CN107338078A - A kind of energy-efficient gasoline products - Google Patents
A kind of energy-efficient gasoline products Download PDFInfo
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- CN107338078A CN107338078A CN201710400376.5A CN201710400376A CN107338078A CN 107338078 A CN107338078 A CN 107338078A CN 201710400376 A CN201710400376 A CN 201710400376A CN 107338078 A CN107338078 A CN 107338078A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/04—Use of additives to fuels or fires for particular purposes for minimising corrosion or incrustation
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/106—Liquid carbonaceous fuels containing additives mixtures of inorganic compounds with organic macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/12—Inorganic compounds
- C10L1/1225—Inorganic compounds halogen containing compounds
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/12—Inorganic compounds
- C10L1/1275—Inorganic compounds sulfur, tellurium, selenium containing compounds
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/16—Hydrocarbons
- C10L1/1616—Hydrocarbons fractions, e.g. lubricants, solvents, naphta, bitumen, tars, terpentine
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/16—Hydrocarbons
- C10L1/1625—Hydrocarbons macromolecular compounds
- C10L1/1633—Hydrocarbons macromolecular compounds homo- or copolymers obtained by reactions only involving carbon-to carbon unsaturated bonds
- C10L1/1641—Hydrocarbons macromolecular compounds homo- or copolymers obtained by reactions only involving carbon-to carbon unsaturated bonds from compounds containing aliphatic monomers
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/192—Macromolecular compounds
- C10L1/198—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid
- C10L1/1985—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid polyethers, e.g. di- polygylcols and derivatives; ethers - esters
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
- C10L1/224—Amides; Imides carboxylic acid amides, imides
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/234—Macromolecular compounds
- C10L1/238—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
- C10L1/2383—Polyamines or polyimines, or derivatives thereof (poly)amines and imines; derivatives thereof (substituted by a macromolecular group containing 30C)
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/234—Macromolecular compounds
- C10L1/238—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
- C10L1/2383—Polyamines or polyimines, or derivatives thereof (poly)amines and imines; derivatives thereof (substituted by a macromolecular group containing 30C)
- C10L1/2387—Polyoxyalkyleneamines (poly)oxyalkylene amines and derivatives thereof (substituted by a macromolecular group containing 30C)
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2270/00—Specifically adapted fuels
- C10L2270/02—Specifically adapted fuels for internal combustion engines
- C10L2270/023—Specifically adapted fuels for internal combustion engines for gasoline engines
Abstract
The invention provides a kind of energy-efficient gasoline products, a kind of energy-efficient gasoline products, including base oil and additive, the base oil is the mixture of catalytic gasoline, Reformed Gasoline, hydrogen gasoline, pentane oil and gasoline alkylate, the additive includes high-activity polyisobutene amine, high activity polyether amine, carries agent, antirust agent, rubbing agent and breaking additive, the high-activity polyisobutene amine and the mass parts ratio for carrying agent are 1: 1.5 3, and the mass parts ratio of the high-activity polyisobutene amine and the rubbing agent is 1: 0.04 0.07.A kind of energy-efficient gasoline products described in the invention, the clean-up performance of engine can be effectively improved, significantly remove engine nozzle and nozzle interior, intake valve etc. deposit, and the accumulation again of carbon distribution can be prevented, hold the cleaning of fuel oil gas handling system, the output of the surge power of engine is persistently kept, the maintenance of engine is reduced, extends the service life of vehicle.
Description
Technical field
The invention belongs to gasoline additive technical field, more particularly, to a kind of energy-efficient gasoline products.
Background technology
Mainly there are octane number, sulphur for the index that motor vehicle emission performance and fuel economy have a great influence in motor petrol
Content, olefin(e) centent, arene content, benzene content, density and distillation characteristic (T10, T50, T90 and EP).As various countries are for row
The increasingly strict of control and fuel economy requirement is put,《Specification》General trend for clean gasoline requirement is progressively to lower
Evaporating temperature, sulfur content, arene content, olefin(e) centent and benzene content are reduced, narrow density range, improve minimum octane rating etc.
Level.
