CN103396167A - Porous building decoration material capable of adjusting humidity, reducing harm and releasing negative ions - Google Patents
Porous building decoration material capable of adjusting humidity, reducing harm and releasing negative ions Download PDFInfo
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Abstract
A porous building decoration material capable of adjusting humidity, reducing harm and releasing negative ions is characterized by comprising a sintered functional layer, and the functional layer comprises 1-65 wt% of a negative-ion powder capable of releasing the negative ions and 0.1-60 wt% of a humidity-adjusting harm-reducing material, wherein the humidity-adjusting harm-reducing material is one or two or more of porous materials comprising zeolite, diatomite, allophane, vitreous trass, meerschaum, acidic white clay, active carbon, silica gel, white carbon black, active alumina and aluminium hydroxide. Compared with the prior art, the porous building decoration material of the invention has the advantage of releasing a large number of the negative ions.
Description
Technical field:
The present invention relates to a kind of building and ornament materials.
Background technology:
Along with the progress of social technology and the raising of manufacture level, more and more New Building Materials are applied, and when obtaining convenient, cheap and comfortable living environment, the air in buildings quality worse and worse.Because of the bubble-tight raising of buildings, the application of composite recycled material, paint, coating makes IAQ (indoor air quality) worse and worse, the serious harm HUMAN HEALTH.
Thus, people make great efforts the development of new building and ornament materials always, wish that new decorative material for building self does not produce obnoxious flavour, can replace the finishing material such as coating, wallpaper to play decoration function, have capable of purifying airly, produce the natural air quality of large nature healthiness.
People are long-standing to the research of negative aeroion, negative ion be known as in medical circle " air VITAMIN ".Medical research shows, in air, electronegative particulate can make oxygen level in blood increase, and is conducive to blood oxygen and carries, absorbs and utilize, and has the metabolism of the human body of promotion, improves the human immunological competence, strengthens human body flesh energy, regulates the effect of human body function balance.According to textual criticism, negative ion is to 7 systems of human body, and nearly 30 various diseases have inhibition, alleviation and auxiliary therapeutic action, and is especially more obvious to the health-care effect of human body.After thunderstorm, the negative ion of air increases, and it is happy that people feel.And at air-conditioned room, because negative ion in air almost all disappears after a series of air conditioning purges processing and very long ventilator trunk, that people's stop for a long time therein can be felt is uncomfortable in chest, dizzy, weak, working efficiency and healthy state descend, and is referred to as " air conditioner comprehensive disease ".The dictorial advisor of Tsing-Hua University, Chinese Academy of Sciences's expert Lin Jin penetrating judgment is awarded " Environmental Health and the negative oxygen ion " shown also negative ion is had many research and elaboration.
Mention in Chinese invention patent 200410079022.8 and add the nano composite negative ion powder in ceramic tile; fire the glaze for glazed tile that forms under 1080 ~ 1200 ℃; has anion releasing effect; adopt the test of air ion static method of testing; burst size is about 200/CM3; though make a breakthrough, negative ion concentration or far from being enough, and the glaze for glazed tile that covers the vitreous enamel layer is applied to toilet more and has also limited to its use.
The corresponding effect table of the negative ion concentration that professor Ye Zhengtao of Taiwan University of Science and Technology compiles:
| Environment place negative ion concentration (individual/cm3) | With the human health degree |
| Forest waterfall: 10,000-20,000 | Human body has spontaneous recovery power |
| High mountain seashore: 5000-1 ten thousand | Sterilization, minimizing disease propagation |
| Rural area field: 1000-5000 | Strengthen body immunity, antimicrbial power |
| Suburb, wilderness: 100-1000 | Strengthen body immunity, antimicrbial power |
| Park: 400-1000 | Strengthen body immunity, antimicrbial power |
| Urban Parks: 400-600 | Improve physical integrity |
| Street greening area: 200-400 | The faint physical integrity that improves |
| Room, city: 100 | Bring out physiological barrier headache and insomnia etc. |
| Building office: 40-50 | Bring out physiological barrier headache and insomnia etc. |
| Industry Development Area: 0 | Easily send out various diseases |
Can draw from table, the building and ornament materials that a kind of negative ion burst size of demand is large could be alleviated the atmospheric pollution of Modern Urban Living.
