CN107383516A - A kind of cold-proof anti-skid multifunctional safety shoe of antistatic oil-resistant - Google Patents
A kind of cold-proof anti-skid multifunctional safety shoe of antistatic oil-resistant Download PDFInfo
- Publication number
- CN107383516A CN107383516A CN201710630578.9A CN201710630578A CN107383516A CN 107383516 A CN107383516 A CN 107383516A CN 201710630578 A CN201710630578 A CN 201710630578A CN 107383516 A CN107383516 A CN 107383516A
- Authority
- CN
- China
- Prior art keywords
- parts
- cold
- proof
- sole
- safety shoe
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B23/00—Uppers; Boot legs; Stiffeners; Other single parts of footwear
- A43B23/02—Uppers; Boot legs
- A43B23/0205—Uppers; Boot legs characterised by the material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
- C08L21/02—Latex
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D191/00—Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
The invention discloses a kind of cold-proof anti-skid multifunctional safety shoe of the antistatic oil-resistant for belonging to clothes manufacturing technology field.The material for sole of shoe is made up of the raw material of following parts by weight：30 50 parts of latex, 10 20 parts of ethyl butyrate, 58 parts of clay, 58 parts of accelerator, 38 parts of furfural resin, 12 parts of mine tailing, 38 parts of butyl oxide, 12 parts of barium sulfate, 12 parts of sulphur；The vamp material coats cold-proof NBR by canvas and is made.The cold-proof anti-skid multifunctional safety shoe of antistatic oil-resistant of the present invention, using brand-new formula, the safety shoe wearing comfort of preparation, antistatic effect is strong, and grease proofing ability is strong, spot is not easy to be infected with, worn for long periods under cold conditions, it will not become fragile, service life length, vamp coats cold-proof NBR, it is not easy to is infected with spot.
Description
Technical field
The invention belongs to clothes manufacturing technology field, and in particular to a kind of cold-proof anti-skid multifunctional safety of antistatic oil-resistant
Footwear.
Background technology
The safety shoe prepared using vulcanization rubber process, there is certain insulation function, good toughness, still, easily produce
Electrostatic, oil resistant, does not adhere to spot easily, and service life is short, in addition, it is permanent using easily becoming fragile at low temperature, it is hardened, wears
Become uncomfortable.
Patent CN101569441 discloses a kind of oil resistant, insulation, acid and alkali-resistance, high temperature resistant multifunctional safety shoe, and its sole is former
It is resistance to factice to expect to form, natural gum, carbon black, clay, barium sulfate, stearic acid, dibutyl ester, accelerator, sulphur, vaseline.But
The sole cold tolerance is poor, easily becomes fragile under cold conditions.Patent CN 102336973 discloses a kind of safe sole material
And preparation method thereof, in its 100 parts of the following TPE of component and parts by weight；150 parts of PS；111 parts of PE；70 parts of rice bran；Two
22 parts of butyl ether；36 parts of ethyl acetate；27 parts of thiosulfate；18 parts of olive oil；19 parts of acetone, 10 parts of aniline.The sole oil resistant,
Insulation, cold tolerance are bad.
The content of the invention
It is an object of the invention to provide a kind of cold-proof anti-skid multifunctional safety shoe of antistatic oil-resistant.
A kind of cold-proof anti-skid multifunctional safety shoe of antistatic oil-resistant, including material for sole of shoe and vamp material, the sole material
Material is made up of the raw material of following parts by weight：Latex 30-50 parts, ethyl butyrate 10-20 parts, clay 5-8 parts, accelerator 5-8 parts,
Furfural resin 3-8 parts, mine tailing 1-2 parts, butyl oxide 3-8 parts, barium sulfate 1-2 parts, sulphur 1-2 parts；The vamp material is by sail
Cloth coats cold-proof NBR and is made.
The accelerator is diphenylguanidine or altax.
The mine tailing is phosphorus mine tailing, iron tailings powder, molybdic tailing powder, copper tailing powder, aluminium mine tailing, in tailing powder
It is one or more kinds of.
The amount of the cold-proof NBR coating is the 5-15% of canvas quality, is made up of the component of following parts by weight：Rubber
Glue seed oil 20-30 parts, bisphenol A type epoxy resin 3-8 parts, chlorinated rubber 10-15 parts, cellulose ether 2-5 parts, the double vinegar of fluoxyprednisolone
Acid esters 3-5 parts, 5,6,11,12- tetraphenyl naphthonaphthalene 3-5 parts.