The operating temperature of automobile fuel engine is higher, and the component in fuel oil forms carbon distribution after burning and can be deposited on
In engine, it during carbon distribution total amount increase, may increase the compression ratio of engine, and not easy heat radiation, it can also increase when serious
Mechanical disturbance between the top land and cylinder cap of engine chamber, causes engine consumption to increase.At present, it is existing
After gasoline is reconciled by additive, can decarbonizing, but efficiency is unsatisfactory.
The content of the invention
In view of this, the invention is directed to a kind of energy-efficient gasoline products, to improve the cleaning of engine
Performance, engine nozzle and nozzle interior, intake valve etc. deposit are significantly removed, and the accumulation again of carbon distribution can be prevented, held
The cleaning of fuel oil gas handling system, the output of the surge power of engine is persistently kept, the maintenance of engine is reduced, extends vehicle
Service life.
To reach above-mentioned purpose, what the technical scheme of the invention was realized in：
A kind of energy-efficient gasoline products, including base oil and additive, the base oil are catalytic gasoline, reformed
Gasoline, hydrogen gasoline, the mixture of pentane oil and gasoline alkylate, the additive include high-activity polyisobutene amine, high activity
Polyetheramine, carrying agent, antirust agent, rubbing agent and breaking additive, the mass percent of above each component are：
The high-activity polyisobutene amine and the mass parts ratio for carrying agent are 1: 1.5-3, and the high activity is gathered different
The mass parts ratio of butenylamine and the rubbing agent is 1: 0.04-0.07.
Preferably, the base oil is the mixing of catalytic gasoline, Reformed Gasoline, hydrogen gasoline, pentane oil and gasoline alkylate
Thing, has good vapo(u)rability, anti-knock properties, stability and corrosivity, inside containing a large amount of branched alkane, alkene and
Aromatic hydrocarbons, octane number is higher, function admirable.
Preferably, the high activity polyether amine is at least one of nonyl phenol polyethers amine or quaternized polyetheramine, nonyl
The semipolar amido of base phenol polyetheramine can be adsorbed onto the metal surface of engine, the structure of its structure and carbon distribution relatively,
Therefore the carbon distribution for the metal surface that engine can be will be attached to strips down, and is dispersed into small particle, so as in a combustion chamber
Burn-up, and quaternized polyetheramine is used to reducing or preventing the spraying system in DI diesel engine as additive
In deposit purposes, being used for especially in common-rail injection system, which reduces the fuel of DI diesel engine, disappears
Consumption, makes the power loss in DI diesel engine as small as possible, the two reconciles as additive according to a certain percentage
It can further improve gasoline cleaning performance and pre- anti-carbon deposition formed.
Preferably, it is described to carry agent as the one or more in polyethers, mineral oil, polyalphaolefin, the carrying agent mixing
Thing can extend gasoline combustion stroke, be introduced into combustion chamber and fully burn, and lift engine power.
Preferably, the rubbing agent is vegetable oil acid and butylamine reactant, can effectively lower rubbing for interior engine surface
Wipe, because vegetable oil acid is natural oil production, comprising various aliphatic acid, the vegetable oil acid amine salt employed in rubbing agent is
The aliphatic acid amine salt of 16,18,20 and 22 carbon atoms is mainly contained, solves and is rubbed in gasoline composite additive in the prior art
The problem of liniment concertedness is poor, and oil-saving discharging-reducing function is low.
Preferably, the antirust agent is succinimide or succinamide compound, and the antirust agent is selected from commercially available
One kind in T703, T706, T747, this benzene 80, this benzene 85, its polar group has very strong absorption affinity to metal surface, in gold
Metal surface forms close unimolecule or polymolecular protective layer, prevents corrosive medium from being contacted with metal, plays anti-rust action.
Preferably, the demulsifier is bromic acid salt, Chlorates, persulfuric acid salt and their mixture.It is described
The one kind of breaking additive in SP169, BAKER T9310, BAKER T9372, can not only reduce oil water interfacial tension with
And boundary strength, and with good hydrophilic, oleophylic ability, product is applied to oil-in-water type crude oil emulsion and oil
Water-in type crude oil emulsion, have dosage it is few, divide water fast, demulsification temperature it is low, it is applied widely the advantages that.