Summary of the invention:
Goal of the invention of the present invention is to provide the porous building and ornament materials of the adjustable moisture and reducing harm of a large amount of anion releasings of a kind of energy.
The present invention realizes like this, comprise and fire the functional layer that forms, functional layer comprises that content is that negative ion powder, the content that 1 ~ 65wt% can anion releasing is 0.1 ~ 60 wt % damping harm reduction material, and damping harm reduction material is one or more the mixture in zeolite, diatomite, malthacite, glassiness volcanic soil, sepiolite, acidic white earth, gac, silica gel, white carbon black, activated alumina, aluminium hydroxide; Or functional layer is the glaze layer that contains the negative ion powder that 1 ~ 20wt% can anion releasing, and glaze layer bottom is the ceramic tile layer, the firing temperature of glaze layer is 830-, 1050 ℃.
The consumption of negative ion powder that here, can anion releasing is 2 ~ 20wt% preferably.Should suitably increase add-on when certainly, the negative ion powder burst size is low; The product special purpose, be not subjected to cost constraint, can strengthen the add-on of negative ion powder while needing to make the material of larger negative ion burst size yet.
Research learns, the electronics that negative ion powder can produce the constraint of escape nucleus is called unbound electron, and is electronegative.After other neutral particle is combined, just form electronegative negative aeroion when unbound electron.The air main component is nitrogen, oxygen, carbonic acid gas and water vapour.Nitrogen is to electronics without avidity, and an aerobic, carbonic acid gas and water vapour have avidity to electronics, and oxygen level is 700 times of carbon dioxide content, and therefore, the negative ion overwhelming majority who generates in air is combined the negative ion of producing with oxygen and water vapour.Negative aeroion is not of uniform size, by the difference of mean particle dia size, can be divided into small particle size negative ion (0.001-0.003um), middle particle diameter negative ion (0.003-0.03um), large particle diameter negative ion (0.03-0.1um) 3 classes.
Therefore, the material of construction that obtain the negative ion of efficient release high density has both direction, and the one, produce abundant negative electricity unbound electron by the add-on that increases negative ion powder; The 2nd, allow as much as possible the negative electricity unbound electron move to material surface and form effective negative ion.The negative ion powder add-on is crossed senior general increases cost, has a strong impact on economic benefit.
Owing to adopting the material can produce porous, like this, fired after, can produce the pore of a large amount of dense distribution, thereby, promoted significantly the free list area of negative ion, effectively promoted the burst size of negative ion.
In addition,, by reducing the firing temperature of glaze layer, make the not vitrifying of glaze layer, not vitrified glaze layer has and enriches intensive cavity, makes the negative ion that negative ion powder discharges can escape from successfully, in large quantities.
here, intensity for improving product, functional layer also contains clay, perhaps the bottom of functional layer is ceramic tile basic unit, functional layer is glazed layer, glazed layer contains the negative ion powder of 0.1 ~ 60 wt % damping harm reduction material and 1 ~ 20wt% energy anion releasing, damping harm reduction material is zeolite, diatomite, malthacite, glassiness volcanic soil, sepiolite, acidic white earth, gac, silica gel, white carbon black, activated alumina, the mixture of one or more in aluminium hydroxide, it is perhaps glazed layer above functional layer, glazed layer contains the negative ion powder of 0.1 ~ 60 wt % damping harm reduction material and 1 ~ 20wt% energy anion releasing, damping harm reduction material is zeolite, diatomite, malthacite, glassiness volcanic soil, sepiolite, acidic white earth, gac, silica gel, white carbon black, activated alumina, the mixture of one or more in aluminium hydroxide.Because glazed layer contains damping harm reduction material, like this, form intensive and small hole intercommunication in glazed layer, make negative ion can be smoothly through the glaze layer and discharge.
The present invention compared with the prior art, produce the medium of unbound electron as negative ion powder due to the material that is rich in fine pore that newly adds, make inner, the outside unbound electron that produces of porousness building and ornament materials can effectively be combined into negative ion, and can effectively be diffused in extraneous air, the compound use of bi-material has played collaborative amplification, and amplification effect is obvious, and therefore, having advantages of can a large amount of anion releasing.
