CN107338010B - A kind of sealant and preparation method thereof for alkaline zinc-manganese dioxide cell sealing ring - Google Patents
A kind of sealant and preparation method thereof for alkaline zinc-manganese dioxide cell sealing ring Download PDFInfo
- Publication number
- CN107338010B CN107338010B CN201710620541.8A CN201710620541A CN107338010B CN 107338010 B CN107338010 B CN 107338010B CN 201710620541 A CN201710620541 A CN 201710620541A CN 107338010 B CN107338010 B CN 107338010B
- Authority
- CN
- China
- Prior art keywords
- weight
- parts
- sealant
- sealing ring
- manganese dioxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000565 sealant Substances 0.000 title claims abstract description 57
- 238000007789 sealing Methods 0.000 title claims abstract description 35
- SZKTYYIADWRVSA-UHFFFAOYSA-N zinc manganese(2+) oxygen(2-) Chemical compound [O--].[O--].[Mn++].[Zn++] SZKTYYIADWRVSA-UHFFFAOYSA-N 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title claims abstract description 24
- 229920002050 silicone resin Polymers 0.000 claims abstract description 29
- FRWYFWZENXDZMU-UHFFFAOYSA-N 2-iodoquinoline Chemical compound C1=CC=CC2=NC(I)=CC=C21 FRWYFWZENXDZMU-UHFFFAOYSA-N 0.000 claims abstract description 23
- LTPBRCUWZOMYOC-UHFFFAOYSA-N beryllium oxide Inorganic materials O=[Be] LTPBRCUWZOMYOC-UHFFFAOYSA-N 0.000 claims abstract description 23
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Chemical compound CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229920000459 Nitrile rubber Polymers 0.000 claims abstract description 22
- 150000001875 compounds Chemical class 0.000 claims abstract description 22
- 229920001971 elastomer Polymers 0.000 claims abstract description 22
- 239000005060 rubber Substances 0.000 claims abstract description 22
- 239000010433 feldspar Substances 0.000 claims abstract description 20
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 claims abstract description 17
- JQCXWCOOWVGKMT-UHFFFAOYSA-N phthalic acid diheptyl ester Natural products CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC JQCXWCOOWVGKMT-UHFFFAOYSA-N 0.000 claims abstract description 11
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 72
- 238000003756 stirring Methods 0.000 claims description 31
- 239000000203 mixture Substances 0.000 claims description 24
- 238000006243 chemical reaction Methods 0.000 claims description 19
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 16
- 239000005046 Chlorosilane Substances 0.000 claims description 16
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 16
- KOPOQZFJUQMUML-UHFFFAOYSA-N chlorosilane Chemical compound Cl[SiH3] KOPOQZFJUQMUML-UHFFFAOYSA-N 0.000 claims description 16
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 14
- 238000010438 heat treatment Methods 0.000 claims description 11
- 238000002156 mixing Methods 0.000 claims description 11
- 229920001296 polysiloxane Polymers 0.000 claims description 10
- 238000010792 warming Methods 0.000 claims description 10
- 238000004821 distillation Methods 0.000 claims description 9
- 239000005054 phenyltrichlorosilane Substances 0.000 claims description 8
- 229920000642 polymer Polymers 0.000 claims description 8
- 239000011780 sodium chloride Substances 0.000 claims description 8
- 239000006228 supernatant Substances 0.000 claims description 8
- ZOYFEXPFPVDYIS-UHFFFAOYSA-N trichloro(ethyl)silane Chemical compound CC[Si](Cl)(Cl)Cl ZOYFEXPFPVDYIS-UHFFFAOYSA-N 0.000 claims description 8
- ORVMIVQULIKXCP-UHFFFAOYSA-N trichloro(phenyl)silane Chemical compound Cl[Si](Cl)(Cl)C1=CC=CC=C1 ORVMIVQULIKXCP-UHFFFAOYSA-N 0.000 claims description 8
- CVEGDJIFCXGXJU-UHFFFAOYSA-N chloro(3-chloropropyl)silane Chemical compound ClCCC[SiH2]Cl CVEGDJIFCXGXJU-UHFFFAOYSA-N 0.000 claims description 7
- BYLOHCRAPOSXLY-UHFFFAOYSA-N dichloro(diethyl)silane Chemical compound CC[Si](Cl)(Cl)CC BYLOHCRAPOSXLY-UHFFFAOYSA-N 0.000 claims description 6
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid group Chemical group C(C=1C(C(=O)O)=CC=CC1)(=O)O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 4
- 239000003814 drug Substances 0.000 claims description 2
- 229940079593 drug Drugs 0.000 claims description 2
- 230000035484 reaction time Effects 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- 239000000243 solution Substances 0.000 description 16
- 239000012153 distilled water Substances 0.000 description 7
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 6
- 239000003921 oil Substances 0.000 description 6
- 229910000077 silane Inorganic materials 0.000 description 6
- 239000007788 liquid Substances 0.000 description 5
