CN107353781A - A kind of aqueous epoxy floor coating - Google Patents
A kind of aqueous epoxy floor coating Download PDFInfo
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- CN107353781A CN107353781A CN201710722794.6A CN201710722794A CN107353781A CN 107353781 A CN107353781 A CN 107353781A CN 201710722794 A CN201710722794 A CN 201710722794A CN 107353781 A CN107353781 A CN 107353781A
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- floor coating
- epoxy resin
- aqueous epoxy
- coating according
- epoxy floor
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/04—Epoxynovolacs
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The present invention discloses a kind of aqueous epoxy floor coating, including following components, by mass percentage：30 35% modified epoxy containing amino, 18 20% polyacrylate resins, 10 12% mixed crystal type titanium oxide, 5 8% calcium carbonate, 3 5% talcum powder, 2 4% kaolin, 1 2% carboxymethyl cellulose, 1 2% calgon, 1 3% ethylene glycol, remaining be deionized water.The aqueous epoxy floor coating antimycotic antiseptic performance is better than existing commercialized aqueous epoxy floor coating.And there is good weatherability properties, scratch resistance and anti-stoning energy after the coating film forming.
Description
Technical field
The present invention relates to the technical field of coating, more particularly to a kind of aqueous epoxy floor coating.
Background technology
With being continuously increased of population in the world, air temperature warming, bacterial virus attacks people, especially cured whenever and wherever possible
Institute, house, pharmacy and food service industry, often because of epoxide terrace painted surface and internal bacterium, mould breeding, cause environment dirty
Dye, in order to promote health, make the life better with working environment, it is necessary to develop a water-base epoxy with antimycotic antiseptic effect
Floor coatings.
The content of the invention
It is an object of the invention to provide a kind of aqueous epoxy floor coating method, solves one in above-mentioned prior art problem
It is or multiple.
A kind of aqueous epoxy floor coating provided by the invention, including following components, by mass percentage：30-35%
The modified epoxy containing amino, 18-20% polyacrylate resins, 10-12% mixed crystal type titanium oxide, 5-8% carbon
Sour calcium, 3-5% talcum powder, 2-4% kaolin, 1-2% carboxymethyl cellulose, 1-2% calgon, 1-3%
Ethylene glycol, remaining be deionized water.
In some embodiments, the modified epoxy preparation method containing amino is by novolac epoxy resin, epoxy
Resin and chain extender, in the presence of catalyst, 130 DEG C of -190 DEG C of progress open loop chain extending reactions of reaction temperature, reach theory
After epoxide equivalent, 80-90 DEG C of addition organic amine compound is cooled to, amination and chain extending reaction are carried out between 110-130 DEG C, is obtained
The modified epoxy containing amino after amination.
In some embodiments, novolac epoxy resin is phenol type novolac epoxy resin, orthoresol type epoxy novolac tree
One or more in fat, bisphenol A-type novolac epoxy resin.
In some embodiments, epoxy resin is bisphenol A type epoxy resin, bisphenol-s epoxy resin, Bisphenol F type ring
One or more in oxygen tree fat, polyethyleneglycol diglycidylether and polypropylene glycol diglycidyl ether.
In some embodiments, chain extender is single phenol, bisphenol compound, bisphenol A-type PPG, binary carboxylic
One or more in acid, PPG, PEPA, binary mercapto alcohol.
In some embodiments, catalysts are triethanolamine, triethylamine, diethanol amine, diethylamine, triphenyl
One or more in phosphorus, tri-phenyl-phosphorus bromide, dimethyl benzylamine, imidazoles, methylimidazole, 2- ethyl 4-methylimidazoles.
In some embodiments, organic amine compound is diethanol amine, N- methylethanolamines, methyl iso-butyl ketone (MIBK) Asia
One or more in amine, ketimide modified polyamide.
In some embodiments, mixed crystal type titanium oxide preparation method is as follows：
α 1, by TiO2·nH2Both O and KOH mol ratios are 0.4-0.6, add appropriate water, are ground, then in horse
2h is incubated after being not warming up to 880-900 DEG C in stove, slow cooling to room temperature, obtains interphase K6Ti2O7；
α 2 and then by scattered intermediate product K6Ti2O7Put into a small amount of water, place 1-2 days, then by gained
It is stirred in hydrated product input suitable quantity of water, 0.5mol/L hydrochloric acid is constantly added dropwise, the pH value for controlling solution with acidometer is
2.0-3.0；
α 3, intermediate product is filtered out after stable system reaches balance, be washed with water to neutral and drying to constant weight and produced
Thing metatitanic acid, 800-1200 DEG C then is sintered to 10 DEG C of min-1 speed in Muffle furnace, be incubated 2h, slow cooling to room temperature, obtain
To described mixed crystal titanium oxide.
