CN107365520B - Water-based water transfer printing pigment and preparation method thereof - Google Patents
Water-based water transfer printing pigment and preparation method thereof Download PDFInfo
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- CN107365520B CN107365520B CN201710758837.6A CN201710758837A CN107365520B CN 107365520 B CN107365520 B CN 107365520B CN 201710758837 A CN201710758837 A CN 201710758837A CN 107365520 B CN107365520 B CN 107365520B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/06—Artists' paints
Abstract
The invention discloses a water-based water transfer printing pigment and a preparation method thereof, wherein the water-based water transfer printing pigment comprises 5-20% of water-based binder, 4-9% of alkyl ammonium salt containing acidic group copolymer, 5-8% of antifreezing agent, 0.2-0.5% of defoaming agent, 0.3-0.8% of stabilizing agent, 3-10% of water-based color paste, 0.05-0.2% of flatting agent and the balance of water, and the water-based water transfer printing pigment is prepared by uniformly mixing the components in the formula amount in sequence. The water-based water transfer printing pigment can be uniformly diffused on the water surface, is free of color cross, easy to transfer, high in playability, low in cost, safe, environment-friendly, easy to clean after being used and suitable for popularization.
Description
Technical Field
The invention relates to the technical field of art pigments, in particular to a water-based water transfer printing pigment and a preparation method thereof.
Background
The current painting varieties and the painting methods are more and more abundant, and the traditional paper paintings such as watercolor paintings, oil paintings and the like and Turkey floating paintings are also available. At present, two drawing modes of Turkish floating water painting are available, one mode is a traditional method, glue solution is required to be prepared as painting solution, and then pigment is dripped on the special painting solution, the method is complicated, the viscosity of the glue solution cannot be controlled, so that the effect of the work is directly influenced, and the painting tool is difficult to clean; the other method is that according to the mechanism of oil-water incompatibility, clear water is used as drawing liquid, oily pigment is directly dripped on the water surface, and the pigment can be diffused on the water surface, so that the drawing of the pigment on the water surface can be realized.
Disclosure of Invention
Aiming at the defects of the prior art, the invention provides a water-based water transfer printing pigment and a preparation method thereof.
The invention discloses a water-based water transfer printing pigment which comprises 5-20% of water-based binder, 4-9% of alkyl ammonium salt containing acidic group copolymer, 5-8% of antifreezing agent, 0.2-0.5% of defoaming agent, 0.3-0.8% of antibacterial preservative, 3-10% of water-based color paste, 0.05-0.2% of flatting agent and the balance of water.
According to an embodiment of the present invention, the aqueous binder includes one or a mixture of an aqueous polyurethane-polyacrylic acid copolymer emulsion and an aqueous polyurethane-polyacrylic acid dispersion.
According to an embodiment of the present invention, the anti-freezing agent includes propylene glycol, sorbitol or glycerol.
According to an embodiment of the present invention, the defoaming agent includes a mixture of polysiloxanes.
According to an embodiment of the present invention, the antibacterial preservative includes phenoxyl compounds.
According to an embodiment of the present invention, the leveling agent includes a polydimethylsiloxane compound, a polyether, or an acrylate-modified polydimethylsiloxane.
The invention also discloses a preparation method of the water-based water transfer printing pigment, which comprises the following steps:
adding the aqueous binder with the formula amount into water, stirring at the use rotating speed of 800r/min, sequentially adding the alkylhydroxy ammonium salt containing the acidic group copolymer and the leveling agent, and uniformly mixing and stirring;
and adding the aqueous color paste, stirring at the rotation speed of 1200r/min, and adding an antifreezing agent, a defoaming agent and an antibacterial preservative to prepare the aqueous water transfer printing pigment.
Compared with the prior art, the invention can obtain the following technical effects:
the water-based water transfer printing pigment can be uniformly diffused on the water surface, is free of color cross, easy to transfer, high in playability, low in cost, safe, environment-friendly, easy to clean after being used and suitable for popularization.
Detailed Description
In the following description, numerous implementation-specific details are set forth in order to provide a thorough understanding of the various embodiments of the present application. It should be understood, however, that these implementation details should not be used to limit the application. That is, in some embodiments of the present application, such practical details are not necessary.