Embodiment:
Now in conjunction with the embodiments the present invention is described in further detail:
Negative ion burst size:, without obvious cross-ventilated room, the anion test instrument is put in product after positive static 5 minutes, the instrument display value.
The ventilation property test of porousness matrix or porousness ornament layer: use the laboratory plastic dropper, highly drip clear water in the test body surface apart from test surfaces 10CM, be adsorbed within 1 second and disappear and be judged to be " excellent ", be adsorbed within 2 seconds and disappear and be judged to be " good ", be adsorbed within 6 seconds and disappear and be judged to be " generally ", have no more than 20 seconds to eliminate and be judged to be " airtight ".
Damping ability: in humidity remains on 40% constant temperature and humidity cabinet standing 24 hours, claim to obtain sample weight; Constant temperature and humidity cabinet humidity is converted to 90% rear standing 24 hours, claims to obtain sample weight, the weight increased value is the damping amount of sample.The damping amount (gram) of unit surface (every square metre) is tried to achieve in calculating.
Formaldehyde is eliminated ability: 1 square metre of sample is put into the stainless steel test chamber of airtight 1 cubic metre that initial concentration of formaldehyde is 0.6mg/m3, detect the concentration of formaldehyde in test chamber after 8 hours, concentration of formaldehyde reduction value is eliminated ability divided by the formaldehyde that the starting point concentration value is sample.
Matrix: adopt ceramic batch as matrix, the blank raw material carries out raw material crushing-ball milling-spraying drying-moulding according to conventional ceramic production technology.
Ornament layer: adopt ceramic glaze as ornament layer, the glaze raw material carries out raw material ball according to conventional ceramic production technology and grinds standby glazing mud.
The embodiment negative ion powder: 500 gram negative ion powders are stacked on sheet glass at random, the anion test instrument was apart from static 5 minutes of surperficial two centimeters of negative ion powder, the negative ion powder negative ion burst size of test gained is 50000/CM3, consider the ratio of cost and effect, optimum additional proportion is 2% ~ 30%.
Comparative example 1:
Matrix (ceramic batch): negative ion powder 5%, quartz sand 20%, clay 50%, glassiness composition 25 %;
Firing temperature 1200, fire 45 minutes cycles;
Comparative example 2:
Matrix (ceramic batch): quartz sand 21%, clay 55%, glassiness composition 24%;
Ornament layer (ceramic glaze): cullet of glaze 70%, negative ion powder 10%, clay and pigment 20%;
Firing temperature 1200, fire 45 minutes cycles;
Comparative example 3:
Matrix (ceramic batch): quartz sand 21%, clay 55%, glassiness composition 24%;
Ornament layer (ceramic glaze): cullet of glaze 76%, negative ion powder 10%, clay and pigment 23%;
900 ℃ of firing temperatures, fire 45 minutes cycles;
Comparative example 4:
Matrix (ceramic batch): quartz sand 21%, clay 55%, glassiness composition 24%;
Ornament layer (ceramic glaze): cullet of glaze 70%, negative ion powder 10%, clay and pigment 20%;
Firing temperature 900, fire 45 minutes cycles;
Comparative example 5:
Matrix (ceramic batch): quartz sand 21%, clay 55%, glassiness composition 24%;
Ornament layer (ceramic glaze): cullet of glaze 62%, negative ion powder 20%, clay and pigment 18%;
Firing temperature 900, fire 45 minutes cycles;
Comparative example 6:
Matrix (ceramic batch): sepiolite 16%, clay 60%, glassiness composition 24%;
Ornament layer (ceramic glaze): eutectic cullet of glaze 70%, white carbon black 5%, clay and pigment 25%;
Firing temperature 900, fire 45 minutes cycles;
Embodiment 1:
Matrix (ceramic batch): negative ion powder 2%, sepiolite 16%, clay 58%, glassiness composition 24%;
