CN107383695A - A kind of compound package material and preparation method thereof - Google Patents
A kind of compound package material and preparation method thereof Download PDFInfo
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- CN107383695A CN107383695A CN201710725756.6A CN201710725756A CN107383695A CN 107383695 A CN107383695 A CN 107383695A CN 201710725756 A CN201710725756 A CN 201710725756A CN 107383695 A CN107383695 A CN 107383695A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of compound package material and preparation method thereof, the compound package material is prepared from the following raw materials in parts by weight：60 85 parts of Corvic, 15 25 parts of nickel-coated carbon fibers, 25 parts of barium stearate, 36 parts of aziridine crosslinker, 38 parts of phenyl silane, 15 parts of lead oxide, 38 parts of zinc oxide, 15 parts of lubricant, 8 16 parts of polyvinyl alcohol, 15 25 parts of Fypro, 3 10 parts of polyisobutene, 7 13 parts of polyphenylene sulfide, 10 16 parts of acrylic acid, 5 12 parts of mica powder, 8 13 parts of polypentenol, 12 20 parts of octyl group succinic acid starch ester, 27 parts of melamine sodium phosphate, 16 parts of anti-wear agent, 6 15 parts of tetramethoxy-silicane, 5 12 parts of triallylamine.Compared with prior art, the compound package material in the present invention has the advantages that intensity is high, wearability is strong, so as to preferably meet industrial demand.
Description
Technical field
The invention belongs to field of packaging material, more particularly to a kind of compound package material and preparation method thereof.
Background technology
Packaging material is widely used in the fields such as packing container, packing and decorating, packages printing, packed and transported, and it is for work
Industry production, people's daily life play an important roll.With the industrialized continuous development in China, the species of industrial products and production
The raising year by year of amount, the Year's consumption of packaging material is also increasing, thus, Chinese society to the demand of packaging material drastically
Rise.However, although existing packaging material species is various, its anti-wear performance and intensity are difficult to obtain larger dash forward
It is broken, and be difficult to meet industrial demand.
The content of the invention
It is an object of the invention to provide a kind of compound package material and preparation method thereof, the compound package material has intensity
High, the advantages that wearability is strong.
To achieve the above object, the present invention provides following technical scheme：
A kind of compound package material is prepared from the following raw materials in parts by weight：Corvic 60-85 parts, nickel-plated carbon are fine
Tie up 15-25 parts, barium stearate 2-5 parts, aziridine crosslinker 3-6 parts, phenyl silane 3-8 parts, lead oxide 1-5 parts, zinc oxide 3-8
Part, lubricant 1-5 parts, polyvinyl alcohol 8-16 parts, Fypro 15-25 parts, polyisobutene 3-10 parts, polyphenylene sulfide 7-13
Part, acrylic acid 10-16 parts, mica powder 5-12 parts, polypentenol 8-13 parts, octyl group succinic acid starch ester 12-20 parts, melamine
Sodium phosphate 2-7 parts, anti-wear agent 1-6 parts, tetramethoxy-silicane 6-15 parts, triallylamine 5-12 parts.
Preferably, described compound package material is prepared from the following raw materials in parts by weight：80 parts of Corvic, plating
22 parts of nickel carbon fiber, 3 parts of barium stearate, 4 parts of aziridine crosslinker, 6 parts of phenyl silane, 3 parts of lead oxide, 4 parts of zinc oxide, lubrication
2 parts of agent, 11 parts of polyvinyl alcohol, 18 parts of Fypro, 7 parts of polyisobutene, 10 parts of polyphenylene sulfide, 13 parts of acrylic acid, mica powder 9
Part, 10 parts of polypentenol, 16 parts of octyl group succinic acid starch ester, 4 parts of melamine sodium phosphate, 3 parts of anti-wear agent, tetramethoxy-silicane
8 parts, 11 parts of triallylamine.
