CN107376855A - A kind of preparation method of composite humidity adjusting material - Google Patents
A kind of preparation method of composite humidity adjusting material Download PDFInfo
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- CN107376855A CN107376855A CN201710424372.0A CN201710424372A CN107376855A CN 107376855 A CN107376855 A CN 107376855A CN 201710424372 A CN201710424372 A CN 201710424372A CN 107376855 A CN107376855 A CN 107376855A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/24—Naturally occurring macromolecular compounds, e.g. humic acids or their derivatives
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
- B01J20/041—Oxides or hydroxides
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/165—Natural alumino-silicates, e.g. zeolites
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
Abstract
The invention discloses a kind of preparation method of composite humidity adjusting material, belong to conditioning technique field.The present invention by poplar wood powder by hydrolyzing and being modified the modified cellulose prepared with potassium hydroxide, it is compound with collagen powder and prepare water absorbent gel with glyoxalic acid carboxymethyl-modification processing, again by by peanut shell fermentation process, microorganism decomposition is set to form micro-pore adsorbent zeolite particle, water absorbent gel powder is adsorbed by zeolite granular, makes its pay(useful) load and efficient absorbent.Composite humidity adjusting material hygroscopicity prepared by the present invention is strong, and absorbent capacity is high, compound ideal humidity scope, and preparation process is simple, and safe green is pollution-free.
Description
Technical field
The invention discloses a kind of preparation method of composite humidity adjusting material, belong to building material technical field.
Background technology
" humidity adjusting material " refers to not by any artificial energy source and plant equipment, the change of ambient air humidity where perceiving
Change, the material of air humidity is automatically adjusted by the moisture absorption and desorption property of itself.When ambient humidity is higher, humidity adjusting material can adsorb
Vapor in air, reduce ambient humidity;When ambient humidity is relatively low, material can be desorbed the moisture of its absorption, improve environment
Humidity, so as to keep the relatively stable of ambient humidity.Any energy is not consumed during the materials'use, environment can be automatically adjusted
Humidity, to improving ambient humidity, save the energy, promote Sustainable Development of Ecological Environment to have great importance.Humidity adjusting material by
There is diversity, and the controllability of humid control in its product form, its application is not limited solely to the art work, historical relic
Deng the occasion with different humidity requirement, the antistaling agent of food, agricultural are alternatively arranged as, in building field etc..In addition, damping
Material also has broad application prospects in fields such as leather industry, daily-use chemical industries.
Integrate, the humidity adjusting material of Recent study exploitation can substantially be summarized as following 5 class:(1)Special silica-gel, silica gel
It is a kind of unbodied silica, there is loose structure, surface has substantial amounts of Si-OH, and hydrophily is preferable, has to hydrone
There is preferable absorption property.Silica gel absorption hydrone is mainly shown as physisorption.Silica gel is as a kind of most common tune
Wet stock, has been obtained for wide application, but its hygroscopic capacity is small and the problems such as hysteresis quality is serious, still greatly limitation
It is applied;(2)Inorganic salts, many inorganic salts can serve as humidity adjusting material, such as calcium chloride, zinc chloride, lithium chloride, potassium carbonate
Deng, but saltoutd because most of solid inorganic salt easily produces, and it is unstable, in addition will in view of Special uses such as transportation and packing
Ask, the saturated salt solution of liquid condition is also unable to reach, and is extremely limited its use;(3)Inorganic mineral material, such as
Montmorillonite, diatomite, sepiolite etc., the material have the advantages that distribution is wide, cost is low, processing is simple, and right wet volume capacity is low, duct
The problems such as uncontrollability of structure and size, seriously limits its application;(4)High-molecular organic material, exist mostly substantial amounts of
The hydrophilic groups such as carboxyl, amino, hydroxyl, and there is tridimensional network, there are very strong water absorbing properties.Compared to inorganic material,
For high-molecular organic material as conditioning agent, maximum advantage is exactly that hygroscopic capacity is big, but there is also one to limit its application for the material
The shortcomings that, it is exactly that hydrone is difficult to resolve analysis, thus it is barely satisfactory compared to excellent moisture pick-up properties, moisture releasing performance;(5)Composite wood
Material, as described above, four kinds of humidity adjusting materials can not all meet the requirement of high moisture adsorption and releasing speed and high moisture adsorption and releasing amount simultaneously above.Cause
This, it would be highly desirable to developing a kind of high humidity adjusting material of absorbent capacity has necessary meaning.
