CN107354566A - A kind of preparation method of environmentally friendly graphene antistatic antibiotic Anti-cut Gloves - Google Patents

A kind of preparation method of environmentally friendly graphene antistatic antibiotic Anti-cut Gloves Download PDF

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Publication number
CN107354566A
CN107354566A CN201710473217.8A CN201710473217A CN107354566A CN 107354566 A CN107354566 A CN 107354566A CN 201710473217 A CN201710473217 A CN 201710473217A CN 107354566 A CN107354566 A CN 107354566A
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graphene
weight polyethylene
molecular weight
ultra
high molecular
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张炜栋
黄旭
张娟
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Nantong Textile Vocational Technology College
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Nantong Textile Vocational Technology College
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Abstract

The invention discloses a kind of preparation method of environmentally friendly graphene antistatic antibiotic Anti-cut Gloves, the gloves with yarn under working braiding by being formed：One or more in ultra-high molecular weight polyethylene/graphite alkene polyamide fibre coating cotton thread, ultra-high molecular weight polyethylene/graphite alkene terylene coating cotton thread, ultra-high molecular weight polyethylene+glass covering yarn, spandex-coated yarn, shirr；Gloves after braiding are modified NBR latex impregnation using graphene, obtain finished product.Preparation technology of the present invention is simple, can mass produce, and the anti-cutting performance of the gloves is high, has a performance such as preferable antistatic, antibacterial, anti-cutting, chemicals-resistant, anti-skidding, wearing comfort, conveniently.It can be widely applied to equipment manufacture, outdoor exercises etc..

Description

A kind of preparation method of environmentally friendly graphene antistatic antibiotic Anti-cut Gloves
Technical field
The invention belongs to Labor protection gloves field, and in particular to a kind of environmentally friendly graphene antistatic antibiotic anti-cutting The preparation method of gloves.
Background technology
Graphene is a kind of graphite flake of individual layer, and one layer of carbon atom that is intensive, being wrapped in honeycomb crystal lattice is with sp2 Hybridized orbit composition hexagon is in the flat film of an only carbon atom thickness for honeycomb lattice.The special construction of graphene is determined Fixed its has many unique performances：Graphene be at present most it is thin but and the most firm nano material of structure, or electricity at present The minimum material of resistance rate.In addition, part researcher prepares nano-graphene fibre using graphene as raw material, by electrostatic spinning technique Tie up antibacterial felt.
The content of the invention
Goal of the invention：In order to solve the deficiencies in the prior art, resist the invention provides a kind of environmentally friendly graphene quiet The preparation method of reactance bacterium Anti-cut Gloves, the gloves prepared have excellent antistatic, antibacterial, cold-resistant, anti-cut, waterproof, Grease proofing, chemically effect, meanwhile, there is comfortable feel, super soft, absorbing sweat, it is anti-skidding, adhesive force is strong the features such as, Ke Yiguang It is general to apply to automobile, machinery, glass and outdoor goods.
Technical scheme：A kind of preparation method of environmentally friendly graphene antistatic antibiotic Anti-cut Gloves, the gloves lead to Cross and formed with yarn under working braiding：Ultra-high molecular weight polyethylene/graphite alkene polyamide fibre coating cotton thread, ultra-high molecular weight polyethylene/graphite One or more in alkene terylene coating cotton thread, ultra-high molecular weight polyethylene+glass covering yarn, spandex-coated yarn, shirr； Gloves after braiding are modified NBR latex impregnation using graphene, obtain finished product；Wherein：The graphene is modified NBR latex, NBR latex, carbon black, graphene nano material, metal oxide, accelerator and polyurethane resin are taken, specific prescription of preparing is by such as Lower parts by weight composition：
Above chemicals, which is mixed, must impregnate glue, and weaving good hand is covered into dipping, drying, obtains product.