In addition, technical solutions between various embodiments may be combined with each other, but must be realized by a person skilled in the art, and when the technical solutions are contradictory or cannot be realized, such a combination should not be considered to exist, and is not within the protection scope of the present invention.
The water-based water transfer printing pigment comprises 5-20% of water-based binder, 4-9% of alkyl ammonium salt containing acid group copolymer, 5-8% of antifreezing agent, 0.2-0.5% of defoaming agent, 0.3-0.8% of antibacterial preservative, 3-10% of water-based color paste, 0.05-0.2% of flatting agent and the balance of water.
In the preparation process, the waterborne polyurethane-polyacrylic acid copolymer emulsion is selected as a waterborne binder, and the waterborne binder provides good adhesive force and film-forming property for a pigment system, so that the pigment can be completely transferred to a substrate from the water surface; the content range is the optimal proportioning range value, if the content range is lower than the optimal proportioning range value, the adhesive force is poor, and the patterns on the water surface cannot be completely transferred; if the value is higher than the range, the adhesion force is too strong, the pigment layer cannot be completely separated from the water surface, water is easily adhered during transfer printing, the patterns have watermarks and deformation, the pigment density is increased, and the pigment is easily precipitated in water. The alkyl ammonium salt containing the acid group copolymer can disperse and wet the pigment, and the pigment can be uniformly diffused on the water surface without precipitation; the content range is the optimal proportioning range value, and if the content range is lower than the optimal proportioning range value, the pigment has poor diffusion capacity on the water surface and is easy to settle; if the value is higher than the range, the pigment has too strong diffusion capacity on the water surface, so that the color is light and difficult to control during painting; the leveling agent acrylate modified polydimethylsiloxane can improve the smoothness of the pigment during transfer printing film forming, so that a transfer printing pattern is clear and fine, the content range is the optimal proportioning range value, and if the content range is lower than the optimal proportioning range value, the leveling property is poor, and the pigment in the transfer printing pattern is accumulated to be rough and fuzzy; if the amount is more than the above range, the leveling property is strong, the pigment in the transferred pattern is thin, and the blank colorless phenomenon is likely to occur. And adding the water-based color pastes with different colors according to color matching requirements to prepare the water-based water transfer printing pigments with different colors. In the preparation process, the defoaming agent is added to eliminate bubbles generated during stirring, so that the surface unevenness during film forming is avoided. In addition, an antifreezing agent is added to prevent the pigment from solidifying in a low-temperature storage environment and influencing the use. The addition of the antibacterial preservative can prolong the service life of the pigment and prevent the pigment from deteriorating.
Furthermore, the prepared pigment is filled in a rubber tube, and when the paint is used, a container is only used for containing clear water to draw a picture. The pigment is dripped onto the surface of clear water, the alkyl ammonium salt of the copolymer containing the acid group in the pigment plays a role in diffusion, the pigment is diffused on the water surface to form a pigment layer, the waterborne polyurethane-polyacrylic acid copolymer emulsion has good adhesive force and film-forming property, so that the pigment can be completely transferred to a substrate from the water surface, and the acrylate modified polydimethylsiloxane enables the pigment to be transferred into a film and has good smoothness, so that the transferred pattern is clear and fine. Preferably, the substrate to be transferred may be white paper, cloth, wood or ceramic. Because the pigment of this application is water pigment, can wash the container fast with clear water, clean convenient pollution-free is fit for children and uses.
Aqueous water transfer pigments will be prepared by a number of examples below.
Example 1
Preparing 5 parts of aqueous bonding material, 4 parts of alkyl ammonium salt containing acidic group copolymer, 5 parts of antifreezing agent, 0.2 part of defoaming agent, 0.3 part of antibacterial preservative, 3 parts of aqueous color paste, 0.05 part of flatting agent and 82.45 parts of water, wherein the parts are parts by weight. The water-based binder is a water-based polyurethane-polyacrylic acid copolymer emulsion, the antifreezing agent is a mixture of propylene glycol and sorbitol, and the weight ratio of the propylene glycol to the sorbitol is 1: 1, the defoaming agent is polysiloxane, the antibacterial preservative is phenoxyethanol, and the flatting agent is acrylate modified polydimethylsiloxane.
