CN107353443A - A kind of inorganic compound synthetic plastic filler and preparation method thereof - Google Patents
A kind of inorganic compound synthetic plastic filler and preparation method thereof Download PDFInfo
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- CN107353443A CN107353443A CN201710667361.5A CN201710667361A CN107353443A CN 107353443 A CN107353443 A CN 107353443A CN 201710667361 A CN201710667361 A CN 201710667361A CN 107353443 A CN107353443 A CN 107353443A
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- phenyl ether
- expoxy propane
- inorganic compound
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/04—Ingredients characterised by their shape and organic or inorganic ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/15—Heterocyclic compounds having oxygen in the ring
- C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
- C08K5/1515—Three-membered rings
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/524—Esters of phosphorous acids, e.g. of H3PO3
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/549—Silicon-containing compounds containing silicon in a ring
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/06—Elements
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A kind of inorganic compound synthetic plastic filler and preparation method thereof, is made up of the raw material components of following number：Perfluor alkyl ethide phosphite ester 34, polyethylene glycol 45, carbon nano-fiber 58, isocyanates 35, expoxy propane phenyl ether 48, diphenyl silanediol 5 12, polyester acrylate 1.5 3.5, alum 8 12, alundum (Al2O3) 37, expoxy propane phenyl ether 37, auxiliary agent 59, deionized water are some, a kind of inorganic compound synthetic plastic filler of the present invention and preparation method thereof lipophile is good, there is good compatibility with plastic cement, the intensity and impact resistance of plastic cement can be increased, self lubricity is good, and resistance to low temperature is good.
Description
Technical field
The present invention relates to plastic cement technical field, and in particular to a kind of inorganic compound synthetic plastic filler and its preparation side
Method.
Background technology
Plastic cement application is very extensive, is portion indispensable in household electrical appliances, automobile, mobile phone, PC, medicine equipment, electric lighting
Part.China's economy realizes the industry such as steady and stabilized growth, household electrical appliances, automobile, mobile phone, PC, medicine equipment and benefited from recent years
Good external environment condition also achieves fast development, and the development of downstream industry has further pulled on the demand to plastic cement, but and
Foreign Advanced Lerel is compared, and China's synthetic resin industry still suffers from certain gap, and some domestic high-end product quantity can not meet
The market demand, quality also have much room for improvement and improved.At present performance deficiency existing for plastic cement show wearability, ageing-resistant, oil resistant,
High temperature resistant, intensity, chemical stability, bending strength, croop property etc. are, it is necessary to constantly improve.Improved approach has pair
The improvement of raw material, technique, also it is exactly to be improved by adding filler, the performance of filler improves plastic cement to a certain extent
Performance, so research filler modified technique it is critically important.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of inorganic compound synthetic plastic filler and preparation method thereof.
The present invention is achieved through the following technical solutions：
A kind of inorganic compound synthetic plastic filler, is made up of the raw material components of following number：Perfluor alkyl ethide phosphorous acid
Ester 3-4, polyethylene glycol 4-5, carbon nano-fiber 5-8, isocyanates 3-5, expoxy propane phenyl ether 4-8, diphenyl silanediol 5-
12nd, polyester acrylate 1.5-3.5, alum 8-12, alundum (Al2O3) 3-7, expoxy propane phenyl ether 3-7, auxiliary agent 5-9, go from
Sub- water is some.
The auxiliary agent is made from the following raw materials in parts by weight：Magnesium stearate 0.2-0.3, di-n-octyl sebacate 0.2-0.3, second
The double oleamide 0.4-0.6 of support, OPE 0.3-0.5, tall oil 0.3-0.4, graphene oxide 0.3-0.5, wool
Lipidol APEO 0.2-0.3, nano titanium oxide 2-3, polyamide wax micropowder 0.2-0.3, urethane acrylate 0.3-
0.5th, allyl glycidyl ether 0.2-0.3, toluene di-isocyanate(TDI) 0.1-0.2, phosphoesterase 30 .2-0.3, tripropylene glycol
Diacrylate 13-16；Preparation method is：Urethane acrylate, allyl glycidyl ether are added to two contractings 3 the third two
In alcohol diacrylate, 50-55 DEG C is heated to, stirs 20-30 minutes, adds the double oil of magnesium stearate, di-n-octyl sebacate, ethylene
Sour acid amides, OPE, tall oil, graphene oxide, lanolin alcohol APEO, nano titanium oxide, polyamide
Wax micro mist, phosphate, are continuously heating to 70-80 DEG C after stirring, stirring reaction 30-40 minutes, are cooled to 35-40 DEG C, then
Other residual components are added, stirring reaction 50-60 minutes, are produced.
