CN107383511A - A kind of corrosion resistance covers membrane material - Google Patents
A kind of corrosion resistance covers membrane material Download PDFInfo
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- CN107383511A CN107383511A CN201710735309.9A CN201710735309A CN107383511A CN 107383511 A CN107383511 A CN 107383511A CN 201710735309 A CN201710735309 A CN 201710735309A CN 107383511 A CN107383511 A CN 107383511A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L11/00—Compositions of homopolymers or copolymers of chloroprene
- C08L11/02—Latex
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical Kinetics & Catalysis (AREA)
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- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
The invention discloses a kind of corrosion resistance to cover membrane material, and it is made up of the raw material of following parts by weight：20 30 parts of polychloroprene latex, 10 20 parts of polybutadiene latex, 8 15 parts of ACM, 5 12 parts of tributoxyethyl phosphate, 37 parts of acroleic acid polyurethane, 39 parts of trioctyl trimellitate (TOTM), 6 12 parts of curing resin, 5 10 parts of pentaerythrite, 13 parts of Cosan, 48 parts of Tissuemat E, 7 14 parts of hexamethylenetetramine, 26 parts of diatomite, 5 13 parts of tristerin, 26 parts of zinc diethyl dithiocarbamate, 58 parts of polybutadiene, poly- 3 12 parts of terephthalyl alcohol, 15 parts of zinc stearate, 13 parts of organo montmorillonite, 36 parts of aromatic naphtha, 14 parts of age resistor.The covering membrane material has good corrosion resistance and stretch-resistance, is hardly damaged during use.
Description
Technical field
The invention belongs to technical field of composite materials, more particularly to a kind of corrosion resistance covering membrane material.
Background technology
Film is typically made of polyvinyl chloride, polyethylene, polypropylene, polystyrene and other resins, for pack or
As coating layer.It is well known that coating layer is substantially all in field, easily being corroded by surrounding environment corrosive substance
Effect, in addition, people can spread out in placement process, the tensile resistance difference for covering membrane material is then easily damaged, and is entered
And using effect is influenceed, later stage replacement cost can also greatly improve.
The content of the invention
It is an object of the invention to provide a kind of corrosion resistance to cover membrane material, and it can be effectively solved in above-mentioned background technology
The technical problem being previously mentioned.
To achieve the above object, the present invention provides following technical scheme：
A kind of corrosion resistance covering membrane material is made up of the raw material of following parts by weight：Polychloroprene latex 20-30 parts, polybutadiene
Alkene latex 10-20 parts, ACM 8-15 parts, tributoxyethyl phosphate 5-12 parts, acroleic acid polyurethane 3-7 parts, partially
The monooctyl ester 3-9 parts of benzenetricarboxylic acid three, curing resin 6-12 parts, pentaerythrite 5-10 parts, Cosan 1-3 parts, Tissuemat E 4-8 parts, six
Methine tetramine 7-14 parts, diatomite 2-6 parts, tristerin 5-13 parts, zinc diethyl dithiocarbamate 2-6 parts,
Polybutadiene 5-8 parts, poly- terephthalyl alcohol 3-12 parts, zinc stearate 1-5 parts, organo montmorillonite 1-3 parts, aromatic naphtha 3-6 parts, prevent
Old agent 1-4 parts.
Preferably, described corrosion resistance covering membrane material is made up of the raw material of following parts by weight：22 parts of polychloroprene latex,
12 parts of polybutadiene latex, 9 parts of ACM, 11 parts of tributoxyethyl phosphate, 5 parts of acroleic acid polyurethane, inclined benzene three
Sour 6 parts of three monooctyl ester, 6 parts of curing resin, 8 parts of pentaerythrite, 1.6 parts of Cosan, 5 parts of Tissuemat E, 10 parts of hexamethylenetetramine,
4 parts of diatomite, 11 parts of tristerin, 3 parts of zinc diethyl dithiocarbamate, 7 parts of polybutadiene, poly- terephthalyl alcohol
8 parts, 1.8 parts of zinc stearate, 1 part of organo montmorillonite, 4.5 parts of aromatic naphtha, 2.8 parts of age resistor.