The preparation method of the above-mentioned cold-proof anti-skid multifunctional safety shoe of antistatic oil-resistant, is made as follows：
(1) latex 30-50 parts are taken according to parts by weight, ethyl butyrate 10-20 parts, clay 5-8 parts, accelerator 5-8 parts,
Furfural resin 3-8 parts, mine tailing 1-2 parts, butyl oxide 3-8 parts, barium sulfate 1-2 parts, sulphur 1-2 parts, it is kneaded synthesis raw stock；
(2) raw stock is loaded in die for shoe-sole, imposes to film 80-90 kilograms of pressure using hydraulic press, and
Vulcanized under 100-115 DEG C of temperature conditionss, cure time 8-12 minutes, sole is made；
(3) coating accounts for canvas quality 5-15% cold-proof NBR on canvas, dries or dries, using sewing, glue
It is viscous, the method for cutting, sole is combined with vamp, safety shoe is made.
Beneficial effects of the present invention：The cold-proof anti-skid multifunctional safety shoe of antistatic oil-resistant of the present invention, is matched somebody with somebody using brand-new
Side, the safety shoe wearing comfort of preparation, antistatic effect is strong, and grease proofing ability is strong, and spot is not easy to be infected with, and grows under cold conditions
Phase dresses, and will not become fragile, and service life length, vamp coats cold-proof NBR, it is not easy to is infected with spot, and can grow at low temperature
Time dresses.
Embodiment
With reference to specific embodiment, the present invention will be further described.
Embodiment 1
A kind of cold-proof anti-skid multifunctional safety shoe of antistatic oil-resistant, including material for sole of shoe and vamp material, the sole material
Material is made up of the raw material of following parts by weight：40 parts of latex, 15 parts of ethyl butyrate, 6 parts of clay, 6 parts of diphenylguanidine, furfural resin
5 parts, 1 part of phosphorus mine tailing, 5 parts of butyl oxide, 1 part of barium sulfate, 1 part of sulphur；The vamp material coats cold-proof NBR by canvas
It is made.The amount of the cold-proof NBR coating is the 10% of canvas quality, is made up of the component of following parts by weight：Rubber seed oil
25 parts, 5 parts of bisphenol A type epoxy resin, 12 parts of chlorinated rubber, 4 parts of cellulose ether, 4 parts of fluoxyprednisolone diacetate, 5,6,11,
4 parts of 12- tetraphenyls naphthonaphthalene.
The preparation method of the above-mentioned cold-proof anti-skid multifunctional safety shoe of antistatic oil-resistant, is made as follows：
(1) according to parts by weight, 40 parts of latex, 15 parts of ethyl butyrate, 6 parts of clay, 6 parts of diphenylguanidine, furfural resin 5 are taken
Part, 1 part of phosphorus mine tailing, 5 parts of butyl oxide, 1 part of barium sulfate, 1 part of sulphur, it is kneaded synthesis raw stock；
(2) raw stock is loaded in die for shoe-sole, 85 kilograms of pressure is imposed to film using hydraulic press, and 110
Vulcanized under DEG C temperature conditionss, cure time 10 minutes, sole is made；
(3) coating accounts for the cold-proof NBR of canvas quality 10% on canvas, dries or dries, gluing using sewing,
The method of cutting, sole is combined with vamp, safety shoe is made.
Embodiment 2
A kind of cold-proof anti-skid multifunctional safety shoe of antistatic oil-resistant, including material for sole of shoe and vamp material, the sole material
Material is made up of the raw material of following parts by weight：30 parts of latex, 10 parts of ethyl butyrate, 5 parts of clay, 5 parts of altax, furfural tree
3 parts of fat, 1 part of iron tailings powder, 3 parts of butyl oxide, 1 part of barium sulfate, 1 part of sulphur；The vamp material is coated cold-proof grease proofing by canvas
Glue is made.The amount of the cold-proof NBR coating is the 5% of canvas quality, is made up of the component of following parts by weight：Rubber seed
20 parts of oil, 3 parts of bisphenol A type epoxy resin, 10 parts of chlorinated rubber, 2 parts of cellulose ether, 3 parts of fluoxyprednisolone diacetate, 5,6,
3 parts of 11,12- tetraphenyls naphthonaphthalene.
