CN107338543A - A kind of nanofiber covering yarn preparation facilities - Google Patents

A kind of nanofiber covering yarn preparation facilities Download PDF

Info

Publication number
CN107338543A
CN107338543A CN201610855535.6A CN201610855535A CN107338543A CN 107338543 A CN107338543 A CN 107338543A CN 201610855535 A CN201610855535 A CN 201610855535A CN 107338543 A CN107338543 A CN 107338543A
Authority
CN
China
Prior art keywords
magnetic
yarn
spinning solution
nanofiber
spinning
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610855535.6A
Other languages
Chinese (zh)
Inventor
钟海炎
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tongxiang Guardian Applied Technology Research Institute Co Ltd
Original Assignee
Tongxiang Guardian Applied Technology Research Institute Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tongxiang Guardian Applied Technology Research Institute Co Ltd filed Critical Tongxiang Guardian Applied Technology Research Institute Co Ltd
Priority to CN201610855535.6A priority Critical patent/CN107338543A/en
Publication of CN107338543A publication Critical patent/CN107338543A/en
Pending legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/22Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
    • D02G3/36Cored or coated yarns or threads
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Textile Engineering (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)

Abstract

The invention discloses a kind of nanofiber covering yarn preparation method.The yarn is made up of nanofiber covering yarn preparation facilities, comprises the following steps:(1), by magnetic polymer spinning solution inject spinning appts in, magnetic polymer spinning solution is sprayed by micro-injection pump,(2), the magnetic polymer spinning solution in spinning appts spray jet, jet is drawn into fiber under the action of a magnetic force, forms bundles of nanofibers,(3), long filament fed respectively from the left and right sides by filament feeding device, contact respectively with the bundles of nanofibers of the left and right sides, is compound, bundles of nanofibers is coated on the outer surface of long filament, forms or so two with composite core-spun yarn,(4), left and right two pass through wire sub-panel, coiler device and twister successively with composite core-spun yarn,(5), two composite core-spun yarns in left and right twist left and right twisting and resultant yarn in the rotation of twister, on coiler device.