The content of the invention
Present invention mainly solves technical problem:During existing composite humidity adjusting material use, humidity adjusting material moisture absorption
A kind of the problem of capacity is low, there is provided preparation method of composite humidity adjusting material.
In order to solve the above-mentioned technical problem, the technical solution adopted in the present invention is:
(1)In mass ratio 1:2:8,40~50 mesh poplar wood powders, sodium chlorite and glacial acetic acid are stirred, mistake after heating water bath
Filter to obtain filter cake, washing, dry modified wood powder, in mass ratio 1:10, by modified wood powder and the potassium hydroxide solution of mass fraction 2%
It is stirred, is stood after heating and be cooled to room temperature, ultrasonic disperse simultaneously filters to obtain filter residue, dry modified cellulose;
(2)In mass ratio 1:1, modified cellulose and collagen powder mixing and ball milling are crossed into 200 mesh sieves, mixed-powder is obtained, presses
Mass ratio 1:10, mixed-powder and deionized water are stirred, obtain mixing swelling solution, in mass ratio 1:10, by mass fraction
40% glyoxalic acid is stirred with mixing swelling solution, is adjusted pH to 6.5~7.0, heating water bath, is filtered and must be modified filter cake, washing,
Dry and mill, cross 200 mesh sieves and obtain modified water absorbent gel powder;
(3)Take peanut shell to be milled after drying and cross 100 mesh sieves, obtain peanut shell powder, in mass ratio 3:5, by deionized water and flower
Raw shell powder is stirred, and sealing and fermenting processing, is filtered the filter cake that must ferment, is washed to obtain fermenting peanut shell, fermenting peanut shell is forged
Stood after burning and be cooled to room temperature, obtain calcining charcoal, in mass ratio 1:3:5, by modified water absorbent gel powder, 80 mesh zeolite powders and forge
Mixing and ball milling of making charcoal crosses 120 mesh sieves, you can is prepared into a kind of composite humidity adjusting material.
Step(2)Described regulation pH is using 1mol/L sodium hydroxide solutions.
Step(3)Described calcining heat is 650~700 DEG C.
The beneficial effects of the invention are as follows:
The present invention is prepared into modified cellulose by hydrolyzing and being modified with potassium hydroxide poplar wood powder, is answered with collagen powder
Merging prepares water absorbent gel with glyoxalic acid carboxymethyl-modification processing, then by by peanut shell fermentation process, making microorganism point
Solution forms micro-pore adsorbent zeolite particle, and zeolite granular adsorbs water absorbent gel powder and forms multiaspect absorption preparation damping material again
Material, water absorbent gel powder is adsorbed by zeolite granular, makes its pay(useful) load and efficient absorbent, efficiently solve humidity adjusting material suction
Wet volume capacity is low, the defects of to temperature change low-response.