The preparation method of the above-mentioned cold-proof anti-skid multifunctional safety shoe of antistatic oil-resistant, is made as follows：
(1) according to parts by weight, 30 parts of latex, 10 parts of ethyl butyrate, 5 parts of clay, 5 parts of altax, furfural resin are taken
3 parts, 1 part of iron tailings powder, 3 parts of butyl oxide, 1 part of barium sulfate, 1 part of sulphur, it is kneaded synthesis raw stock；
(2) raw stock is loaded in die for shoe-sole, 80 kilograms of pressure is imposed to film using hydraulic press, and 100
Vulcanized under DEG C temperature conditionss, cure time 8 minutes, sole is made；
(3) coating accounts for the cold-proof NBR of canvas quality 5% on canvas, dries or dries, gluing using sewing,
The method of cutting, sole is combined with vamp, safety shoe is made.
Embodiment 3
A kind of cold-proof anti-skid multifunctional safety shoe of antistatic oil-resistant, including material for sole of shoe and vamp material, the sole material
Material is made up of the raw material of following parts by weight：50 parts of latex, 20 parts of ethyl butyrate, 8 parts of clay, 8 parts of diphenylguanidine, furfural resin
8 parts, 2 parts of molybdic tailing powder, 8 parts of butyl oxide, 2 parts of barium sulfate, 2 parts of sulphur；The vamp material coats cold-proof NBR by canvas
It is made.The amount of the cold-proof NBR coating is the 15% of canvas quality, is made up of the component of following parts by weight：Rubber seed oil
30 parts, 8 parts of bisphenol A type epoxy resin, 15 parts of chlorinated rubber, 5 parts of cellulose ether, 5 parts of fluoxyprednisolone diacetate, 5,6,11,
5 parts of 12- tetraphenyls naphthonaphthalene.
The preparation method of the above-mentioned cold-proof anti-skid multifunctional safety shoe of antistatic oil-resistant, is made as follows：
(1) according to parts by weight, 50 parts of latex, 20 parts of ethyl butyrate, 8 parts of clay, 8 parts of diphenylguanidine, furfural resin 8 are taken
Part, 2 parts of molybdic tailing powder, 8 parts of butyl oxide, 2 parts of barium sulfate, 2 parts of sulphur, it is kneaded synthesis raw stock；
(2) raw stock is loaded in die for shoe-sole, 90 kilograms of pressure is imposed to film using hydraulic press, and 115
Vulcanized under DEG C temperature conditionss, cure time 12 minutes, sole is made；
(3) coating accounts for the cold-proof NBR of canvas quality 15% on canvas, dries or dries, gluing using sewing,
The method of cutting, sole is combined with vamp, safety shoe is made.
Embodiment 4
A kind of cold-proof anti-skid multifunctional safety shoe of antistatic oil-resistant, including material for sole of shoe and vamp material, the sole material
Material is made up of the raw material of following parts by weight：40 parts of latex, 15 parts of ethyl butyrate, 6 parts of clay, 6 parts of diphenylguanidine, furfural resin
5 parts, 1 part of phosphorus mine tailing, 5 parts of butyl oxide, 1 part of barium sulfate, 1 part of sulphur, 1 part of cypress vine pine extract；The cypress vine pine extract
Prepare with the following method：The juice of its Fresh Plants is obtained using physical squeezing method, 2-5 times of volume concentration is made.It is described
Vamp material coats cold-proof NBR by canvas and is made.The amount of the cold-proof NBR coating is the 10% of canvas quality, by such as
The component composition of lower parts by weight：25 parts of rubber seed oil, 5 parts of bisphenol A type epoxy resin, 12 parts of chlorinated rubber, cellulose ether 4
Part, 4 parts of fluoxyprednisolone diacetate, 5,6,11,12- 4 parts of tetraphenyl naphthonaphthalenes.
The preparation method of the above-mentioned cold-proof anti-skid multifunctional safety shoe of antistatic oil-resistant, is made as follows：
(1) according to parts by weight, 40 parts of latex, 15 parts of ethyl butyrate, 6 parts of clay, 6 parts of diphenylguanidine, furfural resin 5 are taken
Part, 1 part of phosphorus mine tailing, 5 parts of butyl oxide, 1 part of barium sulfate, 1 part of sulphur, 1 part of cypress vine pine extract, it is kneaded synthesis raw stock；
(2) raw stock is loaded in die for shoe-sole, 85 kilograms of pressure is imposed to film using hydraulic press, and 110
Vulcanized under DEG C temperature conditionss, cure time 10 minutes, sole is made；
(3) coating accounts for the cold-proof NBR of canvas quality 10% on canvas, dries or dries, gluing using sewing,
The method of cutting, sole is combined with vamp, safety shoe is made.