Description

A kind of nanofiber covering yarn preparation facilities
Technical field
The present invention relates to a kind of preparation facilities of covering yarn, and in particular to a kind of nanofiber bag prepared by magnetic spinning equipment The preparation facilities of heart yarn.
Background technology
Method of electrostatic spinning is to prepare one of most simple efficient method of polymer nanofiber at present, with the letter of its process equipment Singly, many advantages, such as raw material sources are extensive, spinning technique is controllable, Electrospun nano-fibers have superhigh specific surface area, Gao Kong The features such as gap rate and strong adsorptivity, it can be widely applied to the fields such as filtering, photocatalysis, sensor and biologic applications.
Static Spinning is mainly for the preparation of the tunica fibrosa of non-woven cloth form, and its product is mostly with film or the shape similar to film Formula is present, therefore the strength of electrostatic spinning nano fiber is not general high, because the low strength of electrostatic spinning nano fiber makes it in reality Application in enjoy obstruction, therefore, it is necessary to strengthen the strength of nanofiber by other technologies means.Such as by nanofiber with Other high-tenacity Material claddings use, and this, which just needs with other machinery equipments to put Nano- fiber preparation device together, makes With.
In addition, also there is following technical problem for nanofiber in electro-spinning:Static Spinning need higher spinning voltage with Form electric field, this voltage be typically up to it is tens of thousands of to hundreds of thousands volt, by the equipment with such big voltage and other equipment company With can produce potential danger, and so high voltage and high electric field are likely to the risk of breakdown plus other equipment.Therefore, A kind of means for preparing nanofiber are needed, and the use that the means and other machines equipment can be put together.
The content of the invention
It is an object of the invention to overcome the deficiencies of the prior art and provide a kind of device for preparing nanofiber covering yarn, The device replaces electric field force during the spinning of yarn with magnetic field force, the strained polymer spinning solution under the effect of alternating magnetic field power Nanofiber is prepared, polymer nanofiber is coated on to the surface of long filament, forms the core-spun composite yarn using long filament as core, by In the presence of core long filament, the strength of nanofiber is greatly improved, has expanded its application, whole preparation process need not High pressure electro ultrafiltration, potential safety hazard is effectively reduced, obtained is a kind of covering yarn with nanoscale clad.
To achieve these goals, technical scheme provided by the invention is as follows:
A kind of nanofiber covering yarn preparation facilities, it is characterised in that the nanofiber cored preparation facilities includes polymer Spinning solution spinning appts, micro-injection pump, magneto-receptive disk, yarn-guiding duct, filament feeding device, guide roller, wire sub-panel, volume Winding apparatus, twister and motor, the polymer dope spinning appts are that magnetic spins spinning appts, the polymer spinning Liquid is magnetic polymer spinning solution, and the magneto-receptive disk is used to receive magnetic polymer spinning to form magnetic polymer nanometer Fiber, the magnetic polymer nanofiber are covered by filament surface.
The magneto-receptive disk be used for form high-intensity magnetic field, by the spinning solution jet that spinning appts eject high-intensity magnetic field drawing Attenuate under the effect of stretching, form nano fiber coated in filament surface;The micro-injection pump regulation polymer dope spinneret dress The fltting speed put;The bar permanent magnet for being provided with magnetic field, the length of the bar magnet are fixed in the surface of the magneto-receptive disk Axle is vertical with the axis of magneto-receptive disk.
A kind of nanofiber covering yarn is prepared using the preparation facilities of the present invention, the nanofiber covering yarn is by magnetic Property polymer nanofiber clad and core long filament composition, the magnetic polymer nano fiber coated layer is by magnetic polymer Spinning solution forms by magnetic field force spinning.
The magnetic polymer spinning solution is magnetic fluid spinning solution;The magnetic fluid spinning solution includes high molecular polymer, Surfactant, organic solvent and magnetic nanoparticle.
The method for preparing nanofiber covering yarn using the nanofiber covering yarn preparation facilities of the present invention, its step is such as Under:
(1), by magnetic polymer spinning solution inject spinning appts in, magnetic polymer spinning solution is sprayed by micro-injection pump Go out;
(2), the magnetic polymer spinning solution in spinning appts spray jet, jet is drawn into fibre under the action of a magnetic force Dimension, form bundles of nanofibers;
(3), while bundles of nanofibers is formed, long filament by filament feeding device respectively from the left and right sides feed, respectively with a left side The bundles of nanofibers of right both sides contacts, is compound, and bundles of nanofibers is coated on the outer surface of long filament, forms left and right two with compound core-spun Yarn;
(4), left and right two pass through wire sub-panel, coiler device and twister successively with composite core-spun yarn;
(5), two composite core-spun yarns in left and right twist left and right twisting and resultant yarn in the rotation of twister, wound on coiler device On.
