CN107345044A - A kind of high tenacity fire retardation PC/ABS - Google Patents

A kind of high tenacity fire retardation PC/ABS Download PDF

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Publication number
CN107345044A
CN107345044A CN201710782547.5A CN201710782547A CN107345044A CN 107345044 A CN107345044 A CN 107345044A CN 201710782547 A CN201710782547 A CN 201710782547A CN 107345044 A CN107345044 A CN 107345044A
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CN
China
Prior art keywords
abs
high tenacity
fire retardation
raw material
tenacity fire
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201710782547.5A
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Chinese (zh)
Inventor
赖树兴
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Foshan North Source Science And Technology Service Co Ltd
Original Assignee
Foshan North Source Science And Technology Service Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Foshan North Source Science And Technology Service Co Ltd filed Critical Foshan North Source Science And Technology Service Co Ltd
Priority to CN201710782547.5A priority Critical patent/CN107345044A/en
Publication of CN107345044A publication Critical patent/CN107345044A/en
Withdrawn legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/221—Oxides; Hydroxides of metals of rare earth metal
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/38—Boron-containing compounds
    • C08K2003/382—Boron-containing compounds and nitrogen
    • C08K2003/385—Binary compounds of nitrogen with boron
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/20—Recycled plastic

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

A kind of high tenacity fire retardation PC/ABS of the present invention, its raw material and raw material weight percentage composition are as follows：PC reclaimed materials 40 50%；Palmitin acid copolymer 0.1 1%；Boron nitride 0.1 3%；Lanthana 0.1 3%；Polytetrafluoroethylene (PTFE) 0.1 3%；ABS 40 60%.High tenacity fire retardation PC/ABS provided by the invention carries out blending and modifying using efficient alloy compatilizer to PC reclaimed materials and ABS, PC/ABS alloy materials are made, on the one hand PC melt viscosity can be reduced, improve its processing characteristics, on the other hand economic recycling is carried out to PC, extra burden will not be caused to environment.

Description

A kind of high tenacity fire retardation PC/ABS
Technical field
The present invention relates to thermoplastic resin composition field in high polymer material technology, and in particular to a kind of PC (Polycarbonate, makrolon) reclaimed materials is modified as the formula of high tenacity fire retardation PC (makrolon)/ABS alloys.
Background technology
PC is a kind of superior engineering plastics of combination property, have excellent impact flexibility, dimensional stability, electrically absolutely The advantages that edge, creep resistant, weatherability, the transparency and nontoxicity, it is widely used in plant equipment, architectural engineering, traffic fortune The field such as defeated, instrument and electric illumination.
PC also has the defects of some are obvious, such as：Processing fluidity is poor, easy stress cracking, to notch sensitive, easily abrasion, Chemical proofing is poor, on the high side etc..PC consumption is larger, while caused defective material, regrinding-material in article manufacturing process It is also more with the amount of reclaimed materials, therefore PC reclaimed materials is modified and can reused, it is significant.And ABS has Preferable chemical resistance, good processability and higher cost performance.PC reclaimed materials and ABS are subjected to blending and modifying PC/ABS alloy materials are made, on the one hand can reduce PC melt viscosity, improve its processing characteristics, while PC breach can be improved Sensitiveness and chemical proofing, on the other hand PC can be recycled and reused again.
The content of the invention
To solve above-mentioned existing technical problem, the present invention uses following scheme：
A kind of high tenacity fire retardation PC/ABS, its raw material and raw material weight percentage composition are as follows：
PC reclaimed materials 40-50%；
Palmitin acid copolymer 0.1-1%；
Boron nitride 0.1-3%；
Lanthana 0.1-3%；
Polytetrafluoroethylene (PTFE) 0.1-3%；
ABS 40-60%.
High tenacity fire retardation PC/ABS provided by the invention is entered using efficient alloy compatilizer to PC reclaimed materials with ABS Row blending and modifying, PC/ABS alloy materials are made, on the one hand can reduce PC melt viscosity, improve its processing characteristics, on the other hand Economic recycling is carried out to PC, extra burden will not be caused to environment.
Embodiment
The present invention is described in detail below in conjunction with specific embodiment, herein illustrative examples and explanation of the invention For explaining the present invention, but it is not as a limitation of the invention.
Embodiment
A kind of high tenacity fire retardation PC/ABS of the present invention, its raw material and raw material weight percentage composition are as follows：PC is returned Rewinding 45%, palmitin acid copolymer 0.5%, boron nitride 0.5%, lanthana 1%, polytetrafluoroethylene (PTFE) 2%, ABS 51%.
The above-described embodiments merely illustrate the principles and effects of the present invention, not for the limitation present invention.It is any ripe Know the personage of this technology all can carry out modifications and changes under the spirit and scope without prejudice to the present invention to above-described embodiment.Cause This, those of ordinary skill in the art is complete without departing from disclosed spirit and institute under technological thought such as Into all equivalent modifications or change, should by the present invention claim be covered.

Claims (1)

1. a kind of high tenacity fire retardation PC/ABS, it is characterised in that its raw material and raw material weight percentage composition are as follows：
PC reclaimed materials 40-50%；
Palmitin acid copolymer 0.1-1%；
Boron nitride 0.1-3%；
Lanthana 0.1-3%；
Polytetrafluoroethylene (PTFE) 0.1-3%；
ABS 40-60%.
CN201710782547.5A 2017-09-02 2017-09-02 A kind of high tenacity fire retardation PC/ABS Withdrawn CN107345044A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710782547.5A CN107345044A (en) 2017-09-02 2017-09-02 A kind of high tenacity fire retardation PC/ABS

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710782547.5A CN107345044A (en) 2017-09-02 2017-09-02 A kind of high tenacity fire retardation PC/ABS

Publications (1)

Publication Number Publication Date
CN107345044A true CN107345044A (en) 2017-11-14

Family

ID=60257493

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710782547.5A Withdrawn CN107345044A (en) 2017-09-02 2017-09-02 A kind of high tenacity fire retardation PC/ABS

Country Status (1)

Country Link
CN (1) CN107345044A (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101003676A (en) * 2006-01-20 2007-07-25 佛山市顺德区汉达精密电子科技有限公司 High flexible flame retardant PC(polycarbonate)/ABS alloy
CN101003675A (en) * 2006-01-20 2007-07-25 佛山市顺德区汉达精密电子科技有限公司 High flexible flame retardant PC(polycarbonate)/ABS alloy
CN101003671A (en) * 2006-01-20 2007-07-25 佛山市顺德区汉达精密电子科技有限公司 High flexible flame retardant PC(polycarbonate)/ABS alloy

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101003676A (en) * 2006-01-20 2007-07-25 佛山市顺德区汉达精密电子科技有限公司 High flexible flame retardant PC(polycarbonate)/ABS alloy
CN101003675A (en) * 2006-01-20 2007-07-25 佛山市顺德区汉达精密电子科技有限公司 High flexible flame retardant PC(polycarbonate)/ABS alloy
CN101003671A (en) * 2006-01-20 2007-07-25 佛山市顺德区汉达精密电子科技有限公司 High flexible flame retardant PC(polycarbonate)/ABS alloy

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
欧育湘等: "《塑料助剂性能与选用速查手册》", 31 January 2012, 国防工业出版社 *
郑德等: "《稳定剂》", 30 June 2011, 国防工业出版社 *

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Application publication date: 20171114