Embodiment 5
A kind of cold-proof anti-skid multifunctional safety shoe of antistatic oil-resistant, including material for sole of shoe and vamp material, the sole material
Material is made up of the raw material of following parts by weight：40 parts of latex, 15 parts of ethyl butyrate, 6 parts of clay, 6 parts of diphenylguanidine, furfural resin
5 parts, 1 part of phosphorus mine tailing, 5 parts of butyl oxide, 1 part of barium sulfate, 1 part of sulphur；The vamp material coats cold-proof NBR by canvas
It is made.The amount of the cold-proof NBR coating is the 10% of canvas quality, is made up of the component of following parts by weight：Rubber seed oil
25 parts, 5 parts of bisphenol A type epoxy resin, 12 parts of chlorinated rubber, 4 parts of cellulose ether, 4 parts of fluoxyprednisolone diacetate, 5,6,11,
4 parts of 12- tetraphenyls naphthonaphthalene, flat 2 parts of calyx tongue extract；The flat calyx tongue extract is prepared with the following method：Using physics
Pressing method obtains the juice of its Fresh Plants, and 2-5 times of volume concentration is made.
The preparation method of the above-mentioned cold-proof anti-skid multifunctional safety shoe of antistatic oil-resistant, is made as follows：
(1) according to parts by weight, 40 parts of latex, 15 parts of ethyl butyrate, 6 parts of clay, 6 parts of diphenylguanidine, furfural resin 5 are taken
Part, 1 part of phosphorus mine tailing, 5 parts of butyl oxide, 1 part of barium sulfate, 1 part of sulphur, it is kneaded synthesis raw stock；
(2) raw stock is loaded in die for shoe-sole, 85 kilograms of pressure is imposed to film using hydraulic press, and 110
Vulcanized under DEG C temperature conditionss, cure time 10 minutes, sole is made；
(3) coating accounts for the cold-proof NBR of canvas quality 10% on canvas, dries or dries, gluing using sewing,
The method of cutting, sole is combined with vamp, safety shoe is made.
Comparative example 1
A kind of cold-proof anti-skid multifunctional safety shoe of antistatic oil-resistant, including material for sole of shoe and vamp material, the sole material
Material is made up of the raw material of following parts by weight：40 parts of latex, 15 parts of ethyl butyrate, 6 parts of clay, 6 parts of diphenylguanidine, furfural resin
5 parts, 5 parts of butyl oxide, 1 part of barium sulfate, 1 part of sulphur；The vamp material coats cold-proof NBR by canvas and is made.It is described cold-proof
The amount of NBR coating is the 10% of canvas quality, is made up of the component of following parts by weight：25 parts of rubber seed oil, bisphenol A-type
5 parts of epoxy resin, 12 parts of chlorinated rubber, 4 parts of cellulose ether, 4 parts of fluoxyprednisolone diacetate, 5,6,11,12- tetraphenyl naphtho-s
4 parts of naphthalene.
The preparation method of the above-mentioned cold-proof anti-skid multifunctional safety shoe of antistatic oil-resistant, is made as follows：
(1) according to parts by weight, 40 parts of latex, 15 parts of ethyl butyrate, 6 parts of clay, 6 parts of diphenylguanidine, furfural resin 5 are taken
Part, 5 parts of butyl oxide, 1 part of barium sulfate, 1 part of sulphur, it is kneaded synthesis raw stock；
(2) raw stock is loaded in die for shoe-sole, 85 kilograms of pressure is imposed to film using hydraulic press, and 110
Vulcanized under DEG C temperature conditionss, cure time 10 minutes, sole is made；
(3) coating accounts for the cold-proof NBR of canvas quality 10% on canvas, dries or dries, gluing using sewing,
The method of cutting, sole is combined with vamp, safety shoe is made.