The preparation method of described a kind of inorganic compound synthetic plastic filler, it is characterised in that comprise the following steps：
(1) by perfluor alkyl ethide phosphite ester, polyethylene glycol, carbon nano-fiber, isocyanates, expoxy propane phenyl ether
It is added in deionized water, stirs, be heated to 75-85 DEG C, obtains slurry；
(2) diphenyl silanediol, polyester acrylate, alum, alundum (Al2O3), expoxy propane phenyl ether are mixed, then
75-85 DEG C of hot-air is blown to it seethes it, then the slurry that vaporific (1) step obtains is sprayed into the powder seethed, makes
After the two is sufficiently mixed, keeping temperature is 75-85 DEG C, continues to seethe 40-50 minutes；
(3) mixed material for obtaining (2) step is dried, and is added in high-speed kneading machine, is added other residual components, then rise
For temperature to 120-130 DEG C, 15-20 minutes are mediated in insulation, then are ground into 10-50 μm of particle, produce this product.
The beneficial effects of the present invention are：A kind of inorganic compound synthetic plastic filler of the present invention and preparation method thereof parent
Oiliness is good, has good compatibility with plastic cement, by increasing capacitance it is possible to increase the intensity and impact resistance of plastic cement, self lubricity is good, lower temperature resistance
Can be good.
Embodiment
Embodiment:A kind of inorganic compound synthetic plastic filler, is made up of the raw material components of following number：Perfluor alkyl ethide
Phosphite ester 3-4, polyethylene glycol 4-5, carbon nano-fiber 5-8, isocyanates 3-5, expoxy propane phenyl ether 4-8, diphenyl silicon
Glycol 5-12, polyester acrylate 1.5-3.5, alum 8-12, alundum (Al2O3) 3-7, expoxy propane phenyl ether 3-7, auxiliary agent 5-
9th, deionized water is some.
The auxiliary agent is made from the following raw materials in parts by weight：Magnesium stearate 0.2-0.3, di-n-octyl sebacate 0.2-0.3, second
The double oleamide 0.4-0.6 of support, OPE 0.3-0.5, tall oil 0.3-0.4, graphene oxide 0.3-0.5, wool
Lipidol APEO 0.2-0.3, nano titanium oxide 2-3, polyamide wax micropowder 0.2-0.3, urethane acrylate 0.3-
0.5th, allyl glycidyl ether 0.2-0.3, toluene di-isocyanate(TDI) 0.1-0.2, phosphoesterase 30 .2-0.3, tripropylene glycol
Diacrylate 13-16；Preparation method is：Urethane acrylate, allyl glycidyl ether are added to two contractings 3 the third two
In alcohol diacrylate, 50-55 DEG C is heated to, stirs 20-30 minutes, adds the double oil of magnesium stearate, di-n-octyl sebacate, ethylene
Sour acid amides, OPE, tall oil, graphene oxide, lanolin alcohol APEO, nano titanium oxide, polyamide
Wax micro mist, phosphate, are continuously heating to 70-80 DEG C after stirring, stirring reaction 30-40 minutes, are cooled to 35-40 DEG C, then
Other residual components are added, stirring reaction 50-60 minutes, are produced.
The preparation method of described inorganic compound synthetic plastic filler, it is characterised in that comprise the following steps：
(1) by perfluor alkyl ethide phosphite ester, polyethylene glycol, carbon nano-fiber, isocyanates, expoxy propane phenyl ether
It is added in deionized water, stirs, be heated to 75-85 DEG C, obtains slurry；
(2) diphenyl silanediol, polyester acrylate, alum, alundum (Al2O3), expoxy propane phenyl ether are mixed, then
75-85 DEG C of hot-air is blown to it seethes it, then the slurry that vaporific (1) step obtains is sprayed into the powder seethed, makes
After the two is sufficiently mixed, keeping temperature is 75-85 DEG C, continues to seethe 40-50 minutes；
(3) mixed material for obtaining (2) step is dried, and is added in high-speed kneading machine, is added other residual components, then rise
For temperature to 120-130 DEG C, 15-20 minutes are mediated in insulation, then are ground into 10-50 μm of particle, produce this product.
Described above is only the preferred application implementation mode of the present invention, it is noted that for the common skill of the art
For art personnel, without departing from the technical principles of the invention, some improvement can also be made.