Preferably, described corrosion resistance covering membrane material is made up of the raw material of following parts by weight：24 parts of polychloroprene latex,
13 parts of polybutadiene latex, 11 parts of ACM, 7 parts of tributoxyethyl phosphate, 4 parts of acroleic acid polyurethane, inclined benzene three
Sour 4 parts of three monooctyl ester, 9 parts of curing resin, 9 parts of pentaerythrite, 1.3 parts of Cosan, 5 parts of Tissuemat E, 8 parts of hexamethylenetetramine,
5 parts of diatomite, 6 parts of tristerin, 5 parts of zinc diethyl dithiocarbamate, 8 parts of polybutadiene, poly- terephthalyl alcohol
10 parts, 3.5 parts of zinc stearate, 1.5 parts of organo montmorillonite, 3 parts of aromatic naphtha, 3 parts of age resistor.
Preferably, described corrosion resistance covering membrane material is made up of the raw material of following parts by weight：30 parts of polychloroprene latex,
11 parts of polybutadiene latex, 10 parts of ACM, 9 parts of tributoxyethyl phosphate, 6 parts of acroleic acid polyurethane, inclined benzene three
Sour 9 parts of three monooctyl ester, 6 parts of curing resin, 6 parts of pentaerythrite, 3 parts of Cosan, 5 parts of Tissuemat E, 13 parts of hexamethylenetetramine, silicon
3.6 parts of diatomaceous earth, 12 parts of tristerin, 3 parts of zinc diethyl dithiocarbamate, 7 parts of polybutadiene, poly- terephthalyl alcohol
11 parts, 4 parts of zinc stearate, 1.8 parts of organo montmorillonite, 5 parts of aromatic naphtha, 2 parts of age resistor.
The preparation method of the corrosion resistance covering membrane material, comprises the following steps：
(1) each raw material components are weighed according to ratio of weight and number；
(2) by polychloroprene latex, polybutadiene latex, ACM, tributoxyethyl phosphate, the poly- ammonia of acrylic acid
Ester, trioctyl trimellitate (TOTM), curing resin and tristerin add kneading machine, and melting temperature is controlled at 105-115 DEG C, is mixed
The refining time is 30-35 minutes；
(3) pentaerythrite, Cosan, Tissuemat E, hexamethylenetetramine, diatomite, diethyl-dithio ammonia are added
Base zinc formate, polybutadiene, poly- terephthalyl alcohol, zinc stearate, organo montmorillonite, aromatic naphtha and age resistor mixing, are kneaded temperature
At 120-118 DEG C, mixing time is 20-25 minutes, obtains raw mixture for degree control；
(4) raw mixture in step (3) is added in double screw extruder and is blended, extrudes, and be granulated, obtained
Corrosion resistance covering membrane material into the present invention.
Compared with prior art, the beneficial effects of the invention are as follows：
Corrosion resistance covering membrane material in the present invention mainly contains polychloroprene latex, polybutadiene latex, acrylate rubber
Glue, tributoxyethyl phosphate, while also it is specifically added Cosan, Tissuemat E, hexamethylenetetramine, diatomite, diethyl
The raw materials such as zinc dithiocarbamate, zinc stearate, organo montmorillonite, aromatic naphtha, each advantages of reasonable raw material components collocation, and manufacturing
During control the temperature and time of mixing, and then cause corrosion resistance covering membrane material have good corrosion resistance and
The advantages that stretch-resistance.
Embodiment
Technical scheme is described in detail with reference to embodiment, but protection domain is not limited thereto.
Embodiment one：
A kind of corrosion resistance covering membrane material is made up of the raw material of following parts by weight：23 parts of polychloroprene latex, polybutadiene
13 parts of latex, 9 parts of ACM, 9 parts of tributoxyethyl phosphate, 7 parts of acroleic acid polyurethane, trioctyl trimellitate (TOTM) 7
Part, 11 parts of curing resin, 8 parts of pentaerythrite, 1.8 parts of Cosan, 5 parts of Tissuemat E, 11 parts of hexamethylenetetramine, diatomite 5
Part, 12 parts of tristerin, 5 parts of zinc diethyl dithiocarbamate, 7 parts of polybutadiene, poly- 12 parts of terephthalyl alcohol, firmly
3 parts of resin acid zinc, 2 parts of organo montmorillonite, 4 parts of aromatic naphtha, 4 parts of age resistor.