Preferably, described compound package material is prepared from the following raw materials in parts by weight：72 parts of Corvic, plating
22 parts of nickel carbon fiber, 5 parts of barium stearate, 4 parts of aziridine crosslinker, 5 parts of phenyl silane, 2 parts of lead oxide, 6 parts of zinc oxide, lubrication
3 parts of agent, 9 parts of polyvinyl alcohol, 20 parts of Fypro, 6 parts of polyisobutene, 8 parts of polyphenylene sulfide, 13 parts of acrylic acid, mica powder 6
Part, 9 parts of polypentenol, 16 parts of octyl group succinic acid starch ester, 5 parts of melamine sodium phosphate, 2 parts of anti-wear agent, tetramethoxy-silicane 7
Part, 10 parts of triallylamine.
Preferably, described compound package material is prepared from the following raw materials in parts by weight：80 parts of Corvic, plating
20 parts of nickel carbon fiber, 5 parts of barium stearate, 5 parts of aziridine crosslinker, 4 parts of phenyl silane, 3 parts of lead oxide, 6 parts of zinc oxide, lubrication
3 parts of agent, 11 parts of polyvinyl alcohol, 22 parts of Fypro, 7 parts of polyisobutene, 8 parts of polyphenylene sulfide, 15 parts of acrylic acid, mica powder 9
Part, 9 parts of polypentenol, 18 parts of octyl group succinic acid starch ester, 3 parts of melamine sodium phosphate, 4 parts of anti-wear agent, tetramethoxy-silicane
10 parts, 9 parts of triallylamine.
The preparation method of described compound package material, it comprises the following steps：
(1) each raw material components are weighed according to ratio of weight and number；
(2) each raw material components in step (1) are added in rotor mixer and stirred, mixing speed is 300-315 revs/min
Clock, mixing time 12-16 minutes；
(3) temperature of rotor mixer is adjusted to 172-178 DEG C, mixing speed is 245-255 revs/min, lasting stirring
16-22 minutes, obtain raw mixture；
(4) raw mixture in step (3) is extruded；
(5) through extruding the cooling of obtained raw mixture, drying, plastotype will be then drawn high, as compound bag in step (4)
Package material finished product.
Compared with prior art, the beneficial effects of the invention are as follows：
Compound package material in the present invention has been especially added with nickel-coated carbon fibers, barium stearate, aziridine crosslinker, oxidation
The raw materials such as lead, Fypro, polyphenylene sulfide, mica powder, anti-wear agent, and by the rational proportion with other raw materials, so that
It has the advantages that intensity is high, wearability is strong and service life is long, preferably meets industrial demand.
Embodiment
Technical scheme is described in detail with reference to embodiment, but protection domain is not limited thereto.
Embodiment one：
A kind of compound package material is prepared from the following raw materials in parts by weight：83 parts of Corvic, nickel-coated carbon fibers
23 parts, 4 parts of barium stearate, 4 parts of aziridine crosslinker, 6 parts of phenyl silane, 2 parts of lead oxide, 6 parts of zinc oxide, 3 parts of lubricant, gather
14 parts of vinyl alcohol, 24 parts of Fypro, 8 parts of polyisobutene, 11 parts of polyphenylene sulfide, 15 parts of acrylic acid, 10 parts of mica powder, poly- penta
10 parts of enol, 16 parts of octyl group succinic acid starch ester, 6 parts of melamine sodium phosphate, 5 parts of anti-wear agent, 13 parts of tetramethoxy-silicane, three
8 parts of allyl amine.
The preparation method of described compound package material, it comprises the following steps：
(1) each raw material components are weighed according to ratio of weight and number；
(2) each raw material components in step (1) are added in rotor mixer and stirred, mixing speed is 300-315 revs/min
Clock, mixing time 12-16 minutes；
(3) temperature of rotor mixer is adjusted to 172-178 DEG C, mixing speed is 245-255 revs/min, lasting stirring
16-22 minutes, obtain raw mixture；
(4) raw mixture in step (3) is extruded；
(5) through extruding the cooling of obtained raw mixture, drying, plastotype will be then drawn high, as compound bag in step (4)
Package material finished product.