Claims (2)
- A kind of 1. inorganic compound synthetic plastic filler, it is characterised in that：It is made up of the raw material components of following number：Perfluoroalkyl second Base phosphite ester 3-4, polyethylene glycol 4-5, carbon nano-fiber 5-8, isocyanates 3-5, expoxy propane phenyl ether 4-8, diphenyl Silicon diol 5-12, polyester acrylate 1.5-3.5, alum 8-12, alundum (Al2O3) 3-7, expoxy propane phenyl ether 3-7, auxiliary agent 5-9, deionized water are some.The auxiliary agent is made from the following raw materials in parts by weight：Magnesium stearate 0.2-0.3, di-n-octyl sebacate 0.2-0.3, ethylene are double Oleamide 0.4-0.6, OPE 0.3-0.5, tall oil 0.3-0.4, graphene oxide 0.3-0.5, lanolin alcohol APEO 0.2-0.3, nano titanium oxide 2-3, polyamide wax micropowder 0.2-0.3, urethane acrylate 0.3-0.5, Allyl glycidyl ether 0.2-0.3, toluene di-isocyanate(TDI) 0.1-0.2, phosphoesterase 30 .2-0.3, tripropylene glycol dipropyl Olefin(e) acid ester 13-16；Preparation method is：Urethane acrylate, allyl glycidyl ether are added to tripropylene glycol two In acrylate, 50-55 DEG C is heated to, stirs 20-30 minutes, adds the double oleic acid acyls of magnesium stearate, di-n-octyl sebacate, ethylene Amine, OPE, tall oil, graphene oxide, lanolin alcohol APEO, nano titanium oxide, polyamide wax are micro- Powder, phosphate, 70-80 DEG C is continuously heating to after stirring, stirring reaction 30-40 minutes, 35-40 DEG C is cooled to, adds Other residual components, stirring reaction 50-60 minutes, produce.
- A kind of 2. preparation method of inorganic compound synthetic plastic filler according to claim 1, it is characterised in that including Following steps：(1) perfluor alkyl ethide phosphite ester, polyethylene glycol, carbon nano-fiber, isocyanates, expoxy propane phenyl ether are added to In deionized water, stir, be heated to 75-85 DEG C, obtain slurry；(2) by diphenyl silanediol, polyester acrylate, alum, alundum (Al2O3), expoxy propane phenyl ether mix, then to its Blowing 75-85 DEG C of hot-air seethes it, then the slurry that vaporific (1) step obtains is sprayed into the powder seethed, makes the two After being sufficiently mixed, keeping temperature is 75-85 DEG C, continues to seethe 40-50 minutes；(3) mixed material for obtaining (2) step is dried, and is added in high-speed kneading machine, is added other residual components, then be warming up to 120-130 DEG C, 15-20 minutes are mediated in insulation, then are ground into 10-50 μm of particle, produce this product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201710667361.5A CN107353443A (en) | 2017-08-07 | 2017-08-07 | A kind of inorganic compound synthetic plastic filler and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710667361.5A CN107353443A (en) | 2017-08-07 | 2017-08-07 | A kind of inorganic compound synthetic plastic filler and preparation method thereof |
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| CN107353443A true CN107353443A (en) | 2017-11-17 |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104211995A (en) * | 2014-08-14 | 2014-12-17 | 青阳县吉祥塑胶有限公司 | Anticorrosive plastic filler and preparation method thereof |
| CN104277428A (en) * | 2014-10-31 | 2015-01-14 | 合肥鼎雅家具有限责任公司 | Epoxy resin composite material with corrosion-resisting and wear-resisting properties and production method thereof |
| CN104592551A (en) * | 2015-01-12 | 2015-05-06 | 安徽玉堂雨具有限公司 | Filler capable of enhancing low-temperature resistance of plastic and preparation method thereof |
| CN104592742A (en) * | 2015-01-12 | 2015-05-06 | 安徽玉堂雨具有限公司 | Special filler for modified light calcium carbonate plastic and preparation method for special filler |
-
2017
- 2017-08-07 CN CN201710667361.5A patent/CN107353443A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104211995A (en) * | 2014-08-14 | 2014-12-17 | 青阳县吉祥塑胶有限公司 | Anticorrosive plastic filler and preparation method thereof |
| CN104277428A (en) * | 2014-10-31 | 2015-01-14 | 合肥鼎雅家具有限责任公司 | Epoxy resin composite material with corrosion-resisting and wear-resisting properties and production method thereof |
| CN104592551A (en) * | 2015-01-12 | 2015-05-06 | 安徽玉堂雨具有限公司 | Filler capable of enhancing low-temperature resistance of plastic and preparation method thereof |
| CN104592742A (en) * | 2015-01-12 | 2015-05-06 | 安徽玉堂雨具有限公司 | Special filler for modified light calcium carbonate plastic and preparation method for special filler |
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Application publication date: 20171117 |