CN107353470A - A kind of high-weatherability low water absorption carbon wood composite material - Google Patents

A kind of high-weatherability low water absorption carbon wood composite material Download PDF

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Publication number
CN107353470A
CN107353470A CN201710530754.1A CN201710530754A CN107353470A CN 107353470 A CN107353470 A CN 107353470A CN 201710530754 A CN201710530754 A CN 201710530754A CN 107353470 A CN107353470 A CN 107353470A
Authority
CN
China
Prior art keywords
carbon
water absorption
composite material
low water
wood composite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710530754.1A
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Chinese (zh)
Inventor
王同文
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhejiang Motomori State Wood Polytron Technologies Inc
Original Assignee
Zhejiang Motomori State Wood Polytron Technologies Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhejiang Motomori State Wood Polytron Technologies Inc filed Critical Zhejiang Motomori State Wood Polytron Technologies Inc
Priority to CN201710530754.1A priority Critical patent/CN107353470A/en
Publication of CN107353470A publication Critical patent/CN107353470A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00Compositions of lignin-containing materials
    • C08L97/02Lignocellulosic material, e.g. wood, straw or bagasse
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Abstract

The invention belongs to building material technical field, more particularly to a kind of high-weatherability low water absorption carbon wood composite material.It is made up of carbon dust, wood powder, polyethylene, EVA, lubricant, coupling agent, antioxidant, anti ultraviolet agent.The advantages of invention, is:Carbon wood composite material provided by the invention is due to introducing carbon dust, weatherability and wearability are improved, reduces water absorption rate, while obtained biological carbon after sludge carbonization treatment is introduced into the formula of the present invention, the performance of Wood plastic composite is not only increased, improves the cyclic utilization rate of carbon on the earth.

