CN107356915A - A kind of scaling method and calibration system of middle infrared differential absorption lidar - Google Patents

A kind of scaling method and calibration system of middle infrared differential absorption lidar Download PDF

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Publication number
CN107356915A
CN107356915A CN201710810558.XA CN201710810558A CN107356915A CN 107356915 A CN107356915 A CN 107356915A CN 201710810558 A CN201710810558 A CN 201710810558A CN 107356915 A CN107356915 A CN 107356915A
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gas
concentration
atmosphere pollution
infrared differential
measurement
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卜令兵
徐玲
郜海阳
蔡镐泽
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Nanjing University of Information Science and Technology
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Nanjing University of Information Science and Technology
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01SRADIO DIRECTION-FINDING; RADIO NAVIGATION; DETERMINING DISTANCE OR VELOCITY BY USE OF RADIO WAVES; LOCATING OR PRESENCE-DETECTING BY USE OF THE REFLECTION OR RERADIATION OF RADIO WAVES; ANALOGOUS ARRANGEMENTS USING OTHER WAVES
    • G01S7/00Details of systems according to groups G01S13/00, G01S15/00, G01S17/00
    • G01S7/48Details of systems according to groups G01S13/00, G01S15/00, G01S17/00 of systems according to group G01S17/00
    • G01S7/497Means for monitoring or calibrating

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  • Computer Networks & Wireless Communication (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Radar, Positioning & Navigation (AREA)
  • Remote Sensing (AREA)
  • Investigating Or Analysing Materials By Optical Means (AREA)

Abstract

The invention discloses a kind of scaling method of middle infrared differential absorption lidar, this method carries out concentration mensuration by infrared differential absorption lidar use simultaneously in and existing atmosphere pollution detection instrument to the standard solid gas of various concentrations, obtains the linearly dependent coefficient between the measurement result of middle infrared differential absorption lidar and atmosphere pollution detection instrument.The present invention is demarcated by existing atmosphere pollution detection instrument centering infrared differential absorption lidar, it is possible to increase the measurement accuracy of middle infrared differential absorption lidar, while higher sensitivity, farther detection range can be obtained.