- 150000003022 phthalic acids Chemical class 0.000 description 5
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 4
- 229910002808 Si–O–Si Inorganic materials 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- -1 aliphatic cyclic amine Chemical class 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000003292 glue Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 230000017525 heat dissipation Effects 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- YAGBAUUBKBTRNY-UHFFFAOYSA-N CO[SiH](OC)OC.C(C=C)(=O)OCCC[SiH2]OCC Chemical compound CO[SiH](OC)OC.C(C=C)(=O)OCCC[SiH2]OCC YAGBAUUBKBTRNY-UHFFFAOYSA-N 0.000 description 1
- 229910018557 Si O Inorganic materials 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052790 beryllium Inorganic materials 0.000 description 1
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 125000005641 methacryl group Chemical group 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J115/00—Adhesives based on rubber derivatives
- C09J115/005—Hydrogenated nitrile rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
- C08G77/24—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen halogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/183—Sealing members
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/206—Applications use in electrical or conductive gadgets use in coating or encapsulating of electronic parts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Sealing Material Composition (AREA)
Abstract
The present invention relates to field of batteries, disclose a kind of sealant and preparation method thereof for alkaline zinc-manganese dioxide cell sealing ring.The sealant includes following component by weight: 40 ~ 50 parts by weight of hydrogenated nitrile-butadiene rubber rubber compound, 20 ~ 30 parts by weight of modified organic silicone resin, 10 ~ 15 parts by weight of feldspar, 2 ~ 6 parts by weight of beryllium oxide, 1 ~ 3 parts by weight of di-n-octyl phthalate, 0.2 ~ 0.6 parts by weight of methacryloxypropyl trimethoxy silane.Sealant intensity of the present invention is high, and thermal stability is good.
Description
Technical field
The present invention relates to field of batteries, more particularly, to a kind of sealant for alkaline zinc-manganese dioxide cell sealing ring and its
Preparation method.
Background technique
The leakproofness of battery is to evaluate important one of the index of battery performance, battery sealing-performance difference will appear battery sepage,
The case where leakage, not only shortens the service life of battery, also will cause environmental pollution, is unfavorable for the health of people.?
During preparing alkaline zinc-manganese dioxide cell, sealing process is to spray upper sealant in the outer surface of sealing ring, then by sealing ring
It is inserted into the outer cylinder of battery, the sealing of battery is realized after glue cooled and solidified to be sealed.Currently, the dry cell occurred in the market is close
Most of sealing does not have high temperature resistance, and battery is encountering high temperature in special circumstances, and sealant is easy melting and leakage occurs
The case where, cause the pollution of environment.
China Patent Publication No. CN103468192B discloses a kind of accumulator sealant and preparation method thereof, the sealant
Be made of resin portion and curing agent part, resin portion include 80~95 parts of bisphenol A type epoxy resin, reactive diluent 5~
15 parts, 0~3 part of defoaming agent, curing agent part include 40~60 parts of aliphatic polyamine, 10~30 parts of aliphatic cyclic amine, activity dilution
20~40 parts of agent.Although the sealant of preparation can achieve the effect that sealing, poor with non-refractory and stability
Disadvantage.
Summary of the invention
The present invention is to provide a kind of high temperature resistant, stabilization to overcome the problems, such as prior art cell sealing glue non-refractory
The good cell sealing glue of property.
The present invention also provides a kind of preparation methods of sealant for alkaline zinc-manganese dioxide cell sealing ring.
To achieve the goals above, the invention adopts the following technical scheme: a kind of be used for alkaline zinc-manganese dioxide cell sealing ring
Sealant, including following component: 40~50 parts by weight of hydrogenated nitrile-butadiene rubber rubber compound, 20~30 weight of modified organic silicone resin
Part, 10~15 parts by weight of feldspar, 2~6 parts by weight of beryllium oxide, 1~3 parts by weight of di-n-octyl phthalate, methacryl
0.2~0.6 parts by weight of oxygroup propyl trimethoxy silicane.
Organic siliconresin is as a kind of filler, and skeleton structure Si-O-Si, Si-O has biggish bond energy, in high temperature
Under conditions of do not allow easy fracture and decomposition, therefore there is excellent heat-resisting quantity and stability.Part is organic under the high temperature conditions
The organic group being connected on silicone resin Si-O-Si main chain and element silicon is destroyed, and is will form in new activity in this breaking part
The heart, can and the inorganic matters such as feldspar and beryllium oxide interact, this effect not only performance intrinsic without destruction sealant, also into
One step enhances the high heat resistance of organic siliconresin.In addition, part silicone resin will form after by thermal oxide it is highly cross-linked
Si-O-Si key can form a protective layer in hydrogenated nitrile-butadiene rubber rubber compound polymer surfaces, play protection to polymer and make
With.
Feldspar silicate fillers are not only heat-resist, also have certain intensity, can be improved sealant heat resistance and
Intensity.In addition, under the high temperature conditions, part silicone resin will form new activated centre, silicate surfaces have a small amount of
Hydroxyl can react under the catalytic action of oxide with activated centre, form a kind of new substance, formation it is new
Substance further enhances the heat resistance of sealant.
Beryllium oxide can be catalyzed silicate under the high temperature conditions and react with organic siliconresin as a kind of catalyst, be formed
Substance enhance the heat resistance of sealant.At high temperature, beryllium oxide can also interact with organosilicon, generate silicon oxygen
Alkane further improves the heat resistance of sealing ring.In addition, beryllium oxide can also improve the heat dissipation performance of material.
Preferably, the preparation method of the modified organic silicone resin includes:
(1) 14~20g trichloroethyl silane, 3~10g phenyl trichlorosilane and 40~50mL propyl alcohol are added to there-necked flask
In, it is placed in the water-bath of ice cube, magnetic stirrer 40~after sixty minutes, add the chloro- 3- chloropropyl first of 12~18g bis-
Base silane, 4~12g dichloro-diethyl silane, continue stirring 10~20 minutes, obtain chlorosilane mixture；
(2) at a certain temperature, be added into another there-necked flask 50~80mL toluene, 10~15mL acetone and 200~
Then the chlorosilane mixture that step (1) obtains is slowly added dropwise in 220mL distilled water, heating, stirring 2~3 hours, at normal temperature
After standing 1~2 hour, removal supernatant obtains organic-silicone prepolymer solution after being washed with NaCl to neutrality；
(3) organosilicon that 100~120mL toluene, 6~14g diatomite and step (2) obtain is sequentially added in there-necked flask
Prepolymer solution stirs 5~10 minutes, then carries out heating heating for the first time, after toluene distillation is gone out, carries out second liter
Temperature heating, finally distills out other solvents and obtains modified organic silicone resin reaction a period of time.
Organic siliconresin is modified using diatomite.Silica surface contains a large amount of hydroxyl, hydroxyl in diatomite
With the hydroxyl in organic siliconresin condensation reaction can occur for base, increase the degree of cross linking of organic siliconresin, further improve
The thermal stability of organic siliconresin.Silica has certain colloidal nature, will form siliceous colloid particle after meeting water, has
Certain adsorption capacity, the curing time that can not only shorten organic siliconresin can also reduce the solidification temperature of organic siliconresin.
Preferably, being added before drug in the step (2) into there-necked flask, controlled at 10~18 DEG C.
Preferably, heating temperature is 50~55 DEG C in the step (2).
Preferably, being warming up to 111~120 DEG C for the first time in the step (3), it is warming up to 170~190 DEG C for the second time.
Preferably, the reaction time is 2~3.5 hours in the step (3).
A kind of preparation method of the sealant of alkaline zinc-manganese dioxide cell sealing ring, comprising the following steps:
(1) successively by 20~30 part by weight modified organic siliconresins, 40~50 parts by weight of hydrogenated nitrile rubber rubber compounds,
0.2~0.6 parts by weight methacryloxypropyl trimethoxy silane, 10~15 parts by weight feldspars, the oxidation of 2~6 parts by weight
Beryllium, 1~3 parts by weight di-n-octyl phthalate are added in reaction kettle；
(2) control temperature of reaction kettle is 40~50 DEG C, is then stirred, and control mixing speed is 350~400 revs/min
Clock, stirring obtained sealant mixture after 4~7 hours.
Preferably, mixing speed is 350~400 revs/min in the step (2), mixing time is 4~6 hours.
Therefore, the invention has the following beneficial effects: (1) modified organic silicone resins to have preferable stability, improves
The heat resistance of sealant, curing time shorten, and solidification temperature reduces；(2) under high temperature, part silicone will form highly cross-linked
Si-O-Si group is covered on hydrogenated nitrile-butadiene rubber rubber compound surface, protects hydrogenated nitrile-butadiene rubber rubber compound；(3) under high temperature,
Part silicone can be decomposed to form new activated centre, can react with inorganic matter, the substance of generation further enhances sealant
Heat resistance；(4) at high temperature, beryllium oxide can not only be catalyzed silicate and react with organic silicon rubber, and beryllium oxide may be used also
To improve the heat dissipation performance of sealant.
Specific embodiment
Below by specific embodiment, technical scheme is described further.
In the present invention, if not refering in particular to, used raw material and equipment etc. are commercially available or commonly used in the art,
Method in embodiment is unless otherwise instructed the conventional method of this field.
Embodiment 1
The invention adopts the following technical scheme: a kind of sealant for alkaline zinc-manganese dioxide cell sealing ring, the sealant
Including 40 parts by weight of hydrogenated nitrile-butadiene rubber rubber compound, 20 parts by weight of modified organic silicone resin, 10 parts by weight of feldspar, 2 weight of beryllium oxide
Measure part, 1 parts by weight of di-n-octyl phthalate, 0.2 parts by weight of methacryloxypropyl trimethoxy silane.
Wherein, the preparation method of modified organic silicone resin, includes the following steps:
(1) 14g trichloroethyl silane, 3g phenyl trichlorosilane and 40mL propyl alcohol are added in there-necked flask, have been placed in ice
In the water-bath of block, magnetic stirrer after forty minutes, adds the chloro- 3- chloropropyl silane of 12g bis-, 4g Dichlorodiethyl
Silane continues stirring 10 minutes, obtains chlorosilane mixture；
(2) under the conditions of 10 DEG C, 50mL toluene, 10mL acetone and 200mL distilled water are added into another there-necked flask, then
The chlorosilane mixture that step (1) obtains is slowly added dropwise, is heated to 50 DEG C, stirs 2 hours, after standing 1 hour at normal temperature, goes
Organic-silicone prepolymer solution is obtained after being washed with NaCl to neutrality except supernatant；
(3) it is molten that the organosilicon performed polymer that 100mL toluene, 6g diatomite and step (2) obtain is sequentially added in there-necked flask
Liquid stirs 5 minutes, then increases oil bath temperature to 111 DEG C, after toluene distillation is gone out, is warming up to 170 DEG C, reacts 2 hours,
It finally distills out other solution and obtains modified organic silicone resin.
A kind of preparation method of the sealant of alkaline zinc-manganese dioxide cell sealing ring, comprising the following steps:
(1) successively by 20 part by weight modified organic siliconresins, 40 parts by weight of hydrogenated nitrile rubber rubber compounds, 0.2 parts by weight
Methacryloxypropyl trimethoxy silane, 10 parts by weight feldspars, 2 parts by weight beryllium oxide, 1 parts by weight phthalic acid two
N-octyl is added in reaction kettle；
(2) control temperature of reaction kettle is 40 DEG C, is then stirred, and control mixing speed is 350 revs/min, and stirring 4 is small
When after obtain sealant mixture.
Embodiment 2
The invention adopts the following technical scheme: a kind of sealant for alkaline zinc-manganese dioxide cell sealing ring, the sealant
Including 42 parts by weight of hydrogenated nitrile-butadiene rubber rubber compound, 22 parts by weight of modified organic silicone resin, 11 parts by weight of feldspar, 3 weight of beryllium oxide
Measure part, 1.2 parts by weight of di-n-octyl phthalate, 0.3 parts by weight of methacryloxypropyl trimethoxy silane.