The preparation principle of mixed crystal titanium oxide is as follows：After obtaining product metatitanic acid, in Muffle furnace sinter dehydration obtain anatase titanium dioxide
Titanium oxide, transition temperature from anatase type titanium oxide to Titanium Dioxide Rutile Top grade be 800 DEG C or so.And due to its high thermal stability,
Make the anatase type titanium oxide whisker at 800 DEG C that there is very excellent degree of crystallization and one-dimension oriented property, its photo-catalyst
Excellent performance.And as temperature continues to raise, anatase type titanium oxide changes to the Titanium Dioxide Rutile Top grade of more temperature, so that
Rutile titania-rutile-type mixed crystal titanium oxide whisker that degree of crystallization is excellent, one-dimension oriented property is good is obtained under 1200 °C.And sintering temperature
900 DEG C, 2h is incubated, rutile titania in obtained rutile titania-rutile-type mixed crystal titanium oxide, wherein rutile titania-rutile-type mixed crystal titanium oxide
The weight/mass percentage composition of type titanium oxide is 20%, its photo-catalyst best results.
In some embodiments, a kind of aqueous epoxy floor coating, including following components, by mass percentage：
32% modified epoxy containing amino, 19% polyacrylate resin, 11% mixed crystal type titanium oxide, 7% calcium carbonate,
4% talcum powder, 3% kaolin, 1.5% carboxymethyl cellulose, 1.5% calgon, 2% ethylene glycol, its
Remaining is deionized water.
The operation principle of fungus and mildew resistance：The electronic structure feature of titanium oxide is full valence band and empty conduction band, its band-gap energy
For 3.2ev, it is necessary to which wavelength is less than 387.5nm ultraviolet light, electronics could produce from valence to conduction band, while in valence band
Raw corresponding hole, form the electron-hole pair of high activity.And mixed crystal titanium oxide is due to the presence of its heterojunction structure, its band
Gap can be less than 3ev, can directly be excited by the longer visible ray of wavelength or sunshine, form the electron hole of high activity
It is right.The H of redox reaction, hole and adsorption will now occur on surface2O or OH-Reaction, which is formed, has very Strong oxdiative
The activity hydroxy of property；Electronics then reacts with the oxygen molecule of adsorption, generates superoxide ion.Superoxide ion can be further anti-with water
Should, generate perhydroxyl radical and hydrogen peroxide, these materials can be with large biological molecule such as lipid, protein, enzyme and nucleic acid molecules
Reaction, directly damage or by a series of oxidation chain reactions, and cause extensive damaging fearness bad to biological cell structure, with
Reach the effect of antimycotic antiseptic.
Embodiment
The present invention is described in more detail below by embodiment.
Case study on implementation 1：
A1, by TiO2·nH2Both O and KOH mol ratios are 0.4, add appropriate water, are ground, then in Muffle furnace
In be warming up to 880 DEG C after be incubated 2h, slow cooling to room temperature, obtain interphase K6Ti2O7；
A2 and then by scattered intermediate product K6Ti2O7Put into a small amount of water, place 1 day, then by the water of gained
Close and be stirred in product input suitable quantity of water, 0.5mol/L hydrochloric acid is constantly added dropwise, the pH value for controlling solution with acidometer is
2.0；
A3, intermediate product is filtered out after stable system reaches balance, be washed with water to neutral and drying to constant weight and produced
Thing metatitanic acid, 800 DEG C then are sintered to 10 DEG C of min-1 speed in Muffle furnace, be incubated 2h, slow cooling to room temperature, obtain
Mixed crystal titanium oxide；
A4, by phenol type novolac epoxy resin, bisphenol A type epoxy resin and single phenol, in the work of catalyst triethanolamine
Under, 130 DEG C of reaction temperature carries out open loop chain extending reactions, after the epoxide equivalent for reaching theory, is cooled to 80 DEG C of addition diethanols
Amine, amination and chain extending reaction are carried out between 110 DEG C, obtains the modified epoxy containing amino after amination；
A5, by mass percentage：30% modified epoxy containing amino, 18% polyacrylate resin, 10%
Mixed crystal type titanium oxide, 5% calcium carbonate, 3% talcum powder, 2% kaolin, 1% carboxymethyl cellulose, the six of 1%
Sodium metaphosphate, 1% ethylene glycol, remaining be deionized water mixing after stir, obtain aqueous epoxy floor coating a.