Comparative example 2
A kind of cold-proof anti-skid multifunctional safety shoe of antistatic oil-resistant, including material for sole of shoe and vamp material, the sole material
Material is made up of the raw material of following parts by weight：40 parts of latex, 15 parts of ethyl butyrate, 6 parts of clay, 6 parts of diphenylguanidine, furfural resin
5 parts, 1 part of phosphorus mine tailing, 5 parts of butyl oxide, 1 part of barium sulfate, 1 part of sulphur；The vamp material coats cold-proof NBR by canvas
It is made.The amount of the cold-proof NBR coating is the 10% of canvas quality, is made up of the component of following parts by weight：Rubber seed oil
25 parts, 5 parts of bisphenol A type epoxy resin, 12 parts of chlorinated rubber, 4 parts of cellulose ether, 5,6,11,12- 4 parts of tetraphenyl naphthonaphthalenes.
The preparation method of the above-mentioned cold-proof anti-skid multifunctional safety shoe of antistatic oil-resistant, is made as follows：
(1) according to parts by weight, 40 parts of latex, 15 parts of ethyl butyrate, 6 parts of clay, 6 parts of diphenylguanidine, furfural resin 5 are taken
Part, 1 part of phosphorus mine tailing, 5 parts of butyl oxide, 1 part of barium sulfate, 1 part of sulphur, it is kneaded synthesis raw stock；
(2) raw stock is loaded in die for shoe-sole, 85 kilograms of pressure is imposed to film using hydraulic press, and 110
Vulcanized under DEG C temperature conditionss, cure time 10 minutes, sole is made；
(3) coating accounts for the cold-proof NBR of canvas quality 10% on canvas, dries or dries, gluing using sewing,
The method of cutting, sole is combined with vamp, safety shoe is made.
Comparative example 3
A kind of cold-proof anti-skid multifunctional safety shoe of antistatic oil-resistant, including material for sole of shoe and vamp material, the sole material
Material is made up of the raw material of following parts by weight：40 parts of latex, 15 parts of ethyl butyrate, 6 parts of clay, 6 parts of diphenylguanidine, furfural resin
5 parts, 1 part of phosphorus mine tailing, 5 parts of butyl oxide, 1 part of barium sulfate, 1 part of sulphur；The vamp material coats cold-proof NBR by canvas
It is made.The amount of the cold-proof NBR coating is the 10% of canvas quality, is made up of the component of following parts by weight：Rubber seed oil
25 parts, 5 parts of bisphenol A type epoxy resin, 12 parts of chlorinated rubber, 4 parts of cellulose ether, 4 parts of fluoxyprednisolone diacetate.
The preparation method of the above-mentioned cold-proof anti-skid multifunctional safety shoe of antistatic oil-resistant, is made as follows：
(1) according to parts by weight, 40 parts of latex, 15 parts of ethyl butyrate, 6 parts of clay, 6 parts of diphenylguanidine, furfural resin 5 are taken
Part, 1 part of phosphorus mine tailing, 5 parts of butyl oxide, 1 part of barium sulfate, 1 part of sulphur, it is kneaded synthesis raw stock；
(2) raw stock is loaded in die for shoe-sole, 85 kilograms of pressure is imposed to film using hydraulic press, and 110
Vulcanized under DEG C temperature conditionss, cure time 10 minutes, sole is made；
(3) coating accounts for the cold-proof NBR of canvas quality 10% on canvas, dries or dries, gluing using sewing,
The method of cutting, sole is combined with vamp, safety shoe is made.
Using standard clause GB12011-2000 4.2.1 (in 20 DEG C of temperature, relative humidity 60%, performance test voltage
6kV, duration 1min, Leakage Current are less than 1.8 to be qualified), detect embodiment 1-5 and comparative example 1-3 product sole and
The insulating properties of vamp, data are as shown in table 1：
Table 1
As can be seen from Table 1, the sole Leakage Current of comparative example 1 is not too high up to standard, compared with Example 1, other conditions phase
Together, phosphorus mine tailing is only added less, it was demonstrated that phosphorus mine tailing has the performance for promoting sole structure combinations thing to keep insulation；Vamp is let out
The electric current of comparative example 2 is not too high up to standard in dew current detecting, and compared with Example 1, other conditions are identical, only add less
Fluoxyprednisolone diacetate, it was demonstrated that fluoxyprednisolone diacetate has the performance for promoting vamp to keep insulation.
