CN107340282A - The method for quick identification of Cashmere and Woolens - Google Patents

The method for quick identification of Cashmere and Woolens Download PDF

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Publication number
CN107340282A
CN107340282A CN201710511850.1A CN201710511850A CN107340282A CN 107340282 A CN107340282 A CN 107340282A CN 201710511850 A CN201710511850 A CN 201710511850A CN 107340282 A CN107340282 A CN 107340282A
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China
Prior art keywords
cashmere
wool
sample
raman
woolens
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CN201710511850.1A
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Chinese (zh)
Inventor
刘志红
肖红梅
王志新
赵艳红
米璐
谢遇春
马丽娜
李金泉
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Inner Mongolia Agricultural University
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Inner Mongolia Agricultural University
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/62Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light
    • G01N21/63Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light optically excited
    • G01N21/65Raman scattering

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  • Health & Medical Sciences (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Physics & Mathematics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Investigating, Analyzing Materials By Fluorescence Or Luminescence (AREA)

Abstract

The invention discloses a kind of method for quick identification of Cashmere and Woolens, including:Fiber is gathered as sample, sample is placed directly on the slide of Raman spectroscopy instrument;Sample is tested in Raman spectroscopy instrument, distinguishes in fiber whether contain cashmere or wool using the characteristic peak of Raman spectrum.The present invention by the method for Raman spectrum, can quickly, accurate, inexpensive identify cashmere and wool.

