CN107353480A - A kind of discrete type is modified HDPE synthetic plastic fillers and preparation method thereof - Google Patents
A kind of discrete type is modified HDPE synthetic plastic fillers and preparation method thereof Download PDFInfo
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- CN107353480A CN107353480A CN201710667363.4A CN201710667363A CN107353480A CN 107353480 A CN107353480 A CN 107353480A CN 201710667363 A CN201710667363 A CN 201710667363A CN 107353480 A CN107353480 A CN 107353480A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/062—HDPE
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- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A kind of discrete type is modified HDPE synthetic plastic fillers and preparation method thereof, is made up of the raw material components of following number：High-density polyethylene resin 120 200, chlorinated polyethylene resin 60 80, anti-oxidant ultraviolet radiation resisting master batch 5 12, polysiloxane polyether copolymer 15 30, di-n-octyl sebacate 58, octyl epoxy stearate 35, nanometer Iron-ore Slag 7 10, magnesium stearate 5 12, tall oil 24, hydroxyethyl methacrylate 12, APEO 12 15, precipitated calcium carbonate 150 250, auxiliary agent 8 10, deionized water is some, discrete type modification HDPE synthetic plastic fillers of the present invention and preparation method thereof improve the stability in plastic cement, prevent from reuniting, the intensity and wearability of plastic cement can be improved.
Description
Technical field
The present invention relates to plastic cement technical field, and in particular to a kind of discrete type is modified HDPE synthetic plastics filler and its preparation
Method.
Background technology
Plastic cement application is very extensive, is portion indispensable in household electrical appliances, automobile, mobile phone, PC, medicine equipment, electric lighting
Part.China's economy realizes the industry such as steady and stabilized growth, household electrical appliances, automobile, mobile phone, PC, medicine equipment and benefited from recent years
Good external environment condition also achieves fast development, and the development of downstream industry has further pulled on the demand to plastic cement, but and
Foreign Advanced Lerel is compared, and China's synthetic resin industry still suffers from certain gap, and some domestic high-end product quantity can not meet
The market demand, quality also have much room for improvement and improved.At present performance deficiency existing for plastic cement show wearability, ageing-resistant, oil resistant,
High temperature resistant, intensity, chemical stability, bending strength, croop property etc. are, it is necessary to constantly improve.Improved approach has pair
The improvement of raw material, technique, also it is exactly to be improved by adding filler, the performance of filler improves plastic cement to a certain extent
Performance, so research filler modified technique it is critically important.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of discrete type to be modified HDPE synthetic plastics filler and its preparation side
Method.
The present invention is achieved through the following technical solutions：
A kind of discrete type is modified HDPE synthetic plastic fillers, is made up of the raw material components of following number：High density polyethylene (HDPE) tree
Fat 120-200, chlorinated polyethylene resin 60-80, anti-oxidant ultraviolet radiation resisting master batch 5-12, polysiloxane polyether copolymer
15-30, di-n-octyl sebacate 5-8, octyl epoxy stearate 3-5, nanometer Iron-ore Slag 7-10, magnesium stearate 5-12, tall oil 2-
If the 4th, hydroxyethyl methacrylate 1-2, APEO 12-15, precipitated calcium carbonate 150-250, auxiliary agent 8-10, deionized water
It is dry.
The auxiliary agent is made from the following raw materials in parts by weight：Magnesium stearate 0.2-0.3, di-n-octyl sebacate 0.2-0.3, second
The double oleamide 0.4-0.6 of support, OPE 0.3-0.5, tall oil 0.3-0.4, graphene oxide 0.3-0.5, wool
Lipidol APEO 0.2-0.3, nano titanium oxide 2-3, polyamide wax micropowder 0.2-0.3, urethane acrylate 0.3-
0.5th, allyl glycidyl ether 0.2-0.3, toluene di-isocyanate(TDI) 0.1-0.2, phosphoesterase 30 .2-0.3, tripropylene glycol
Diacrylate 13-16；Preparation method is：Urethane acrylate, allyl glycidyl ether are added to two contractings 3 the third two
In alcohol diacrylate, 50-55 DEG C is heated to, stirs 20-30 minutes, adds the double oil of magnesium stearate, di-n-octyl sebacate, ethylene
Sour acid amides, OPE, tall oil, graphene oxide, lanolin alcohol APEO, nano titanium oxide, polyamide
Wax micro mist, phosphate, are continuously heating to 70-80 DEG C after stirring, stirring reaction 30-40 minutes, are cooled to 35-40 DEG C, then
Other residual components are added, stirring reaction 50-60 minutes, are produced.