Preferably, described high-activity polyisobutene amine structure formula is：
Wherein, R1、R2And R3One group be respectively selected from following group：H、CH3、C2H5、C3H7And C4H9, n=5-16, m=2-
4。
Preferably, the high-activity polyisobutene amine molecule amount is 900-1300.
Preferably, the high-activity polyisobutene amine is included in two amido PIBAs or five amido PIBAs
At least one, there is peace and quiet peptizaiton, can prevent because multicomponent addition caused by engine aspirating system and burning
Room carbon deposit, it can effectively lift the clean performance of gasoline itself.
Preferably, the mass percent of each component is：Catalytic gasoline 20%-30%, Reformed Gasoline 10%-15%, hydrogen vapour
Oily 35%-40%, pentane oil 10%-15%, gasoline alkylate 12%-17%, two amido PIBA 1.5%-2%, nonyl
Base phenol polyetheramine 3.2%-4.3%, polyethers 3.6%-3.8%, succinimide 0.15%-0.25%, vegetable oil acid amine salt
0.07%-0.09%, bromate 0.025%-0.035%.
Preferably, the mass percent of each component is：Catalytic gasoline 20%-30%, Reformed Gasoline 10%-15%, hydrogen vapour
Oily 35%-40%, pentane oil 10%-15%, gasoline alkylate 12%-17%, five amido PIBA 1.7%-1.9%,
Quaternized polyetheramine 3.4%-4.2%, polyalphaolefin 3.7%-3.75%, succinamide compound 0.2%-0.23%, plant
Oleic acid amine salt 0.075%-0.085%, chlorate 0.027%-0.03%.
Preferably, the mass percent of each component is：Catalytic gasoline 20%, Reformed Gasoline 12%, hydrogen gasoline 35%, penta
Alkane oil 10%, gasoline alkylate 15%, two amido PIBAs 12%, five amido PIBAs 13%, nonyl phenol polyethers
Amine 18%, quaternized polyetheramine 22.7%, polyethers 14%, mineral oil 17%, succinimide 2.2%, aliphatic acid amine salt
0.8%th, persulfate 0.1%, chlorate 0.2%.
Preferably, the mass percent of each component is：Catalytic gasoline 20%, Reformed Gasoline 12%, hydrogen gasoline 35%, penta
Alkane oil 10%, gasoline alkylate 15%, two amido PIBAs 0.9%, five amido PIBAs 1.6%, nonyl phenol gather
Ether amines 1.5%, quaternized polyetheramine 2.57%, polyethers 1.4%, mineral oil 1.4%, polyalphaolefin 0.3%, succinimide
0.17%th, succinamide compound 0.05%, aliphatic acid amine salt 0.08%, chlorate 0.01%, bromate 0.01%, over cure
Hydrochlorate 0.01%.
A kind of preparation method of described energy-efficient gasoline products is uniformly to mix each component.
Relative to prior art, a kind of energy-efficient gasoline products described in the invention have the advantage that：
(1) a kind of energy-efficient gasoline products described in the invention significantly improve the clean-up performance of engine, clearly
Except engine nozzle and nozzle interior, intake valve etc. deposit, and the accumulation again of carbon distribution can be prevented.
(2) excellent performance such as a kind of energy-efficient gasoline products cleaning, antirust and demulsification described in the invention,
The output of the surge power of engine is persistently kept, reduces the maintenance of engine, effectively extends the service life of vehicle.
Brief description of the drawings
The accompanying drawing for forming the part of the invention is used for providing further understanding the invention, the present invention
The schematic description and description of creation is used to explain the invention, does not form the improper restriction to the invention.
In the accompanying drawings：
Fig. 1 is that 1#-5# products and base oil subtract burnt rate experimental result；
Fig. 2 is that 1# products and offshore company's product subtract burnt rate comparative test result；
Fig. 3 is 1# and 5# products and base oil corrosion comparative test result；
Fig. 4 is 1# and 5# product emulsification test results；
Fig. 5 is 98 gasoline gum deposit rear nozzle state diagrams；
Fig. 6 is 1# product gum deposit rear nozzle state diagrams；
Fig. 7 is power performance test result figure.