Using GB16756-1997 3.5 (under the conditions of 23 DEG C of angular test temperature, volume increase is less than 12% to be qualified),
Detect embodiment 1-5 and comparative example 1-3 product sole and the oil resistance of vamp, data are as shown in table 2：
Table 2
As can be seen from Table 2, the increase of the sole volume of embodiment 4 is less, and compared with Example 1, other conditions are identical, only
It is to add cypress vine pine extract less, it was demonstrated that cypress vine pine extract has oil resistant effect.
Store 20 days under the conditions of -20 DEG C of low temperature, then normal temperature storage one day again, detect sole tearing strength and vamp pulls
Disconnected intensity, data are as shown in table 3：
Table 3
As can be seen from Table 2, the vamp breaking strength of embodiment 5 is above embodiment 1, compared with Example 1, other conditions
It is identical, flat calyx tongue extract is only added less, illustrates the harm that flat calyx tongue extract can keep out the cold to shoe wear,
Strengthen its cold tolerance；The vamp breaking strength of comparative example 3 is above embodiment 1, and compared with Example 1, other conditions are identical, only
Only it is to add 5,6,11,12- tetraphenyl naphthonaphthalenes more, illustrates that 5,6,11,12- tetraphenyl naphthonaphthalenes can keep out the cold to footwear
The harm that face is brought, strengthen its cold tolerance.
Claims (5)
1. a kind of cold-proof anti-skid multifunctional safety shoe of antistatic oil-resistant, including material for sole of shoe and vamp material, it is characterised in that institute
Material for sole of shoe is stated to be made up of the raw material of following parts by weight：Latex 30-50 parts, ethyl butyrate 10-20 parts, clay 5-8 parts, promote
Agent 5-8 parts, furfural resin 3-8 parts, mine tailing 1-2 parts, butyl oxide 3-8 parts, barium sulfate 1-2 parts, sulphur 1-2 parts；The vamp
Material coats cold-proof NBR by canvas and is made.
2. the cold-proof anti-skid multifunctional safety shoe of antistatic oil-resistant according to claim 1, it is characterised in that the accelerator is
Diphenylguanidine or altax.
3. the cold-proof anti-skid multifunctional safety shoe of antistatic oil-resistant according to claim 1, it is characterised in that the mine tailing is
Phosphorus mine tailing, iron tailings powder, molybdic tailing powder, copper tailing powder, aluminium mine tailing, the one or more in tailing powder.
4. the cold-proof anti-skid multifunctional safety shoe of antistatic oil-resistant according to claim 1, it is characterised in that described cold-proof grease proofing
The amount of glue coating is the 5-15% of canvas quality, is made up of the component of following parts by weight：Rubber seed oil 20-30 parts, bisphenol A-type
Epoxy resin 3-8 parts, chlorinated rubber 10-15 parts, cellulose ether 2-5 parts, fluoxyprednisolone diacetate 3-5 parts, 5,6,11,12-
Tetraphenyl naphthonaphthalene 3-5 parts.
5. the preparation method of the cold-proof anti-skid multifunctional safety shoe of antistatic oil-resistant described in claim 1, it is characterised in that according to such as
Lower section method is made：
(1) according to parts by weight, latex 30-50 parts, ethyl butyrate 10-20 parts, clay 5-8 parts, accelerator 5-8 parts, furfural are taken
Resin 3-8 parts, mine tailing 1-2 parts, butyl oxide 3-8 parts, barium sulfate 1-2 parts, sulphur 1-2 parts, it is kneaded synthesis raw stock；
(2) raw stock is loaded in die for shoe-sole, 80-90 kilograms of pressure is imposed to film using hydraulic press, and in 100-
Vulcanized under 115 DEG C of temperature conditionss, cure time 8-12 minutes, sole is made；
(3) coating accounts for canvas quality 5-15% cold-proof NBR on canvas, dries or dries, gluing using sewing, cuts out
The method cut, sole is combined with vamp, safety shoe is made.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710630578.9A CN107383516B (en) | 2017-07-28 | 2017-07-28 | A kind of cold-proof anti-skid multifunctional safety shoe of antistatic oil-resistant |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710630578.9A CN107383516B (en) | 2017-07-28 | 2017-07-28 | A kind of cold-proof anti-skid multifunctional safety shoe of antistatic oil-resistant |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107383516A true CN107383516A (en) | 2017-11-24 |
| CN107383516B CN107383516B (en) | 2019-02-26 |
Family
ID=60341346
