyl acrylate 10-20 parts, third
Olefin(e) acid ethyl ester 10-20 parts, GMA 1-2 parts, octamethylcy-clotetrasiloxane（D4）5-10 parts, dodecyl
Allyl succinic acid sodium 4-8 parts, ammonium persulfate 0.1-1.0 parts, deionized water 60-80 parts.
3. a kind of environmentally friendly anti-pollution type exterior wall latex paint according to claim 1, it is characterised in that described titanium dioxide is gold
Red stone-type titanium dioxide.
A kind of 4. environmentally friendly anti-pollution type exterior wall latex paint according to claim 1, it is characterised in that described shell Ultramicro-powder
Preparation method is that ultramicro grinding to 325 mesh form after shell is sintered into 1h in 600-800 DEG C under atmosphere of inert gases.
A kind of 5. environmentally friendly anti-pollution type exterior wall latex paint according to claim 1, it is characterised in that described compound emulsifying agent
Compare 1-3 according to weight for nonionic fluorocarbon surfactant and dodecyl alcohol:1 is combined.
6. a kind of environmentally friendly anti-pollution type exterior wall latex paint according to claim 1, it is characterised in that described ceramic is
One or two kinds of arbitrary proportion mixture in aluminium oxide ceramics micro mist, titanium dioxide ceramic micro mist.
7. a kind of environmentally friendly anti-pollution type exterior wall latex paint according to claim 1, it is characterised in that described antiseptic is nothing
Machine antiseptic, including one or both of silver orthophosphate, wolframic acid silver mixture, and when being mixture, mixed weight ratio is 1:1.
8. a kind of environmentally friendly anti-pollution type exterior wall latex paint according to claim 1, it is characterised in that described mould inhibitor is anti-
Mould dose of M-8.
9. a kind of environmentally friendly anti-pollution type exterior wall latex paint according to claim 1, it is characterised in that described defoamer is water
Dissolubility silicone oil defoamer.
10. a kind of environmentally friendly anti-pollution type exterior wall latex paint according to claim 1, it is characterised in that described antifreezing agent is
Propane diols.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710861056.XA CN107383964A (en) | 2017-09-21 | 2017-09-21 | A kind of environmentally friendly anti-pollution type exterior wall latex paint |
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| CN201710861056.XA CN107383964A (en) | 2017-09-21 | 2017-09-21 | A kind of environmentally friendly anti-pollution type exterior wall latex paint |
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| CN101338099A (en) * | 2007-07-02 | 2009-01-07 | 深圳市海川实业股份有限公司 | Exterior wall latex paint and preparation method thereof |
| CN101597453A (en) * | 2009-07-01 | 2009-12-09 | 广州飞宇建材科技有限公司 | Emulsion paint of a kind of high dirt resistance and preparation method thereof and application |
| CN105199040A (en) * | 2014-06-30 | 2015-12-30 | 五邑大学 | Organic silicone modified acrylate emulsion and preparation method thereof |
| CN105440851A (en) * | 2015-12-16 | 2016-03-30 | 三棵树涂料股份有限公司 | High-efficiency anti-sticking transparent outer wall water-based finishing varnish and preparation method thereof |
| CN105462410A (en) * | 2015-12-15 | 2016-04-06 | 沪宝新材料科技（上海）股份有限公司 | High dirt resistance exterior wall latex paint capable of degrading haze and production process thereof |
| CN106752471A (en) * | 2016-11-29 | 2017-05-31 | 青岛海之星生物科技有限公司 | A kind of exterior wall environment friendly emulsion paint and preparation method thereof |
-
2017
- 2017-09-21 CN CN201710861056.XA patent/CN107383964A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101338099A (en) * | 2007-07-02 | 2009-01-07 | 深圳市海川实业股份有限公司 | Exterior wall latex paint and preparation method thereof |
| CN101597453A (en) * | 2009-07-01 | 2009-12-09 | 广州飞宇建材科技有限公司 | Emulsion paint of a kind of high dirt resistance and preparation method thereof and application |
| CN105199040A (en) * | 2014-06-30 | 2015-12-30 | 五邑大学 | Organic silicone modified acrylate emulsion and preparation method thereof |
| CN105462410A (en) * | 2015-12-15 | 2016-04-06 | 沪宝新材料科技（上海）股份有限公司 | High dirt resistance exterior wall latex paint capable of degrading haze and production process thereof |
| CN105440851A (en) * | 2015-12-16 | 2016-03-30 | 三棵树涂料股份有限公司 | High-efficiency anti-sticking transparent outer wall water-based finishing varnish and preparation method thereof |
| CN106752471A (en) * | 2016-11-29 | 2017-05-31 | 青岛海之星生物科技有限公司 | A kind of exterior wall environment friendly emulsion paint and preparation method thereof |
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Application publication date: 20171124 |
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