Embodiment
40~50 mesh poplar wood powders of selection first, in mass ratio 1:2:8, poplar wood powder, sodium chlorite and glacial acetic acid are stirred
Mixing is mixed, at 65~75 DEG C after 1~2h of heating water bath, filters and obtains filter cake, be washed with deionized to cleaning solution in neutrality
Afterwards, 3~5h is dried at 45~50 DEG C, is prepared into modified wood powder, then in mass ratio 1:10, by modified wood powder and mass fraction 2%
Potassium hydroxide solution is stirred, then 2~3h of oil bath heating at 95~100 DEG C, is then stood and is cooled to room temperature, 200~
10~15min of ultrasonic disperse under 300W, filter cake is filtered to obtain, 6~8h is dried at 65~70 DEG C, obtains modified cellulose;By quality
Than 1:1, modified cellulose and 40~50 mesh collagen powder are stirred and be placed in ball grinder, the ball under 300r/min
After grinding 3~5h, cross 200 mesh sieves and be prepared into mixed-powder, then in mass ratio 1:10, mixed-powder and deionized water are stirred mixed
Merging is placed in 10~12h of swelling at room temperature, is prepared into mixing swelling solution;In mass ratio 1:10, by the glyoxalic acid of mass fraction 40% with
Mixing swelling solution be stirred, with 1mol/L sodium hydroxides adjust pH to 6.5~7.0, at 35~40 DEG C heating water bath 5~
8h, after the completion for the treatment of heating water bath, filter cake must be modified by filtering, and after being washed with deionized 3~5 times, vacuum freeze drying is simultaneously milled,
Cross 200 mesh sieves and be prepared into modified water absorbent gel powder;Take peanut shell to be placed in drying 6~8h at 65~70 DEG C, then mill simultaneously
100 mesh sieves are crossed, obtain peanut shell powder, in mass ratio 3:5, deionized water and peanut shell powder are stirred and are placed in 35~40
Processing 10~15 days is sealed by fermentation at DEG C, waits after the completion of fermenting, filters the filter cake that must ferment, after deionized water rinsing 3~5 times,
Fermenting peanut shell is obtained, fermenting peanut shell is being placed in 100~125 DEG C of Muffle furnaces, after preheating 25~30min, by 10 DEG C/min
It is warming up to 650~700 DEG C.After 2~3h of insulation calcining, standing is cooled to room temperature, is prepared into calcining charcoal;In mass ratio 1:3:5, will
Modified water absorbent gel powder, 80 mesh zeolite powders and calcining charcoal mixing are placed in ball grinder, the ball milling under 350~400r/min
After 3~5h, 120 mesh sieves are crossed, you can be prepared into a kind of composite humidity adjusting material.
Example 1
Choose 40 mesh poplar wood powders first, in mass ratio 1:2:8, poplar wood powder, sodium chlorite and glacial acetic acid are stirred,
At 65 DEG C after heating water bath 1h, filter and obtain filter cake, be washed with deionized after being in neutral to cleaning solution, dried at 45 DEG C
3h, it is prepared into modified wood powder, then in mass ratio 1:10, modified wood powder and the potassium hydroxide solution of mass fraction 2% are stirred,
The oil bath heating 2h at 95 DEG C again, then stand and be cooled to room temperature, the ultrasonic disperse 10min under 200W, filter cake is filtered to obtain, 65
6h is dried at DEG C, obtains modified cellulose;In mass ratio 1:1, modified cellulose and 40 mesh collagen powder are stirred simultaneously
It is placed in ball grinder, under 300r/min after ball milling 3h, crosses 200 mesh sieves and be prepared into mixed-powder, then in mass ratio 1:10, will
Mixed-powder is stirred juxtaposition with deionized water and is swelled 10h at room temperature, is prepared into mixing swelling solution;In mass ratio 1:10,
The glyoxalic acid of mass fraction 40% is stirred with mixing swelling solution, pH to 6.5 is adjusted with 1mol/L sodium hydroxides, at 35 DEG C
Heating water bath 5h, after the completion for the treatment of heating water bath, filter cake must be modified by filtering, and after being washed with deionized 3 times, vacuum freeze drying is simultaneously
Mill, cross 200 mesh sieves and be prepared into modified water absorbent gel powder;Take peanut shell to be placed in drying 6h at 65 DEG C, then mill and mistake
100 mesh sieves, obtain peanut shell powder, in mass ratio 3:5, deionized water is stirred with peanut shell powder be placed in it is close at 35 DEG C
Seal fermentation process 10 days, wait after the completion of fermenting, filter the filter cake that must ferment, after deionized water rinsing 3 times, obtain fermenting peanut shell,
Fermenting peanut shell is being placed in 100 DEG C of Muffle furnaces, after preheating 25min, 650 DEG C are warming up to by 10 DEG C/min.Insulation calcining 2h
Afterwards, stand and be cooled to room temperature, be prepared into calcining charcoal;In mass ratio 1:3:5, by modified water absorbent gel powder, 80 mesh zeolite powders
It is placed in calcining charcoal mixing in ball grinder, under 350r/min after ball milling 3h, crosses 120 mesh sieves, you can is prepared into a kind of compound
Humidity adjusting material.
