CN107383676A - A kind of environmentally friendly toy for children film and preparation method thereof - Google Patents
A kind of environmentally friendly toy for children film and preparation method thereof Download PDFInfo
- Publication number
- CN107383676A CN107383676A CN201710561117.0A CN201710561117A CN107383676A CN 107383676 A CN107383676 A CN 107383676A CN 201710561117 A CN201710561117 A CN 201710561117A CN 107383676 A CN107383676 A CN 107383676A
- Authority
- CN
- China
- Prior art keywords
- toy
- environmentally friendly
- parts
- children
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2491/00—Characterised by the use of oils, fats or waxes; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Toys (AREA)
Abstract
A kind of environmentally friendly toy for children film of the present invention and preparation method thereof, include the following raw materials according of mass fraction：100 parts of the polyvinyl chloride resin powder of the degree of polymerization 1,300 2500, add 50 70 parts citrate environment-friendly plasticizer, 23 parts of epoxidized soybean oil, 0.3 0.6 parts of lubricant, 1.5 2.5 parts of colorant, 25 parts of environmentally friendly calcium-zinc composite stabilizing agent and 1.5 2.5 parts of processing aid, the present invention have the advantages that to be free of phthalate, without bisphenol-A, meet the German class standard of polycyclic aromatic hydrocarbon 1, meet national toy technical specification of security GB6675 2003.Compared with prior art, product employs the polyvinyl chloride resin powder of ethylene process high polymerization degree and is process, and has excellent physical and mechanical properties, it is ensured that product meets European Union EN71 1《Toy safety part 1s:Machinery and physical property》It is required that it is process from citrate environment-friendly plasticizer as materials such as primary plasticizer, high-performance environment-friendly calcium-zinc composite stabilizing agents.So as to realize the requirement for meeting national toy technical specification of security GB6675 2003.
Description
Technical field
The present invention relates to chemical technology field, new material class, the processed and applied technology of high-molecular organic material are specific next
Say it is a kind of environmentally friendly toy for children film and preparation method thereof.
Background technology
Phthalic acid ester Phthalates is one group of chemical compound, is mainly used in pvc material, makes polychlorostyrene second
Alkene is changed into flexible plastic cement from hard plastic glue, plays a part of plasticizer.This material is widely present in cosmetics, Er Tongwan
In tool, packaging for foodstuff, if its content overproof, very big harm can be produced to health.Research shows that phthalate exists
The effect of human body female hormone similar with being played in animal body, may interfere with endocrine, as people are to (adjacent to Phthalates
Phthalate) understanding, the phthalate in articles for children is increasingly taken seriously.Expert has found to contain phthalic acid
The flexible plastic toy and articles for children of salt are possible to be put into mouth by child, if the time long enough placed, may result in neighbour
The stripping quantity of Phthalate exceedes level of security, can endanger the liver and kidney of children, can also cause children's sexual precocity to endanger.
Polycyclic aromatic hydrocarbon (Polycyclic Aromatic Hydrocarbons PAHs) is coal, oil, timber, tobacco, is had
Volatile hydrocarbon caused by the organic matter imperfect combustion such as machine high-molecular compound, it is that important environment and food are dirty
Contaminate thing.Hitherto it is found that there is more than 200 kinds of PAHs, wherein there is considerable part that there is carcinogenicity, such as benzo[α, benzo α anthracenes etc..
PAHs is distributed widely in environment, can be found in each corner that we live, in polycyclic aromatic hydrocarbon molecule containing two with
The hydrocarbon of upper phenyl ring, including naphthalene, anthracene, phenanthrene, pyrene etc. more than 150 plant compound.
According to experts, polycyclic aromatic hydrocarbon is a kind of organic compound, there is very strong carcinogenicity, can by breathing or
Direct skin contact makes human carcinogen.Maximum to body effect among polycyclic aromatic hydrocarbon is BaP, is a kind of Mutagen, is
One carcinogenic material, it is a fat-soluble stronger material, this can be drawn into vivo, into alveolar even blood, lead
Cause lung cancer and angiocardiopathy.