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710630578.9A Active CN107383516B (en) | 2017-07-28 | 2017-07-28 | A kind of cold-proof anti-skid multifunctional safety shoe of antistatic oil-resistant |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107383516B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111150169A (en) * | 2020-01-07 | 2020-05-15 | 宁乡陆戈鞋业科技有限公司 | Insulation shoe for electrician and manufacturing method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2306392B (en) * | 1995-10-31 | 1999-01-27 | British United Shoe Machinery | Waterproof insole material |
| CN1237609A (en) * | 1999-05-31 | 1999-12-08 | 陈锦荣 | Emulsion glue and its non-toxic application in shoe-making industry |
| CN101899176A (en) * | 2010-08-20 | 2010-12-01 | 温州市海滨秀龙鞋材有限公司 | Material for sole |
| CN104829892A (en) * | 2015-05-22 | 2015-08-12 | 罗满清 | High-wear-resistance rubber material for shoe soles and preparation method thereof |
-
2017
- 2017-07-28 CN CN201710630578.9A patent/CN107383516B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2306392B (en) * | 1995-10-31 | 1999-01-27 | British United Shoe Machinery | Waterproof insole material |
| CN1237609A (en) * | 1999-05-31 | 1999-12-08 | 陈锦荣 | Emulsion glue and its non-toxic application in shoe-making industry |
| CN101899176A (en) * | 2010-08-20 | 2010-12-01 | 温州市海滨秀龙鞋材有限公司 | Material for sole |
| CN104829892A (en) * | 2015-05-22 | 2015-08-12 | 罗满清 | High-wear-resistance rubber material for shoe soles and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111150169A (en) * | 2020-01-07 | 2020-05-15 | 宁乡陆戈鞋业科技有限公司 | Insulation shoe for electrician and manufacturing method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107383516B (en) | 2019-02-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103205026B (en) | A kind of Ultralight high-elastic rubber sole material and preparation method thereof | |
| CN106543505A (en) | A kind of high-performance acrylonitrile butadiene packing material and preparation method thereof | |
| CN103965524B (en) | A kind of low temperature resistance sole material and preparation method thereof | |
| CN101569441B (en) | Oil-resistant, insulating, acid and alkali resistant, and high temperature resistant multifunctional safety shoe | |
| CN103788439B (en) | Wide temperature range height shock-absorbing sport shoes sole rubber material and preparation method thereof | |
| CN103554561A (en) | High-hardness and extremely-cold-resistant sole material and preparation method thereof | |
| CN105694149A (en) | Oil-resistant and low-temperature-resistant material for shoe sole and method for preparing oil-resistant and low-temperature-resistant material | |
| CN104804227A (en) | Cellulose-modified light rubber material for sole and preparation method of cellulose-modified light rubber material | |
| CN105348573A (en) | Rubber composition improving anti-reversion performance and application thereof | |
| CN107383516B (en) | A kind of cold-proof anti-skid multifunctional safety shoe of antistatic oil-resistant | |
| CN102993492A (en) | High wear-resisting rubber and preparation method thereof | |
| CN114133589A (en) | Novel butyronitrile butadiene styrene composite latex dipping slurry and preparation method thereof | |
| CN104961933A (en) | Anti-slip wear-resistant rubber | |
| CN101524195A (en) | Multifunctional safety shoes with oil resistance, insulation, acid and alkali resistance and high temperature resistance | |
| CN108864615A (en) | A kind of wear-resisting resistance to migration high resiliency PVC bottom leather imitation material | |
| CN105237824B (en) | Lightweight rain boot and making method thereof | |
| CN103665451A (en) | Molded rubber outsole without exhaust hole and preparation method of molded rubber outsole | |
| CN105670056A (en) | High-strength low-temperature-resistant material for shoes and preparation method of high-strength low-temperature-resistant material | |
| CN108084517A (en) | A kind of rubber for meeting oil expansion and preparation method thereof | |
| CN104774348A (en) | Rubber material added with heat stabilizer (HS-80) and preparation method thereof | |
| CN105330911A (en) | Abrasion-resistant environment-friendly rubber sole and preparing method thereof | |
| CN105218886A (en) | At the bottom of the extremely cold-resistant high elasticity abrasion-proof glue of one | |
| CN108329538B (en) | Rubber shoe sole | |
| CN102363649A (en) | Cis-1,4-polyisoprene rubber | |
| CN106046469A (en) | All-steel radial tire tread rubber |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |