CN107383490A - A kind of butadiene acrylonitrile rubber medical gloves - Google Patents

A kind of butadiene acrylonitrile rubber medical gloves Download PDF

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Publication number
CN107383490A
CN107383490A CN201710855030.4A CN201710855030A CN107383490A CN 107383490 A CN107383490 A CN 107383490A CN 201710855030 A CN201710855030 A CN 201710855030A CN 107383490 A CN107383490 A CN 107383490A
Authority
CN
China
Prior art keywords
parts
rubber
raw material
butadiene acrylonitrile
ninhydrin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710855030.4A
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Chinese (zh)
Inventor
李季
戴宇辉
魏巍
李俊
李志远
梁天也
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Wei Wei Environmental Protection Technology Co Ltd
Original Assignee
Anhui Wei Wei Environmental Protection Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Wei Wei Environmental Protection Technology Co Ltd filed Critical Anhui Wei Wei Environmental Protection Technology Co Ltd
Priority to CN201710855030.4A priority Critical patent/CN107383490A/en
Publication of CN107383490A publication Critical patent/CN107383490A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/02Copolymers with acrylonitrile
    • C08L9/04Latex
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61BDIAGNOSIS; SURGERY; IDENTIFICATION
    • A61B42/00Surgical gloves; Finger-stalls specially adapted for surgery; Devices for handling or treatment thereof
    • A61B42/10Surgical gloves
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2265Oxides; Hydroxides of metals of iron
    • C08K2003/2272Ferric oxide (Fe2O3)
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses a kind of butadiene acrylonitrile rubber medical gloves, according to the number of parts by weight, include the raw material of following number:30 40 parts of nitrile rubber latex, 20 28 parts of polytetrafluoroethylene (PTFE) natural gum, 8 16 parts of dimethylformamide, 7 14 parts of pyridine, 9 11 parts of acetone, 8 14 parts of ninhydrin, 37 parts of stannous oxide, 0.6 1.5 parts of phthalate ester, 8 10 parts of calcinated argil, 37 parts of white oil, 0.3 0.8 parts of age resistor, 0.1 0.3 parts of antimitotic agent, 0.5 2 parts of thyme essential oil, 5 15 parts of cellulose, 5 15 parts of mineral wool, 0.1 0.3 parts of iron oxide red, 0.2 0.5 parts of sodium isopropyl xanthate, 0.4 0.9 parts of thiazole, 0.1 0.3 parts of di-t-butyl peroxide, 12 parts of Sulfur.This product raw material is simple, and yellowing-resistant, toughness is strong, and elasticity is good.Allergic reaction will not be caused to skin, wear-resisting not fragile, ageing resistance is strong, can effective antibacterial, preserve for a long time not by germ contamination, it is permanent to keep palm dry and comfortable.

Description

A kind of butadiene acrylonitrile rubber medical gloves
Technical field
The invention belongs to technical field of rubber material, more particularly to a kind of butadiene acrylonitrile rubber medical gloves.
Background technology
Rubber is widely used in all aspects of industry or life.There are many rubbers answering in medical department With the diagnosis of department of anesthesia, urological department, surgery, cranial surgery, orthopaedics, five palace sections, dept. of radiology's trick in such as hospital, transfusing blood, lead Mostly urine, the gloves of various glue color operations of intestinal lavage stomach, ice capsule, sponge seat cushion etc. are rubbers.As Medical Devices and instrument The accessory of device also has rubber.Druggist rubber sundrier often also has particular/special requirement to it, such as nontoxic, sterilization, physiological inertia, Resistance to radiation etc..The butyl rubber of rubber towel just has higher biologically inert, chemical stability and more micro- permeable breathable, uses Carry out processing rubber bottle stopper, can guarantee that the preservation of highly hygroscopic antibiosis meaning and anticancer preparation.
Current various infectious diseases are propagated by air or the way of contact, and the way of contact is the main of disease propagation Channel.To avoid passing through the pathogen transmission of the way of contact, disposable hand can be all used in medical treatment, medicine, the healthy prevention etc. Set.With the development of society, the usage amount of disposable glove is significantly increased, therefore, have excellent performance, it is cheap once Property gloves will certainly reduce use cost.
The content of the invention
It is an object of the invention to provide a kind of butadiene acrylonitrile rubber medical gloves.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of butadiene acrylonitrile rubber medical gloves, according to the number of parts by weight, include the raw material of following number:Nitrile rubber latex 30-40 parts, polytetrafluoroethylene (PTFE) natural gum 20-28 parts, dimethylformamide 8-16 parts, pyridine 7-14 parts, acetone 9-11 parts, ninhydrin 8-14 parts, stannous oxide 3-7 parts, phthalate ester 0.6-1.5 parts, calcinated argil 8-10 parts, white oil 3-7 parts, age resistor 0.3-0.8 Part, antimitotic agent 0.1-0.3 parts, thyme essential oil 0.5-2 parts, cellulose 5-15 parts, mineral wool 5-15 parts, iron oxide red 0.1- 0.3 part, sodium isopropyl xanthate 0.2-0.5 parts, thiazole 0.4-0.9 parts, di-t-butyl peroxide 0.1-0.3 parts, Sulfur 1-2 Part.
A kind of described butadiene acrylonitrile rubber medical gloves, according to the number of parts by weight, include the raw material of following number:Butyronitrile rubber 35 parts of glue latex, 25 parts of polytetrafluoroethylene (PTFE) natural gum, 10 parts of dimethylformamide, 10 parts of pyridine, 10 parts of acetone, 10 parts of ninhydrin, 4 parts of stannous oxide, 1 part of phthalate ester, 9 parts of calcinated argil, 5 parts of white oil, 0.5 part of age resistor, 0.3 part of antimitotic agent, thyme essential oil 1 Part, 10 parts of cellulose, 10 parts of mineral wool, 0.2 part of iron oxide red, 0.3 part of sodium isopropyl xanthate, 0.5 part of thiazole, peroxidating two 0.2 part of the tert-butyl group, 2 parts of Sulfur.
A kind of described butadiene acrylonitrile rubber medical gloves, its preparation method comprise the following steps:
(1) each raw material components are weighed according to ratio of weight and number;
(2) nitrile rubber latex, polytetrafluoroethylene (PTFE) natural gum, dimethylformamide, pyridine, acetone, ninhydrin are added into refining It is kneaded in glue machine;
(3) stannous oxide is added in the rubber mixing machine into step (2), phthalate ester, calcinated argil, white oil, thyme essential oil, Cellulose, mineral wool, iron oxide red, sodium isopropyl xanthate, thiazole, di-t-butyl peroxide, Sulfur, after being well mixed, mix 80-86 minutes are refined, obtain mixing virgin rubber;
(4) age resistor is added in the mixing virgin rubber into step (3), antimitotic agent, 15-18 minutes is kneaded, that is, obtains the rubber Glue composite.
Beneficial effects of the present invention:This product raw material is simple, and yellowing-resistant, toughness is strong, and elasticity is good.Skin will not be caused Quick reaction, wear-resisting not fragile, ageing resistance is strong, can effective antibacterial, preserve for a long time by germ contamination, it is permanent to keep palm not to do It is refreshing.
Embodiment
The present invention is described in further detail with reference to specific embodiment.
Embodiment 1
A kind of butadiene acrylonitrile rubber medical gloves, according to the number of parts by weight, include the raw material of following number:Nitrile rubber latex 30 parts, 20 parts of polytetrafluoroethylene (PTFE) natural gum, 8 parts of dimethylformamide, 7 parts of pyridine, 9 parts of acetone, 8 parts of ninhydrin, stannous oxide 3 Part, 0.6 part of phthalate ester, 8 parts of calcinated argil, 3 parts of white oil, 0.3 part of age resistor, 0.1 part of antimitotic agent, 0.5 part of thyme essential oil, fibre 5 parts of dimension element, 5 parts of mineral wool, 0.1 part of iron oxide red, 0.2 part of sodium isopropyl xanthate, 0.4 part of thiazole, di-t-butyl peroxide 0.1 part, 1 part of Sulfur.
Its preparation method comprises the following steps:
(1) each raw material components are weighed according to ratio of weight and number;
(2) nitrile rubber latex, polytetrafluoroethylene (PTFE) natural gum, dimethylformamide, pyridine, acetone, ninhydrin are added into refining It is kneaded in glue machine;
(3) stannous oxide is added in the rubber mixing machine into step (2), phthalate ester, calcinated argil, white oil, thyme essential oil, Cellulose, mineral wool, iron oxide red, sodium isopropyl xanthate, thiazole, di-t-butyl peroxide, Sulfur, after being well mixed, mix 80-86 minutes are refined, obtain mixing virgin rubber;
(4) age resistor is added in the mixing virgin rubber into step (3), antimitotic agent, 15-18 minutes is kneaded, that is, obtains the rubber Glue composite.
Embodiment 2
A kind of butadiene acrylonitrile rubber medical gloves, according to the number of parts by weight, include the raw material of following number:Nitrile rubber latex 40 parts, 28 parts of polytetrafluoroethylene (PTFE) natural gum, 16 parts of dimethylformamide, 14 parts of pyridine, 11 parts of acetone, 14 parts of ninhydrin, oxidation Asia 7 parts of tin, 1.5 parts of phthalate ester, 10 parts of calcinated argil, 7 parts of white oil, 0.8 part of age resistor, 0.3 part of antimitotic agent, 2 parts of thyme essential oil, 15 parts of cellulose, 15 parts of mineral wool, 0.3 part of iron oxide red, 0.5 part of sodium isopropyl xanthate, 0.9 part of thiazole, the uncle of peroxidating two 0.3 part of butyl, 2 parts of Sulfur.
Its preparation method comprises the following steps:
(1) each raw material components are weighed according to ratio of weight and number;
(2) nitrile rubber latex, polytetrafluoroethylene (PTFE) natural gum, dimethylformamide, pyridine, acetone, ninhydrin are added into refining It is kneaded in glue machine;
(3) stannous oxide is added in the rubber mixing machine into step (2), phthalate ester, calcinated argil, white oil, thyme essential oil, Cellulose, mineral wool, iron oxide red, sodium isopropyl xanthate, thiazole, di-t-butyl peroxide, Sulfur, after being well mixed, mix 80-86 minutes are refined, obtain mixing virgin rubber;
(4) age resistor is added in the mixing virgin rubber into step (3), antimitotic agent, 15-18 minutes is kneaded, that is, obtains the rubber Glue composite.
Embodiment 3
A kind of butadiene acrylonitrile rubber medical gloves, according to the number of parts by weight, include the raw material of following number:Nitrile rubber latex 35 parts, 25 parts of polytetrafluoroethylene (PTFE) natural gum, 10 parts of dimethylformamide, 10 parts of pyridine, 10 parts of acetone, 10 parts of ninhydrin, oxidation Asia 4 parts of tin, 1 part of phthalate ester, 9 parts of calcinated argil, 5 parts of white oil, 0.5 part of age resistor, 0.3 part of antimitotic agent, 1 part of thyme essential oil are fine 10 parts of dimension element, 10 parts of mineral wool, 0.2 part of iron oxide red, 0.3 part of sodium isopropyl xanthate, 0.5 part of thiazole, two tertiary fourth of peroxidating 0.2 part of base, 2 parts of Sulfur.
Its preparation method comprises the following steps:
(1) each raw material components are weighed according to ratio of weight and number;
(2) nitrile rubber latex, polytetrafluoroethylene (PTFE) natural gum, dimethylformamide, pyridine, acetone, ninhydrin are added into refining It is kneaded in glue machine;
(3) stannous oxide is added in the rubber mixing machine into step (2), phthalate ester, calcinated argil, white oil, thyme essential oil, Cellulose, mineral wool, iron oxide red, sodium isopropyl xanthate, thiazole, di-t-butyl peroxide, Sulfur, after being well mixed, mix 80-86 minutes are refined, obtain mixing virgin rubber;
(4) age resistor is added in the mixing virgin rubber into step (3), antimitotic agent, 15-18 minutes is kneaded, that is, obtains the rubber Glue composite.
Above content is only to design example and explanation of the invention, affiliated those skilled in the art Various modifications or supplement are made to described specific embodiment or is substituted using similar mode, without departing from invention Design or surmount scope defined in the claims, protection scope of the present invention all should be belonged to.