Bisphenol-A is formed by two molecule phenol and a molecule condensation of acetone, is important Organic Chemicals, frequently as polymerization
Inhibitor is added in PVC.Bisphenol-A can trigger the hormonal reaction of human body, long-time inspiration bisphenol-A powder similar to estrogen
It is harmful to liver function and renal function, especially severe is that it can reduce the content of ferroheme in blood.There are some researches prove 18 months
Baby before may by plastics jarred baby foods, baby's plastic bottle, plastic toy Excess free enthalpy are this has female to swash
The chemicals of element effect, although content is very low, but if concentration is got up, than the amount of estrogen contained naturally in mankind body
Want high about 1000 times.On October 18th, 2008, federal government of Canada announced, determined bisphenol-A (BPA) being included in Toxic
In matter list, it means that this chemicals for being widely used in packaging for foodstuff will be prohibitted the use of in Canada soon, and science is ground
Very clearly, threat of the bisphenol-A for health is very big to the evidence studied carefully, particularly with children and developmental tire
Youngster, forbid selling product of the Ganlei containing bisphenol-A if the multiple states of European Union and the U.S. have been made laws.
Its difficult point is：
1. the regulation that each country is limited harmful substance in toy for children is inconsistent, it is necessary in view of each national method
Rule；
2. the limited content for the product bisphenol-A of toy for children is too low, it is desirable to bisphenol-A (BPA) is less than 1mg/kg, it is difficult to
Control；
3. the limitation for the product polycyclic aromatic hydrocarbon of toy for children is strict, it is desirable to less than 0.2mg/kg, it is easy to surpass
Target phenomenon；Polycyclic aromatic hydrocarbon (PAHs) is coal, oil, timber, tobacco, the organic matter imperfect combustion such as organic high molecular compound
Caused volatile hydrocarbon, it is easy to decompose in process of manufacture；
4. toy for children film is highly contaminating in process of manufacture, toy for children film is in process of manufacture
It is easy to occur decomposing to produce polycyclic aromatic hydrocarbon, production equipment, raw material, which bring impurity into, causes phthalate, polycyclic aromatic hydrocarbon to surpass
Mark.
The content of the invention
Instant invention overcomes in the prior art the shortcomings that, there is provided a kind of environmentally friendly toy for children film and preparation method thereof, symbol
Various countries' toy for children articles for use environmental regulation is closed, without being limited by country variant toy for children articles for use environmental regulation.
In order to solve the above-mentioned technical problem, the present invention is achieved by the following technical solutions：
A kind of environmentally friendly toy for children film, include the following raw materials according of mass fraction：Degree of polymerization 1300-2500 polyvinyl chloride tree
100 parts of cosmetics, add the citrate environment-friendly plasticizer of 50-70 parts, the epoxidized soybean oil of 2-3 parts, the lubrication of 0.3-0.6 parts
Agent, the colorant of 1.5-2.5 parts, 2-5 parts environmentally friendly calcium-zinc composite stabilizing agent and 1.5-2.5 part processing aid.
Further, it is additionally added the graphene of 1-2 parts of the polyvinyl chloride resin powder.
A kind of preparation method of environmentally friendly toy for children film, comprises the following steps：
1) dispensing and metering；
2) dispensing hot mixing；
3) banburying；
4) roll squeezer carries out roll-in；
5) filtering extruder is filtered；
6) deflect from and after wheel is drawn be embossed by embossed wheel；
7) thickness measuring is carried out to toy for children film by calibrator；
8) water cooling wheel cools down to toy for children film；
9) trimming and curling are cut.
Further, the step of dispensing hot mixing includes：First low rate start mixer, then the right 1300-2500 of addition polymerization
Polyvinyl chloride resin powder, then plus environmentally friendly calcium-zinc composite stabilizing agent, lubricant, graphene and colorant；Low speed rotation high speed, when mixed
Temperature is closed to 80 DEG C, starts to be gradually added into citrate environment-friendly plasticizer, when plasticizer is sufficiently mixed, adds processing aid, by
Gradually being warmed to 115 DEG C can stop stirring.