Description

The method for quick identification of Cashmere and Woolens
Technical field
The present invention relates to a kind of discrimination method, specifically, is related to a kind of method for quick identification of Cashmere and Woolens.
Background technology
How the discriminating of quick and easy progress Cashmere and Woolens, be many textile enterprise demand.Unlike wool, The surface scale thickness ratio wool of cashmere fiber is thin, is annularly coated on more on hair shaft, and it is in zyklopisch that the scale of wool is thicker. The density cashmere of scale covering hair shaft is smaller than wool, causes the cashmere fiber feel different from wool:Cashmere fiber feel is slided It is refreshing, and wool is relatively rough with respect to feel.Because the scale of cashmere is thinner than wool, the through performance of light under the microscope Good, printing opacity is uniform, fiber brightness uniformity, shadow-free sense, no projection;And the scale of wool is thick, printing opacity is uneven, the more shades of hair shaft Sense and projection.The scale cladding hair shaft of cashmere fiber is close, rake angle very little, and smoother is smooth;And wool is compared due to scale Thick and cause rake angle big, protrusion of surface is more, lacks smooth sense.The Length of the scale of cashmere is longer, and spacing is big, arranges closeer than wool Spend small, the coefficient of friction between scale is small, therefore its to wash rear feltability better than wool;And wool difference.Cashmere fiber hair shaft is uniform, Seldom reverse, deformation;And wool fiber hair shaft is uneven, reverse more.Because positive and negative cortical layer is in both sides distribution, the volume of cashmere Curvature is smaller than the crimpness of wool.
Difference based on cashmere and wool, in cashmere and wool differentiate, currently used method is to utilize optical microphotograph Mirror carries out the discriminating of cashmere and wool, it is necessary to observe two kinds of fiber scale structures and configuration to be distinguish between.But this mirror Identification person is not needed to have stronger professional knowledge, and the understanding to Cashmere and Woolens characteristic.
The content of the invention
Technical problem solved by the invention is to provide a kind of method for quick identification of Cashmere and Woolens, can be quick, accurate, low Cost identifies cashmere and wool.
Technical scheme is as follows:
A kind of method for quick identification of Cashmere and Woolens, including:
Fiber is gathered as sample, sample is placed directly on the slide of Raman spectroscopy instrument;
Sample is tested in Raman spectroscopy instrument, whether contained to distinguish in fiber using the characteristic peak of Raman spectrum There are cashmere or wool.
Further:Principal component identification and classification analysis is carried out to gathered data, further discriminates between cashmere and wool.
Further:Each sample collection at least 3 times, obtain the Raman spectrogram of difference.
Further:The excitation source of Raman spectroscopy instrument uses 532nm laser, time for exposure 0.03s.
Further:The characteristic peak that Raman spectrum chooses 1207cm-1 is analyzed.
Further:Raman spectroscopy instrument selects DXRxi microscopic Raman imaging spectrometers.
Compared with prior art, the technology of the present invention effect includes:
1st, the method that the present invention passes through Raman spectrum, it is not necessary to stronger professional knowledge background, you can quick, accurate, low Cost identifies cashmere and wool.
2nd, discrimination of the present invention is high.
The present invention can not only differentiate to the fiber of different cultivars, while can carry out the source of species of different cultivars Differentiate, more can even carry out the discriminating of same kind individual, be a kind of discrimination method of high sensitivity high accuracy, it is this super Quickly, inexpensive Cashmere and Woolens differentiates significant to textile enterprise.The present invention is not only for same, to same The woollen and cashmere of body may also differentiate between.
3rd, of the invention, sample process is simple, it is not necessary to which any direct loading of processing is i.e. detectable;It is easy to operate, it is not necessary to Too high technical background, it is easy to grasp, it is only necessary to which 1 equipment is acquired data.
4th, testing result is stable, and sample multiplicity is high.
5th, detection low cost.Slide is only needed for single sample, single sample can't detect 1 mao.
Brief description of the drawings
Fig. 1 is the Raman spectrogram of embodiment one in the present invention;
Fig. 2 is the TQ software Raman spectrum analysis figures of embodiment one in the present invention;
Fig. 3 is the mahalanobis distance schematic diagram of the principal component cluster of embodiment one in the present invention;
Fig. 4 is the mahalanobis distance schematic diagram of the principal component cluster of embodiment two in the present invention;
Fig. 5 is the Raman spectrogram of embodiment three in the present invention;
Fig. 6 is the mahalanobis distance schematic diagram of the principal component cluster of embodiment three in the present invention;
Fig. 7 is the mahalanobis distance schematic diagram of the principal component cluster of example IV in the present invention.
Embodiment
Technical solution of the present invention is elaborated below with reference to example embodiment.However, example embodiment can Implement in a variety of forms, and be not understood as limited to embodiment set forth herein;On the contrary, these embodiments are provided so that The design of example embodiment more comprehensively and completely, and is comprehensively communicated to those skilled in the art by the present invention.
Uniqueness of the invention according to Raman spectroscopy fingerprint recognition, it is possible to achieve the composition of unknown sample is qualitative, together When according to the high sensitivity of DXR2xi microscopic Raman imaging spectrometers and the characteristic of high spatial resolution, can easily realize micro-nano The test of meter level sample, and preparation of the test process without sample, do not destroy sample;With reference to TQ software fast spectrum preview work( Can, it is simple to operate quick.Supper-fast imaging is realized using the DXR2xi microscopic Raman imaging spectrometers of innovation, according to analysis purpose Obtain the distribution situation of each composition of microcell of sample.
The method for quick identification of Cashmere and Woolens, including:
Step 1:Fiber is gathered as sample, sample is placed directly on the slide of Raman spectroscopy instrument;
Raman spectroscopy instrument selects DXRxi (DXRxi Raman Imaging Microscope) microscopic Raman imaging Spectrometer.
Step 2:Sample is made a preliminary test in Raman spectroscopy instrument, fibre is distinguished using the characteristic peak of Raman spectrum Whether contain cashmere or wool in dimension;
Each minimum 3 times of sample collection, obtain the Raman spectrogram of difference.The excitation source of Raman spectroscopy instrument uses 532nm laser, time for exposure 0.03s.Be scanned through result show down producing goat equally cashmere Raman spectrum in 1207cm- The characteristic peak of 1 (1207 sites are C-O singly-bounds) nearby is relatively stronger than fine-wool sheep hair Raman spectrogram.
Step 3:Principal component identification and classification analysis is carried out to gathered data, further discriminates between cashmere and wool.
Further expand colony's checking, carry out principal component identification and classification analysis by TQ softwares, as a result show heterogeneous fleece quilt Individual in wool and cashmere can be very good to distinguish.
TQ softwares (TQ Analyst softwares) are a general spectral analysis softwares, its infrared, near-infrared in being, The application of far infrared and Raman spectrum analysis provides various qualitative and quantitative analysis instruments.The software is except including various algorithm works Tool is outer, additionally it is possible to provides the user friendly, easy-to-use graphical interfaces directly perceived, and extensive online help information.