As optimization：The gloves are woven from full-computerized U3 high speed glove knitting machines, select 13,15,18 pins to compile Program is knitted, chooses following component braiding in parts by weight：Described ultra-high molecular weight polyethylene/graphite alkene polyamide fibre coating cotton thread Or ultra-high molecular weight polyethylene/graphite alkene terylene coating cotton thread：50-70 parts, ultra-high molecular weight polyethylene+glass covering yarn： 20-30 parts, spandex-coated yarn：10-20 parts.
As optimization：The ultra-high molecular weight polyethylene/graphite alkene polyamide fibre coating cotton thread is specially：Superhigh molecular weight polyethylene One kind in alkene 30D, 32D, 35D, 50D and 30-40D graphene polyamide fibre.
As optimization：The ultra-high molecular weight polyethylene/graphite alkene terylene coating cotton thread is specially：Superhigh molecular weight polyethylene One kind in alkene 30D, 32D, 35D, 50D and 30-40D graphene terylene.
As optimization：The graphene polyamide fibre, graphene polyester fiber are to add single-layer graphene, the list before spinning Layer graphene content is 0.3-0.8%.
As optimization：In the ultra-high molecular weight polyethylene+glass covering yarn, yarn footpath is：0.3-0.7mm, with glass For core, one kind in specification 10S, 16S, 20S.
As optimization：The spandex-coated yarn is：Polyamide fibre spandex is：2030th, one kind in 2040,2050,2070；Wash Synthetic fibre spandex is：2050th, one kind in 2075,3075,4075,7075.
As optimization：The NBR latex is the one or more in NBR102, QN-01, NBR-1704, FM-201.
As optimization：The metal oxide be nano zine oxide, nano phase ag_2 o, one kind in nano titanium oxide or It is several.
As optimization：The polyurethane resin is the one or more in ASM-2009, MR-709, PU200B.
Beneficial effect：Present invention process is simple, can be achieved mass automatic production, the gloves antibacterial, heat resistanceheat resistant, cold-resistant, Anti-cut, antistatic, uvioresistant.5 grades of 13 pins leaching palm gloves anti-cut index, has Water-proof and oil-proof, the effect of chemically, Comfortable feel, super soft, absorbing sweat, it is anti-skidding, adhesive force is strong the features such as.
Antibacterial, heat resistanceheat resistant, cold-resistant, anti-cut, antistatic, uvioresistant performance are by ultra-high molecular weight polyethylene/stone in the present invention Black alkene polyamide fibre coating cotton thread, ultra-high molecular weight polyethylene/graphite alkene terylene coating cotton thread provide, and are the main supports of anti-cut. Another woven into fabric is super soft, and absorbing sweat has good feel.
Ultra-high molecular weight polyethylene+glass composite yarn is the secondary branch that anti-cutting gloves put cutting performance in the present invention Hold, strengthen the anti-cutting performance of gloves.
Spandex covered yarn in the present invention has good elasticity, there is provided the resilience of gloves, woven into fabric are super soft.
Modified butyronitrile coating provides Water-proof and oil-proof, chemically characteristic in the present invention, resists wherein adding graphene and providing The function such as bacterium, heat resistanceheat resistant, cold-resistant, anti-cut, antistatic, uvioresistant, add metal oxide and antibacterial, antistatic, uvioresistant are provided The functions such as automatically cleaning.
Embodiment
The technical scheme in the embodiment of the present invention will be clearly and completely described below, so that the technology of this area Personnel can be better understood from advantages and features of the invention, so as to make apparent boundary to protection scope of the present invention It is fixed.Embodiment described in the invention is only part of the embodiment of the present invention, rather than whole embodiments, based on the present invention In embodiment, the every other implementation that those of ordinary skill in the art are obtained on the premise of creative work is not made Example, belongs to the scope of protection of the invention.
As summary, heretofore described ultra-high molecular weight polyethylene/graphite alkene polyamide fibre coating cotton thread is specially：Superelevation point One kind in sub- weight northylen 30D, 32D, 35D, 50D and 30-40D graphene polyamide fibre.