Firing temperature 900, fire 45 minutes cycles;
Embodiment 2:
Matrix (ceramic batch): negative ion powder 5%, sepiolite 16%, clay 55%, glassiness composition 24%;
Ornament layer (ceramic glaze): eutectic cullet of glaze 70%, white carbon black 5%, negative ion powder 5%, clay and pigment 20%;
Firing temperature 900, fire 45 minutes cycles;
Embodiment 3:
Matrix (ceramic batch): sepiolite 16%, clay 60%, glassiness composition 24%;
Ornament layer (ceramic glaze): eutectic cullet of glaze 70%, white carbon black 5%, negative ion powder 5%, clay and pigment 20%;
Firing temperature 900, fire 45 minutes cycles;
Embodiment 4:
Matrix (ceramic batch): diatomite 16%, clay 60%, glassiness composition 24%;
Ornament layer (ceramic glaze): eutectic cullet of glaze 67%, white carbon black 5%, negative ion powder 8%, clay and pigment 20%;
The first mixing and ball milling of negative ion powder and white carbon black, then add other material and frit ball milling together; Firing temperature 900, fire 45 minutes cycles;
Embodiment 5:
Matrix (ceramic batch): activated alumina 10%, quartz sand 11%, clay 55%, glassiness composition 24%;
Ornament layer (ceramic glaze): cullet of glaze 70%, negative ion powder 10%, clay and pigment 20%;
Firing temperature 870, fire 45 minutes cycles; Appropriateness reduces firing temperature, controls thickness and the vitreous degree of decorating the glaze layer, keeps certain ventilation property.
Embodiment 6:
Matrix (ceramic batch): sepiolite 25%, clay 10%, negative ion powder 65%;
Embodiment 7:
Matrix (ceramic batch): sepiolite 60%, clay 34%, negative ion powder 1%;
| Kind | Porous breathable | Water-intake rate | The negative ion burst size (individual/cm3) | The damping ability (g/m) | Formaldehyde elimination factor (%) |
| Comparative example 1 | Airtight | 2% | 250 | 2 | 2% |
| Comparative example 2 | Airtight | 2% | 180 | 3 | 1% |
| Comparative example 3 | Generally | 7% | 700 | 5 | 8% |
| Comparative example 4 | Generally | 7% | 800 | 5 | 8% |
| Comparative example 5 | Generally | 7% | 900 | 5 | 8% |
| Comparative example 6 | Excellent | 20% | 25 | 150 | 75% |
| Embodiment 1 | Excellent | 21% | 2200 | 140 | 95% |
| Embodiment 2 | Excellent | 23% | 2500 | 160 | 98% |
| Embodiment 3 | Excellent | 22% | 2100 | 150 | 98% |
| Embodiment 4 | Excellent | 32% | 3800 | 250 | 99% |
| Embodiment 5 | Good | 30% | 2500 | 200 | 89% |
| Embodiment 6 | Excellent | 28% | 5800 | 150 | 99% |
| Embodiment 7 | Excellent | 28% | 1000 | 150 | 99% |
Can be understood by upper table, comparative example 3,4,5 relatively example 1,2 has reduced firing temperature, the burst size of negative ion is greatly improved, the proof free charge is converted into negative ion and moves in air and needs the hole passage, and traditional pottery is because of base substrate and the glaze layer of densification, stoped most migratory movement, what successfully realize migration on microcosmic is combination and the migration that the exposed or approaching negative ion powder that is exposed to surface occurs.
Embodiment 1-7 is significantly improved than the negative ion burst size of comparative example 1-4, illustrates and adds damping harm reduction porous material, to the release of negative ion, obvious stiffening effect is arranged.
Can be understood by upper table data, embodiment 1,2,3,4,5,6 has had and has significantly improved than comparative example 1,2,3,4,5 ventilation properties and water-intake rate, the negative ion burst size has also had and has significantly improved, adding of the porous material that specific surface area is large, allow negative ion powder produce free charge and can more multipathly be converted into negative ion and move in air, effect is fairly obvious.
Embodiment 1 and embodiment 7 explanations, when the negative ion powder add-on reaches 2% when above, the negative ion amount that discharges can meet the demands.