Beneficial effects of the present invention are:By the device, electric field force is replaced with magnetic field force, acts on and pulling down in alternating magnetic field power Stretch magnetic polymer spinning solution and prepare polymer nanofiber, polymer nanofiber is coated on to the surface of long filament, formed with Long filament is the core-spun composite yarn of core, due to the presence of core long filament, greatly improves the strength of nanofiber, has expanded it Application;Whole preparation process effectively reduces potential safety hazard, obtained is that one kind has nanoscale bag without high pressure electro ultrafiltration The covering yarn of coating.
Brief description of the drawings
Fig. 1 is the structural representation of the present invention.
As shown in Figure 1:The nanofiber covering yarn preparation facilities includes right side polymer dope spinning appts 1, a left side Side polymer dope spinning appts 1 ', right side magneto-receptive disk 2, left side magneto-receptive disk 2 ', right side yarn-guiding duct 3, left side Yarn-guiding duct 3 ', right side filament feeding device 4, left side filament feeding device 4 ', right motor 5, left motor 5 ', right side are led Leno draws 6, left side guide roller 6 ', wire sub-panel 7, coiler device 8, rotation twisting plate 9 etc..
With reference to shown in Fig. 1, nanofiber covering yarn preparation facilities of the present invention includes right side polymer dope spinneret Device 1 and left side polymer dope spinning appts 1 ', right side polymer dope spinning appts 1 and left side polymer spinning Liquid spinning appts 1 ' are connected with respective micro-injection pump, and their Injection nozzle is respectively aligned to right side magneto-receptive disk 2 With left side magneto-receptive disk 2 ', right side polymer dope spinning appts 1 and right side magneto-receptive disk 2 are formed a branch of by magnetic field Nanofiber, left side polymer dope spinning appts 1 ' and left side magneto-receptive disk 2 ' form another beam Nanowire by magnetic field Dimension;The surface of the right side magneto-receptive disk 2 and left side magneto-receptive disk 2 ' is respectively and fixedly provided with the bar permanent magnet for providing magnetic field, institute The major axis for stating bar magnet is vertical with the axis of magneto-receptive disk.Magneto-receptive disk 2 and left side magneto-receptive disk 2 ' on right side Centre bore in respectively set right side yarn-guiding duct 3 and left side yarn-guiding duct 3 ', right side long filament and left side long filament be each passed through the right side Side yarn-guiding duct 3 and left side yarn-guiding duct 3 ';Right motor 5 and left motor 5 ' are respectively to drive the He of right side magneto-receptive disk 2 Left side magneto-receptive disk 2 ' rotates, and on right side, magneto-receptive disk 2 and the rear of left side magneto-receptive disk 2 ' set right side guide respectively Roller 6 and left side guide roller 6 ';Set gradually below the right side magneto-receptive disk 6 and left side magneto-receptive disk 6 ' point Filament plate 7, devices for taking-up 8 and rotation twisting plate 9.
A kind of nanofiber covering yarn is prepared using the preparation facilities of the present invention, the nanofiber covering yarn is by magnetic Property polymer nanofiber clad and core long filament composition, the magnetic polymer nano fiber coated layer is by magnetic polymer Spinning solution forms by magnetic field force spinning.
The magnetic polymer spinning solution is magnetic fluid spinning solution;The magnetic fluid spinning solution includes high molecular polymer, Surfactant, organic solvent and magnetic nanoparticle.
Its high molecular polymer is polyethylene glycol oxide, Kynoar, polycaprolactone, polystyrene, polymethylacrylic acid One or more in methyl esters;The surfactant is neopelex, lauryl sodium sulfate, Tween 80, oil One kind in acid, alkyl quaternary ammonium salts;The organic solvent is the one or more in chloroform, N,N-dimethylformamide, acetone; The magnetic nanoparticle is γ-Fe2O3、Fe3O4, cobalt, one kind in nickel, or received for the composite magnetic of a variety of magnetic elements Rice grain.Long filament can select the common chemical-fibres filaments that fineness is 30-300D.
Its course of work is as follows:Magnetic polymer spinning solution pushes away magnetic polymer spinning in the presence of micro-injection pump Go out to be formed magnetic jet, magnetic jet stretches in the presence of magneto-receptive disk obtains two beam nanofibers of left and right, and this two beam is received Rice fiber is respectively coated by the same time from the long filament of left and right sides feeding, compound resultant yarn, then via wire sub-panel, devices for taking-up and is added Twist with the fingers coiling take twisting after on coiler device.Concretely comprise the following steps:
(1), by magnetic polymer spinning solution inject spinning appts in, magnetic polymer spinning solution is sprayed by micro-injection pump Go out;
(2), the magnetic polymer spinning solution in spinning appts spray jet, jet is drawn into fibre under the action of a magnetic force Dimension, form bundles of nanofibers;
(3), while bundles of nanofibers is formed, long filament by filament feeding device respectively from the left and right sides feed, respectively with a left side The bundles of nanofibers of right both sides contacts, is compound, and bundles of nanofibers is coated on the outer surface of long filament, forms left and right two with compound core-spun Yarn;
(4), left and right two pass through wire sub-panel, coiler device and twister successively with composite core-spun yarn;
(5), two composite core-spun yarns in left and right twist left and right twisting and resultant yarn in the rotation of twister, wound on coiler device On.

