CN107383515A - A kind of novel high polymer composite and preparation method thereof - Google Patents
A kind of novel high polymer composite and preparation method thereof Download PDFInfo
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- CN107383515A CN107383515A CN201710729999.7A CN201710729999A CN107383515A CN 107383515 A CN107383515 A CN 107383515A CN 201710729999 A CN201710729999 A CN 201710729999A CN 107383515 A CN107383515 A CN 107383515A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/222—Magnesia, i.e. magnesium oxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Abstract
The present invention relates to a kind of novel high polymer composite and preparation method thereof, raw material constituent is made up of following ratio in parts by weight：68 parts of calcium stearate, 57 parts of zinc stearate, 36 parts of TBHQ, 48 parts of octadecanoid acid, 26 parts of papain, 6 10 parts of silicone oil, 59 parts of cocoanut fatty acid diethanolamide, 25 parts of PPD, 3 10 parts of AEO, 8 10 parts of deionized water.Material of the present invention is easy to get, and cost is low, environment-friendly and green, reduces frictional behaviour, reduces resistance, easily absorbs, and accelerates lubrication speed, improves wearability, improve wettability, strengthen surface tension, improves toughness, emulsifying rate is fast, and antioxidant effect is good, increases the service life.
Description
Technical field
The present invention relates to field of compound material, and in particular to a kind of novel high polymer composite and preparation method thereof.
Background technology
Composite with fully having proved the advantages of exceeding conventional construction material, particularly with extremely low density of material
Superior mechanical properties are provided.Therefore, become increasingly prevalent using such material, their application field
From " industry " and " motion and leisure " to high performance turbine component.Prepreg includes the fiber impregnated with resin such as epoxy resin
Arrangement, the prepreg are widely used in as production
Composite.This technique is in production process generally use backing sheets, but other abandon calcellation after the completion of producing, and cause one
Determine the waste of degree, improve cost, so needing new technique to replace.
The content of the invention
A kind of novel high polymer composite and its preparation are provided the invention aims to overcome the shortcomings of the above
Method.
Technical scheme includes：A kind of novel high polymer composite and preparation method thereof, raw material constituent
It is made up of in parts by weight following ratio：Rubber 30-40 parts, graphite 6-10 parts, magnesia 3-5 parts, aramid fiber 6-10 parts, ring
Oxygen tree fat 20-30 parts, polyamide 4-8 parts, silicone oil 6-12 parts, phenolic resin 10-15 parts, ethanol 30-40 parts, phytic acid 3-
5 parts, helium 20-30 parts.
Further improvement of the present invention is：Its preparation method is as follows：
A, rubber, epoxy resin, phenolic resin and polyamide are added in ethanol and carries out polycondensation reaction, temperature is set to 360-480
DEG C, pressure 1.2-1.4MPa, band obtains mixture A after being cooled to room temperature；
B, under normal temperature and pressure, graphite, magnesia, aromatic hydrocarbons fiber are added in silicone oil and be stirred, phytic acid is added and mixes
Close, stir speed (S.S.) 600-800r/min, obtain mixture B；
C, it is carrier by helium by mixture B, high pressure is packed into mixture A, pressure 1.5-1.8MPa, extrude, stretch,
Forging, forging stress pressure is 250-300N/cm2, obtain product.
Beneficial effects of the present invention：Material of the present invention is easy to get, and cost is low, environment-friendly and green, and wearing coefficient is high, anti-pressure ability
By force, good from profit effect, high temperature resistant, high pressure, oxidation resistance is strong, and internal viscosity is big, compact-sized, and density is small, and light weight is plastic
Property is strong, applied widely.
Embodiment：
In order to deepen the understanding of the present invention, below in conjunction with embodiment, the invention will be further described, and the embodiment is only used
In explaining the present invention, it is not intended to limit the scope of the present invention..
Embodiment 1
A kind of novel high polymer composite and preparation method thereof, raw material constituent is made up of following ratio in parts by weight：
32 parts of rubber, 7 parts of graphite, 4 parts of magnesia, 9 parts of aramid fiber, 28 parts of epoxy resin, polyamide 6 part, 10 parts of silicone oil, phenolic aldehyde tree
14 parts of fat, 36 parts of ethanol, 5 parts of phytic acid, 30 parts of helium.