Embodiment two：
A kind of compound package material is prepared from the following raw materials in parts by weight：80 parts of Corvic, nickel-coated carbon fibers
22 parts, 3 parts of barium stearate, 4 parts of aziridine crosslinker, 6 parts of phenyl silane, 3 parts of lead oxide, 4 parts of zinc oxide, 2 parts of lubricant, gather
11 parts of vinyl alcohol, 18 parts of Fypro, 7 parts of polyisobutene, 10 parts of polyphenylene sulfide, 13 parts of acrylic acid, 9 parts of mica powder, poly- penta
10 parts of enol, 16 parts of octyl group succinic acid starch ester, 4 parts of melamine sodium phosphate, 3 parts of anti-wear agent, 8 parts of tetramethoxy-silicane, three
11 parts of allyl amine.
The preparation method of described compound package material, it comprises the following steps：
(1) each raw material components are weighed according to ratio of weight and number；
(2) each raw material components in step (1) are added in rotor mixer and stirred, mixing speed is 300-315 revs/min
Clock, mixing time 12-16 minutes；
(3) temperature of rotor mixer is adjusted to 172-178 DEG C, mixing speed is 245-255 revs/min, lasting stirring
16-22 minutes, obtain raw mixture；
(4) raw mixture in step (3) is extruded；
(5) through extruding the cooling of obtained raw mixture, drying, plastotype will be then drawn high, as compound bag in step (4)
Package material finished product.
Embodiment three：
A kind of compound package material is prepared from the following raw materials in parts by weight：72 parts of Corvic, nickel-coated carbon fibers
22 parts, 5 parts of barium stearate, 4 parts of aziridine crosslinker, 5 parts of phenyl silane, 2 parts of lead oxide, 6 parts of zinc oxide, 3 parts of lubricant, gather
9 parts of vinyl alcohol, 20 parts of Fypro, 6 parts of polyisobutene, 8 parts of polyphenylene sulfide, 13 parts of acrylic acid, 6 parts of mica powder, polypenthylene
9 parts of alcohol, 16 parts of octyl group succinic acid starch ester, 5 parts of melamine sodium phosphate, 2 parts of anti-wear agent, 7 parts of tetramethoxy-silicane, three allyls
10 parts of base amine.
The preparation method of described compound package material, it comprises the following steps：
(1) each raw material components are weighed according to ratio of weight and number；
(2) each raw material components in step (1) are added in rotor mixer and stirred, mixing speed is 300-315 revs/min
Clock, mixing time 12-16 minutes；
(3) temperature of rotor mixer is adjusted to 172-178 DEG C, mixing speed is 245-255 revs/min, lasting stirring
16-22 minutes, obtain raw mixture；
(4) raw mixture in step (3) is extruded；
(5) through extruding the cooling of obtained raw mixture, drying, plastotype will be then drawn high, as compound bag in step (4)
Package material into.
Example IV：
A kind of compound package material is prepared from the following raw materials in parts by weight：80 parts of Corvic, nickel-coated carbon fibers
20 parts, 5 parts of barium stearate, 5 parts of aziridine crosslinker, 4 parts of phenyl silane, 3 parts of lead oxide, 6 parts of zinc oxide, 3 parts of lubricant, gather
11 parts of vinyl alcohol, 22 parts of Fypro, 7 parts of polyisobutene, 8 parts of polyphenylene sulfide, 15 parts of acrylic acid, 9 parts of mica powder, polypenthylene
9 parts of alcohol, 18 parts of octyl group succinic acid starch ester, 3 parts of melamine sodium phosphate, 4 parts of anti-wear agent, 10 parts of tetramethoxy-silicane, triolefin
9 parts of propyl group amine.
The preparation method of described compound package material, it comprises the following steps：
(1) each raw material components are weighed according to ratio of weight and number；
(2) each raw material components in step (1) are added in rotor mixer and stirred, mixing speed is 300-315 revs/min
Clock, mixing time 12-16 minutes；
(3) temperature of rotor mixer is adjusted to 172-178 DEG C, mixing speed is 245-255 revs/min, lasting stirring
16-22 minutes, obtain raw mixture；
(4) raw mixture in step (3) is extruded；
(5) through extruding the cooling of obtained raw mixture, drying, plastotype will be then drawn high, as compound bag in step (4)
Package material finished product.
Embodiment five：
A kind of compound package material is prepared from the following raw materials in parts by weight：60 parts of Corvic, nickel-coated carbon fibers
15 parts, 2 parts of barium stearate, 3 parts of aziridine crosslinker, 3 parts of phenyl silane, 1 part of lead oxide, 3 parts of zinc oxide, 1 part of lubricant, gather
8 parts of vinyl alcohol, 15 parts of Fypro, 3 parts of polyisobutene, 7 parts of polyphenylene sulfide, 10 parts of acrylic acid, 5 parts of mica powder, polypenthylene
8 parts of alcohol, 12 parts of octyl group succinic acid starch ester, 2 parts of melamine sodium phosphate, 1 part of anti-wear agent, 6 parts of tetramethoxy-silicane, three allyls
5 parts of base amine.
The preparation method of described compound package material, it comprises the following steps：
(1) each raw material components are weighed according to ratio of weight and number；
(2) each raw material components in step (1) are added in rotor mixer and stirred, mixing speed is 300-315 revs/min
Clock, mixing time 12-16 minutes；
(3) temperature of rotor mixer is adjusted to 172-178 DEG C, mixing speed is 245-255 revs/min, lasting stirring
16-22 minutes, obtain raw mixture；
(4) raw mixture in step (3) is extruded；
(5) through extruding the cooling of obtained raw mixture, drying, plastotype will be then drawn high, as compound bag in step (4)
Package material finished product.
Embodiment six：
A kind of compound package material is prepared from the following raw materials in parts by weight：85 parts of Corvic, nickel-coated carbon fibers
25 parts, 5 parts of barium stearate, 6 parts of aziridine crosslinker, 8 parts of phenyl silane, 5 parts of lead oxide, 8 parts of zinc oxide, 5 parts of lubricant, gather
16 parts of vinyl alcohol, 25 parts of Fypro, 10 parts of polyisobutene, 13 parts of polyphenylene sulfide, 16 parts of acrylic acid, 12 parts of mica powder, gather
13 parts of pentenol, 20 parts of octyl group succinic acid starch ester, 7 parts of melamine sodium phosphate, 6 parts of anti-wear agent, 15 parts of tetramethoxy-silicane,
12 parts of triallylamine.
The preparation method of described compound package material, it comprises the following steps：
(1) each raw material components are weighed according to ratio of weight and number；
(2) each raw material components in step (1) are added in rotor mixer and stirred, mixing speed is 300-315 revs/min
Clock, mixing time 12-16 minutes；
(3) temperature of rotor mixer is adjusted to 172-178 DEG C, mixing speed is 245-255 revs/min, lasting stirring
16-22 minutes, obtain raw mixture；
(4) raw mixture in step (3) is extruded；
(5) through extruding the cooling of obtained raw mixture, drying, plastotype will be then drawn high, as compound bag in step (4)
Package material finished product.
Finally illustrate, the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted, although with reference to compared with
The present invention is described in detail good embodiment, it will be understood by those within the art that, can be to the skill of the present invention
Art scheme is modified or equivalent substitution, and without departing from the objective and scope of the technical program, it all should cover in the present invention
Right among.
Claims (5)
1. a kind of compound package material, it is characterised in that be prepared from the following raw materials in parts by weight：Corvic 60-85
Part, nickel-coated carbon fibers 15-25 parts, barium stearate 2-5 parts, aziridine crosslinker 3-6 parts, phenyl silane 3-8 parts, lead oxide 1-5
Part, zinc oxide 3-8 parts, lubricant 1-5 parts, polyvinyl alcohol 8-16 parts, Fypro 15-25 parts, polyisobutene 3-10 parts, gather
Diphenyl sulfide 7-13 parts, acrylic acid 10-16 parts, mica powder 5-12 parts, polypentenol 8-13 parts, octyl group succinic acid starch ester 12-20
Part, melamine sodium phosphate 2-7 parts, anti-wear agent 1-6 parts, tetramethoxy-silicane 6-15 parts, triallylamine 5-12 parts.