Claims (3)

1. a kind of butadiene acrylonitrile rubber medical gloves, it is characterised in that according to the number of parts by weight, include the raw material of following number:Fourth Nitrile rubber latex 30-40 parts, polytetrafluoroethylene (PTFE) natural gum 20-28 parts, dimethylformamide 8-16 parts, pyridine 7-14 parts, acetone 9- 11 parts, ninhydrin 8-14 parts, stannous oxide 3-7 parts, phthalate ester 0.6-1.5 parts, calcinated argil 8-10 parts, white oil 3-7 parts, prevent old Agent 0.3-0.8 parts, antimitotic agent 0.1-0.3 parts, thyme essential oil 0.5-2 parts, cellulose 5-15 parts, mineral wool 5-15 parts, oxidation Iron oxide red 0.1-0.3 parts, sodium isopropyl xanthate 0.2-0.5 parts, thiazole 0.4-0.9 parts, di-t-butyl peroxide 0.1-0.3 parts, Sulfur 1-2 parts.
A kind of 2. butadiene acrylonitrile rubber medical gloves according to claim 1, it is characterised in that according to the number of parts by weight, bag Include the raw material of following number:35 parts of nitrile rubber latex, 25 parts of polytetrafluoroethylene (PTFE) natural gum, 10 parts of dimethylformamide, pyridine 10 Part, 10 parts of acetone, 10 parts of ninhydrin, 4 parts of stannous oxide, 1 part of phthalate ester, 9 parts of calcinated argil, 5 parts of white oil, 0.5 part of age resistor, 0.3 part of antimitotic agent, 1 part of thyme essential oil, 10 parts of cellulose, 10 parts of mineral wool, 0.2 part of iron oxide red, sodium isopropyl xanthate 0.3 part, 0.5 part of thiazole, 0.2 part of di-t-butyl peroxide, 2 parts of Sulfur.
3. a kind of butadiene acrylonitrile rubber medical gloves according to claim 1, it is characterised in that its preparation method includes following step Suddenly:
(1) each raw material components are weighed according to ratio of weight and number;
(2) nitrile rubber latex, polytetrafluoroethylene (PTFE) natural gum, dimethylformamide, pyridine, acetone, ninhydrin are added into rubber mixing machine In be kneaded;
(3) stannous oxide, phthalate ester, calcinated argil, white oil, thyme essential oil, fiber are added in the rubber mixing machine into step (2) Element, mineral wool, iron oxide red, sodium isopropyl xanthate, thiazole, di-t-butyl peroxide, Sulfur, after being well mixed, it is kneaded 80- 86 minutes, obtain mixing virgin rubber;
(4) age resistor is added in the mixing virgin rubber into step (3), antimitotic agent, 15-18 minutes is kneaded, that is, obtains the rubber and answer Condensation material.
CN201710855030.4A 2017-09-20 2017-09-20 A kind of butadiene acrylonitrile rubber medical gloves Pending CN107383490A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108641357A (en) * 2018-05-14 2018-10-12 安徽和义新能源汽车充电设备有限公司 A kind of electric vehicle yielding rubber pad
CN114891284A (en) * 2022-06-06 2022-08-12 安徽英科医疗用品有限公司 Fragrant butyronitrile gloves and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104804342A (en) * 2015-04-27 2015-07-29 安徽美祥实业有限公司 Medical rubber material
WO2016175954A2 (en) * 2015-04-28 2016-11-03 Avent, Inc. Nitrile rubber glove with stretch modifier
CN106189197A (en) * 2016-07-25 2016-12-07 中红普林(北京)医疗用品高新技术研究院有限公司 A kind of preparation method of slim polyurethane medical glove
CN106496696A (en) * 2016-09-29 2017-03-15 四川三和医用材料有限公司 A kind of can absorbing sweat medical glovess
CN106496697A (en) * 2016-09-29 2017-03-15 四川三和医用材料有限公司 A kind of butadiene acrylonitrile rubber medical gloves

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104804342A (en) * 2015-04-27 2015-07-29 安徽美祥实业有限公司 Medical rubber material
WO2016175954A2 (en) * 2015-04-28 2016-11-03 Avent, Inc. Nitrile rubber glove with stretch modifier
CN106189197A (en) * 2016-07-25 2016-12-07 中红普林(北京)医疗用品高新技术研究院有限公司 A kind of preparation method of slim polyurethane medical glove
CN106496696A (en) * 2016-09-29 2017-03-15 四川三和医用材料有限公司 A kind of can absorbing sweat medical glovess
CN106496697A (en) * 2016-09-29 2017-03-15 四川三和医用材料有限公司 A kind of butadiene acrylonitrile rubber medical gloves

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108641357A (en) * 2018-05-14 2018-10-12 安徽和义新能源汽车充电设备有限公司 A kind of electric vehicle yielding rubber pad
CN114891284A (en) * 2022-06-06 2022-08-12 安徽英科医疗用品有限公司 Fragrant butyronitrile gloves and preparation method thereof

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Application publication date: 20171124