Embodiment
In addition to being defined, technical term used has and the invention art technology people in following examples
The identical meanings that member is commonly understood by.Test reagent used in following examples, it is routine biochemistry examination unless otherwise specified
Agent；The experimental method, it is conventional method unless otherwise specified.
The invention is described in detail with reference to embodiment.
A kind of preparation method of energy-efficient gasoline products：
Take each component to be reconciled in room temperature to 60 DEG C according to selected weight part ratio, first by catalytic gasoline, reform vapour
Oil, hydrogen gasoline, pentane oil, gasoline alkylate are placed on steam spacer heated at constant temperature in reactor, sequentially add high activity afterwards and gather
Isobutyl enamine and high activity polyether amine, after being sufficiently stirred 10-15 minutes, product viscosity no longer changes, and sequentially adds
Agent, antirust agent and rubbing agent are carried, obtains emulsifying shape product after stirring 15-20 minutes are well mixed, is eventually adding demulsification addition
Agent, stir to product elimination emulsification and standing and may occur in which complete lamination, obtain final product.
Embodiment 1
Each component content is：Catalytic gasoline 20%, Reformed Gasoline 12%, hydrogen gasoline 35%, pentane oil 10%, alkylation
Gasoline 15%, two amido PIBAs 0.9%, five amido PIBAs 1.6%, nonyl phenol polyethers amine 1.5%, quaternary ammonium
Change polyetheramine 2.57%, polyethers 1.4%, mineral oil 1.4%, polyalphaolefin 0.3%, succinimide 0.17%, succinamide
Compound 0.05%, aliphatic acid amine salt 0.08%, chlorate 0.01%, bromate 0.01%, persulfate 0.01%, wherein
R in high-activity polyisobutene amine structure formula1For CH3、 R2For C2H5And R3For C3H7, n=10, m=3, prepared according to preparation method
Products therefrom is labeled as 1# afterwards.
Embodiment 2
Each component content is：Two amido PIBAs 1.1%, five amido PIBAs 1.4%, nonyl phenol polyethers
Amine 1.5%, quaternized polyetheramine 2.57%, polyethers 1.4%, mineral oil 1.4%, polyalphaolefin 0.3%, succinimide
0.17%th, succinamide compound 0.05%, aliphatic acid amine salt 0.08%, chlorate 0.01%, bromate 0.01%, over cure
Hydrochlorate 0.01%, other conditions are same as Example 1, and products therefrom is labeled as 2#.
Embodiment 3
Each component content is：Two amido PIBAs 1.1%, five amido PIBAs 1.4%, nonyl phenol polyethers
Amine 1.3%, quaternized polyetheramine 2.77%, polyethers 1.4%, mineral oil 1.4%, polyalphaolefin 0.3%, succinimide
0.17%th, succinamide compound 0.05%, aliphatic acid amine salt 0.08%, chlorate 0.01%, bromate 0.01%, over cure
Hydrochlorate 0.01%, other conditions are same as Example 1, and products therefrom is labeled as 3#.
Embodiment 4
Each component content is：Two amido PIBAs 1.1%, five amido PIBAs 1.4%, nonyl phenol polyethers
Amine 1.3%, quaternized polyetheramine 2.77%, polyethers 1.1%, mineral oil 1.2%, polyalphaolefin 0.7%, succinimide
0.17%th, succinamide compound 0.05%, aliphatic acid amine salt 0.08%, chlorate 0.01%, bromate 0.01%, over cure
Hydrochlorate 0.01%, other conditions are same as Example 1, and products therefrom is labeled as 4#.
Embodiment 5
Each component content is：Two amido PIBAs 1.1%, five amido PIBAs 1.4%, nonyl phenol polyethers
Amine 1.3%, quaternized polyetheramine 2.77%, polyethers 1.1%, mineral oil 1.2%, polyalphaolefin 0.7%, succinimide
0.15%th, succinamide compound 0.07%, aliphatic acid amine salt 0.08%, chlorate 0.01%, bromate 0.01%, over cure
Hydrochlorate 0.01%, other conditions are same as Example 1, and products therefrom is labeled as 5#.