Description

A kind of scaling method and calibration system of middle infrared differential absorption lidar
Technical field
Present invention relates particularly to a kind of demarcation of the middle infrared differential absorption lidar of pollutant measure Method.
Background technology
Laser radar is a kind of active contemporary optics remote sensing equipment, combines conventional radar technology and Modern Laser skill Art, it is the product that traditional radio or microwave radar extend to optics frequency range.Laser radar spatial and temporal resolution is high, detection blind area It is small, conventional detection instrument can be relatively well made up not with dusty gas particulate optical characteristic Characteristics of Vertical Distribution in atmospheric sounding Foot.These particular advantages of laser radar, make it the effective means of detection study atmosphere pollution.In recent decades, greatly The research and development of gas pollutant is quickly, it has also become an important branch of environmental monitoring.With Modern Laser radar system and technology Development, laser radar detection atmosphere pollution technology, atmospheric environment, Atmospheric Chemistry, atmospheric radiation monitoring with analysis and The fields such as climatic prediction are just playing very important effect.
Normal atmospheric pollutant monitoring mode mainly has electric chemical formula, catalytic combustion type, semiconductor-type and infrared-type, base Single in the instrument probe gas species of these modes, distance is near, short life.Laser gas monitoring technology is to develop in recent years Come new gas Detection Techniques, feature be it is non-contact without sampling, high sensitivity, the response time soon, can long-haul telemetry.Mesh Before, the most frequently used spectral technique has the differential optical absorption spectrum of ultraviolet/visible waveband in domestic and international laser radar system (DOAS), Fourier trasform spectroscopy (FTIR), the tunable semiconductor laser of DIAL (DIAL), infrared band Absorption spectrum (TDLAS) etc..Prior art uses ultraviolet, near-infrared fixed wave length laser more, and gas absorption is weaker in this wave band, Laser limited transmission distance in an atmosphere.Many toxic and harmful gas have strong absworption peak (than visible in middle infrared band Light and near infrared band absorb high several orders of magnitude), infrared band can obtain higher sensitivity, farther detection in utilization Distance.
Therefore, on the basis of existing instrument, centering infrared differential absorption lidar is surveyed data accuracy and demarcated It is most important to follow-up practical application.
The content of the invention
The invention aims to solve defect present in prior art, there is provided a kind of centering infrared differential, which absorbs, to swash Scaling method of the optical radar to atmosphere pollution measurement data.
In order to achieve the above object, should the invention provides a kind of scaling method of middle infrared differential absorption lidar Method is by infrared differential absorption lidar use simultaneously in and existing atmosphere pollution detection instrument to various concentrations Standard solid gas carries out concentration mensuration, obtains the measurement of middle infrared differential absorption lidar and atmosphere pollution detection instrument As a result the linearly dependent coefficient between.
Further, scaling method is demarcated including absorption cell, is concretely comprised the following steps:
(1) when the standard solid gas of various concentrations is filled with into absorption cell and balloon, and ensureing measurement every time, absorption cell It is consistent with gas concentration in balloon;
(2) using gas concentration value in atmosphere pollution detection instrument measure balloon, as reference concentration;
(3) infrared differential absorption lidar sends light path and is divided into two-way in, enters the second power by absorption cell all the way Meter, another way are directly entered the first power meter, are calculated by the first power evaluation and the second power evaluation corresponding in absorption cell Gas concentration, as measurement concentration;
(4) reference concentration and measurement concentration are fitted, draw linearly dependent coefficient between the two.
Further, above-mentioned scaling method also includes opening demarcation, concretely comprises the following steps:
(1) opening is selected as demarcation place, infrared differential absorption lidar and existing air in placement Detection of pollutants instrument;
(2) infrared differential absorption lidar in adjusting, makes its horizontal emission laser;Using big under different measuring conditions Gas detection of pollutants instrument and middle infrared differential absorption lidar carry out the measurement of concetration of standard solid gas simultaneously;Measure bar Part is:Dusty gas is not discharged, various concentrations standard solid gas is discharged successively by low concentration to high concentration;Various concentrations standard The off-position of dusty gas is atmosphere pollution detection instrument opening position;Atmosphere pollution is drawn according to measurement result respectively The measurement concentration profile of detection instrument and middle infrared differential absorption lidar;
(3) measurement of the atmosphere pollution detection instrument and middle infrared differential absorption lidar that are obtained according to step (2) Concentration profile, draw the linearly dependent coefficient between two measurement results.
Wherein, atmosphere pollution detection instrument uses high sensitivity thermoelectrometry apparatus or portable nitrogen oxides.