Its preparation method is as follows：
A, rubber, epoxy resin, phenolic resin and polyamide are added in ethanol and carries out polycondensation reaction, temperature is set to 450 DEG C, pressure
Power is 1.3MPa, and band obtains mixture A after being cooled to room temperature；
B, under normal temperature and pressure, graphite, magnesia, aromatic hydrocarbons fiber are added in silicone oil and be stirred, phytic acid is added and mixes
Close, stir speed (S.S.) 650r/min, obtain mixture B；
C, it is carrier by helium by mixture B, high pressure is packed into mixture A, pressure 1.7MPa, extruding, stretching, forging
Make, forging stress pressure is 280N/cm2, obtain product.
Embodiment 2
A kind of novel high polymer composite and preparation method thereof, raw material constituent is made up of following ratio in parts by weight：
40 parts of rubber, 6 parts of graphite, 3 parts of magnesia, 10 parts of aramid fiber, 20 parts of epoxy resin, 8 parts of polyamide, 12 parts of silicone oil, phenolic aldehyde
10 parts of resin, 30 parts of ethanol, 3 parts of phytic acid, 20 parts of helium.
Its preparation method is as follows：
A, rubber, epoxy resin, phenolic resin and polyamide are added in ethanol and carries out polycondensation reaction, temperature is set to 360-480
DEG C, pressure 1.2-1.4MPa, band obtains mixture A after being cooled to room temperature；
B, under normal temperature and pressure, graphite, magnesia, aromatic hydrocarbons fiber are added in silicone oil and be stirred, phytic acid is added and mixes
Close, stir speed (S.S.) 600r/min, obtain mixture B；
C, it is carrier by helium by mixture B, high pressure is packed into mixture A, pressure 1.5MPa, extruding, stretching, forging
Make, forging stress pressure is 250N/cm2, obtain product.
Embodiment 3
A kind of novel high polymer composite and preparation method thereof, raw material constituent is made up of following ratio in parts by weight：
40 parts of rubber, 6 parts of graphite, 5 parts of magnesia, 6 parts of aramid fiber, 20 parts of epoxy resin, 8 parts of polyamide, 6 parts of silicone oil, phenolic aldehyde tree
15 parts of fat, 30 parts of ethanol, 3 parts of phytic acid, 30 parts of helium.
Its preparation method is as follows：
A, rubber, epoxy resin, phenolic resin and polyamide are added in ethanol and carries out polycondensation reaction, temperature is set to 480 DEG C, pressure
Power is 1.2MPa, and band obtains mixture A after being cooled to room temperature；
B, under normal temperature and pressure, graphite, magnesia, aromatic hydrocarbons fiber are added in silicone oil and be stirred, phytic acid is added and mixes
Close, stir speed (S.S.) 800r/min, obtain mixture B；
C, it is carrier by helium by mixture B, high pressure is packed into mixture A, pressure 1.8MPa, extruding, stretching, forging
Make, forging stress pressure is 300N/cm2, obtain product.
Embodiment 4
A kind of novel high polymer composite and preparation method thereof, raw material constituent is made up of following ratio in parts by weight：
34 parts of rubber, 8 parts of graphite, 4 parts of magnesia, 9 parts of aramid fiber, 22 parts of epoxy resin, 5 parts of polyamide, 10 parts of silicone oil, phenolic aldehyde tree
13 parts of fat, 35 parts of ethanol, 4 parts of phytic acid, 26 parts of helium.
Its preparation method is as follows：
A, rubber, epoxy resin, phenolic resin and polyamide are added in ethanol and carries out polycondensation reaction, temperature is set to 400 DEG C, pressure
Power is 1.3MPa, and band obtains mixture A after being cooled to room temperature；
B, under normal temperature and pressure, graphite, magnesia, aromatic hydrocarbons fiber are added in silicone oil and be stirred, phytic acid is added and mixes
Close, stir speed (S.S.) 650r/min, obtain mixture B；
C, it is carrier by helium by mixture B, high pressure is packed into mixture A, pressure 1.7MPa, extruding, stretching, forging
Make, forging stress pressure is 260N/cm2, obtain product.
Embodiment 5
A kind of novel high polymer composite and preparation method thereof, raw material constituent is made up of following ratio in parts by weight：
38 parts of rubber, 9 parts of graphite, 4 parts of magnesia, 6 parts of aramid fiber, 24 parts of epoxy resin, polyamide 6 part, 8 parts of silicone oil, phenolic aldehyde tree
11 parts of fat, 34 parts of ethanol, 5 parts of phytic acid, 28 parts of helium.