Further, deflect from and take turns the calendering wheel for including setting gradually and deflect from roller, the roller that deflects from passes for two along toy film
Dynamic orient diameter increase deflects from roller.
Further, described deflect from takes turns the calendering wheel for including setting gradually, deflects from roller and several dragging rollers
Further, the embossing includes vertical embossing and horizontal embossing.
Further, the calibrator includes beta ray source and β ray receivers.
Further, the trimming includes cooling down cutting position, carries out trimming while cooling.
Further, cutting position also installs audio signal reception device, and the audio signal reception device is connected with audio contrast device.
Compared with prior art, the beneficial effects of the invention are as follows：
A kind of environmentally friendly toy for children film of the present invention and preparation method thereof, include the following raw materials according of mass fraction：Polymerization
1300-2500 100 parts of polyvinyl chloride resin powder is spent, adds the citrate environment-friendly plasticizer, the epoxy of 2-3 parts of 50-70 parts
Soybean oil, the lubricant of 03-0.6 parts, the colorant of 1.5-2.5 parts, environmentally friendly calcium-zinc composite stabilizing agent and 1.5-2.5 part of 2-5 parts
Processing aid, the present invention has without phthalate, without bisphenol-A, meet the German class standard of polycyclic aromatic hydrocarbon 1, meet
The advantages that national toy technical specification of security GB6675-2003.Compared with prior art, product employs ethylene process high polymerization degree
Polyvinyl chloride resin powder be process, there is excellent physical and mechanical properties, it is ensured that product meets European Union EN71-1《Toy is pacified
Full part 1s:Machinery and physical property》It is required that from citrate environment-friendly plasticizer as primary plasticizer, high-performance environment-friendly
The materials such as calcium-zinc composite stabilizing agent are process.Meet wanting for national toy technical specification of security GB6675-2003 so as to realize
Ask.
Brief description of the drawings
Accompanying drawing is used for providing a further understanding of the present invention, is used to explain the present invention together with embodiments of the present invention,
It is not construed as limiting the invention, in the accompanying drawings：
Fig. 1 is a kind of structural representation of the preparation method of environmentally friendly toy for children film of the present invention；
Fig. 2 is that embodiment 1 deflects from wheel construction schematic diagram；
Fig. 3 is that embodiment 2 deflects from wheel construction schematic diagram；
Fig. 4 is the structural representation being vertically embossed；
Fig. 5 is the structural representation of horizontal embossing；
Fig. 6 is the structural representation of calibrator；
Fig. 7 is the structural representation of trimming.
In figure, 1 --- proportioner；2 --- metering device；
3 --- mixer；4 --- banbury；
5 --- roll squeezer；6 --- filtering extruder；
7 --- deflect from wheel；8 --- calendering wheel；
9 --- deflect from roller；10 --- rubber wheel；
11 --- embossed wheel；12 --- calibrator；
13 --- beta ray source device；14 --- β rays receive；
15 --- water cooling wheel；16 --- cutting position；
17 --- cutting knife；18 --- dragging roller.
Embodiment
The preferred embodiments of the present invention are illustrated below in conjunction with accompanying drawing, it will be appreciated that described herein preferred real
Apply example to be merely to illustrate and explain the present invention, be not intended to limit the present invention.
A kind of environmentally friendly toy for children film, include the following raw materials according of mass fraction：Degree of polymerization 1300-2500 polyvinyl chloride tree
100 parts of cosmetics, add 60 parts citrate environment-friendly plasticizer, 2.5 parts of epoxidized soybean oil, 0.5 part of lubricant, 2 parts
Colorant, 3 parts of environmentally friendly calcium-zinc composite stabilizing agent and 2 parts of processing aids acrylic resin, are additionally added polyvinyl chloride resin powder 1.5
The graphene of part, graphene make toy film in the case where not adding other dispensings, have excellent physical and mechanical properties, really
Protect product and meet European Union EN71-1《Toy safety part 1s:Machinery and physical property》It is required that.
Embodiment 1：
As shown in figure 1, a kind of preparation method of environmentally friendly toy for children film of the present invention, comprises the following steps：
1) proportioner 1 carries out dispensing and metering device 2 is measured；
2) dispensing hot mixing, include the step of dispensing hot mixing：First low rate start mixer 3, then the right 1300- of addition polymerization
2500 polyvinyl chloride resin powder, then add environmentally friendly calcium-zinc composite stabilizing agent, lubricant, graphene and colorant；Low speed rotation high speed,
When mixing temperature is to 80 DEG C, start to be gradually added into citrate environment-friendly plasticizer, when plasticizer is sufficiently mixed, adds processing and help
Agent, being gradually warmed to 115 DEG C can stop stirring, and raw material proportioning combines the raw material adition process, and the temperature used, make each
Composition mixes and reaction, product is reached the performance of requirement；
3) banbury 4 carries out banburying；
4) roll squeezer 5 carries out roll-in；
5) filtering extruder 6 is filtered；
6) deflect from wheel 7 to be drawn, take turns the 7 calendering wheels 8 for including setting gradually as shown in Fig. 2 deflecting from and deflect from roller 9, draw
It is two from roller 9 and deflects from roller 9 along the increase of toy film transmission direction diameter, wheel 7 is deflected from by the structure, realizes toy film
Stretch, be then embossed by rubber wheel 10 and embossed wheel 11, as shown in figure 4, the present embodiment is using vertical embossing；
7) as shown in fig. 6, carrying out thickness measuring to toy for children film by calibrator 12, calibrator 12 includes beta ray source 13 and β
Ray receiver 14；
8) water cooling wheel 15 cools down to toy for children film；
9) as shown in fig. 7, trimming and curling are cut, trimming includes cooling down cutting position 16, enters while cooling
Row trimming, cut in the case of cooling by cutting knife 17, cutting is more neat, and cutting position 16 also installs audio signal reception device, receives
Mixer is connected with audio contrast device, and audio signal reception device monitors sound during cutting, when sound and inconsistent reserved sound, enters
Row alarm, toy film cutting position 16 are likely to occur the substandard products such as flash.
The present invention has without phthalate, without bisphenol-A, meet the German class standard of polycyclic aromatic hydrocarbon 1, meet country
The advantages that toy safety technical specification GB6675-2003.Compared with prior art, product employs the poly- of ethylene process high polymerization degree
Vinyl chloride resin powder is process, and has excellent physical and mechanical properties, it is ensured that product meets European Union EN71-1《Toy safety
Part 1:Machinery and physical property》It is required that from citrate environment-friendly plasticizer as primary plasticizer, high-performance environment-friendly calcium zinc
The materials such as compound stabilizer are process.So as to realize the requirement for meeting national toy technical specification of security GB6675-2003.
Embodiment 2：
The present embodiment and the technical scheme of embodiment 1 are essentially identical, and something in common repeats no more, and its difference is：
Take turns the calendering wheel 8 for including setting gradually as shown in figure 3, deflecting from, deflect from roller 9 and several dragging rollers 18, passing through the knot
Structure, stretching for toy film is realized, beneficial to embossing below, as shown in figure 5, using horizontal embossing.
Finally it should be noted that：The preferred embodiments of the present invention are these are only, are not intended to limit the invention, although
The present invention is described in detail with reference to embodiment, for those skilled in the art, it still can be to foregoing
Technical scheme described in each embodiment is modified, or to which part technical characteristic carry out equivalent substitution, but it is all
Within the spirit and principles in the present invention, any modification, equivalent substitution and improvements made etc., the protection of the present invention should be included in
Within the scope of.
Claims (10)
- A kind of 1. environmentally friendly toy for children film, it is characterised in that the following raw materials according including mass fraction：Degree of polymerization 1300-2500's 100 parts of polyvinyl chloride resin powder, add the citrate environment-friendly plasticizer of 50-70 parts, the epoxidized soybean oil of 2-3 parts, 0.3-0.6 Part lubricant, the colorant of 1.5-2.5 parts, 2-5 parts environmentally friendly calcium-zinc composite stabilizing agent and 1.5-2.5 part processing aid.
- 2. a kind of preparation method of environmentally friendly toy for children film according to claim 1, it is characterised in that be additionally added the polychlorostyrene The graphene of 1-2 parts of vinyl powder.
- 3. a kind of preparation method of environmentally friendly toy for children film according to claim 1, it is characterised in that comprise the following steps：1) dispensing and metering；2) dispensing hot mixing；3) banburying；4) roll squeezer carries out roll-in；5) filtering extruder is filtered；6) deflect from and after wheel is drawn be embossed by embossed wheel；7) thickness measuring is carried out to toy for children film by calibrator；8) water cooling wheel cools down to toy for children film；9) trimming and curling are cut.
- A kind of 4. preparation method of environmentally friendly toy for children film according to claim 3, it is characterised in that the dispensing hot mixing The step of include：First low rate start mixer, then the right 1300-2500 of addition polymerization polyvinyl chloride resin powder, then add environmentally friendly calcium Zinc composite stabilizer, lubricant, graphene and colorant；Low speed rotation at a high speed, when mixing temperature is to 80 DEG C, starts to be gradually added into lemon Acid esters environment-friendly plasticizer, when plasticizer is sufficiently mixed, addition processing aid, being gradually warmed to 115 DEG C can stop stirring.
- 5. a kind of preparation method of environmentally friendly toy for children film according to claim 3, it is characterised in that the wheel that deflects from includes The calendering wheel that sets gradually and roller is deflected from, the roller that deflects from deflects from roller for two along the increase of toy film transmission direction diameter.
- 6. a kind of preparation method of environmentally friendly toy for children film according to claim 3, it is characterised in that the wheel that deflects from includes The calendering wheel that sets gradually, deflect from roller and several dragging rollers.
- 7. a kind of preparation method of environmentally friendly toy for children film according to claim 3, it is characterised in that the embossing includes hanging down Vertical compression is spent and horizontal embossing.
- 8. a kind of preparation method of environmentally friendly toy for children film according to claim 3, it is characterised in that the calibrator includes Beta ray source and β ray receivers.
- A kind of 9. preparation method of environmentally friendly toy for children film according to claim 3, it is characterised in that the trimming include pair Cutting position is cooled down, and carries out trimming while cooling.
- 10. a kind of preparation method of environmentally friendly toy for children film according to claim 9, it is characterised in that cutting position is also pacified Audio signal reception device is filled, the audio signal reception device is connected with audio contrast device.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710561117.0A CN107383676A (en) | 2017-07-11 | 2017-07-11 | A kind of environmentally friendly toy for children film and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710561117.0A CN107383676A (en) | 2017-07-11 | 2017-07-11 | A kind of environmentally friendly toy for children film and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107383676A true CN107383676A (en) | 2017-11-24 |
Family
ID=60340496
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710561117.0A Pending CN107383676A (en) | 2017-07-11 | 2017-07-11 | A kind of environmentally friendly toy for children film and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107383676A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108409574A (en) * | 2018-04-16 | 2018-08-17 | 山东万图高分子材料股份有限公司 | A kind of citrate and its preparation method and application |
| CN109280287A (en) * | 2018-08-08 | 2019-01-29 | 广东冠盛新材料有限公司 | A kind of fire-retardant electric heating blanket film and preparation method thereof |
| CN112169743A (en) * | 2020-11-30 | 2021-01-05 | 北京艾科美特新材料开发有限公司 | Inorganic-organic composite material preparation system |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103059473A (en) * | 2013-01-09 | 2013-04-24 | 浙江明士达新材料有限公司 | Super-wide environmental-friendly decorative film material and preparation technology thereof |
-
2017
- 2017-07-11 CN CN201710561117.0A patent/CN107383676A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103059473A (en) * | 2013-01-09 | 2013-04-24 | 浙江明士达新材料有限公司 | Super-wide environmental-friendly decorative film material and preparation technology thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108409574A (en) * | 2018-04-16 | 2018-08-17 | 山东万图高分子材料股份有限公司 | A kind of citrate and its preparation method and application |
| CN109280287A (en) * | 2018-08-08 | 2019-01-29 | 广东冠盛新材料有限公司 | A kind of fire-retardant electric heating blanket film and preparation method thereof |
| CN112169743A (en) * | 2020-11-30 | 2021-01-05 | 北京艾科美特新材料开发有限公司 | Inorganic-organic composite material preparation system |
| CN112169743B (en) * | 2020-11-30 | 2021-03-23 | 北京艾科美特新材料开发有限公司 | Inorganic-organic composite material preparation system |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107383676A (en) | A kind of environmentally friendly toy for children film and preparation method thereof | |
| Mahcene et al. | Development and characterization of sodium alginate based active edible films incorporated with essential oils of some medicinal plants | |
| Mohamad et al. | Development of active agents filled polylactic acid films for food packaging application | |
| Montero et al. | Nanocellulose functionalized with cinnamon essential oil: A potential application in active biodegradable packaging for strawberry | |
| Lee et al. | Development of a chicken feet protein film containing essential oils | |
| Su et al. | Preparation and characterization of ethyl cellulose film modified with capsaicin | |
| Sogut et al. | The properties of κ-carrageenan and whey protein isolate blended films containing pomegranate seed oil | |
| CN104861398A (en) | Glazing PVC plastic soaking liquid and preparation method thereof | |
| CN107627706A (en) | Degradable high-barrier active fresh-keeping film and preparation method thereof | |
| CN106117880A (en) | A kind of transparent type medical antibacterial pvc material and preparation method thereof | |
| CN107353485A (en) | A kind of antibacterial, ventilating film master batch and preparation method thereof | |
| CN108299711B (en) | Antibacterial packaging film and processing method | |
| Holcapkova et al. | Thermal stability of bacteriocin nisin in polylactide-based films | |
| CN101519517B (en) | Medical rubber-plastic composite material | |
| CN105566799B (en) | A kind of environment-friendly type high transparency PVC composition for being used to make medical infusion lines | |
| US20210309816A1 (en) | Protein/polysaccharide/essential oil nanometer edible film and preparation method therefor | |
| CN106977832A (en) | Woven hose environment-friendly type high transparency PVC composition | |
| WO2017032516A1 (en) | Polyolefin composition comprising an antimicrobial additive | |
| CN101434732A (en) | Medical soft polychloroethylene plastic without o-benzene series plasticiser | |
| CN105218919A (en) | A kind of safe preservative film of high light transmittance and preparation technology thereof | |
| CN104725732B (en) | Low-hardness medical thermoplastic brominated butyl rubber and preparation method thereof | |
| CN106554580B (en) | A kind of PVC food packaging composition and preparation method thereof | |
| Nasution et al. | Properties of active packaging of PLA-PCL film integrated with chitosan as an antibacterial agent and syzygium cumini seed extract as an antioxidant agent | |
| KR101465414B1 (en) | Manufacturing method of master batches for resins using lacquer sap | |
| CN104403281B (en) | A kind of medical fibre based high molecular material and its preparation method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information | ||
| CB02 | Change of applicant information |
Address after: 528315 Guangdong Foshan Shunde District Lecong Town, good village industrial zone Applicant after: Guangdong Guan Sheng new material Co., Ltd. Address before: 528315 Guangdong Foshan Shunde District Lecong Town, good village industrial zone Applicant before: Guangdong Guansheng Plastics Co.,Ltd. |
|
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20171124 |