Description

A kind of high-weatherability low water absorption carbon wood composite material
Technical field
The invention belongs to building material technical field, more particularly to a kind of high-weatherability low water absorption carbon wood composite material.
Background technology
Similar with this product at present has wood plastic composite and timber, stone material, and wood plastic composite is through being to utilize poly- second Alkene, polypropylene and polyvinyl chloride etc. with wood powder, rice husk, the useless string such as stalk mix the modeling such as extruding, molding, injection moulding The section bar that material processing technology is produced is referred to as Wood-plastic profiles, is mainly used in the industries such as building materials, furniture, logistics packaging.Wood plastic sectional Material has good processing characteristics, good strength character, corrosion resistant performance, and service life is grown, excellent adjustable energy, these Performance makes plastic-wood section substitute solid wood, stone material, and more and more extensive application is obtained in building trade.Make for a long time outdoor With, it is necessary to be subjected to constantly being subjected to the friction of hard thing, the invasion and attack of spot and Exposure to Sunlight, wind, drench with rain etc., it is necessary to its have it is good Anti-wear performance, weather resistance and extremely low water absorption rate, but Wood-plastic profiles are absorbing water, it is wear-resisting, weather-proof etc. to need further Improve, common water suction cracking, mouldy in large batch of application project domestic at present, fades, and occurs situations such as surface tear, influences The further genralrlization application of Wood-plastic material.
The earth possesses a carbon cycle system in itself, and carbon can be by plant, soil, under ocean and other natural processes deposition Come.But the current serious excess load of these systems.Biological carbon can deposit 10 to 20 hundred million tons of carbons every year.It this Kind mystery, unique characteristic, become the most popular field of research climate change.For example, the life after sludge carbonization The content of carbon is 40% in thing carbon, and surplus is the various trace elements and organic matter etc. such as nitrogen, phosphorus, potassium.
The content of the invention
The purpose of invention is in view of the above-mentioned problems, providing a kind of high-weatherability low water absorption carbon wood composite material, is solved Wood plastic composite of the prior art anti-wear performance and weather resistance in outdoor long-time use are low, while reduce type The water absorption rate of material.
To reach above-mentioned purpose, invention employs following technical proposal:High-weatherability low water absorption carbon wood composite material, its It is characterised by, it is made up of carbon dust, wood powder, polyethylene, EVA, lubricant, coupling agent, antioxidant, anti ultraviolet agent.
Composition is by weight percentage in a kind of above-mentioned high-weatherability low water absorption carbon wood composite material, in the material For:Carbon dust is 20-64%, wood powder 10-44%, polyethylene 20-54%, EVA 3-10%, lubricant 1-3%, is coupled Agent is 1-5%, antioxidant 0.1-0.5%, anti ultraviolet agent 0.1-0.5%.
In a kind of above-mentioned high-weatherability low water absorption carbon wood composite material, described carbon dust is biological carbon, described Biological carbon is that sludge is made after carbonization, and the carbon content in described biological carbon is 35-89%.
In a kind of above-mentioned high-weatherability low water absorption carbon wood composite material, described carbon dust is 60-80 mesh.
In a kind of above-mentioned high-weatherability low water absorption carbon wood composite material, described antioxidant is selected from antioxidant 1010th, at least one of irgasfos 168.
In a kind of above-mentioned high-weatherability low water absorption carbon wood composite material, described anti ultraviolet agent be selected from hindered amine, At least one of BTA.
In a kind of above-mentioned high-weatherability low water absorption carbon wood composite material, it is hard that described lubricant is selected from metal soap At least one of resin acid calcium, fatty acid soaps, fatty acid amide.
In a kind of above-mentioned high-weatherability low water absorption carbon wood composite material, affiliated coupling agent is selected from silane coupler At least one of with titanate coupling agent.
Compared with prior art, it is the advantages of invention:Carbon wood composite material provided by the invention carries due to introducing carbon dust High weatherability and wearability, reduce water absorption rate, while obtained biological carbon after sludge carbonization treatment is introduced into the present invention's In formula, the performance of Wood plastic composite is not only increased, improves the cyclic utilization rate of carbon on the earth.
Embodiment
The technical scheme in inventive embodiments will be clearly and completely described below, it is clear that described embodiment Only invention part of the embodiment, rather than whole embodiments.Based on the embodiment in invention, ordinary skill people The every other embodiment that member is obtained under the premise of creative work is not made, belong to the scope of invention protection.
High-weatherability low water absorption carbon wood composite material, it is characterised in that it is by carbon dust, wood powder, polyethylene, EVA, lubrication Agent, coupling agent, antioxidant, anti ultraviolet agent composition.Composition is by weight percentage in the material:Carbon dust is 20-64%, carbon dust For biological carbon, described biological carbon is that sludge is made after carbonization, and the carbon content in described biological carbon is 35-89%, institute The carbon dust stated is 60-80 mesh.
Wood powder is 10-44%, and polyethylene 20-54%, EVA 3-10%, lubricant 1-3%, lubricant is selected from golden Belong at least one of soaps calcium stearate, fatty acid soaps, fatty acid amide.Coupling agent is 1-5%, and coupling agent is selected from silane coupled At least one of agent and titanate coupling agent.Antioxidant is 0.1-0.5%, and antioxidant is selected from antioxidant 1010, irgasfos 168 At least one of.Anti ultraviolet agent is 0.1-0.5%, and anti ultraviolet agent is selected from least one of hindered amine, BTA.
Embodiment 1-7
Table 1
Component in above-mentioned table 1 is added in double screw extruder according to mass ratio, extrusion temperature is 190-210 DEG C, is filled The Wood plastic composite that the present invention is made is extruded after dividing mixing.
Wood plastic composite made from above-described embodiment is subjected to performance test, test result such as table 2 below
Table 2
It can be drawn according to above test result, Wood plastic composite provided by the invention is more of the prior art wear-resisting 60-70mg is improved:50%, the existing like product technology of ageing resistace improves:30%, water absorption rate reduces:50%.
The preferred embodiment of invention is the foregoing is only, it is all in the spiritual and former of invention not to limit invention Within then, any modification, equivalent substitution and improvements made etc., it should be included within the protection domain of invention.

Claims (8)

1. high-weatherability low water absorption carbon wood composite material, it is characterised in that it is by carbon dust, wood powder, polyethylene, EVA, lubrication Agent, coupling agent, antioxidant, anti ultraviolet agent composition.
2. high-weatherability low water absorption carbon wood composite material according to claim 1, it is characterised in that composition in the material It is by weight percentage:Carbon dust is 20-64%, wood powder 10-44%, polyethylene 20-54%, EVA 3-10%, is lubricated Agent is 1-3%, coupling agent 1-5%, antioxidant 0.1-0.5%, anti ultraviolet agent 0.1-0.5%.
3. high-weatherability low water absorption carbon wood composite material according to claim 1, it is characterised in that described carbon dust is Biological carbon, described biological carbon are that sludge is made after carbonization, and the carbon content in described biological carbon is 35-89%.
4. high-weatherability low water absorption carbon wood composite material according to claim 1, it is characterised in that described carbon dust is 60-80 mesh.
5. high-weatherability low water absorption carbon wood composite material according to claim 1, it is characterised in that described antioxidant Selected from least one of antioxidant 1010, irgasfos 168.
6. high-weatherability low water absorption carbon wood composite material according to claim 1, it is characterised in that described uvioresistant Agent is selected from least one of hindered amine, BTA.
7. high-weatherability low water absorption carbon wood composite material according to claim 1, it is characterised in that described lubricant Selected from least one of metal soap calcium stearate, fatty acid soaps, fatty acid amide.
8. high-weatherability low water absorption carbon wood composite material according to claim 1, it is characterised in that affiliated coupling agent Selected from least one of silane coupler and titanate coupling agent.
CN201710530754.1A 2017-06-28 2017-06-28 A kind of high-weatherability low water absorption carbon wood composite material Pending CN107353470A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710530754.1A CN107353470A (en) 2017-06-28 2017-06-28 A kind of high-weatherability low water absorption carbon wood composite material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710530754.1A CN107353470A (en) 2017-06-28 2017-06-28 A kind of high-weatherability low water absorption carbon wood composite material

Publications (1)

Publication Number Publication Date
CN107353470A true CN107353470A (en) 2017-11-17

Family

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CN201710530754.1A Pending CN107353470A (en) 2017-06-28 2017-06-28 A kind of high-weatherability low water absorption carbon wood composite material

Country Status (1)

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CN (1) CN107353470A (en)

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WO2015039237A1 (en) * 2013-09-17 2015-03-26 University Of Guelph Hybrid sustainable composites and methods of making and using thereof
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CN106009748A (en) * 2016-07-04 2016-10-12 山东理工大学 Carbon-plastic compound material prepared by virtue of charcoal and production method of carbon-plastic compound material
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* Cited by examiner, † Cited by third party
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CN101724190A (en) * 2008-10-14 2010-06-09 李秋义 Asbestos fiber reinforced thermoplastic base wood and plastic composite material and preparing method thereof
CN101585970A (en) * 2009-05-13 2009-11-25 杭州师范大学 Polyolefin wood-plastic composite with low rate of water absorption
CN101781470A (en) * 2010-02-09 2010-07-21 华南师范大学 High wear-resistant wood-plastic composite and preparation method thereof
CN102757592A (en) * 2012-08-10 2012-10-31 惠东美新塑木型材制品有限公司 Plastic wood profile with abrasion resistance, scratch resistance, fouling resistance and weather resistance and preparation method thereof
CN103059596A (en) * 2013-01-23 2013-04-24 浙江大学 Nano-reinforced wood-plastic composite and preparation method thereof
US20140275355A1 (en) * 2013-03-15 2014-09-18 Solazyme, Inc. Wood plastic and thermoplastic composites
CN103205132A (en) * 2013-03-22 2013-07-17 国际竹藤中心 Weather-resistant bamboo-plastic composite and preparation method thereof
WO2015039237A1 (en) * 2013-09-17 2015-03-26 University Of Guelph Hybrid sustainable composites and methods of making and using thereof
CN104479388A (en) * 2014-12-31 2015-04-01 广东华慧生环保科技有限公司 PP wood-plastic composite and preparation method thereof
CN104672697A (en) * 2015-01-22 2015-06-03 浙江保森新型材料有限公司 Wood-plastic composite material
CN106009748A (en) * 2016-07-04 2016-10-12 山东理工大学 Carbon-plastic compound material prepared by virtue of charcoal and production method of carbon-plastic compound material
CN106867112A (en) * 2017-03-27 2017-06-20 江苏锦禾高新科技股份有限公司 A kind of straw charcoal plastics rich in charcoal and preparation method thereof

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Application publication date: 20171117