It is as follows to add the gasoline quality index of gasoline products, technical requirements and test method in the application：
The limit value of These parameters requires that purpose is wider for the octane Distribution value of gasoline, can have within a short period of time excellent
Good volatility, sufficient power is provided to engine.
Testing result：
1st, burnt rate testing result is subtracted
1#-5# products and base gasoline subtract burnt rate experimental result and see accompanying drawing 1, above test result indicates that, 1# and 5# products
Show more excellent cleaning performance.Accompanying drawing 2, data above are shown in the burnt rate contrast that subtracts of 1# products and offshore company's product
Show, either 1# products or foreign capitals brand gasoline, all show excellent clean-keeping function, can suppress to start very well
New deposit is generated inside machine.
2nd, rust-preventing characteristic testing result
According to the gasoline cleaning agent test for rust preventing ability methods of standard GB/T/T 19230.1,1# and 5# products are carried out
Corrosion test under harsh conditions, is as a result shown in accompanying drawing 3, and result of the test shows, 1# and 5# products show excellent anti-
Rust performance, it is ensured that engine interior persistently keeps optimal rust-preventing characteristic.
3rd, breaking
According to standard GB/T/T19230.2 gasoline cleaning agent demulsification performance test methods, 1# and 5# products are carried out
Emulsification test under harsh conditions, as a result see accompanying drawing 4, result of the test shows, the specialist additive interfaces of 1# and 5# products without
Fragment, ribbon or film, it is completely absent any emulsion or sediment.Excellent demulsification performance is shown, can be with
Ensure not to be emulsified in accumulating link, ensure that oil quality is qualified.
4. detergency bench test
According to standard GB/T/T19230.6 gasoline cleaning agents to gasoline intake valve and combustion chamber deposit generation tendency
The engine rig test method (M111 methods) of influence, engine bench test, country of commission Shi Ke institutes stone are carried out to 1# and 5# products
Oil product Quality Supervision and Inspection Center, in the enterprising traveling air valves of electric spraying type engine M111 and the detergency of combustion chamber deposit
Test, using CEC F-20-A-98 methods.Test result is as follows：
CEC F-20-A-98 benz M111 engine rig tests (1#)
CEC F-20-A-98 benz M111 engine rig tests (5#)
Tested in the enterprising traveling air valve of model engine M111 types and combustion chamber deposit, using CEC F-20-A-98 sides
Method, test result show that the inlet valve deposits slip of 1# products reaches the inlet valve deposits reduction of 99.6%, 5# products
Rate reaches 99.1%, and it is good to repeat test effect.
5th, application performance test
1) direct fuel-injection engine atomizer contrast test
According to direct fuel-injection engine bench test (engine parameter see the table below) observation atomizer deposit generation situation.Often
Cleaned before secondary engine test by regulated procedure about part and carry out the inspection of system.This item purpose deposit is observed
Method uses high definition endoscopic visualisation.
| Manufacturer | It is popular |
| Engine model | ARR-1.41 77KW 4V FSI |
| Discharge capacity | 1390cm3 |
| Compression ratio | 11.5∶1 |
| Air-fuel mixture form | Direct-injection, maximum pressure 110bar |
| Peak torque | 130Nm@4250rpm |
| Peak power | 77kw@6200rpm |
On direct fuel-injection engine, commercially available 98 gasoline of application and 1# products carry out same operating mode, with time mileage accumulation respectively.
By contrast before and after 98 gasoline and 1# product mileage accumulations and during engine power performance change, investigate plus agent fuel oil be to straight
Fuel-injection engine dynamic property, economy and the influence of pollutant emission.The commercially available quick gum deposit analog portion run time of 98 gasoline is
60h, condition of nozzles using 1# products as shown in figure 5, carry out the durable 60h of engine, durable end rear nozzle state such as Fig. 6 institutes
Show.Experimental result shows that 1# products have fine elimination effect to direct fuel-injection engine atomizer deposit.
2) power performance is tested
According to the experimental result of national car Quality Supervision and Inspection Center, shown in dynamic property test effect figure below.
Experimental result, which is shown, uses regular gasoline, continues 100 hours, power does not recover, using 1# products, by 100
The cleaning of hour, the power of engine is restored, and according to the engine after deterioration, power lifting reaches 5.5%.
