CN107363122B - The preparation process of aluminum-magnesium alloy wire - Google Patents

The preparation process of aluminum-magnesium alloy wire Download PDF

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Publication number
CN107363122B
CN107363122B CN201710447456.6A CN201710447456A CN107363122B CN 107363122 B CN107363122 B CN 107363122B CN 201710447456 A CN201710447456 A CN 201710447456A CN 107363122 B CN107363122 B CN 107363122B
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China
Prior art keywords
weight
parts
aluminum
magnesium alloy
alloy wire
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CN201710447456.6A
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CN107363122A (en
Inventor
杨仁忠
史建华
谈菊新
王培培
卞保靖
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FEILONG FINE TECHNOLOGY (SUZHOU) CO LTD
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FEILONG FINE TECHNOLOGY (SUZHOU) CO LTD
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21CMANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
    • B21C37/00Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape
    • B21C37/04Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape of bars or wire
    • B21C37/042Manufacture of coated wire or bars
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/026Alloys based on aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/06Alloys based on aluminium with magnesium as the next major constituent
    • C22C21/08Alloys based on aluminium with magnesium as the next major constituent with silicon

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Organic Chemistry (AREA)
  • Metallurgy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Treatment Of Metals (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)

Abstract

The invention discloses a kind of preparation process of aluminum-magnesium alloy wire, the raw material of the aluminum-magnesium alloy wire is by weight percentage are as follows: 0.4% scandium, 0.6% molybdenum, 0.8% rhodium, 9% magnesium, 0.2% zirconium, 0.1% silicon, 0.05% hafnium, 0.06% tin, surplus are aluminium;The preparation process includes the following steps: A1) almag bar is prepared with above-mentioned raw materials;A2) by almag bar wire drawing at aluminum-magnesium alloy wire;A3 coating processing) is carried out to aluminum-magnesium alloy wire.The preparation process of aluminum-magnesium alloy wire of the present invention, can eliminate aluminum-magnesium alloy wire phenomenon easy to oxidize, and tensile strength improves, and silk is not easy that circle is bent, be not easy to abrade, corrosion-resistant, anti-oxidant, finish is good.