Indoors during room paint coating, in mass ratio 1:10, composite humidity adjusting material prepared by the present invention is stirred with coating
Mixing is mixed, is prepared into compo, then coats compo to wall surface, it is 500g/ to control humidity adjusting material load capacity
m2, after the completion of to be coated, spontaneous curing.
Example 2
Choose 45 mesh poplar wood powders first, in mass ratio 1:2:8, poplar wood powder, sodium chlorite and glacial acetic acid are stirred,
At 70 DEG C after heating water bath 2h, filter and obtain filter cake, be washed with deionized after being in neutral to cleaning solution, dried at 48 DEG C
4h, it is prepared into modified wood powder, then in mass ratio 1:10, modified wood powder and the potassium hydroxide solution of mass fraction 2% are stirred,
The oil bath heating 3h at 98 DEG C again, then stand and be cooled to room temperature, the ultrasonic disperse 13min under 250W, filter cake is filtered to obtain, 68
7h is dried at DEG C, obtains modified cellulose;In mass ratio 1:1, modified cellulose and 45 mesh collagen powder are stirred simultaneously
It is placed in ball grinder, under 300r/min after ball milling 4h, crosses 200 mesh sieves and be prepared into mixed-powder, then in mass ratio 1:10, will
Mixed-powder is stirred juxtaposition with deionized water and is swelled 11h at room temperature, is prepared into mixing swelling solution;In mass ratio 1:10,
The glyoxalic acid of mass fraction 40% is stirred with mixing swelling solution, pH to 6.8 is adjusted with 1mol/L sodium hydroxides, at 38 DEG C
Heating water bath 7h, after the completion for the treatment of heating water bath, filter cake must be modified by filtering, and after being washed with deionized 4 times, vacuum freeze drying is simultaneously
Mill, cross 200 mesh sieves and be prepared into modified water absorbent gel powder;Take peanut shell to be placed in drying 7h at 68 DEG C, then mill and mistake
100 mesh sieves, obtain peanut shell powder, in mass ratio 3:5, deionized water is stirred with peanut shell powder be placed in it is close at 38 DEG C
Seal fermentation process 13 days, wait after the completion of fermenting, filter the filter cake that must ferment, after deionized water rinsing 4 times, obtain fermenting peanut shell,
Fermenting peanut shell is being placed in 113 DEG C of Muffle furnaces, after preheating 28min, 680 DEG C are warming up to by 10 DEG C/min.Insulation calcining 3h
Afterwards, stand and be cooled to room temperature, be prepared into calcining charcoal;In mass ratio 1:3:5, by modified water absorbent gel powder, 80 mesh zeolite powders
It is placed in calcining charcoal mixing in ball grinder, under 380r/min after ball milling 4h, crosses 120 mesh sieves, you can is prepared into a kind of compound
Humidity adjusting material.
Indoors during room paint coating, in mass ratio 1:10, composite humidity adjusting material prepared by the present invention is stirred with coating
Mixing is mixed, is prepared into compo, then coats compo to wall surface, it is 525g/ to control humidity adjusting material load capacity
m2, after the completion of to be coated, spontaneous curing.