Claims (5)

1. a kind of nanofiber covering yarn preparation facilities, it is characterised in that the nanofiber cored preparation facilities includes polymerization Thing spinning solution spinning appts, micro-injection pump, magneto-receptive disk, yarn-guiding duct, filament feeding device, guide roller, wire sub-panel, Coiler device, twister and motor, the polymer dope spinning appts are that magnetic spins spinning appts, the polymer spun Silk liquid is magnetic polymer spinning solution, and the magneto-receptive disk is received for receiving magnetic polymer spinning with forming magnetic polymer Rice fiber, the magnetic polymer nanofiber are covered by filament surface;The surface of the magneto-receptive disk is fixed and is provided with The bar permanent magnet in magnetic field, the major axis of the bar magnet are vertical with the axis of magneto-receptive disk.
2. a kind of nanofiber covering yarn, it is characterised in that the nanofiber covering yarn uses system as described in claim 1 Prepared by standby device, the nanofiber covering yarn is made up of magnetic polymer nano fiber coated layer and core long filament, institute Magnetic polymer nano fiber coated layer is stated to be formed by magnetic field force spinning by magnetic polymer spinning solution.
3. nanofiber covering yarn as claimed in claim 2, it is characterised in that the magnetic polymer spinning solution is magnetic fluid Spinning solution.
4. nanofiber covering yarn as claimed in claim 3, it is characterised in that the magnetic fluid spinning solution includes polyphosphazene polymer Compound, surfactant, organic solvent and magnetic nanoparticle.
A kind of 5. side that nanofiber covering yarn is prepared using nanofiber covering yarn preparation facilities as claimed in claim 1 Method, it is characterised in that comprise the following steps:
(1), by magnetic polymer spinning solution inject spinning appts in, magnetic polymer spinning solution is sprayed by micro-injection pump Go out;
(2), the magnetic polymer spinning solution in spinning appts spray jet, jet is drawn into fibre under the action of a magnetic force Dimension, form bundles of nanofibers;
(3), while bundles of nanofibers is formed, long filament by filament feeding device respectively from the left and right sides feed, respectively with a left side The bundles of nanofibers of right both sides contacts, is compound, and bundles of nanofibers is coated on the outer surface of long filament, forms left and right two with compound core-spun Yarn;
(4), left and right two pass through wire sub-panel, coiler device and twister successively with composite core-spun yarn;
(5), two composite core-spun yarns in left and right twist left and right twisting and resultant yarn in the rotation of twister, wound on coiler device On.
CN201610855535.6A 2016-09-28 2016-09-28 A kind of nanofiber covering yarn preparation facilities Pending CN107338543A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610855535.6A CN107338543A (en) 2016-09-28 2016-09-28 A kind of nanofiber covering yarn preparation facilities

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610855535.6A CN107338543A (en) 2016-09-28 2016-09-28 A kind of nanofiber covering yarn preparation facilities

Publications (1)

Publication Number Publication Date
CN107338543A true CN107338543A (en) 2017-11-10

Family

ID=60222315

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610855535.6A Pending CN107338543A (en) 2016-09-28 2016-09-28 A kind of nanofiber covering yarn preparation facilities

Country Status (1)

Country Link
CN (1) CN107338543A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109234882A (en) * 2018-09-04 2019-01-18 苏州大学 A kind of continuous preparation method and preparation facilities of covering yarn
CN113388939A (en) * 2021-06-21 2021-09-14 常州大学 Preparation method and application of core-shell type composite fluorescent fiber
CN115233351A (en) * 2022-07-01 2022-10-25 无锡裕盛纱线有限公司 Sensing conductive yarn and processing device and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103132194A (en) * 2011-11-30 2013-06-05 杨恩龙 Orientation electro-spinning nanometer fiber spinning method and device thereof
CN104032423A (en) * 2014-06-20 2014-09-10 东华大学 Nano-fiber covering yarn electrostatic spinning device and application thereof
CN104878456A (en) * 2015-05-26 2015-09-02 青岛大学 Magnetic spinning device and method using device for manufacturing micro-nano-meter fibers
US20150345049A1 (en) * 2014-05-28 2015-12-03 University Of Georgia Research Foundation, Inc. Magnetospinning apparatus for low-magnetic materials and methods of use
CN105200540A (en) * 2015-10-27 2015-12-30 北京航空航天大学 Electrostatic spinning device for preparing axial orderly arranged tubes by means of magnetic field inducement
CN105332131A (en) * 2015-12-04 2016-02-17 江南大学 Method for preparing acetic acid nano fiber/polyester filament composite yarn