Described discrete type is modified the preparation method of HDPE synthetic plastic fillers, it is characterised in that comprises the following steps：
(1) by high-density polyethylene resin, chlorinated polyethylene resin, anti-oxidant ultraviolet radiation resisting master batch, polysiloxanes
Copolyether, di-n-octyl sebacate, octyl epoxy stearate are added in deionized water, are stirred, and are heated to 75-
85 DEG C, obtain slurry；
(2) by nanometer Iron-ore Slag, magnesium stearate, tall oil, hydroxyethyl methacrylate, APEO, lightweight carbonic acid
Calcium mixes, then blowing to it 75-85 DEG C of hot-air seethes it, then sprays into vaporific (1) step into the powder seethed and obtain
Slurry, after being sufficiently mixed the two, keeping temperature be 75-85 DEG C, continue to seethe 40-50 minutes；
(3) mixed material for obtaining (2) step is dried, and is added in high-speed kneading machine, is added other residual components, then rise
For temperature to 120-130 DEG C, 15-20 minutes are mediated in insulation, then are ground into 10-50 μm of particle, produce this product.
The beneficial effects of the present invention are：Discrete type modification HDPE synthetic plastic fillers of the present invention improve calcium carbonate and moulded
Stability in glue, prevent from reuniting, it is possible to increase the intensity and wearability of plastic cement.
Embodiment
Embodiment:A kind of discrete type is modified HDPE synthetic plastic fillers, is made up of the raw material components of following number：High density is gathered
Vinyl 120-200, chlorinated polyethylene resin 60-80, anti-oxidant ultraviolet radiation resisting master batch 5-12, silicone polyether are common
Polymers 15-30, di-n-octyl sebacate 5-8, octyl epoxy stearate 3-5, nanometer Iron-ore Slag 7-10, magnesium stearate 5-12, Tuo Er
Oily 2-4, hydroxyethyl methacrylate 1-2, APEO 12-15, precipitated calcium carbonate 150-250, auxiliary agent 8-10, deionized water
It is some.
The auxiliary agent is made from the following raw materials in parts by weight：Magnesium stearate 0.2-0.3, di-n-octyl sebacate 0.2-0.3, second
The double oleamide 0.4-0.6 of support, OPE 0.3-0.5, tall oil 0.3-0.4, graphene oxide 0.3-0.5, wool
Lipidol APEO 0.2-0.3, nano titanium oxide 2-3, polyamide wax micropowder 0.2-0.3, urethane acrylate 0.3-
0.5th, allyl glycidyl ether 0.2-0.3, toluene di-isocyanate(TDI) 0.1-0.2, phosphoesterase 30 .2-0.3, tripropylene glycol
Diacrylate 13-16；Preparation method is：Urethane acrylate, allyl glycidyl ether are added to two contractings 3 the third two
In alcohol diacrylate, 50-55 DEG C is heated to, stirs 20-30 minutes, adds the double oil of magnesium stearate, di-n-octyl sebacate, ethylene
Sour acid amides, OPE, tall oil, graphene oxide, lanolin alcohol APEO, nano titanium oxide, polyamide
Wax micro mist, phosphate, are continuously heating to 70-80 DEG C after stirring, stirring reaction 30-40 minutes, are cooled to 35-40 DEG C, then
Other residual components are added, stirring reaction 50-60 minutes, are produced.
Described discrete type is modified the preparation method of HDPE synthetic plastic fillers, it is characterised in that comprises the following steps：
(1) by high-density polyethylene resin, chlorinated polyethylene resin, anti-oxidant ultraviolet radiation resisting master batch, polysiloxanes
Copolyether, di-n-octyl sebacate, octyl epoxy stearate are added in deionized water, are stirred, and are heated to 75-
85 DEG C, obtain slurry；
(2) by nanometer Iron-ore Slag, magnesium stearate, tall oil, hydroxyethyl methacrylate, APEO, lightweight carbonic acid
Calcium mixes, then blowing to it 75-85 DEG C of hot-air seethes it, then sprays into vaporific (1) step into the powder seethed and obtain
Slurry, after being sufficiently mixed the two, keeping temperature be 75-85 DEG C, continue to seethe 40-50 minutes；
(3) mixed material for obtaining (2) step is dried, and is added in high-speed kneading machine, is added other residual components, then rise
For temperature to 120-130 DEG C, 15-20 minutes are mediated in insulation, then are ground into 10-50 μm of particle, produce this product.
Described above is only the preferred application implementation mode of the present invention, it is noted that for the common skill of the art
For art personnel, without departing from the technical principles of the invention, some improvement can also be made.
Claims (2)
1. a kind of discrete type is modified HDPE synthetic plastic fillers, it is characterised in that：It is made up of the raw material components of following number：High density
Polyvinyl resin 120-200, chlorinated polyethylene resin 60-80, anti-oxidant ultraviolet radiation resisting master batch 5-12, silicone polyether
It is copolymer 1 5-30, di-n-octyl sebacate 5-8, octyl epoxy stearate 3-5, nanometer Iron-ore Slag 7-10, magnesium stearate 5-12, appropriate
The oily 2-4 of that, hydroxyethyl methacrylate 1-2, APEO 12-15, precipitated calcium carbonate 150-250, auxiliary agent 8-10, deionization
Water is some.