Its preparation method is as follows：
A, rubber, epoxy resin, phenolic resin and polyamide are added in ethanol and carries out polycondensation reaction, temperature is set to 420 DEG C, pressure
Power is 1.2MPa, and band obtains mixture A after being cooled to room temperature；
B, under normal temperature and pressure, graphite, magnesia, aromatic hydrocarbons fiber are added in silicone oil and be stirred, phytic acid is added and mixes
Close, stir speed (S.S.) 700r/min, obtain mixture B；
C, it is carrier by helium by mixture B, high pressure is packed into mixture A, pressure 1.6MPa, extruding, stretching, forging
Make, forging stress pressure is 280N/cm2, obtain product.
In above example, embodiment 1 is most preferred embodiment, and from effect number is moistened, tensile strength is big, wearability is high, resistance to height
Warm nature can be good；By helium it is carrier in step C, improves stability, ensures that its fills uniformity.
Explanation embodiments of the present invention are the foregoing is only, are not intended to limit the invention, for the technology of this area
For personnel, within the spirit and principles of the invention, any modification, equivalent substitution and improvements made etc., it should be included in
Within protection scope of the present invention.
Claims (2)
- A kind of 1. novel high polymer composite and preparation method thereof, it is characterised in that：Raw material constituent in parts by weight by Following ratio composition：Rubber 30-40 parts, graphite 6-10 parts, magnesia 3-5 parts, aramid fiber 6-10 parts, epoxy resin 20-30 Part, polyamide 4-8 parts, silicone oil 6-12 parts, phenolic resin 10-15 parts, ethanol 30-40 parts, phytic acid 3-5 parts, helium 20- 30 parts.
- A kind of 2. novel high polymer composite according to claim 1 and preparation method thereof, it is characterised in that：It is prepared Method is as follows：A, rubber, epoxy resin, phenolic resin and polyamide are added in ethanol and carries out polycondensation reaction, temperature is set to 360-480 DEG C, pressure 1.2-1.4MPa, band obtains mixture A after being cooled to room temperature；B, under normal temperature and pressure, graphite, magnesia, aromatic hydrocarbons fiber are added in silicone oil and be stirred, phytic acid is added and mixes Close, stir speed (S.S.) 600-800r/min, obtain mixture B；C, it is carrier by helium by mixture B, high pressure is packed into mixture A, pressure 1.5-1.8MPa, extrude, stretch, Forging, forging stress pressure is 250-300N/cm2, obtain product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710729999.7A CN107383515A (en) | 2017-08-23 | 2017-08-23 | A kind of novel high polymer composite and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710729999.7A CN107383515A (en) | 2017-08-23 | 2017-08-23 | A kind of novel high polymer composite and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
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| CN107383515A true CN107383515A (en) | 2017-11-24 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201710729999.7A Withdrawn CN107383515A (en) | 2017-08-23 | 2017-08-23 | A kind of novel high polymer composite and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108373589A (en) * | 2018-03-13 | 2018-08-07 | 无锡嘉弘塑料科技有限公司 | A kind of low-friction coefficient modification engineering material |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104788791A (en) * | 2015-04-30 | 2015-07-22 | 青岛海蓝海洋复合功能材料科技有限公司 | High-stability low-temperature-resistant plastic |
| CN106084337A (en) * | 2016-08-15 | 2016-11-09 | 合肥万向钱潮汽车零部件有限公司 | The sealing rubber ring of the automatic riveting press equipment of brake-shoe |
| CN106763363A (en) * | 2016-12-27 | 2017-05-31 | 柳州市金岭汽车配件厂 | Automobile brake sheet |
| CN106833252A (en) * | 2016-12-05 | 2017-06-13 | 天长市优信电器设备有限公司 | A kind of wear-resistant coating of aluminum charger case |
-
2017
- 2017-08-23 CN CN201710729999.7A patent/CN107383515A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104788791A (en) * | 2015-04-30 | 2015-07-22 | 青岛海蓝海洋复合功能材料科技有限公司 | High-stability low-temperature-resistant plastic |
| CN106084337A (en) * | 2016-08-15 | 2016-11-09 | 合肥万向钱潮汽车零部件有限公司 | The sealing rubber ring of the automatic riveting press equipment of brake-shoe |
| CN106833252A (en) * | 2016-12-05 | 2017-06-13 | 天长市优信电器设备有限公司 | A kind of wear-resistant coating of aluminum charger case |
| CN106763363A (en) * | 2016-12-27 | 2017-05-31 | 柳州市金岭汽车配件厂 | Automobile brake sheet |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108373589A (en) * | 2018-03-13 | 2018-08-07 | 无锡嘉弘塑料科技有限公司 | A kind of low-friction coefficient modification engineering material |
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Application publication date: 20171124 |
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