By wool fiber classification of type, sheep fleece wool (the whole wools grown on sheep body) can be divided into:Homogeneity hair is (same Type hair) and heterogeneous fleece (special-shaped hair) two major classes.Homogeneity hair refers to the hair that same type of wool fiber is formed, its feature Be wool fibre diameter, length, curling and other barment tags it is essentially identical;And heterogeneous fleece be then had concurrently in hair fine hair, There is marrow hair, differed without the different types of wool fiber such as curling and few frizzle, various chemistry, physical and mechanical properties.
Analyzed and verified as sample using goat cashmere, goat wool, fine wool and coarse-wooled sheep wool below Conclusion.
Embodiment one
1st, for heterogeneous fleece by wool, the carry out Raman spectrum analysis of cashmere in same individual;
Down producing goat is heterogeneous fleece quilt, and the lint ratio in same individual is 1:3~10.This experiment is first by Raman spectrum area Divide same individual different fine hair samples, the wool in same individual, cashmere are placed on Raman spectroscopy instrument as sample Analyzed on slide.
As shown in figure 1, it is the Raman spectrogram of embodiment one in the present invention.
Abscissa is Raman shift, exactly scatters wave-number difference of the light relative to incident light, and ordinate is photon counting, is exactly Scatter the intensity of light.
Light source uses 532nm laser, time for exposure 0.03s, is scanned through same individual wool, the Raman of cashmere sample Spectrogram, as a result show that characteristic peak of the Raman spectrum of cashmere near 1207cm-1 is more relatively strong than wool Raman spectrogram.
According to the important group frequency analysis of representative organic compounds, this characteristic peak is speculated as C-O (carbon oxygen singly-bound) feature Peak.Absorbed from spectral signature peak and judge to cause this difference on Cashmere and Woolens to be by phenols, alcohols, fatty ethers, carboxylic acid C-O keys change in class and esters.Fine hair sample basic composition is keratin, and when forming albumen C- can occur for amino acid The fracture of O keys, amido link is formed with amino, is condensed into peptide bond, illustrate cashmere and the wool difference on peptide formation.
2nd, the identification and classification for expanding colony to woollen and cashmere in the Different Individual of heterogeneous fleece quilt is analyzed.
As shown in Fig. 2 it is the mahalanobis distance schematic diagram of the principal component cluster of embodiment one in the present invention.
Expand colony's checking, carry out principal component identification and classification analysis by TQ softwares, as a result show the individual of heterogeneous fleece quilt In wool and cashmere can be very good to distinguish.
Abscissa is the distance value that sample arrives wool in figure, and ordinate is the distance value of sample to cashmere, can be with from figure Find out that the sample X transverse axis coordinate of cashmere is more than Y ordinate of orthogonal axes, illustrate the sample to cashmere distance closer to belonging to cashmere.And again Duplicate sample is originally got together, and can be very good to differentiate cashmere and wool.
Embodiment two
1st, Raman spectrum analysis is carried out as sample using fine wool and cashmere.
As shown in figure 3, it is the Raman spectrogram of embodiment two in the present invention.
Light source uses 532nm laser, time for exposure 0.03s, is scanned through result and shows down producing goat equally in cashmere Characteristic peak of the Raman spectrum near 1207cm-1 is relatively stronger than fine-wool sheep hair Raman spectrogram.
Abscissa is wavelength, and ordinate is spectral intensity, it can be seen that strong in 1207.45 position cashmere samples Degree is higher than wool sample, cashmere sample existing characteristics peak.
2nd, principal component identification and classification analysis is carried out after expanding colony.
As shown in figure 4, it is the mahalanobis distance schematic diagram of the principal component cluster of embodiment two in the present invention.
Components analysis differentiation is carried out by TQ softwares, as a result shows that same fine wool and cashmere can be very good to distinguish.
Abscissa is distance value of the sample to fine wool from figure, and ordinate is distance value of the sample to cashmere, from figure It can be seen that the sample X transverse axis coordinate of cashmere is more than Y ordinate of orthogonal axes, illustrate the sample to cashmere distance closer to belonging to cashmere.And And repeated sample is got together, can be very good to differentiate cashmere and fine wool.
Embodiment three
1st, Raman spectrum map analysis is carried out as sample using coarse-wooled sheep wool and cashmere;
As shown in figure 5, it is the Raman spectrogram of embodiment three in the present invention.
Light source uses 532nm laser, time for exposure 0.03s, is scanned through result and shows that the Raman spectrum of cashmere exists Characteristic peak near 1207cm-1 is relatively stronger than fine wool Raman spectrogram.
Being scanned through result shows characteristic peak of the Raman spectrum of cashmere near 1207cm-1 than fine wool Raman spectrum Figure is relatively strong.
2nd, principal component identification and classification analysis is carried out after expanding colony.
As shown in fig. 6, it is the mahalanobis distance schematic diagram of the principal component cluster of embodiment three in the present invention.
Principal component identification and classification analysis is carried out by TQ softwares, the common and braid wool and cashmere for as a result showing the sample can be fine Differentiation.
Abscissa be sample arrive common and braid wool distance value, ordinate be sample to the distance value of cashmere, can from figure The sample X transverse axis coordinate for going out cashmere is more than Y ordinate of orthogonal axes, illustrates the sample to cashmere distance closer to belonging to cashmere.And repeat Sample is got together, and can be very good to differentiate cashmere and common and braid wool.
Example IV
Analyzed using goat cashmere, fine wool and coarse-wooled sheep wool as the principal component identification and classification of sample.
As shown in fig. 7, it is the mahalanobis distance schematic diagram of the principal component cluster of example IV in the present invention.
Abscissa is distance value of the sample to coarse wool wool from figure, and ordinate is distance value of the sample to fine, soft fur wool, As can be seen from the figure fine-wool sheep sample is more than Y ordinate of orthogonal axes to X transverse axis coordinate, illustrates the sample to Y distances closer to belonging to thin Mao Yang.Coarse-wooled sheep sample is more than X ordinate of orthogonal axes to Y transverse axis coordinate, illustrates the sample to X distances closer to belonging to coarse-wooled sheep.Cashmere Sample is placed in the middle, and repeated sample is got together, and can be very good to differentiate cashmere and wool.
By result as can be seen that cashmere and fine wool cluster compare concentration, coarse-wooled sheep wool group clustering compares Dissipate, the fineness dispersion of this and coarse-wooled sheep wool matters a lot, but should be apparent that from figure cashmere, coarse-wooled sheep wool and Fine wool cluster is different colony, it is seen that the present invention is that one kind can quickly carry out Cashmere and Woolens mirror method for distinguishing.
Term used herein is explanation and exemplary and nonrestrictive term.Because the present invention can be with a variety of Form specific implementation without departing from the spiritual or substantive of invention, it should therefore be appreciated that above-described embodiment be not limited to it is any foregoing Details, and should widely being explained in the spirit and scope that appended claims are limited, thus fall into claim or its etc. Whole changes and remodeling in the range of effect all should be appended claims and covered.