3) economy
According to the experimental result of national car Quality Supervision and Inspection Center, gasoline turns for two in engine height after adding agent
In the state of speed, rate of economizing gasoline test effect is as shown in table 1 below, table 2.
The 2800rpm fuel economy of table 1. contrasts
The 5600rpm fuel economy of table 2. contrasts
Rate of economizing gasoline result shows that 1# products contrast regular fuel, average fuel consumption reduces 2%.
4) environment protection emission effect
According to the experimental result of national car Quality Supervision and Inspection Center, 1# products are in engine two rotating speeds of height
Under state, Conventional pollution emission testing effect is as shown in table 3, table 4, table 5 and table 6.
The 2800rpmHC emission results of table 3. contrast
The 2800rpmCO emission results of table 4. contrast
The 5600rpmHC emission results of table 5. contrast
The 5600rpmCO emission results of table 6. contrast
Experimental result is shown under any operating mode of different rotating speeds, hydrocarbon (HC) and carbon monoxide (CO) discharge
All reduce, highest reduces 6%.
In summary, a kind of energy-efficient gasoline products of the application not only have good removing fuel engines
The excellent performance such as the ability of carbon distribution, cleaning, antirust and demulsification, oil consumption is reduced, energy-saving and emission-reduction, reduces the maintenance of engine, effectively
Extend the service life of vehicle.
The preferred embodiment of the invention is the foregoing is only, is not intended to limit the invention creation, it is all at this
Within the spirit and principle of innovation and creation, any modification, equivalent substitution and improvements made etc., the invention should be included in
Protection domain within.
Claims (9)
1. a kind of energy-efficient gasoline products, including base oil and additive, it is characterised in that：The base oil is catalysis vapour
Oil, Reformed Gasoline, hydrogen gasoline, the mixture of pentane oil and gasoline alkylate, the additive include high-activity polyisobutene amine,
High activity polyether amine, carrying agent, antirust agent, rubbing agent and breaking additive, the mass percent of above each component are：
The high-activity polyisobutene amine and the mass parts ratio for carrying agent are 1: 1.5-3, the high-activity polyisobutene
The mass parts ratio of amine and the rubbing agent is 1: 0.04-0.07.
A kind of 2. energy-efficient gasoline products according to claim 1, it is characterised in that：The high-activity polyisobutene
Amine includes at least one of two amido PIBAs or five amido PIBAs, and the high activity polyether amine is nonyl phenol
At least one of polyetheramine or quaternized polyetheramine, it is described to carry agent as one kind in polyethers, mineral oil, polyalphaolefin, institute
Rubbing agent is stated as vegetable oil acid and butylamine reactant, the vegetable oil acid amine salt in the rubbing agent is to mainly contain 16,18,20 and
The aliphatic acid amine salt of 22 carbon atoms, the antirust agent are succinimide or succinamide compound, and the demulsifier is bromine
Barbiturates, Chlorates, persulfuric acid salt and their mixture.
A kind of 3. energy-efficient gasoline products according to claim 1, it is characterised in that：The poly- isobutyl of described high activity
Enamine structural formula is：
Wherein, R1、R2And R3One group be respectively selected from following group：H、CH3、C2H5、C3H7And C4H9, n=5-16, m=2-4.
A kind of 4. energy-efficient gasoline products according to claim 3, it is characterised in that：The high-activity polyisobutene
Amine molecule amount is 900-1300.
A kind of 5. energy-efficient gasoline products according to claim 2, it is characterised in that：The mass percent of each component
For：Catalytic gasoline 20%-30%, Reformed Gasoline 10%-15%, hydrogen gasoline 35%-40%, pentane oil 10%-15%, alkylation
Gasoline 12%-17%, two amido PIBA 1.5%-2%, nonyl phenol polyethers amine 3.2%-4.3%, polyethers 3.6%-
3.8%th, succinimide 0.15%-0.25%, vegetable oil acid amine salt 0.07%-0.09%, bromate 0.025%-
0.035%.