The preparation method of the corrosion resistance covering membrane material, comprises the following steps：
(1) each raw material components are weighed according to ratio of weight and number；
(2) by polychloroprene latex, polybutadiene latex, ACM, tributoxyethyl phosphate, the poly- ammonia of acrylic acid
Ester, trioctyl trimellitate (TOTM), curing resin and tristerin add kneading machine, and melting temperature is controlled at 105-115 DEG C, is mixed
The refining time is 30-35 minutes；
(3) pentaerythrite, Cosan, Tissuemat E, hexamethylenetetramine, diatomite, diethyl-dithio ammonia are added
Base zinc formate, polybutadiene, poly- terephthalyl alcohol, zinc stearate, organo montmorillonite, aromatic naphtha and age resistor mixing, are kneaded temperature
At 120-118 DEG C, mixing time is 20-25 minutes, obtains raw mixture for degree control；
(4) raw mixture in step (3) is added in double screw extruder and is blended, extrudes, and be granulated, obtained
Corrosion resistance covering membrane material into the present invention.
Embodiment two：
A kind of corrosion resistance covering membrane material is made up of the raw material of following parts by weight：30 parts of polychloroprene latex, polybutadiene
11 parts of latex, 10 parts of ACM, 9 parts of tributoxyethyl phosphate, 6 parts of acroleic acid polyurethane, trioctyl trimellitate (TOTM) 9
Part, 6 parts of curing resin, 6 parts of pentaerythrite, 3 parts of Cosan, 5 parts of Tissuemat E, 13 parts of hexamethylenetetramine, diatomite 3.6
Part, 12 parts of tristerin, 3 parts of zinc diethyl dithiocarbamate, 7 parts of polybutadiene, poly- 11 parts of terephthalyl alcohol, firmly
4 parts of resin acid zinc, 1.8 parts of organo montmorillonite, 5 parts of aromatic naphtha, 2 parts of age resistor.
The preparation method of the corrosion resistance covering membrane material, comprises the following steps：
(1) each raw material components are weighed according to ratio of weight and number；
(2) by polychloroprene latex, polybutadiene latex, ACM, tributoxyethyl phosphate, the poly- ammonia of acrylic acid
Ester, trioctyl trimellitate (TOTM), curing resin and tristerin add kneading machine, and melting temperature is controlled at 105-115 DEG C, is mixed
The refining time is 30-35 minutes；
(3) pentaerythrite, Cosan, Tissuemat E, hexamethylenetetramine, diatomite, diethyl-dithio ammonia are added
Base zinc formate, polybutadiene, poly- terephthalyl alcohol, zinc stearate, organo montmorillonite, aromatic naphtha and age resistor mixing, are kneaded temperature
At 120-118 DEG C, mixing time is 20-25 minutes, obtains raw mixture for degree control；
(4) raw mixture in step (3) is added in double screw extruder and is blended, extrudes, and be granulated, obtained
Corrosion resistance covering membrane material into the present invention.
Embodiment three：
A kind of corrosion resistance covering membrane material is made up of the raw material of following parts by weight：27 parts of polychloroprene latex, polybutadiene
12 parts of latex, 10 parts of ACM, 8 parts of tributoxyethyl phosphate, 5 parts of acroleic acid polyurethane, trioctyl trimellitate (TOTM) 5
Part, 8 parts of curing resin, 9 parts of pentaerythrite, 2.5 parts of Cosan, 6 parts of Tissuemat E, 11 parts of hexamethylenetetramine, diatomite 4
Part, 8 parts of tristerin, 4 parts of zinc diethyl dithiocarbamate, 7 parts of polybutadiene, poly- 12 parts of terephthalyl alcohol, firmly
3 parts of resin acid zinc, 1 part of organo montmorillonite, 3 parts of aromatic naphtha, 3 parts of age resistor.