According to the formula amount, adding the waterborne polyurethane-polyacrylic acid copolymer emulsion into water, stirring at a rotating speed of 800r/min, sequentially adding the alkyl ammonium salt containing the acidic group copolymer and the acrylate modified polydimethylsiloxane while stirring, wherein the alkyl ammonium salt containing the acidic group copolymer is used as a dispersing agent, and a high molecular weight auxiliary agent is added firstly to form steric hindrance in a pigment system so as to deflocculate the pigment and provide the same charges, so that the subsequently added components can be well wetted to form a uniform and suspended state, and after the components are uniformly mixed, adding the waterborne color paste, and increasing the rotating speed to 1200 r/min. Because the color paste contains the particle groups, the specific gravity of the components is high, the wetting degree of the particle groups can be increased by improving the dispersion speed, so that the particle groups can be uniformly and stably dispersed in a pigment system, and finally, the propylene glycol, the sorbitol, the polysiloxane and the phenoxyethanol are added and uniformly mixed to obtain the water transfer pigment. The same charge provided by the alkyl ammonium salt of the acid-group-containing copolymer prevents the co-flocculation of pigments of different colors when superimposed during painting.
The water transfer pigment prepared in this example was dropped on the water surface, and the spreading range on the water surface was about 0.08m2Density of about 1.00 g/ml. The diffused pigment has a smooth and glossy surface, is fine and smooth, is not easy to settle, has strong adhesive force, and can be quickly transferred to a substrate.
Example 2
Preparing 13 parts of aqueous bonding material, 6 parts of alkyl ammonium salt containing acidic group copolymer, 7 parts of antifreezing agent, 0.3 part of defoaming agent, 0.5 part of antibacterial preservative, 5 parts of aqueous color paste, 0.1 part of flatting agent and 66.10 parts of water, wherein the parts are parts by weight. The water-based binder is a water-based polyurethane-polyacrylic acid copolymer emulsion, the antifreezing agent is a mixture of propylene glycol and sorbitol, and the weight ratio of the propylene glycol to the sorbitol is 1: 1, the defoaming agent is polysiloxane, the antibacterial preservative is phenoxyethanol, and the flatting agent is acrylate modified polydimethylsiloxane.
According to the formula amount, adding the waterborne polyurethane-polyacrylic acid copolymer emulsion into water, stirring at a rotating speed of 800r/min, and sequentially adding the alkyl ammonium salt containing the acidic group copolymer and the acrylate modified polydimethylsiloxane while stirring until the mixture is uniformly mixed. And then adding the aqueous color paste, increasing the rotating speed to 1200r/min, adding propylene glycol, sorbitol, polysiloxane and phenoxyethanol, and uniformly mixing to obtain the water transfer printing pigment.
The water transfer pigment prepared in this example was dropped on the water surface, and the spreading range on the water surface was about 0.11m2Density of about 1.03 g/ml. The diffused pigment has a smooth and glossy surface, is fine and smooth, is not easy to settle, has strong adhesive force, and can be quickly transferred to a substrate.
Example 3
Preparing 20 parts of aqueous bonding material, 9 parts of alkyl ammonium salt containing acidic group copolymer, 8 parts of antifreezing agent, 0.5 part of defoaming agent, 0.8 part of antibacterial preservative, 10 parts of aqueous color paste, 0.2 part of flatting agent and 51.5 parts of water, wherein the parts are parts by weight. Wherein the water-soluble binder is a water-based polyurethane-polyacrylic acid copolymer emulsion, the antifreezing agent is a mixture of propylene glycol and sorbitol, and the weight ratio of the propylene glycol to the sorbitol is 1: 1, the defoaming agent is polysiloxane, the antibacterial preservative is phenoxyethanol, and the flatting agent is acrylate modified polydimethylsiloxane.
According to the formula amount, adding the waterborne polyurethane-polyacrylic acid copolymer emulsion into water, stirring at a rotating speed of 800r/min, and sequentially adding the alkyl ammonium salt containing the acidic group copolymer and the acrylate modified polydimethylsiloxane while stirring until the mixture is uniformly mixed. And then adding the aqueous color paste, increasing the rotating speed to 1200r/min, adding propylene glycol, sorbitol, polysiloxane and phenoxyethanol, and uniformly mixing to obtain the water transfer printing pigment.
The water transfer pigment prepared in this example was dropped on the water surface, and the spreading range on the water surface was about 0.12m2Density of about 1.05 g/ml. The diffused pigment has a smooth and glossy surface, is fine and smooth, is not easy to settle, has strong adhesive force, and can be quickly transferred to a substrate.