The auxiliary agent is made from the following raw materials in parts by weight：Magnesium stearate 0.2-0.3, di-n-octyl sebacate 0.2-0.3, ethylene are double
Oleamide 0.4-0.6, OPE 0.3-0.5, tall oil 0.3-0.4, graphene oxide 0.3-0.5, lanolin alcohol
APEO 0.2-0.3, nano titanium oxide 2-3, polyamide wax micropowder 0.2-0.3, urethane acrylate 0.3-0.5,
Allyl glycidyl ether 0.2-0.3, toluene di-isocyanate(TDI) 0.1-0.2, phosphoesterase 30 .2-0.3, tripropylene glycol dipropyl
Olefin(e) acid ester 13-16；Preparation method is：Urethane acrylate, allyl glycidyl ether are added to tripropylene glycol two
In acrylate, 50-55 DEG C is heated to, stirs 20-30 minutes, adds the double oleic acid acyls of magnesium stearate, di-n-octyl sebacate, ethylene
Amine, OPE, tall oil, graphene oxide, lanolin alcohol APEO, nano titanium oxide, polyamide wax are micro-
Powder, phosphate, 70-80 DEG C is continuously heating to after stirring, stirring reaction 30-40 minutes, 35-40 DEG C is cooled to, adds
Other residual components, stirring reaction 50-60 minutes, produce.
2. discrete type according to claim 1 is modified the preparation method of HDPE synthetic plastic fillers, it is characterised in that including
Following steps：
(1) by high-density polyethylene resin, chlorinated polyethylene resin, anti-oxidant ultraviolet radiation resisting master batch, silicone polyether
Copolymer, di-n-octyl sebacate, octyl epoxy stearate are added in deionized water, are stirred, and are heated to 75-85
DEG C, obtain slurry；
(2) nanometer Iron-ore Slag, magnesium stearate, tall oil, hydroxyethyl methacrylate, APEO, precipitated calcium carbonate are mixed
Close, then blowing to it 75-85 DEG C of hot-air seethes it, then the slurry that vaporific (1) step obtains is sprayed into the powder seethed
Material, after being sufficiently mixed the two, keeping temperature is 75-85 DEG C, continues to seethe 40-50 minutes；
(3) mixed material for obtaining (2) step is dried, and is added in high-speed kneading machine, is added other residual components, then be warming up to
120-130 DEG C, 15-20 minutes are mediated in insulation, then are ground into 10-50 μm of particle, produce this product.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710667363.4A CN107353480A (en) | 2017-08-07 | 2017-08-07 | A kind of discrete type is modified HDPE synthetic plastic fillers and preparation method thereof |
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| CN201710667363.4A CN107353480A (en) | 2017-08-07 | 2017-08-07 | A kind of discrete type is modified HDPE synthetic plastic fillers and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108976772A (en) * | 2018-07-25 | 2018-12-11 | 苏州清之绿新材料有限公司 | A kind of wear-resisting antistatic composite sheet and preparation method thereof |
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| CN104311953A (en) * | 2014-10-13 | 2015-01-28 | 宏祥新材料股份有限公司 | Synthetic plastic modified cement high-density polyethylene (HDPE) impermeable membrane and production process thereof |
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| CN104592742A (en) * | 2015-01-12 | 2015-05-06 | 安徽玉堂雨具有限公司 | Special filler for modified light calcium carbonate plastic and preparation method for special filler |
| CN104610576A (en) * | 2015-01-12 | 2015-05-13 | 安徽玉堂雨具有限公司 | Plastic-used high-flowability modified calcium carbonate and preparation method thereof |
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2017
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104194309A (en) * | 2014-08-14 | 2014-12-10 | 青阳县吉祥塑胶有限公司 | Plastic filler with high wear resistance and preparation method of plastic filler |
| CN104311953A (en) * | 2014-10-13 | 2015-01-28 | 宏祥新材料股份有限公司 | Synthetic plastic modified cement high-density polyethylene (HDPE) impermeable membrane and production process thereof |
| CN104592551A (en) * | 2015-01-12 | 2015-05-06 | 安徽玉堂雨具有限公司 | Filler capable of enhancing low-temperature resistance of plastic and preparation method thereof |
| CN104592742A (en) * | 2015-01-12 | 2015-05-06 | 安徽玉堂雨具有限公司 | Special filler for modified light calcium carbonate plastic and preparation method for special filler |
| CN104610576A (en) * | 2015-01-12 | 2015-05-13 | 安徽玉堂雨具有限公司 | Plastic-used high-flowability modified calcium carbonate and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108976772A (en) * | 2018-07-25 | 2018-12-11 | 苏州清之绿新材料有限公司 | A kind of wear-resisting antistatic composite sheet and preparation method thereof |
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Application publication date: 20171117 |
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