The preparation method of the corrosion resistance covering membrane material, comprises the following steps：
(1) each raw material components are weighed according to ratio of weight and number；
(2) by polychloroprene latex, polybutadiene latex, ACM, tributoxyethyl phosphate, the poly- ammonia of acrylic acid
Ester, trioctyl trimellitate (TOTM), curing resin and tristerin add kneading machine, and melting temperature is controlled at 105-115 DEG C, is mixed
The refining time is 30-35 minutes；
(3) pentaerythrite, Cosan, Tissuemat E, hexamethylenetetramine, diatomite, diethyl-dithio ammonia are added
Base zinc formate, polybutadiene, poly- terephthalyl alcohol, zinc stearate, organo montmorillonite, aromatic naphtha and age resistor mixing, are kneaded temperature
At 120-118 DEG C, mixing time is 20-25 minutes, obtains raw mixture for degree control；
(4) raw mixture in step (3) is added in double screw extruder and is blended, extrudes, and be granulated, obtained
Corrosion resistance covering membrane material into the present invention.
Example IV：
A kind of corrosion resistance covering membrane material is made up of the raw material of following parts by weight：25 parts of polychloroprene latex, polybutadiene
15 parts of latex, 15 parts of ACM, 6 parts of tributoxyethyl phosphate, 5 parts of acroleic acid polyurethane, trioctyl trimellitate (TOTM) 7
Part, 11 parts of curing resin, 9 parts of pentaerythrite, 1.8 parts of Cosan, 6 parts of Tissuemat E, 12 parts of hexamethylenetetramine, diatomite
4.5 parts, 9 parts of tristerin, 6 parts of zinc diethyl dithiocarbamate, 8 parts of polybutadiene, poly- 11 parts of terephthalyl alcohol,
3.6 parts of zinc stearate, 2.8 parts of organo montmorillonite, 5 parts of aromatic naphtha, 2 parts of age resistor.
The preparation method of the corrosion resistance covering membrane material, comprises the following steps：
(1) each raw material components are weighed according to ratio of weight and number；
(2) by polychloroprene latex, polybutadiene latex, ACM, tributoxyethyl phosphate, the poly- ammonia of acrylic acid
Ester, trioctyl trimellitate (TOTM), curing resin and tristerin add kneading machine, and melting temperature is controlled at 105-115 DEG C, is mixed
The refining time is 30-35 minutes；
(3) pentaerythrite, Cosan, Tissuemat E, hexamethylenetetramine, diatomite, diethyl-dithio ammonia are added
Base zinc formate, polybutadiene, poly- terephthalyl alcohol, zinc stearate, organo montmorillonite, aromatic naphtha and age resistor mixing, are kneaded temperature
At 120-118 DEG C, mixing time is 20-25 minutes, obtains raw mixture for degree control；
(4) raw mixture in step (3) is added in double screw extruder and is blended, extrudes, and be granulated, obtained
Corrosion resistance covering membrane material into the present invention.
Embodiment five：
A kind of corrosion resistance covering membrane material is made up of the raw material of following parts by weight：22 parts of polychloroprene latex, polybutadiene
12 parts of latex, 9 parts of ACM, 11 parts of tributoxyethyl phosphate, 5 parts of acroleic acid polyurethane, trioctyl trimellitate (TOTM) 6
Part, 6 parts of curing resin, 8 parts of pentaerythrite, 1.6 parts of Cosan, 5 parts of Tissuemat E, 10 parts of hexamethylenetetramine, diatomite 4
Part, 11 parts of tristerin, 3 parts of zinc diethyl dithiocarbamate, 7 parts of polybutadiene, poly- 8 parts of terephthalyl alcohol, firmly
1.8 parts of resin acid zinc, 1 part of organo montmorillonite, 4.5 parts of aromatic naphtha, 2.8 parts of age resistor.
The preparation method of the corrosion resistance covering membrane material, comprises the following steps：
(1) each raw material components are weighed according to ratio of weight and number；
(2) by polychloroprene latex, polybutadiene latex, ACM, tributoxyethyl phosphate, the poly- ammonia of acrylic acid
Ester, trioctyl trimellitate (TOTM), curing resin and tristerin add kneading machine, and melting temperature is controlled at 105-115 DEG C, is mixed
The refining time is 30-35 minutes；
(3) pentaerythrite, Cosan, Tissuemat E, hexamethylenetetramine, diatomite, diethyl-dithio ammonia are added
Base zinc formate, polybutadiene, poly- terephthalyl alcohol, zinc stearate, organo montmorillonite, aromatic naphtha and age resistor mixing, are kneaded temperature
At 120-118 DEG C, mixing time is 20-25 minutes, obtains raw mixture for degree control；
(4) raw mixture in step (3) is added in double screw extruder and is blended, extrudes, and be granulated, obtained
Corrosion resistance covering membrane material into the present invention.
Embodiment six：
A kind of corrosion resistance covering membrane material is made up of the raw material of following parts by weight：24 parts of polychloroprene latex, polybutadiene
13 parts of latex, 11 parts of ACM, 7 parts of tributoxyethyl phosphate, 4 parts of acroleic acid polyurethane, trioctyl trimellitate (TOTM) 4
Part, 9 parts of curing resin, 9 parts of pentaerythrite, 1.3 parts of Cosan, 5 parts of Tissuemat E, 8 parts of hexamethylenetetramine, 5 parts of diatomite,
6 parts of tristerin, 5 parts of zinc diethyl dithiocarbamate, 8 parts of polybutadiene, poly- 10 parts of terephthalyl alcohol, stearic acid
3.5 parts of zinc, 1.5 parts of organo montmorillonite, 3 parts of aromatic naphtha, 3 parts of age resistor.
The preparation method of the corrosion resistance covering membrane material, comprises the following steps：
(1) each raw material components are weighed according to ratio of weight and number；
(2) by polychloroprene latex, polybutadiene latex, ACM, tributoxyethyl phosphate, the poly- ammonia of acrylic acid
Ester, trioctyl trimellitate (TOTM), curing resin and tristerin add kneading machine, and melting temperature is controlled at 105-115 DEG C, is mixed
The refining time is 30-35 minutes；
(3) pentaerythrite, Cosan, Tissuemat E, hexamethylenetetramine, diatomite, diethyl-dithio ammonia are added
Base zinc formate, polybutadiene, poly- terephthalyl alcohol, zinc stearate, organo montmorillonite, aromatic naphtha and age resistor mixing, are kneaded temperature
At 120-118 DEG C, mixing time is 20-25 minutes, obtains raw mixture for degree control；
(4) raw mixture in step (3) is added in double screw extruder and is blended, extrudes, and be granulated, obtained
Corrosion resistance covering membrane material into the present invention.
Finally illustrate, the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted, although with reference to compared with
The present invention is described in detail good embodiment, it will be understood by those within the art that, can be to the skill of the present invention
Art scheme is modified or equivalent substitution, and without departing from the objective and scope of the technical program, it all should cover in the present invention
Right among.
Claims (4)
1. a kind of corrosion resistance covers membrane material, it is characterised in that is made up of the raw material of following parts by weight：Polychloroprene latex 20-30
Part, polybutadiene latex 10-20 parts, ACM 8-15 parts, tributoxyethyl phosphate 5-12 parts, acroleic acid polyurethane
3-7 parts, trioctyl trimellitate (TOTM) 3-9 parts, curing resin 6-12 parts, pentaerythrite 5-10 parts, Cosan 1-3 parts, Tissuemat E
4-8 parts, hexamethylenetetramine 7-14 parts, diatomite 2-6 parts, tristerin 5-13 parts, diethyldithiocar bamic acid
Zinc 2-6 parts, polybutadiene 5-8 parts, poly- terephthalyl alcohol 3-12 parts, zinc stearate 1-5 parts, organo montmorillonite 1-3 parts, aromatic naphtha
3-6 parts, age resistor 1-4 parts.
2. a kind of corrosion resistance covering membrane material according to claim 1, it is characterised in that by the raw material of following parts by weight
It is made：22 parts of polychloroprene latex, 12 parts of polybutadiene latex, 9 parts of ACM, 11 parts of tributoxyethyl phosphate, propylene
Sour 5 parts of polyurethane, 6 parts of trioctyl trimellitate (TOTM), 6 parts of curing resin, 8 parts of pentaerythrite, 1.6 parts of Cosan, Tissuemat E 5
Part, 10 parts of hexamethylenetetramine, 4 parts of diatomite, 11 parts of tristerin, 3 parts of zinc diethyl dithiocarbamate, poly- fourth
7 parts of diene, poly- 8 parts of terephthalyl alcohol, 1.8 parts of zinc stearate, 1 part of organo montmorillonite, 4.5 parts of aromatic naphtha, 2.8 parts of age resistor.
3. a kind of corrosion resistance covering membrane material according to claim 1, it is characterised in that by the raw material of following parts by weight
It is made：24 parts of polychloroprene latex, 13 parts of polybutadiene latex, 11 parts of ACM, 7 parts of tributoxyethyl phosphate, propylene
Sour 4 parts of polyurethane, 4 parts of trioctyl trimellitate (TOTM), 9 parts of curing resin, 9 parts of pentaerythrite, 1.3 parts of Cosan, Tissuemat E 5
Part, 8 parts of hexamethylenetetramine, 5 parts of diatomite, 6 parts of tristerin, 5 parts of zinc diethyl dithiocarbamate, polybutadiene
8 parts of alkene, poly- 10 parts of terephthalyl alcohol, 3.5 parts of zinc stearate, 1.5 parts of organo montmorillonite, 3 parts of aromatic naphtha, 3 parts of age resistor.
4. a kind of corrosion resistance covering membrane material according to claim 1, it is characterised in that by the raw material of following parts by weight
It is made：30 parts of polychloroprene latex, 11 parts of polybutadiene latex, 10 parts of ACM, 9 parts of tributoxyethyl phosphate, propylene
Sour 6 parts of polyurethane, 9 parts of trioctyl trimellitate (TOTM), 6 parts of curing resin, 6 parts of pentaerythrite, 3 parts of Cosan, 5 parts of Tissuemat E,
13 parts of hexamethylenetetramine, 3.6 parts of diatomite, 12 parts of tristerin, 3 parts of zinc diethyl dithiocarbamate, poly- fourth
7 parts of diene, poly- 11 parts of terephthalyl alcohol, 4 parts of zinc stearate, 1.8 parts of organo montmorillonite, 5 parts of aromatic naphtha, 2 parts of age resistor.
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| CN201710735309.9A CN107383511A (en) | 2017-08-24 | 2017-08-24 | A kind of corrosion resistance covers membrane material |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710735309.9A CN107383511A (en) | 2017-08-24 | 2017-08-24 | A kind of corrosion resistance covers membrane material |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1164813A (en) * | 1995-08-10 | 1997-11-12 | 阿普尔顿纸张公司 | Mulching composite |
| CN1209443A (en) * | 1998-09-17 | 1999-03-03 | 李嘉琛 | Spray of invisible mulch-film |
| CN104144954A (en) * | 2012-03-02 | 2014-11-12 | 电气化学工业株式会社 | Polychloroprene latex, polychloroprene latex composition, and molded article |
| CN105254962A (en) * | 2015-10-20 | 2016-01-20 | 苏州蔻美新材料有限公司 | Industrial latex gloves and preparation method thereof |
| CN105907075A (en) * | 2016-07-12 | 2016-08-31 | 王根夫 | Packaging thin film material for electronic commerce logistics transportation |
-
2017
- 2017-08-24 CN CN201710735309.9A patent/CN107383511A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1164813A (en) * | 1995-08-10 | 1997-11-12 | 阿普尔顿纸张公司 | Mulching composite |
| CN1209443A (en) * | 1998-09-17 | 1999-03-03 | 李嘉琛 | Spray of invisible mulch-film |
| CN104144954A (en) * | 2012-03-02 | 2014-11-12 | 电气化学工业株式会社 | Polychloroprene latex, polychloroprene latex composition, and molded article |
| CN105254962A (en) * | 2015-10-20 | 2016-01-20 | 苏州蔻美新材料有限公司 | Industrial latex gloves and preparation method thereof |
| CN105907075A (en) * | 2016-07-12 | 2016-08-31 | 王根夫 | Packaging thin film material for electronic commerce logistics transportation |
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Application publication date: 20171124 |