Can be understood by upper table data, do not add negative ion powder in embodiment 3 base substrates, but embodiment 3 is very approaching than embodiment 2 anion releasing quantity, negative ion burst size main contributions strength is described from top layer or near the negative ion powder on top layer, electric charge or negative ion relative difficult that base substrate middle and lower part negative ion powder produces move to outside.Therefore should be preferable over top layer and close to top layer, add negative ion powder, in order to produce economic benefit preferably.
Can be understood by upper table data, embodiment 3,4, eliminate the formaldehyde abilities than comparative example 4 and be significantly improved, illustrate that the elimination of negative ion powder and porous material PARA FORMALDEHYDE PRILLS(91,95) obnoxious flavour has synergy, the negative ion of negative ion powder release helps to eliminate the formaldehyde in space.
Can be understood by upper table data, although decorating the glaze layer than comparative example 3, embodiment 5 do not contain porous material, but embodiment 5 also has obvious lifting than the negative ion burst size of comparative example 3, illustrates that the vesicular structure of base substrate has also participated in the locomotory movement of glaze layer negative ion, helps the diffusion of glaze layer negative ion.Because rationally control the vitreous degree of glaze layer; keep ventilation property preferably; and the negative ion glaze of good permeability is placed on porous, loose base substrate, is understood that the electric charge that glaze layer bottom negative ion powder discharges, by the micropore that porous, loose base substrate connect mutually, space outerpace occurs to move and migrate to.
Can be understood by upper table data, the concentration of the above comparative example of embodiment 6 and embodiment anion releasing is all large, the ratio that negative ion powder and porous material are described is changeable, for special application fields such as some health handicrafts, can consider to adopt special mixture ratio to produce the product that corresponds to actual needs.
Can be understood by upper table data, embodiment 4 each data are all more satisfactory, and cost also is effectively controlled, and is preferred version.
In sum,, according to the present invention, can provide the porousness finishing material of the efficient anion releasing of a kind of energy, not only anion releasing concentration increases obviously, and with porous material, meets the ability of eliminating indoor harmful gas that improved of using.And cost of manufacture is low, and the product commercial value is high.
Claims (10)
1. adjustable moisture and reducing harm and porous building and ornament materials that can anion releasing, it is characterized in that comprising and fire the functional layer that forms, functional layer comprises that content is that negative ion powder, the content that 1 ~ 65wt% can anion releasing is 0.1 ~ 60 wt % damping harm reduction material, and damping harm reduction material is one or more the porous material mixture in zeolite, diatomite, malthacite, glassiness volcanic soil, sepiolite, acidic white earth, gac, silica gel, white carbon black, activated alumina, aluminium hydroxide.
2. adjustable moisture and reducing harm according to claim 1 and porous building and ornament materials that can anion releasing, the preferable amount that it is characterized in that negative ion powder that can anion releasing is 2 ~ 20wt% preferably.
3. the porous building and ornament materials of adjustable moisture and reducing harm and energy anion releasing, is characterized in that comprising and fire the functional layer that forms, and functional layer is the glaze layer that contains the negative ion powder of 1 ~ 20wt% energy anion releasing, and the firing temperature of glaze layer is 830 ~ 1050 ℃.
4. adjustable moisture and reducing harm according to claim 3 and porous building and ornament materials that can anion releasing, it is characterized in that glaze layer bottom is porousness ceramic tile layer, it is 0.1 ~ 60 wt % damping harm reduction material that porous ceramic tile layer contains content, and damping harm reduction material is one or more the mixture in zeolite, diatomite, malthacite, glassiness volcanic soil, sepiolite, acidic white earth, gac, silica gel, white carbon black, activated alumina, aluminium hydroxide.
5. the porous building and ornament materials of adjustable moisture and reducing harm according to claim 1 and 2 and energy anion releasing, is characterized in that functional layer also contains clay.
6. adjustable moisture and reducing harm according to claim 1 and 2 and porous building and ornament materials that can anion releasing, the bottom that it is characterized in that functional layer is ceramic tile basic unit, functional layer is glazed layer, glazed layer contains the negative ion powder that 0.1 ~ 60 wt % damping harm reduction material and 1 ~ 20wt% can anion releasings, and damping harm reduction material is one or more the mixture in zeolite, diatomite, malthacite, glassiness volcanic soil, sepiolite, acidic white earth, gac, silica gel, white carbon black, activated alumina, aluminium hydroxide.