Example 3
Choose 50 mesh poplar wood powders first, in mass ratio 1:2:8, poplar wood powder, sodium chlorite and glacial acetic acid are stirred,
At 75 DEG C after heating water bath 2h, filter and obtain filter cake, be washed with deionized after being in neutral to cleaning solution, dried at 50 DEG C
5h, it is prepared into modified wood powder, then in mass ratio 1:10, modified wood powder and the potassium hydroxide solution of mass fraction 2% are stirred,
The oil bath heating 3h at 100 DEG C again, then stand and be cooled to room temperature, the ultrasonic disperse 15min under 300W, filter to obtain filter cake,
8h is dried at 70 DEG C, obtains modified cellulose;In mass ratio 1:1, modified cellulose and 50 mesh collagen powder are stirred
It is placed in ball grinder, under 300r/min after ball milling 5h, crosses 200 mesh sieves and be prepared into mixed-powder, then in mass ratio 1:10,
Mixed-powder and deionized water are stirred juxtaposition and are swelled 12h at room temperature, is prepared into mixing swelling solution;In mass ratio 1:
10, the glyoxalic acid of mass fraction 40% is stirred with mixing swelling solution, pH to 7.0 is adjusted with 1mol/L sodium hydroxides, at 40 DEG C
Lower heating water bath 8h, after the completion for the treatment of heating water bath, filter cake must be modified by filtering, after being washed with deionized 5 times, vacuum freeze drying
And mill, cross 200 mesh sieves and be prepared into modified water absorbent gel powder;Take peanut shell to be placed in drying 8h at 70 DEG C, then mill simultaneously
100 mesh sieves are crossed, obtain peanut shell powder, in mass ratio 3:5, deionized water and peanut shell powder are stirred and are placed at 40 DEG C
Processing 15 days is sealed by fermentation, waits after the completion of fermenting, filters the filter cake that must ferment, after deionized water rinsing 5 times, obtain fermenting peanut
Shell, fermenting peanut shell is being placed in 125 DEG C of Muffle furnaces, after preheating 30min, 700 DEG C are warming up to by 10 DEG C/min.Insulation calcining
After 3h, standing is cooled to room temperature, is prepared into calcining charcoal;In mass ratio 1:3:5, by modified water absorbent gel powder, 80 mesh zeolite powders
End and calcining charcoal mixing are placed in ball grinder, under 400r/min after ball milling 5h, cross 120 mesh sieves, you can are prepared into a kind of multiple
Close humidity adjusting material.
Indoors during room paint coating, in mass ratio 1:10, composite humidity adjusting material prepared by the present invention is stirred with coating
Mixing is mixed, is prepared into compo, then coats compo to wall surface, it is 550g/ to control humidity adjusting material load capacity
m2, after the completion of to be coated, spontaneous curing.
Composite humidity adjusting material obtained by above-described embodiment is detected with composite diatomite humidity adjusting material, and contrasted,
As a result as shown in Table 1.
Table one:
Example | Absorbent capacity(g/g) | Hydroscopicity(%) | Equilibrium humidity(%) |
Example 1 | Under the conditions of relative humidity is 100%, absorbent capacity 1.9 | Under the conditions of relative humidity is 100%, hydroscopicity 215 | 48 |
Example 2 | Under the conditions of relative humidity is 100%, absorbent capacity 2.1 | Under the conditions of relative humidity is 100%, hydroscopicity 223 | 52 |
Example 3 | Under the conditions of relative humidity is 100%, absorbent capacity 2.0 | Under the conditions of relative humidity is 100%, hydroscopicity 230 | 55 |
Composite diatomite humidity adjusting material | Under the conditions of relative humidity is 100%, absorbent capacity is 1.6~1.8 | Under the conditions of relative humidity is 100%, hydroscopicity is 190~200 | 58~75 |
As seen from the above table, composite humidity adjusting material absorbent capacity of the present invention is high, can active balance indoor humidity after use.