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103132194A (en) * 2011-11-30 2013-06-05 杨恩龙 Orientation electro-spinning nanometer fiber spinning method and device thereof
US20150345049A1 (en) * 2014-05-28 2015-12-03 University Of Georgia Research Foundation, Inc. Magnetospinning apparatus for low-magnetic materials and methods of use
CN104032423A (en) * 2014-06-20 2014-09-10 东华大学 Nano-fiber covering yarn electrostatic spinning device and application thereof
CN104878456A (en) * 2015-05-26 2015-09-02 青岛大学 Magnetic spinning device and method using device for manufacturing micro-nano-meter fibers
CN105200540A (en) * 2015-10-27 2015-12-30 北京航空航天大学 Electrostatic spinning device for preparing axial orderly arranged tubes by means of magnetic field inducement
CN105332131A (en) * 2015-12-04 2016-02-17 江南大学 Method for preparing acetic acid nano fiber/polyester filament composite yarn

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109234882A (en) * 2018-09-04 2019-01-18 苏州大学 A kind of continuous preparation method and preparation facilities of covering yarn
CN109234882B (en) * 2018-09-04 2023-07-21 苏州大学 Continuous preparation method and preparation device of core spun yarn
CN113388939A (en) * 2021-06-21 2021-09-14 常州大学 Preparation method and application of core-shell type composite fluorescent fiber
CN115233351A (en) * 2022-07-01 2022-10-25 无锡裕盛纱线有限公司 Sensing conductive yarn and processing device and preparation method thereof

Similar Documents

Publication Publication Date Title
CN104032423B (en) A kind of device of electrostatic spinning nano fiber covering yarn and its application
CN103088478B (en) A kind of orientation electro-spun nanofiber yarn continuous preparation device
CN109137199B (en) Preparation device and method of orientation-controllable electrostatic spinning nanofiber core-spun yarn
CN104060355B (en) Production method and device for continuous nano-fiber yarn
CN105648547B (en) A kind of preparation method of electrostatic spinning nano fiber yarn feeding device and nano fibre yarn
CN103132194A (en) Orientation electro-spinning nanometer fiber spinning method and device thereof
CN102912502B (en) Device and method for spinning nanofiber and filament composite yarns
CN106835412A (en) The method and apparatus that a kind of electrostatic spinning nano fiber band twists into yarn
CN106868675B (en) A kind of continuous preparation device of nanofiber covering yarn
CN105839253A (en) Ultraviolet-proof nano-fiber yarn and preparation method thereof
CN105220246B (en) A kind of multiply jet friction of electrostatic spinning nano fiber is into yarn feeding device and preparation method
CZ2007179A3 (en) Linear fibrous formation containing polymeric nanofibers, process of its manufacture and apparatus for producing such formation su
CN100575572C (en) The continuously static spinning method of polyamide 6/66 copolymer filament yarns
CN107338543A (en) A kind of nanofiber covering yarn preparation facilities
CN106222763A (en) A kind of electrostatic spinning apparatus preparing spiral micro nanometer fiber continuously and method thereof
CN104695066A (en) Swiveling electrostatic spinning nanofiber yarn preparing device and nanofiber yarn preparing method
CN203333875U (en) Electrostatic spinning nano-fiber air-jet twisting yarn-forming device
CN103993376A (en) Electrostatic spinning device for manufacturing nanometer fiber bundles
CN104711719A (en) Device for preparing electrospun nanofiber yarns by using rotary collector and preparation method thereof
CN109554794B (en) Device and method for forming yarn by using electrostatic spinning nanofiber core-spun yarn
CN105887223A (en) High-speed centrifugal spinning device for producing nanofiber yarn in one-step shaping and production method of nanofiber yarn
CN105734693A (en) Double-electrode electrostatic spinning device and using method thereof
CN104988611A (en) Twister and electrostatic spinning apparatus using same
CN113388928A (en) Spinning and drafting integrated high-performance micro-nanofiber yarn preparation device and method
CN114808437B (en) Method for surface treatment of polymer yarns

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20171110

RJ01 Rejection of invention patent application after publication