Present invention also offers using above-mentioned scaling method calibration system, including middle infrared differential absorption lidar, Beam splitter, absorption cell, the first power meter, the second power meter, computer, balloon, gas pouch, atmosphere pollution detection instrument;Inflation When, the outlet side of the gas pouch connects absorption cell and balloon respectively;The middle infrared differential absorption lidar transmitting laser Two-way is divided into by beam splitter, enters the first power meter after absorption cell all the way, another way is directly entered the second power meter, the One power meter and the second power meter connect computer respectively;The atmosphere pollution detection instrument is connected with balloon.
Wherein, atmosphere pollution detection instrument uses high sensitivity thermoelectrometry apparatus or portable nitrogen oxides.
High sensitivity thermoelectrometry apparatus Measurement Resolution is 0.01ppm, the degree of accuracy is full scale ± 2%.
Absorption cell is short light path gas absorption cell, and optical path length is 500 millimeters, 157 milliliters of volume, and window diameter 12.7 is in the least Rice.
The present invention has advantages below compared with prior art:
Demarcated by existing atmosphere pollution detection instrument centering infrared differential absorption lidar, it is possible to increase in The measurement accuracy of infrared differential absorption lidar, while higher sensitivity, farther detection range can be obtained.
Brief description of the drawings
Fig. 1 is the system structure diagram of absorption cell of the present invention demarcation;
Fig. 2 is the system structure diagram of opening of the present invention demarcation.
In figure, infrared differential absorption lidar in 1-, 2- absorption cells, the power meters of 3- first, the power meters of 4- second, 5- electricity Brain, 6- atmosphere pollution detection instruments, 6A- high sensitivity thermoelectrometry apparatuses, the portable nitrogen oxides detectors of 6B-, 7- balloons, 8- gas Body bag, the hard targets of 9-, 10- beam splitters.
Embodiment
The present invention provide one kind can the sensitivity of centering infrared differential absorption lidar systematic survey, accuracy determined Calibration method, this method are using measurement resolution as the thermoelectrometry apparatus of 0.01ppm, the degree of accuracy for full scale ± 2% and portable nitrogen The measurement result of oxide detector is as reference, and calibration precision is high, relative error is small.
In order to better illustrate the present invention relates to scaling method, divide below two parts combination accompanying drawing to the present invention carry out Describe in detail.Part I is absorption cell internal standard concentration calibration, and infrared differential is inhaled in being measured under known gas concentration levels It is related to existing atmosphere pollution detection instrument (thermoelectrometry apparatus, portable nitrogen oxides detector) measurement result to receive laser radar Coefficient, laid the foundation for the demarcation of follow-up measurement capability;Part II be opening demarcation, be divided into release nitrogen dioxide gas with Nitrogen dioxide gas is not discharged, infrared differential absorption lidar measurement accuracy and sensitivity in confirmation, centering infrared differential Absorption lidar measurement accuracy is demarcated.
Introduce specific steps and respective algorithms in two sub-sections below:
(1) absorption cell internal standard concentration calibration:
Step:
(1) intend before testing, carry out preparation before each unit test of instrument in advance according to instrument use demand respectively, (high sensitivity thermoelectrometry apparatus 6A, portable nitrogen oxides detector 6B and middle infrared differential absorb and swashed each instrument in this calibrating method Optical radar 1) by placement as shown in Figure 1.Air in absorption cell 2 is emptied using vavuum pump, absorption cell 2 is placed in figure middle position Put.Each instrument be in can working condition, after system mode is stable, use wavemeter measurement optical maser wavelength, it is ensured that optical maser wavelength is steady It is fixed;It is two-way that wherein middle infrared differential absorption lidar 1, which launches laser by beam splitter 10, laggard by absorption cell 2 all the way Enter the first power meter 3, another way is directly entered the second power meter 4, and the first power meter 3 and the second power meter 4 connect computer respectively 5, into data collecting system;
(2) is under balanced air pressure, state of temperature, and instrument show value when survey absorption cell, balloon 7 are not filled with dusty gas is more Secondary measurement is averaged as the zero point error x in follow-up measurement process01With y01
(3) be filled with by the gas pouch 8 equipped with nitrogen dioxide gas into absorption cell 2, balloon 7 be filled with respectively it is different dense The standard solid gas of degree, concentration value change from low to high, are initially filled with concentration value close to calibration instrument high sensitivity thermoelectrometry apparatus Measurement Resolution value smaller value in 6A, portable nitrogen oxides detector 6B, and be filled with gas concentration and changed directly using dichotomy Concentration value and high sensitivity thermoelectrometry apparatus 6A, portable nitrogen oxides detector 6B are surveyed to middle infrared differential absorption lidar 1 Close, thus, repeatedly measurement takes minimum value as infrared differential absorption lidar measurement sensitivity S in confirming1
(4) records mutually descend high sensitivity thermoelectrometry apparatus 6A, portable nitrogen oxides detector 6B concentration values and absorption in the same time The first power meter 3 and the second power meter 4 are worth before and after pond, and it is dense to calculate the corresponding gas of transmitance mean value calculation in absorption cell 5 minutes Angle value and optical maser wavelength, whole process will ensure pressure, temperature close to pressure when not being filled with dusty gas in absorption cell, temperature Degree;
(5) is fitted to measurement concentration and actual concentrations, draws middle infrared differential absorption lidar 1 and height respectively Sensitivity thermoelectrometry apparatus 6A, portable nitrogen oxides detector 6B linearly dependent coefficient two-by-two, analysis system measurement result accuracy.