Description

The preparation process of aluminum-magnesium alloy wire
Technical field
The present invention relates to the preparation processes of aluminum-magnesium alloy wire.
Background technique
To use aluminum-magnesium alloy wire in coaxial cable litzendraht wire, pressure pipe litzendraht wire and aluminium welding wire, and existing aluminium Mg alloy wire performance is bad, and not high, easy to oxidize, the easy scratch of easy circle song, tensile strength, brightness are inadequate, in high speed machine It is easy broken string when tool is processed, seriously affects yield, therefore be not able to satisfy customer requirement.
Summary of the invention
The purpose of the present invention is to provide a kind of preparation processes of aluminum-magnesium alloy wire, and it is easy to oxidize can to eliminate aluminum-magnesium alloy wire The phenomenon that, and tensile strength improves, and silk is not easy that circle is bent, be not easy to abrade, corrosion-resistant, anti-oxidant, finish is good.
To achieve the above object, the technical scheme is to design a kind of preparation process of aluminum-magnesium alloy wire, the aluminium The raw material of Mg alloy wire is by weight percentage are as follows: 0.4% scandium, 0.6% molybdenum, and 0.8% rhodium, 9% magnesium, 0.2% zirconium, 0.1% Silicon, 0.05% hafnium, 0.06% tin, surplus is aluminium;
The preparation process includes the following steps:
A1) almag bar is prepared with above-mentioned raw materials;
A2) by almag bar wire drawing at aluminum-magnesium alloy wire;
A3 coating processing) is carried out to aluminum-magnesium alloy wire.
Preferably, the coating processing includes the following steps:
B1) by 1.2 parts by weight cocoanut fatty acid diethanolamides, 1.9 parts by weight inositol hexaphosphates, 2.1 parts by weight N-Methyl pyrrolidone, 1.1 parts by weight 2- phosphate -1,2,4- butane tricarboxylates, 0.9 parts by weight sulfosuccinic acid Diisooctyl Sodium is successively put into 50 parts by weight of deionized water, is stirred evenly;
B2 2.6 parts by weight hydroxy ethylene diphosphonic acids, 3.5 parts by weight diethylene glycol monobutyl ethers, 1.3 weights) are successively put into again Measure part sorbitan mono-oleic acid ester, 1.1 parts by weight maleic anhydrides, 2.5 parts by weight calgons, 0.5 parts by weight dioxane Base zinc dithiophosphate, 2.2 parts by weight benzotriazole, 2.3 parts by weight 1-hydroxy ethylidene-1,1-diphosphonic acids, 3.3 parts by weight carbonic acid diethyls The own ester of base, continues to stir, until being sufficiently mixed uniformly, coating treatment liquid is made;
B3) aluminum-magnesium alloy wire is placed in coating treatment liquid and is impregnated, is dried after taking-up.
Advantages and advantages of the present invention are to provide a kind of preparation process of aluminum-magnesium alloy wire, can eliminate magnalium conjunction Spun gold phenomenon easy to oxidize, and tensile strength improves, silk are not easy that circle is bent, be not easy to abrade, corrosion-resistant, anti-oxidant, finish is good.
Specific embodiment
With reference to embodiment, the specific embodiment of the present invention is further described.Following embodiment is only used for more Add and clearly demonstrate technical solution of the present invention, and not intended to limit the protection scope of the present invention.
The technical solution that the present invention embodies is:
A kind of preparation process of aluminum-magnesium alloy wire, the raw material of the aluminum-magnesium alloy wire is by weight percentage are as follows: 0.4% scandium, 0.6% molybdenum, 0.8% rhodium, 9% magnesium, 0.2% zirconium, 0.1% silicon, 0.05% hafnium, 0.06% tin, surplus are aluminium;
The preparation process includes the following steps:
A1) almag bar is prepared with above-mentioned raw materials;
A2) by almag bar wire drawing at aluminum-magnesium alloy wire;
A3 coating processing) is carried out to aluminum-magnesium alloy wire;
The coating processing includes the following steps:
B1) by 1.2 parts by weight cocoanut fatty acid diethanolamides, 1.9 parts by weight inositol hexaphosphates, 2.1 parts by weight N-Methyl pyrrolidone, 1.1 parts by weight 2- phosphate -1,2,4- butane tricarboxylates, 0.9 parts by weight sulfosuccinic acid Diisooctyl Sodium is successively put into 50 parts by weight of deionized water, is stirred evenly;
B2 2.6 parts by weight hydroxy ethylene diphosphonic acids, 3.5 parts by weight diethylene glycol monobutyl ethers, 1.3 weights) are successively put into again Measure part sorbitan mono-oleic acid ester, 1.1 parts by weight maleic anhydrides, 2.5 parts by weight calgons, 0.5 parts by weight dioxane Base zinc dithiophosphate, 2.2 parts by weight benzotriazole, 2.3 parts by weight 1-hydroxy ethylidene-1,1-diphosphonic acids, 3.3 parts by weight carbonic acid diethyls The own ester of base, continues to stir, until being sufficiently mixed uniformly, coating treatment liquid is made;
B3) aluminum-magnesium alloy wire is placed in coating treatment liquid and is impregnated, is dried after taking-up.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For member, without departing from the technical principles of the invention, several improvements and modifications can also be made, these improvements and modifications Also it should be regarded as protection scope of the present invention.

Claims (2)