Case study on implementation 2：
B1, by TiO2·nH2Both O and KOH mol ratios are 0.6, add appropriate water, are ground, then in Muffle furnace
In be warming up to 900 DEG C after be incubated 2h, slow cooling to room temperature, obtain interphase K6Ti2O7；
B2 and then by scattered intermediate product K6Ti2O7Put into a small amount of water, place 2 days, then by the water of gained
Close and be stirred in product input suitable quantity of water, 0.5mol/L hydrochloric acid is constantly added dropwise, the pH value for controlling solution with acidometer is
3.0；
B3, intermediate product is filtered out after stable system reaches balance, be washed with water to neutral and drying to constant weight and produced
Thing metatitanic acid, 1200 DEG C then are sintered to 10 DEG C of min-1 speed in Muffle furnace, be incubated 2h, slow cooling to room temperature, obtain
Mixed crystal titanium oxide；
B4, by orthoresol type novolac epoxy resin, bisphenol-s epoxy resin and bisphenol A-type PPG, be catalyzed
In the presence of agent methylimidazole, 190 DEG C of reaction temperature carries out open loop chain extending reactions, after the epoxide equivalent for reaching theory, cooling
To 90 DEG C of addition N- methylethanolamines, amination and chain extending reaction are carried out between 130 DEG C, obtains the modification ring containing amino after amination
Oxygen tree fat；
B5, by mass percentage：35% modified epoxy containing amino, 20% polyacrylate resin, 12%
Mixed crystal type titanium oxide, 8% calcium carbonate, 5% talcum powder, 4% kaolin, 2% carboxymethyl cellulose, the six of 2%
Sodium metaphosphate, 3% ethylene glycol, remaining be deionized water mixing after stir, obtain aqueous epoxy floor coating b.
Case study on implementation 3：
C1, by TiO2·nH2Both O and KOH mol ratios are 0.5, add appropriate water, are ground, then in Muffle furnace
In be warming up to 890 DEG C after be incubated 2h, slow cooling to room temperature, obtain interphase K6Ti2O7；
C2 and then by scattered intermediate product K6Ti2O7Put into a small amount of water, place 1.5 days, then by gained
It is stirred in hydrated product input suitable quantity of water, 0.5mol/L hydrochloric acid is constantly added dropwise, the pH value for controlling solution with acidometer is
2.5；
C3, intermediate product is filtered out after stable system reaches balance, be washed with water to neutral and drying to constant weight and produced
Thing metatitanic acid, 900 DEG C then are sintered to 10 DEG C of min-1 speed in Muffle furnace, be incubated 2h, slow cooling to room temperature, obtain
Mixed crystal titanium oxide；
C4, by bisphenol A-type novolac epoxy resin, polypropylene glycol diglycidyl ether and dicarboxylic acids, in catalyst three
In the presence of phenyl phosphorus, 150 DEG C of reaction temperature carries out open loop chain extending reactions, after the epoxide equivalent for reaching theory, is cooled to 85 DEG C
Methyl-isobutyl ketimide is added, amination and chain extending reaction are carried out between 120 DEG C, obtains the modified epoxy containing amino after amination
Resin；
C5, by mass percentage：32% modified epoxy containing amino, 19% polyacrylate resin, 11%
Mixed crystal type titanium oxide, 7% calcium carbonate, 4% talcum powder, 3% kaolin, 1.5% carboxymethyl cellulose, 1.5%
Calgon, 2% ethylene glycol, remaining be deionized water mixing after stir, obtain aqueous epoxy floor coating c.
The aqueous epoxy floor coating obtained in case study on implementation and contrast case is subjected to fungus-proof test.