2. compound package material according to claim 1, it is characterised in that be prepared from the following raw materials in parts by weight：It is poly-
80 parts of vinyl chloride resin, 22 parts of nickel-coated carbon fibers, 3 parts of barium stearate, 4 parts of aziridine crosslinker, 6 parts of phenyl silane, lead oxide 3
Part, 4 parts of zinc oxide, 2 parts of lubricant, 11 parts of polyvinyl alcohol, 18 parts of Fypro, 7 parts of polyisobutene, 10 parts of polyphenylene sulfide,
13 parts of acrylic acid, 9 parts of mica powder, 10 parts of polypentenol, 16 parts of octyl group succinic acid starch ester, 4 parts of melamine sodium phosphate are wear-resisting
3 parts of agent, 8 parts of tetramethoxy-silicane, 11 parts of triallylamine.
3. compound package material according to claim 1, it is characterised in that be prepared from the following raw materials in parts by weight：It is poly-
72 parts of vinyl chloride resin, 22 parts of nickel-coated carbon fibers, 5 parts of barium stearate, 4 parts of aziridine crosslinker, 5 parts of phenyl silane, lead oxide 2
Part, 6 parts of zinc oxide, 3 parts of lubricant, 9 parts of polyvinyl alcohol, 20 parts of Fypro, 6 parts of polyisobutene, 8 parts of polyphenylene sulfide, third
13 parts of olefin(e) acid, 6 parts of mica powder, 9 parts of polypentenol, 16 parts of octyl group succinic acid starch ester, 5 parts of melamine sodium phosphate, anti-wear agent 2
Part, 7 parts of tetramethoxy-silicane, 10 parts of triallylamine.
4. compound package material according to claim 1, it is characterised in that be prepared from the following raw materials in parts by weight：It is poly-
80 parts of vinyl chloride resin, 20 parts of nickel-coated carbon fibers, 5 parts of barium stearate, 5 parts of aziridine crosslinker, 4 parts of phenyl silane, lead oxide 3
Part, 6 parts of zinc oxide, 3 parts of lubricant, 11 parts of polyvinyl alcohol, 22 parts of Fypro, 7 parts of polyisobutene, 8 parts of polyphenylene sulfide, third
15 parts of olefin(e) acid, 9 parts of mica powder, 9 parts of polypentenol, 18 parts of octyl group succinic acid starch ester, 3 parts of melamine sodium phosphate, anti-wear agent 4
Part, 10 parts of tetramethoxy-silicane, 9 parts of triallylamine.
5. the preparation method of the compound package material according to any one of claim 1-4, it is characterised in that including following
Step：
(1) each raw material components are weighed according to ratio of weight and number；
(2) each raw material components in step (1) being added in rotor mixer and stirred, mixing speed is 300-315 revs/min,
Mixing time 12-16 minutes；
(3) temperature of rotor mixer is adjusted to 172-178 DEG C, mixing speed is 245-255 revs/min, persistently stirs 16-22
Minute, obtain raw mixture；
(4) raw mixture in step (3) is extruded；
(5) through extruding the cooling of obtained raw mixture, drying, plastotype, as composite packaging material will then be drawn high in step (4)
Expect finished product.
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| CN201710725756.6A CN107383695A (en) | 2017-08-22 | 2017-08-22 | A kind of compound package material and preparation method thereof |
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Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106243536A (en) * | 2016-08-24 | 2016-12-21 | 安徽顺彤包装材料有限公司 | A kind of high-strength abrasion-proof compound package material and preparation method thereof |
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- 2017-08-22 CN CN201710725756.6A patent/CN107383695A/en not_active Withdrawn
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106243536A (en) * | 2016-08-24 | 2016-12-21 | 安徽顺彤包装材料有限公司 | A kind of high-strength abrasion-proof compound package material and preparation method thereof |
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