The ultra-high molecular weight polyethylene/graphite alkene terylene coating cotton thread is specially：Ultra-high molecular weight polyethylene 30D, One kind in 32D, 35D, 50D and 30-40D graphene terylene.
The graphene polyamide fibre, graphene polyester fiber are to add single-layer graphene, the single-layer graphene before spinning Content is 0.3-0.8%.
In the ultra-high molecular weight polyethylene+glass covering yarn, yarn footpath is：0.3-0.7mm, using glass as core, specification For 10S, one kind in 16S, 20S.
The spandex-coated yarn is：Polyamide fibre spandex is：2030th, one kind in 2040,2050,2070；Terylene spandex is： 2050th, one kind in 2075,3075,4075,7075.
The NBR latex is the one or more in NBR102, QN-01, NBR-1704, FM-201.
The metal oxide is the one or more in nano zine oxide, nano phase ag_2 o, nano titanium oxide.
The polyurethane resin is the one or more in ASM-2009, MR-709, PU200B.
Specific embodiment 1
A kind of preparation method of environmentally friendly graphene antistatic antibiotic Anti-cut Gloves, the gloves pass through with yarn under working Braiding forms：Ultra-high molecular weight polyethylene/graphite alkene polyamide fibre coating cotton thread, ultra-high molecular weight polyethylene/graphite alkene terylene cladding One or more in yarn, ultra-high molecular weight polyethylene+glass covering yarn, spandex-coated yarn, shirr；Hand after braiding Set is modified NBR latex impregnation using graphene, obtains finished product；Wherein：The graphene is modified NBR latex, take NBR latex, Carbon black, graphene nano material, metal oxide, accelerator and polyurethane resin, specific prescription of preparing press following parts by weight Composition：
Above chemicals, which is mixed, must impregnate glue, and weaving good hand is covered into dipping, drying, obtains product.
The gloves are woven from full-computerized U3 high speed glove knitting machines, select 13,15,18 needle knitting programs, choosing Take following component braiding in parts by weight：Described ultra-high molecular weight polyethylene/graphite alkene polyamide fibre coating cotton thread or superelevation Molecular weight polyethylene/graphene terylene coating cotton thread：50 parts, ultra-high molecular weight polyethylene+glass covering yarn：20 parts, spandex bag Cover yarn：10 parts.
Specific embodiment 2
A kind of preparation method of environmentally friendly graphene antistatic antibiotic Anti-cut Gloves, the gloves pass through with yarn under working Braiding forms：Ultra-high molecular weight polyethylene/graphite alkene polyamide fibre coating cotton thread, ultra-high molecular weight polyethylene/graphite alkene terylene cladding One or more in yarn, ultra-high molecular weight polyethylene+glass covering yarn, spandex-coated yarn, shirr；Hand after braiding Set is modified NBR latex impregnation using graphene, obtains finished product；Wherein：The graphene is modified NBR latex, take NBR latex, Carbon black, graphene nano material, metal oxide, accelerator and polyurethane resin, specific prescription of preparing press following parts by weight Composition：
Above chemicals, which is mixed, must impregnate glue, and weaving good hand is covered into dipping, drying, obtains product.
The gloves are woven from full-computerized U3 high speed glove knitting machines, select 13,15,18 needle knitting programs, choosing Take following component braiding in parts by weight：Described ultra-high molecular weight polyethylene/graphite alkene polyamide fibre coating cotton thread or superelevation Molecular weight polyethylene/graphene terylene coating cotton thread：70 parts, ultra-high molecular weight polyethylene+glass covering yarn：30 parts, spandex bag Cover yarn：20 parts.