(1) wet paint corruption experiment
By case study on implementation and contrast case, (sample to be tested in commercialized aqueous epoxy floor coating d), is injected successively
To being respectively provided with the culture dish of agar medium and malt extract medium, the growing state of bacterium and mould is observed, at 25 DEG C
After hatching at least 48 hours, visual evaluation is made according to the area of microbial reproduction, as a result such as following table：
(2) the mould proof experiment of dry film
Each sample coats on gypsum, twice, per pass interval 24h.After drying, every piece of sample board is all cut into two
Half, mixing mould liquid is sprayed onto film coated surface, is then suspended on test plate (panel) in 4-20 DEG C of high humility case 28 days, it is with the naked eye and aobvious
Micro mirror observes the mouldy situation of coating surface.
| Sample | Dry film mould breeding potential | Dry film algae reproduction rate |
| a | 0/0 | 0/0 |
| b | 1/A | 2/B |
| c | 0/A | 0/0 |
| d | 4/C | 3/C |
According to BS 3900-G6 standards, mould/algae reproduction rate is divided into 6 grades, i.e., 0 is to be less than without growth, 1 to grow area
1%, 2 be that growth area is 1-10%, and 3 be that growth area is 11-30%, and 4 be that growth area is 31-70%, and 5 be growth area
More than 70%.Density is divided into：0 is without growth, and A is atomic, and B is slight, and C is moderate, and D is intensive.
From above-mentioned fungus-proof test, it can be found that the aqueous epoxy floor coating antimycotic antiseptic performance that case study on implementation obtains is excellent
In now commercialized aqueous epoxy floor coating.And there is good weatherability properties, scratch resistance and anti-stoning after the coating film forming
Energy.
Presented above is only the preferred embodiment of the present invention, it is noted that to those skilled in the art, not
On the premise of departing from the invention design, various modifications and improvements can be made, these also should be regarded as the protection model of invention
Within enclosing.
Claims (9)
1. a kind of aqueous epoxy floor coating, it is characterised in that including following components, by mass percentage：30-35%'s contains
The modified epoxy of amino, 18-20% polyacrylate resins, 10-12% mixed crystal type titanium oxide, 5-8% calcium carbonate,
3-5% talcum powder, 2-4% kaolin, 1-2% carboxymethyl cellulose, 1-2% calgon, 1-3% second two
Alcohol, remaining be deionized water.
A kind of 2. aqueous epoxy floor coating according to claim 1, it is characterised in that the modified epoxy containing amino
Process for preparing resins is by novolac epoxy resin, epoxy resin and chain extender, in the presence of catalyst, reaction temperature 130
DEG C of -190 DEG C progress open loop chain extending reactions, after reaching theoretical epoxide equivalent, 80-90 DEG C of addition organic amine compound is cooled to,
Amination and chain extending reaction are carried out between 110-130 DEG C, obtains the modified epoxy containing amino after amination.
3. a kind of aqueous epoxy floor coating according to claim 2, it is characterised in that the novolac epoxy resin is benzene
One or more in phenolic novolac epoxy resin, orthoresol type novolac epoxy resin, bisphenol A-type novolac epoxy resin.
4. a kind of aqueous epoxy floor coating according to claim 2, it is characterised in that the epoxy resin is bisphenol-A
Type epoxy resin, bisphenol-s epoxy resin, bisphenol f type epoxy resin, polyethyleneglycol diglycidylether and polypropylene glycol two contract
One or more in water glycerin ether.
5. a kind of aqueous epoxy floor coating according to claim 2, it is characterised in that the chain extender is single phenol, double
One kind in phenolic compound, bisphenol A-type PPG, dicarboxylic acids, PPG, PEPA, binary mercapto alcohol
It is or a variety of.
6. a kind of aqueous epoxy floor coating according to claim 2, it is characterised in that the catalysts are three second
Hydramine, triethylamine, diethanol amine, diethylamine, triphenyl phosphorus, tri-phenyl-phosphorus bromide, dimethyl benzylamine, imidazoles, methylimidazole,
One or more in 2- ethyl 4-methylimidazoles.
7. a kind of aqueous epoxy floor coating according to claim 2, it is characterised in that the organic amine compound is two
One or more in monoethanolamine, N- methylethanolamines, methyl-isobutyl ketimide, ketimide modified polyamide.
8. a kind of aqueous epoxy floor coating according to claim 1, it is characterised in that prepared by the mixed crystal type titanium oxide
Method is as follows：
α 1, by TiO2·nH2Both O and KOH mol ratios are 0.4-0.6, add appropriate water, are ground, then in Muffle furnace
In be warming up to 880-900 DEG C after be incubated 2h, slow cooling to room temperature, obtain interphase K6Ti2O7；
α 2 and then by scattered intermediate product K6Ti2O7Put into a small amount of water, place 1-2 days, then by the hydration of gained
It is stirred in product input suitable quantity of water, 0.5mol/L hydrochloric acid is constantly added dropwise, it is 2.0- to control the pH value of solution with acidometer
3.0；
α 3, intermediate product is filtered out after stable system reaches balance, be washed with water to neutral and drying to constant weight and obtain product titanium
Acid, 800-1200 DEG C then is sintered to 10 DEG C of min-1 speed in Muffle furnace, be incubated 2h, slow cooling to room temperature, obtain institute
The mixed crystal titanium oxide stated.