Algorithm:
(1) described in steps as measured above, by measuring respective power P 1, P2 of two light paths after the light splitting of radar emission light path, Calculate transmitance of the standard gas adsorption pond on, off wavelength
Wherein σOn, offFor gas molecules sorb section, NLFor Loschimite constants 2.687 × 1019For in unit volume Gas molecule Particle density, ε are total gas volume percentage shared by dusty gas, and L is absorption cell optical length.P (R) is environment pressure By force, T (R) is environment temperature.
(2) optical path splitting ratio is calculated
(3) actual measurement air body absorption cell transmitance is calculated
(4) actual measurement charge air conditioning absorption cell transmitance is calculated
(5) actual measurement gas cell concentration x is calculated
According to formula in (1) formula, τ is made02, calculate Nm, i.e. the Particle density of gas, according to molecular weight and Avobenzene gal moral The Particle density conversion of gas is unit mg/m by sieve constant3Concentration value x.
(6) linear regression formula is utilized, infrared differential absorption lidar and thermoelectrometry apparatus, portable nitrogen oxides in calculating Detector measurement concentration linearly dependent coefficient r.
Xi=x-x01Yi=y-y01
Wherein, x, y are that middle infrared differential absorption lidar and thermoelectrometry apparatus (or portable detector) measure nitrogen dioxide Concentration show value;
xi、yiFor measured value after two instrument background amendments;
x0To be filled with dusty gas concentration in absorption cell;
x01And y01Respectively middle infrared differential absorption lidar and thermoelectrometry apparatus (or portable detector) sample-out count Value;
N is pendulous frequency.
(2) opening is demarcated:
Step:
(1), selection more opening can be easy to place system, dispose calibration instrument as shown in Figure 2 as calibration place Device.Distance is 30 meters between setting the hard target 9 of target, such as campus basketball court, and can carry out at night and calibrate, can avoid idler couple Interference caused by experiment;
(2) in advance disposes middle infrared differential absorption lidar system and measuring instrument according to each instrument requirement In measuring environment, beaten in middle infrared differential absorption lidar 1 to being equidistantly positioned other two kinds measurements on the hard target direction of target 9 Instrument 6 (high sensitivity thermoelectrometry apparatus or portable nitrogen oxides detector) settlement, three instrument can be just opened after being all connected with properly Device, and calibration and usage instrument is calibrated respectively, and swashed by infrared differential absorption lidar horizontal emission in the guarantee of hard target 9 Light;
(3) ensures three instruments under measurable state, and hard targets are moved with 30 meters of intervals, in thermoelectrometry apparatus, portable Detector lay down location discharges nitrogen dioxide gas, and measuring condition is not by discharging dusty gas, gas low concentration to gas high concentration Discharge successively, and various concentrations gas is discharged behind each hard target shift position, three kinds of instruments measure 10 minutes gas concentrations Value, to cause the wealthy line Long-term change trend of concentration to tend to measured value, will finally measure average value as measured value;
(4) for after in view of coefficient correlation between zero point error and instrument, being drawn using spot measurement concentration value has distance The concentration profile of resolution ratio, the result of three kinds of measuring instruments is contrasted, analysis system measurement accuracy, sensitivity and dusty gas exist The time and space regularity of distribution in air, draw measurement result linearly dependent coefficient between instrument.
Algorithm:
(1) when DIAL is in measuring route concentration, radar equation can be expressed as:
Wherein, PtIt is peak power, c is the light velocity, and τ is laser radar system transmitance, and A looks in the distance mirror area, η reception systems Efficiency, β (R) atmospheric backscatter coefficient, α (R) atmospheric extinction coefficient, C are under test gas concentration, and L is that gas absorbs light path, γOn, offFor gas molecules sorb coefficient, R is detection range.Generally regard CL as a variable, turn into concentration light path product, also may be used C is referred to as gas mean concentration under the light path.
(2) after infrared differential absorption lidar measures on and off pulse accumulation echo-signals among, first to returning Ripple signal is pre-processed:
1. selection distant location signal (2~3km) is deducted point by point as background signal;
2. denoising smooth is carried out to signal using slipping smoothness, Wavelet Denoising Method scheduling algorithm;
(3) is accumulated to the signal by pretreatment using the mean concentration or concentration light path of ratio method inverting gas, and formula is such as Under:
Wherein, C represents gas path mean concentration, and CL accumulates for concentration light path, and Δ γ is the Difference Absorption system of gas molecule Number, PonAnd PoffFor two wavelength echo powers.T items are atmospheric extinction error term.
(4) is using gas path mean concentration C as measurement concentration value x, using linear regression formula, Infrared Difference in calculating Divide absorption lidar and thermoelectrometry apparatus (portable detector) measurement concentration linearly dependent coefficient r.
Xi=x-x01yi=y-y01
Wherein, x, y are that middle infrared differential absorption lidar and thermoelectrometry apparatus (portable detector) measurement nitrogen dioxide are dense Spend show value;xi、yiFor measured value after two instrument background amendments;
x0To be filled with dusty gas concentration in absorption cell;
x01And y01Respectively middle infrared differential absorption lidar and thermoelectrometry apparatus (portable detector) sample-out count value;
N is pendulous frequency.