Specific embodiment 3
A kind of preparation method of environmentally friendly graphene antistatic antibiotic Anti-cut Gloves, the gloves pass through with yarn under working Braiding forms：Ultra-high molecular weight polyethylene/graphite alkene polyamide fibre coating cotton thread, ultra-high molecular weight polyethylene/graphite alkene terylene cladding One or more in yarn, ultra-high molecular weight polyethylene+glass covering yarn, spandex-coated yarn, shirr；Hand after braiding Set is modified NBR latex impregnation using graphene, obtains finished product；Wherein：The graphene is modified NBR latex, take NBR latex, Carbon black, graphene nano material, metal oxide, accelerator and polyurethane resin, specific prescription of preparing press following parts by weight Composition：
Above chemicals, which is mixed, must impregnate glue, and weaving good hand is covered into dipping, drying, obtains product.
The gloves are woven from full-computerized U3 high speed glove knitting machines, select 13,15,18 needle knitting programs, choosing Take following component braiding in parts by weight：Described ultra-high molecular weight polyethylene/graphite alkene polyamide fibre coating cotton thread or superelevation Molecular weight polyethylene/graphene terylene coating cotton thread：60 parts, ultra-high molecular weight polyethylene+glass covering yarn：23 parts, spandex bag Cover yarn：14 parts.
Present invention process is simple, can be achieved mass automatic production, the gloves antibacterial, heat resistanceheat resistant, cold-resistant, anti-cut, anti- Electrostatic, uvioresistant.5 grades of 13 pins leaching palm gloves anti-cut index, has Water-proof and oil-proof, an effect of chemically, comfortable feel, It is super soft, absorbing sweat, it is anti-skidding, adhesive force is strong the features such as.
Antibacterial, heat resistanceheat resistant, cold-resistant, anti-cut, antistatic, uvioresistant performance are by ultra-high molecular weight polyethylene/stone in the present invention Black alkene polyamide fibre coating cotton thread, ultra-high molecular weight polyethylene/graphite alkene terylene coating cotton thread provide, and are the main supports of anti-cut. Another woven into fabric is super soft, and absorbing sweat has good feel.
Ultra-high molecular weight polyethylene+glass composite yarn is the secondary branch that anti-cutting gloves put cutting performance in the present invention Hold, strengthen the anti-cutting performance of gloves.
Spandex covered yarn in the present invention has good elasticity, there is provided the resilience of gloves, woven into fabric are super soft.
Modified butyronitrile coating provides Water-proof and oil-proof, chemically characteristic in the present invention, resists wherein adding graphene and providing The function such as bacterium, heat resistanceheat resistant, cold-resistant, anti-cut, antistatic, uvioresistant, add metal oxide and antibacterial, antistatic, uvioresistant are provided The functions such as automatically cleaning.

Claims (10)

  1. A kind of 1. preparation method of environmentally friendly graphene antistatic antibiotic Anti-cut Gloves, it is characterised in that：The gloves lead to Cross and formed with yarn under working braiding：Ultra-high molecular weight polyethylene/graphite alkene polyamide fibre coating cotton thread, ultra-high molecular weight polyethylene/graphite One or more in alkene terylene coating cotton thread, ultra-high molecular weight polyethylene+glass covering yarn, spandex-coated yarn, shirr； Gloves after braiding are modified NBR latex impregnation using graphene, obtain finished product；Wherein：The graphene is modified NBR latex, NBR latex, carbon black, graphene nano material, metal oxide, accelerator and polyurethane resin are taken, specific prescription of preparing is by such as Lower parts by weight composition：
    Above chemicals, which is mixed, must impregnate glue, and weaving good hand is covered into dipping, drying, obtains product.
  2. 2. the preparation method of environmentally friendly graphene antistatic antibiotic Anti-cut Gloves according to claim 1, its feature It is：The gloves are woven from full-computerized U3 high speed glove knitting machines, select 13,15,18 needle knitting programs, are chosen such as Under in parts by weight component braiding：Described ultra-high molecular weight polyethylene/graphite alkene polyamide fibre coating cotton thread or supra polymer Weight polyethylene/graphite alkene terylene coating cotton thread：50-70 parts, ultra-high molecular weight polyethylene+glass covering yarn：20-30 parts, spandex Coating cotton thread：10-20 parts.