In conclusion, by the formula and the preparation method, the water-based water transfer printing pigment can be uniformly diffused on the water surface, is free of color cross, easy to transfer, high in playability, low in cost, safe and environment-friendly, easy to clean after being used and suitable for popularization; the diffusion range of the water surface is about 0.08m2/ml～0.12m2A density of about 1.00g/ml to about 1.05 g/ml.
The above description is only an embodiment of the present invention, and is not intended to limit the present invention. Various modifications and alterations to this invention will become apparent to those skilled in the art. Any modification, equivalent replacement, improvement, etc. made within the spirit and principle of the present invention should be included in the scope of the claims of the present invention.
Claims (1)
1. Use of an aqueous water transfer pigment, characterized in that the pigment is used for water transfer printing and that the pigment consists of: 5-20% of water-based binder, 4-9% of alkyl ammonium salt containing acidic group copolymer, 5-8% of antifreezing agent, 0.2-0.5% of defoaming agent, 0.3-0.8% of stabilizer, 3-10% of water-based color paste, 0.05-0.2% of flatting agent and the balance of water; the aqueous connecting material comprises one or the mixture of aqueous polyurethane-polyacrylic acid copolymer emulsion or aqueous polyurethane-polyacrylic acid dispersoid; the antifreeze comprises propylene glycol, sorbitol or glycerol; the defoamer comprises a mixture of polysiloxanes; the stabilizer comprises phenoxyl compounds; the leveling agent comprises a polydimethylsiloxane compound, polyether or acrylate modified polydimethylsiloxane; the preparation method of the pigment comprises the following steps:
adding the aqueous binder with the formula amount into water, stirring at the use rotating speed of 800r/min, sequentially adding the alkylhydroxy ammonium salt containing the acidic group copolymer and the leveling agent, and uniformly mixing and stirring; the aqueous connecting material comprises one or the mixture of aqueous polyurethane-polyacrylic acid copolymer emulsion or aqueous polyurethane-polyacrylic acid dispersoid;
and adding the aqueous color paste, stirring at the rotating speed of 1200r/min, and adding the antifreezing agent, the defoaming agent and the stabilizer to prepare the aqueous water transfer printing pigment.
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| CN111154366A (en) * | 2020-01-20 | 2020-05-15 | 东莞大宝化工制品有限公司 | Self-drying type anti-static coating and preparation method thereof |
| CN112853777A (en) * | 2021-01-05 | 2021-05-28 | 珠海纳思达企业管理有限公司 | Digital pyrograph ink and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103289480A (en) * | 2013-05-24 | 2013-09-11 | 贝碧欧美术颜料(昆山)有限公司 | Aqueous cross-color-free three-dimensional pigment |
| CN104098972A (en) * | 2014-08-07 | 2014-10-15 | 江苏美亿晨新材料科技有限公司 | Water-based antirust and antiseptic paint for metal and preparation method thereof |
| CN106032654A (en) * | 2015-03-09 | 2016-10-19 | 南通市跃达针织服饰有限公司 | Textile pigment |
| CN106833075A (en) * | 2017-02-16 | 2017-06-13 | 隋敏 | A kind of waterproof art painting of dilutable water and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105482532A (en) * | 2015-12-31 | 2016-04-13 | 苏州冰心文化用品有限公司 | Anti-aging traditional Chinese painting pigment and preparation method thereof |
| CN105544246A (en) * | 2016-01-25 | 2016-05-04 | 苏州印丝特纺织数码科技有限公司 | Method for preparing color paste for printing coating |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103289480A (en) * | 2013-05-24 | 2013-09-11 | 贝碧欧美术颜料(昆山)有限公司 | Aqueous cross-color-free three-dimensional pigment |
| CN104098972A (en) * | 2014-08-07 | 2014-10-15 | 江苏美亿晨新材料科技有限公司 | Water-based antirust and antiseptic paint for metal and preparation method thereof |
| CN106032654A (en) * | 2015-03-09 | 2016-10-19 | 南通市跃达针织服饰有限公司 | Textile pigment |
| CN106833075A (en) * | 2017-02-16 | 2017-06-13 | 隋敏 | A kind of waterproof art painting of dilutable water and preparation method thereof |
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