Wherein, the preparation method of modified organic silicone resin, includes the following steps:
(1) 15g trichloroethyl silane, 4g phenyl trichlorosilane and 42mL propyl alcohol are added in there-necked flask, have been placed in ice
In the water-bath of block, after magnetic stirrer 42 minutes, the chloro- 3- chloropropyl silane of 13g bis-, 5g Dichlorodiethyl are added
Silane continues stirring 12 minutes, obtains chlorosilane mixture；
(2) under the conditions of 12 DEG C, 55mL toluene, 11mL acetone and 205mL distilled water are added into another there-necked flask, then
The chlorosilane mixture that step (1) obtains is slowly added dropwise, is heated to 51 DEG C, stirs 2.5 hours, stands 1.5 hours at normal temperature
Afterwards, removal supernatant obtains organic-silicone prepolymer solution after being washed with NaCl to neutrality；
(3) it is molten that the organosilicon performed polymer that 102mL toluene, 7g diatomite and step (2) obtain is sequentially added in there-necked flask
Liquid stirs 6 minutes, then increases oil bath temperature to 112 DEG C, after toluene distillation is gone out, is warming up to 175 DEG C, reaction 2.5 is small
When, it finally distills out other solution and obtains modified organic silicone resin.
A kind of preparation method of the sealant of alkaline zinc-manganese dioxide cell sealing ring, comprising the following steps:
(1) successively by 22 part by weight modified organic siliconresins, 42 parts by weight of hydrogenated nitrile rubber rubber compounds, 0.3 parts by weight
Methacryloxypropyl trimethoxy silane, 11 parts by weight feldspars, 3 parts by weight beryllium oxide, 1.2 parts by weight phthalic acids
Di-n-octyl is added in reaction kettle；
(2) control temperature of reaction kettle is 42 DEG C, is then stirred, and control mixing speed is 360 revs/min, stirring 4.5
Sealant mixture is obtained after hour.
Embodiment 3
The invention adopts the following technical scheme: a kind of sealant for alkaline zinc-manganese dioxide cell sealing ring, the sealant
Including 44 parts by weight of hydrogenated nitrile-butadiene rubber rubber compound, 24 parts by weight of modified organic silicone resin, 12 parts by weight of feldspar, 4 weight of beryllium oxide
Measure part, 1.4 parts by weight of di-n-octyl phthalate, 0.35 parts by weight of methacryloxypropyl trimethoxy silane.
Wherein, the preparation method of modified organic silicone resin, includes the following steps:
(1) 16g trichloroethyl silane, 5g phenyl trichlorosilane and 44mL propyl alcohol are added in there-necked flask, have been placed in ice
In the water-bath of block, after magnetic stirrer 45 minutes, the chloro- 3- chloropropyl silane of 14g bis-, 6g Dichlorodiethyl are added
Silane continues stirring 14 minutes, obtains chlorosilane mixture；
(2) under the conditions of 14 DEG C, 60mL toluene, 13mL acetone and 210mL distilled water are added into another there-necked flask, then
The chlorosilane mixture that step (1) obtains is slowly added dropwise, is heated to 53 DEG C, stirs 2.5 hours, stands 1.5 hours at normal temperature
Afterwards, removal supernatant obtains organic-silicone prepolymer solution after being washed with NaCl to neutrality；
(3) it is molten that the organosilicon performed polymer that 105mL toluene, 9g diatomite and step (2) obtain is sequentially added in there-necked flask
Liquid stirs 7 minutes, then increases oil bath temperature to 114 DEG C, after toluene distillation is gone out, is warming up to 180 DEG C, reacts 3 hours,
It finally distills out other solution and obtains modified organic silicone resin.
A kind of preparation method of the sealant of alkaline zinc-manganese dioxide cell sealing ring, comprising the following steps:
(1) successively by 24 part by weight modified organic siliconresins, 44 parts by weight of hydrogenated nitrile rubber rubber compounds, 0.35 parts by weight
Methacryloxypropyl trimethoxy silane, 12 parts by weight feldspars, 4 parts by weight beryllium oxide, 1.4 parts by weight phthalic acids
Di-n-octyl is added in reaction kettle；
(2) control temperature of reaction kettle is 44 DEG C, is then stirred, and control mixing speed is 370 revs/min, and stirring 5 is small
When after obtain sealant mixture.
Embodiment 4
The invention adopts the following technical scheme: a kind of sealant for alkaline zinc-manganese dioxide cell sealing ring, the sealant
Including 45 parts by weight of hydrogenated nitrile-butadiene rubber rubber compound, 25 parts by weight of modified organic silicone resin, 13 parts by weight of feldspar, 5 weight of beryllium oxide
Measure part, 1.6 parts by weight of di-n-octyl phthalate, 0.4 parts by weight of methacryloxypropyl trimethoxy silane.