Claims (3)
1. a kind of preparation method of composite humidity adjusting material, it is characterised in that specifically preparation process is:
(1)In mass ratio 1:2:8,40~50 mesh poplar wood powders, sodium chlorite and glacial acetic acid are stirred, mistake after heating water bath
Filter to obtain filter cake, washing, dry modified wood powder, in mass ratio 1:10, by modified wood powder and the potassium hydroxide solution of mass fraction 2%
It is stirred, is stood after heating and be cooled to room temperature, ultrasonic disperse simultaneously filters to obtain filter residue, dry modified cellulose;
(2)In mass ratio 1:1, modified cellulose and collagen powder mixing and ball milling are crossed into 200 mesh sieves, mixed-powder is obtained, presses
Mass ratio 1:10, mixed-powder and deionized water are stirred, obtain mixing swelling solution, in mass ratio 1:10, by mass fraction
40% glyoxalic acid is stirred with mixing swelling solution, is adjusted pH to 6.5~7.0, heating water bath, is filtered and must be modified filter cake, washing,
Dry and mill, cross 200 mesh sieves and obtain modified water absorbent gel powder;
(3)Take peanut shell to be milled after drying and cross 100 mesh sieves, obtain peanut shell powder, in mass ratio 3:5, by deionized water and flower
Raw shell powder is stirred, and sealing and fermenting processing, is filtered the filter cake that must ferment, is washed to obtain fermenting peanut shell, fermenting peanut shell is forged
Stood after burning and be cooled to room temperature, obtain calcining charcoal, in mass ratio 1:3:5, by modified water absorbent gel powder, 80 mesh zeolite powders and forge
Mixing and ball milling of making charcoal crosses 120 mesh sieves, you can is prepared into a kind of composite humidity adjusting material.
A kind of 2. preparation method of composite humidity adjusting material according to claim 1, it is characterised in that:Step(2)Described
PH is adjusted using 1mol/L sodium hydroxide solutions.
A kind of 3. preparation method of composite humidity adjusting material according to claim 1, it is characterised in that:Step(3)Described
Calcining heat is 650~700 DEG C.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN108589365A (en) * | 2018-05-22 | 2018-09-28 | 南京林业大学 | The method that polishing prepares II crystal type nano fiber of lignocellulosic |
CN109111814A (en) * | 2018-08-30 | 2019-01-01 | 郭平 | A kind of preparation method of the significant shell powder interior wall paint of humidity |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN101210449A (en) * | 2007-12-25 | 2008-07-02 | 赵俊 | Architectural decoration material capable of adjusting moisture and reducing harm |
CN102976707A (en) * | 2012-11-27 | 2013-03-20 | 东莞大宝化工制品有限公司 | Inorganic silicate conditioning paint and preparation method thereof |
CN103396167A (en) * | 2013-08-05 | 2013-11-20 | 李涛 | Porous building decoration material capable of adjusting humidity, reducing harm and releasing negative ions |
CN104743972A (en) * | 2013-12-30 | 2015-07-01 | 上海墙特节能材料有限公司 | Indoor inorganic dry powder building coating capable of automatically regulating humidity |
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2017
- 2017-06-07 CN CN201710424372.0A patent/CN107376855A/en not_active Withdrawn
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101210449A (en) * | 2007-12-25 | 2008-07-02 | 赵俊 | Architectural decoration material capable of adjusting moisture and reducing harm |
CN102976707A (en) * | 2012-11-27 | 2013-03-20 | 东莞大宝化工制品有限公司 | Inorganic silicate conditioning paint and preparation method thereof |
CN103396167A (en) * | 2013-08-05 | 2013-11-20 | 李涛 | Porous building decoration material capable of adjusting humidity, reducing harm and releasing negative ions |
CN104743972A (en) * | 2013-12-30 | 2015-07-01 | 上海墙特节能材料有限公司 | Indoor inorganic dry powder building coating capable of automatically regulating humidity |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108589365A (en) * | 2018-05-22 | 2018-09-28 | 南京林业大学 | The method that polishing prepares II crystal type nano fiber of lignocellulosic |
CN109111814A (en) * | 2018-08-30 | 2019-01-01 | 郭平 | A kind of preparation method of the significant shell powder interior wall paint of humidity |
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