1. the preparation process of aluminum-magnesium alloy wire, it is characterised in that:
The raw material of the aluminum-magnesium alloy wire is by weight percentage are as follows: 0.4% scandium, 0.6% molybdenum, and 0.8% rhodium, 9% magnesium, 0.2% Zirconium, 0.1% silicon, 0.05% hafnium, 0.06% tin, surplus is aluminium;
The preparation process includes the following steps:
A1) almag bar is prepared with above-mentioned raw materials;
A2) by almag bar wire drawing at aluminum-magnesium alloy wire;
A3 coating processing) is carried out to aluminum-magnesium alloy wire.
2. the preparation process of aluminum-magnesium alloy wire according to claim 1, which is characterized in that the coating processing includes as follows Step:
B1) by 1.2 parts by weight cocoanut fatty acid diethanolamides, 1.9 parts by weight inositol hexaphosphates, 2.1 parts by weight N- first Base pyrrolidones, 1.1 parts by weight 2- phosphate -1,2,4- butane tricarboxylates, 0.9 parts by weight sulfosuccinic acid Diisooctyl sodium according to In 50 parts by weight of deionized water of secondary investment, stir evenly;
B2 2.6 parts by weight hydroxy ethylene diphosphonic acids, 3.5 parts by weight diethylene glycol monobutyl ethers, 1.3 parts by weight) are successively put into again Sorbitan mono-oleic acid ester, 1.1 parts by weight maleic anhydrides, 2.5 parts by weight calgons, 0.5 parts by weight dialkyl group two Thiophosphoric acid zinc, 2.2 parts by weight benzotriazole, 2.3 parts by weight 1-hydroxy ethylidene-1,1-diphosphonic acids, 3.3 parts by weight carbonic acid diethyl oneself Ester continues to stir, until being sufficiently mixed uniformly, coating treatment liquid is made;
B3) aluminum-magnesium alloy wire is placed in coating treatment liquid and is impregnated, is dried after taking-up.
CN201710447456.6A 2017-06-14 2017-06-14 The preparation process of aluminum-magnesium alloy wire Active CN107363122B (en)

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CN107363122B true CN107363122B (en) 2018-12-14

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11343532A (en) * 1998-05-28 1999-12-14 Mitsubishi Heavy Ind Ltd Corrosion resistant and high strength aluminum alloy material, its production, tube for heat exchanger made of aluminum alloy and heat exchanger made of aluminum alloy
CN1107120C (en) * 1998-08-21 2003-04-30 戴姆勒-克莱斯勒股份公司 Novel weldable anti-corrosive aluminium-mangesium alloy containing high amount of magnesium, esp. for use in automobiles
CN1718836A (en) * 2004-07-09 2006-01-11 上海润实防蚀新材料科技有限公司 Rare earth aluminium magnesium alloy spray coating corrosion resistant wire material, its preparation method and application
CN1827815A (en) * 2006-03-24 2006-09-06 杨仁忠 Aluminium magnesium alloy wire
CN101033518A (en) * 2006-03-24 2007-09-12 杨仁忠 Aluminum-magnesium alloy wire
CN104451286A (en) * 2014-12-02 2015-03-25 绥阳县耐环铝业有限公司 Magnesium-aluminum alloy and processing technique thereof
CN104981554A (en) * 2013-01-25 2015-10-14 爱励轧制产品德国有限责任公司 Method of forming an al-mg alloy plate product
CN105489263A (en) * 2015-12-11 2016-04-13 百色学院 Ultra-fine aluminum magnesium alloy filament material and preparation method thereof

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11343532A (en) * 1998-05-28 1999-12-14 Mitsubishi Heavy Ind Ltd Corrosion resistant and high strength aluminum alloy material, its production, tube for heat exchanger made of aluminum alloy and heat exchanger made of aluminum alloy
CN1107120C (en) * 1998-08-21 2003-04-30 戴姆勒-克莱斯勒股份公司 Novel weldable anti-corrosive aluminium-mangesium alloy containing high amount of magnesium, esp. for use in automobiles
CN1718836A (en) * 2004-07-09 2006-01-11 上海润实防蚀新材料科技有限公司 Rare earth aluminium magnesium alloy spray coating corrosion resistant wire material, its preparation method and application
CN1827815A (en) * 2006-03-24 2006-09-06 杨仁忠 Aluminium magnesium alloy wire
CN101033518A (en) * 2006-03-24 2007-09-12 杨仁忠 Aluminum-magnesium alloy wire
CN104981554A (en) * 2013-01-25 2015-10-14 爱励轧制产品德国有限责任公司 Method of forming an al-mg alloy plate product
CN104451286A (en) * 2014-12-02 2015-03-25 绥阳县耐环铝业有限公司 Magnesium-aluminum alloy and processing technique thereof
CN105489263A (en) * 2015-12-11 2016-04-13 百色学院 Ultra-fine aluminum magnesium alloy filament material and preparation method thereof

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