A kind of 6. energy-efficient gasoline products according to claim 2, it is characterised in that：The mass percent of each component
For：Catalytic gasoline 20%-30%, Reformed Gasoline 10%-15%, hydrogen gasoline 35%-40%, pentane oil 10%-15%, alkylation
Gasoline 12%-17%, five amido PIBA 1.7%-1.9%, quaternized polyetheramine 3.4%-4.2%, polyalphaolefin
3.7%-3.75%, succinamide compound 0.2%-0.23%, vegetable oil acid amine salt 0.075%-0.085%, chlorate
0.027%-0.03%.
A kind of 7. energy-efficient gasoline products according to claim 2, it is characterised in that：The mass percent of each component
For：Catalytic gasoline 20%, Reformed Gasoline 12%, hydrogen gasoline 35%, pentane oil 10%, gasoline alkylate 15%, two amidos gather different
Butenylamine 12%, five amido PIBAs 13%, nonyl phenol polyethers amine 18%, quaternized polyetheramine 22.7%, polyethers 14%,
Mineral oil 17%, succinimide 2.2%, aliphatic acid amine salt 0.8%, persulfate 0.1%, chlorate 0.2%.
A kind of 8. energy-efficient gasoline products according to claim 2, it is characterised in that：The mass percent of each component
For：Catalytic gasoline 20%, Reformed Gasoline 12%, hydrogen gasoline 35%, pentane oil 10%, gasoline alkylate 15%, two amidos gather different
Butenylamine 0.9%, five amido PIBAs 1.6%, nonyl phenol polyethers amine 1.5%, quaternized polyetheramine 2.57%, polyethers
1.4%th, mineral oil 1.4%, polyalphaolefin 0.3%, succinimide 0.17%, succinamide compound 0.05%, fatty acid amine
Salt 0.08%, chlorate 0.01%, bromate 0.01%, persulfate 0.01%.
A kind of 9. preparation method of energy-efficient gasoline products any one of claim 1-8, it is characterised in that：Will
A kind of each component of described energy-efficient gasoline products is sufficiently mixed.
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| CN108300529A (en) * | 2018-02-26 | 2018-07-20 | 安迪飞科技（北京）有限公司 | A kind of automotive fuel oil system cleaning additive and preparation method thereof |
| CN108395914A (en) * | 2018-03-09 | 2018-08-14 | 山东京博石油化工有限公司 | A kind of 92# fuel-saving types gasoline and preparation method thereof |
| CN109233916A (en) * | 2018-09-27 | 2019-01-18 | 东营华联石油化工厂有限公司 | A kind of high pure blended gasoline |
| CN110423341A (en) * | 2019-08-09 | 2019-11-08 | 山东益丰生化环保股份有限公司 | A kind of polyether amine compound and preparation method thereof, gasoline cleaning agent |
| CN110437916A (en) * | 2019-07-24 | 2019-11-12 | 天津中石化悦泰科技有限公司 | A kind of gasoline promoting engine power |
| CN110862529A (en) * | 2019-11-01 | 2020-03-06 | 武汉帕浦安科技有限公司 | Polyether polyol for fuel additive and preparation method and application thereof |
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| CN108300529A (en) * | 2018-02-26 | 2018-07-20 | 安迪飞科技（北京）有限公司 | A kind of automotive fuel oil system cleaning additive and preparation method thereof |
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| CN109233916A (en) * | 2018-09-27 | 2019-01-18 | 东营华联石油化工厂有限公司 | A kind of high pure blended gasoline |
| CN110437916A (en) * | 2019-07-24 | 2019-11-12 | 天津中石化悦泰科技有限公司 | A kind of gasoline promoting engine power |
| CN110437916B (en) * | 2019-07-24 | 2021-07-30 | 天津中石化悦泰科技有限公司 | Gasoline for improving engine power |
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| CN110862529B (en) * | 2019-11-01 | 2022-09-06 | 武汉帕浦安科技有限公司 | Polyether polyol for fuel additive and preparation method and application thereof |
| CN111635793A (en) * | 2020-04-27 | 2020-09-08 | 江苏龙蟠科技股份有限公司 | Cleaning type gasoline detergent as well as preparation method and using method thereof |
| CN112159693A (en) * | 2020-09-28 | 2021-01-01 | 惠州市加泽科技有限公司 | Gasoline detergent composition |
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Application publication date: 20171110 |