Claims (6)

1. a kind of method for quick identification of Cashmere and Woolens, including:
Fiber is gathered as sample, sample is placed directly on the slide of Raman spectroscopy instrument;
Sample is tested in Raman spectroscopy instrument, distinguishes in fiber whether contain sheep using the characteristic peak of Raman spectrum Suede or wool.
2. the method for quick identification of Cashmere and Woolens as claimed in claim 1, it is characterised in that:Principal component is carried out to gathered data to sentence Other classification analysis, further discriminates between cashmere and wool.
3. the method for quick identification of Cashmere and Woolens as described in claims 1 or 2, it is characterised in that:Each sample collection at least 3 It is secondary, obtain the Raman spectrogram of difference.
4. the method for quick identification of Cashmere and Woolens as described in claims 1 or 2, it is characterised in that:Raman spectroscopy instrument Excitation source uses 532nm laser, time for exposure 0.03s.
5. the method for quick identification of Cashmere and Woolens as described in claims 1 or 2, it is characterised in that:Raman spectrum is chosen 1207cm-1 characteristic peak is analyzed.
6. the method for quick identification of Cashmere and Woolens as described in claims 1 or 2, it is characterised in that:Raman spectroscopy instrument selects With DXRxi microscopic Raman imaging spectrometers.
CN201710511850.1A 2017-06-27 2017-06-27 The method for quick identification of Cashmere and Woolens Pending CN107340282A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108226129A (en) * 2017-12-28 2018-06-29 广州纤维产品检测研究院 A kind of leather qualitative identification method based on Raman spectrum
CN113637775A (en) * 2021-09-02 2021-11-12 内蒙古农业大学 SNP molecular marker influencing fine character of cashmere and application thereof

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CN101187635A (en) * 2007-12-21 2008-05-28 浙江大学 Method for identifying textile fibers based on Raman spectra qualitative identification
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108226129A (en) * 2017-12-28 2018-06-29 广州纤维产品检测研究院 A kind of leather qualitative identification method based on Raman spectrum
CN113637775A (en) * 2021-09-02 2021-11-12 内蒙古农业大学 SNP molecular marker influencing fine character of cashmere and application thereof
CN113637775B (en) * 2021-09-02 2024-01-30 内蒙古农业大学 SNP molecular marker affecting fine characteristics of cashmere and application thereof

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Application publication date: 20171110