  3. 3. the preparation method of environmentally friendly graphene antistatic antibiotic Anti-cut Gloves according to claim 1, its feature It is：The ultra-high molecular weight polyethylene/graphite alkene polyamide fibre coating cotton thread is specially：Ultra-high molecular weight polyethylene 30D, 32D, One kind in 35D, 50D and 30-40D graphene polyamide fibre.
  4. 4. the preparation method of environmentally friendly graphene antistatic antibiotic Anti-cut Gloves according to claim 1, its feature It is：The ultra-high molecular weight polyethylene/graphite alkene terylene coating cotton thread is specially：Ultra-high molecular weight polyethylene 30D, 32D, One kind in 35D, 50D and 30-40D graphene terylene.
  5. 5. the preparation method of environmentally friendly graphene antistatic antibiotic Anti-cut Gloves according to claim 1, its feature It is：The graphene polyamide fibre, graphene polyester fiber are to add single-layer graphene, the single-layer graphene content before spinning For 0.3-0.8%.
  6. 6. the preparation method of environmentally friendly graphene antistatic antibiotic Anti-cut Gloves according to claim 1, its feature It is：In the ultra-high molecular weight polyethylene+glass covering yarn, yarn footpath is：0.3-0.7mm, using glass as core, specification is One kind in 10S, 16S, 20S.
  7. 7. the preparation method of environmentally friendly graphene antistatic antibiotic Anti-cut Gloves according to claim 1, its feature It is：The spandex-coated yarn is：Polyamide fibre spandex is：2030th, one kind in 2040,2050,2070；Terylene spandex is： 2050th, one kind in 2075,3075,4075,7075.
  8. 8. the preparation method of environmentally friendly graphene antistatic antibiotic Anti-cut Gloves according to claim 1, its feature It is：The NBR latex is the one or more in NBR102, QN-01, NBR-1704, FM-201.
  9. 9. the preparation method of environmentally friendly graphene antistatic antibiotic Anti-cut Gloves according to claim 1, its feature It is：The metal oxide is the one or more in nano zine oxide, nano phase ag_2 o, nano titanium oxide.
  10. 10. the preparation method of environmentally friendly graphene antistatic antibiotic Anti-cut Gloves according to claim 1, its feature It is：The polyurethane resin is the one or more in ASM-2009, MR-709, PU200B.
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CN108823718A (en) * 2018-08-06 2018-11-16 魏桥纺织股份有限公司 A kind of production method of graphene modified fibre core-spun elastic yarn line and elastic fabric
CN109881344A (en) * 2019-02-28 2019-06-14 江苏工程职业技术学院 A kind of preparation method of copper ion modified polyester staple fiber antibacterial gloves
CN110644243A (en) * 2019-08-27 2020-01-03 徐州华通手套有限公司 Processing technology of cutting-resistant gloves
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CN108823718A (en) * 2018-08-06 2018-11-16 魏桥纺织股份有限公司 A kind of production method of graphene modified fibre core-spun elastic yarn line and elastic fabric
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CN113862873A (en) * 2021-10-28 2021-12-31 正凯纺织有限公司 Multifunctional graphene/polyester-viscose interwoven fabric and preparation method thereof
CN114246386A (en) * 2021-12-29 2022-03-29 南通强生新材料科技股份有限公司 Graphene anti-seismic, anti-cutting and anti-needling multifunctional glove and preparation method thereof
WO2023173502A1 (en) * 2022-03-17 2023-09-21 南通强生新材料科技股份有限公司 Cut-resistant protective glove and manufacturing method therefor
WO2023173800A1 (en) * 2022-03-17 2023-09-21 南通强生新材料科技股份有限公司 Cutting-resistant protective gloves and preparation method therefor

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