9. a kind of aqueous epoxy floor coating according to claim 1, it is characterised in that including following components, by quality
Percentages：32% modified epoxy containing amino, 19% polyacrylate resin, 11% mixed crystal type titanium oxide, 7%
Calcium carbonate, 4% talcum powder, 3% kaolin, 1.5% carboxymethyl cellulose, 1.5% calgon, 2%
Ethylene glycol, remaining be deionized water.
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| CN201710722794.6A CN107353781A (en) | 2017-08-22 | 2017-08-22 | A kind of aqueous epoxy floor coating |
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| CN201710722794.6A CN107353781A (en) | 2017-08-22 | 2017-08-22 | A kind of aqueous epoxy floor coating |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107987712A (en) * | 2017-12-21 | 2018-05-04 | 珠海智星荟科技服务有限公司 | There is aqueous epoxy floor coating of anti-corrosive antibacterial and preparation method thereof |
| CN109608987A (en) * | 2018-12-11 | 2019-04-12 | 福州皇家地坪有限公司 | Fire-retardant floor coatings of water-base epoxy texture and preparation method thereof |
| CN113898142A (en) * | 2021-09-03 | 2022-01-07 | 广州市原构设计有限公司 | Indoor decoration construction method for modern interesting kindergarten |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105462445A (en) * | 2015-12-15 | 2016-04-06 | 沪宝新材料科技（上海）股份有限公司 | Water-borne floor paint capable of degrading formaldehyde |
| CN106318114A (en) * | 2016-08-19 | 2017-01-11 | 浩力森涂料（上海）有限公司 | Cationic electro-deposition coating |
| CN106675314A (en) * | 2015-11-11 | 2017-05-17 | 江苏冠军涂料科技集团有限公司 | Novel water-based epoxy floor paint and preparation technique thereof |
| CN106947373A (en) * | 2017-04-12 | 2017-07-14 | 浩力森化学科技（江苏）有限公司 | The SiO of surface-modified nano containing acrylate polymer2The cation electrodeposition coating of microballoon |
| CN106986379A (en) * | 2017-04-17 | 2017-07-28 | 徐英 | A kind of method that high temperature prepares mixed crystal titanium oxide |
-
2017
- 2017-08-22 CN CN201710722794.6A patent/CN107353781A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106675314A (en) * | 2015-11-11 | 2017-05-17 | 江苏冠军涂料科技集团有限公司 | Novel water-based epoxy floor paint and preparation technique thereof |
| CN105462445A (en) * | 2015-12-15 | 2016-04-06 | 沪宝新材料科技（上海）股份有限公司 | Water-borne floor paint capable of degrading formaldehyde |
| CN106318114A (en) * | 2016-08-19 | 2017-01-11 | 浩力森涂料（上海）有限公司 | Cationic electro-deposition coating |
| CN106947373A (en) * | 2017-04-12 | 2017-07-14 | 浩力森化学科技（江苏）有限公司 | The SiO of surface-modified nano containing acrylate polymer2The cation electrodeposition coating of microballoon |
| CN106986379A (en) * | 2017-04-17 | 2017-07-28 | 徐英 | A kind of method that high temperature prepares mixed crystal titanium oxide |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107987712A (en) * | 2017-12-21 | 2018-05-04 | 珠海智星荟科技服务有限公司 | There is aqueous epoxy floor coating of anti-corrosive antibacterial and preparation method thereof |
| CN107987712B (en) * | 2017-12-21 | 2020-06-02 | 珠海智星荟科技服务有限公司 | Water-based epoxy floor coating with anticorrosion and antibacterial functions and preparation method thereof |
| CN109608987A (en) * | 2018-12-11 | 2019-04-12 | 福州皇家地坪有限公司 | Fire-retardant floor coatings of water-base epoxy texture and preparation method thereof |
| CN113898142A (en) * | 2021-09-03 | 2022-01-07 | 广州市原构设计有限公司 | Indoor decoration construction method for modern interesting kindergarten |
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Application publication date: 20171117 |