7. adjustable moisture and reducing harm according to claim 1 and 2 and porous building and ornament materials that can anion releasing, it is characterized in that functional layer above be glazed layer, glazed layer contains the negative ion powder that 0.1 ~ 60 wt % damping harm reduction material and 1 ~ 20wt% can anion releasings, and damping harm reduction material is one or more the mixture in zeolite, diatomite, malthacite, glassiness volcanic soil, sepiolite, acidic white earth, gac, silica gel, white carbon black, activated alumina, aluminium hydroxide.
8. adjustable moisture and reducing harm according to claim 1 and 2 and porous building and ornament materials that can anion releasing, the bottom that it is characterized in that functional layer is porous ceramic tile basic unit, it is 0.1 ~ 60 wt % damping harm reduction material that porous ceramic tile layer contains content, and damping harm reduction material is one or more the mixture in zeolite, diatomite, malthacite, glassiness volcanic soil, sepiolite, acidic white earth, gac, silica gel, white carbon black, activated alumina, aluminium hydroxide.
9. adjustable moisture and reducing harm according to claim 1 and 2 and porous building and ornament materials that can anion releasing, the top that it is characterized in that functional layer is porous glaze layer, it is 0.1 ~ 60 wt % damping harm reduction material that porous glaze layer contains content, and damping harm reduction material is one or more the mixture in zeolite, diatomite, malthacite, glassiness volcanic soil, sepiolite, acidic white earth, gac, silica gel, white carbon black, activated alumina, aluminium hydroxide.
10. adjustable moisture and reducing harm according to claim 7 and porous building and ornament materials that can anion releasing, the bottom that it is characterized in that functional layer is ceramic tile basic unit.
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| CN104150948A (en) * | 2014-07-09 | 2014-11-19 | 华南理工大学 | Composite light weight ceramic ecological building material with humidifying function and preparation method thereof |
| CN104474642A (en) * | 2014-12-16 | 2015-04-01 | 安徽省利特环保技术有限公司 | Natural anion PM2.5 active carbon flame-retardant mask |
| CN105948717A (en) * | 2016-05-11 | 2016-09-21 | 沈平 | Nano negative ion functional material for ceramic and preparation method of material |
| CN106187290A (en) * | 2016-07-05 | 2016-12-07 | 佛山欧神诺陶瓷股份有限公司 | A kind of light-weight ceramic tile with humidity conditioning function and preparation method thereof |
| CN107376855A (en) * | 2017-06-07 | 2017-11-24 | 常州市瑞泰物资有限公司 | A kind of preparation method of composite humidity adjusting material |
| CN107500539A (en) * | 2017-09-30 | 2017-12-22 | 佛山欧神诺陶瓷股份有限公司 | A kind of damping Ceramic Tiles with negative ion-releasing function and preparation method thereof |
| CN108298820A (en) * | 2018-05-11 | 2018-07-20 | 唐山兴象达艺文化发展有限公司 | A kind of production method of anion fine pottery color glaze |
| CN109399927A (en) * | 2018-11-26 | 2019-03-01 | 张晓艳 | A kind of bacteriostasis, and deodorization pottery glaze |
| CN113135661A (en) * | 2021-04-15 | 2021-07-20 | 唐山市丰华陶瓷有限公司 | Glaze layer slurry, sanitary ceramic with smooth surface and ceramic preparation method |
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| CN108298820B (en) * | 2018-05-11 | 2021-07-13 | 唐山兴象达艺文化发展有限公司 | Method for preparing negative ion fine ceramic glaze |
| CN109399927A (en) * | 2018-11-26 | 2019-03-01 | 张晓艳 | A kind of bacteriostasis, and deodorization pottery glaze |
| CN113135661A (en) * | 2021-04-15 | 2021-07-20 | 唐山市丰华陶瓷有限公司 | Glaze layer slurry, sanitary ceramic with smooth surface and ceramic preparation method |
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