Claims (7)

  1. A kind of 1. scaling method of middle infrared differential absorption lidar, it is characterised in that:This method passes through red use simultaneously in Outer DIAL and existing atmosphere pollution detection instrument carry out concentration to the standard solid gas of various concentrations Measure, obtain the linearly related system between the measurement result of middle infrared differential absorption lidar and atmosphere pollution detection instrument Number.
  2. 2. scaling method according to claim 1, it is characterised in that:The scaling method is demarcated including absorption cell, specifically Step is:
    (1)When the standard solid gas of various concentrations is filled with into absorption cell and balloon, and ensureing measurement every time, absorption cell is gentle Gas concentration is consistent in ball;
    (2)Using gas concentration value in atmosphere pollution detection instrument measure balloon, as reference concentration;
    (3)Middle infrared differential absorption lidar sends light path and is divided into two-way, enters the second power meter by absorption cell all the way, separately The first power meter is directly entered all the way, is calculated, drawn by bringing the first power evaluation and the second power evaluation into correlation formula Corresponding gas concentration in absorption cell, as measurement concentration;
    (4)Reference concentration and measurement concentration are fitted, draw linearly dependent coefficient between the two.
  3. 3. scaling method according to claim 1 or 2, it is characterised in that:The scaling method also includes opening mark It is fixed, concretely comprise the following steps:
    (1)Opening is selected as demarcation place, infrared differential absorption lidar and existing atmosphere pollution in placement Thing detection instrument;
    (2)Infrared differential absorption lidar in regulation, make its horizontal emission laser;It is dirty using air under different measuring conditions Dye thing detection instrument and middle infrared differential absorption lidar carry out the measurement of concetration of standard solid gas simultaneously;Measuring condition For:Dusty gas is not discharged, various concentrations standard solid gas is discharged successively by low concentration to high concentration;Various concentrations standard is dirty The off-position for contaminating gas is atmosphere pollution detection instrument opening position;Draw atmosphere pollution physical prospecting respectively according to measurement result Survey the measurement concentration profile of instrument and middle infrared differential absorption lidar;
    (3)According to step(2)Obtained atmosphere pollution detection instrument and the measurement concentration of middle infrared differential absorption lidar Profile, draw the linearly dependent coefficient between two measurement results.
  4. 4. scaling method according to claim 3, it is characterised in that:The atmosphere pollution detection instrument is using highly sensitive Spend thermoelectrometry apparatus or portable nitrogen oxides.
  5. A kind of 5. calibration system using scaling method described in claim 2, it is characterised in that:The calibration system is red in including Outer DIAL, beam splitter, absorption cell, the first power meter, the second power meter, computer, balloon, gas pouch, air Detection of pollutants instrument;During inflation, the outlet side of the gas pouch connects absorption cell and balloon respectively;The middle infrared differential is inhaled Receive laser radar transmitting laser and two-way is divided into by beam splitter, enter the first power meter after absorption cell all the way, another way is straight Tap into and connect computer respectively into the second power meter, the first power meter and the second power meter;The atmosphere pollution detection instrument with Balloon is connected.
  6. 6. calibration system according to claim 5, it is characterised in that:The atmosphere pollution detection instrument is using highly sensitive Spend thermoelectrometry apparatus or portable nitrogen oxides.
  7. 7. calibration system according to claim 6, it is characterised in that:The absorption cell is short light path gas absorption cell, light Cheng Changdu is 500 millimeters, 157 milliliters of volume, 12.7 millimeters of window diameter.
CN201710810558.XA 2017-09-11 2017-09-11 A kind of scaling method and calibration system of middle infrared differential absorption lidar Pending CN107356915A (en)

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CN108490138A (en) * 2018-05-10 2018-09-04 天津大学 Judge the whether super calibration method of Pollution From Ships object according to Laser Radar Observation data
CN109655843A (en) * 2019-01-16 2019-04-19 武汉大学 Detect the pulsed infrared Differential Absorption Laser Radar System of gas concentration lwevel profile
CN110471046A (en) * 2019-08-29 2019-11-19 南京信息工程大学 A kind of Differential Absorption Laser Radar System constant calibrating method
CN110702236A (en) * 2019-11-08 2020-01-17 中国计量科学研究院 High-precision spectrum calibration method for optical fiber wavelength standard device
RU216578U1 (en) * 2022-09-02 2023-02-14 Федеральное государственное бюджетное учреждение науки Институт оптики атмосферы им. В.Е. Зуева Сибирского отделения Российской академии наук AIRBORNE LIDAR IN THE MIDDLE INFRARED RANGE

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CN108490138A (en) * 2018-05-10 2018-09-04 天津大学 Judge the whether super calibration method of Pollution From Ships object according to Laser Radar Observation data
CN108490138B (en) * 2018-05-10 2024-04-09 天津大学 Method for judging whether ship pollutants exceed standard according to laser radar observation data
CN109655843A (en) * 2019-01-16 2019-04-19 武汉大学 Detect the pulsed infrared Differential Absorption Laser Radar System of gas concentration lwevel profile
CN110471046A (en) * 2019-08-29 2019-11-19 南京信息工程大学 A kind of Differential Absorption Laser Radar System constant calibrating method
CN110702236A (en) * 2019-11-08 2020-01-17 中国计量科学研究院 High-precision spectrum calibration method for optical fiber wavelength standard device
RU216578U1 (en) * 2022-09-02 2023-02-14 Федеральное государственное бюджетное учреждение науки Институт оптики атмосферы им. В.Е. Зуева Сибирского отделения Российской академии наук AIRBORNE LIDAR IN THE MIDDLE INFRARED RANGE

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