Wherein, the preparation method of modified organic silicone resin, includes the following steps:
(1) 17g trichloroethyl silane, 6g phenyl trichlorosilane and 45mL propyl alcohol are added in there-necked flask, have been placed in ice
In the water-bath of block, after magnetic stirrer 46 minutes, the chloro- 3- chloropropyl silane of 15g bis-, 7g Dichlorodiethyl are added
Silane continues stirring 15 minutes, obtains chlorosilane mixture；
(2) under the conditions of 15 DEG C, 70mL toluene, 13mL acetone and 210mL distilled water are added into another there-necked flask, then
The chlorosilane mixture that step (1) obtains is slowly added dropwise, is heated to 53 DEG C, stirs 2.5 hours, stands 1.5 hours at normal temperature
Afterwards, removal supernatant obtains organic-silicone prepolymer solution after being washed with NaCl to neutrality；
(3) it is molten that the organosilicon performed polymer that 110mL toluene, 10g diatomite and step (2) obtain is sequentially added in there-necked flask
Liquid stirs 8 minutes, then increases oil bath temperature to 116 DEG C, after toluene distillation is gone out, is warming up to 180 DEG C, reacts 3 hours,
It finally distills out other solution and obtains modified organic silicone resin.
A kind of preparation method of the sealant of alkaline zinc-manganese dioxide cell sealing ring, comprising the following steps:
(1) successively by 25 part by weight modified organic siliconresins, 45 parts by weight of hydrogenated nitrile rubber rubber compounds, 0.4 parts by weight
Methacryloxypropyl trimethoxy silane, 13 parts by weight feldspars, 5 parts by weight beryllium oxide, 1.6 parts by weight phthalic acids
Di-n-octyl is added in reaction kettle；
(2) control temperature of reaction kettle is 45 DEG C, is then stirred, and control mixing speed is 380 revs/min, and stirring 6 is small
When after obtain sealant mixture.
Embodiment 5
The invention adopts the following technical scheme: a kind of sealant for alkaline zinc-manganese dioxide cell sealing ring, the sealant
Including 48 parts by weight of hydrogenated nitrile-butadiene rubber rubber compound, 27 parts by weight of modified organic silicone resin, 14 parts by weight of feldspar, beryllium oxide 5.5
Parts by weight, 2 parts by weight of di-n-octyl phthalate, 0.5 parts by weight of methacryloxypropyl trimethoxy silane.
Wherein, the preparation method of modified organic silicone resin, includes the following steps:
(1) 18g trichloroethyl silane, 9g phenyl trichlorosilane and 48mL propyl alcohol are added in there-necked flask, have been placed in ice
In the water-bath of block, after magnetic stirrer 48 minutes, the chloro- 3- chloropropyl silane of 17g bis-, 10g dichlorodiethyl are added
Base silane continues stirring 18 minutes, obtains chlorosilane mixture；
(2) under the conditions of 16 DEG C, 70mL toluene, 14mL acetone and 215mL distilled water are added into another there-necked flask, then
The chlorosilane mixture that step (1) obtains is slowly added dropwise, is heated to 54 DEG C, stirs 2.5 hours, stands 1.5 hours at normal temperature
Afterwards, removal supernatant obtains organic-silicone prepolymer solution after being washed with NaCl to neutrality；
(3) it is molten that the organosilicon performed polymer that 115mL toluene, 13g diatomite and step (2) obtain is sequentially added in there-necked flask
Liquid stirs 8 minutes, then increases oil bath temperature to 118 DEG C, after toluene distillation is gone out, is warming up to 185 DEG C, reacts 3 hours,
It finally distills out other solution and obtains modified organic silicone resin.
A kind of preparation method of the sealant of alkaline zinc-manganese dioxide cell sealing ring, comprising the following steps:
(1) successively by 27 part by weight modified organic siliconresins, 48 parts by weight of hydrogenated nitrile rubber rubber compounds, 0.5 parts by weight
Methacryloxypropyl trimethoxy silane, 14 parts by weight feldspars, 5 parts by weight beryllium oxide, 2 parts by weight phthalic acids two
N-octyl is added in reaction kettle；
(2) control temperature of reaction kettle is 48 DEG C, is then stirred, and control mixing speed is 390 revs/min, stirring 6.5
Sealant mixture is obtained after hour.
Embodiment 6
The invention adopts the following technical scheme: a kind of sealant for alkaline zinc-manganese dioxide cell sealing ring, the sealant
Including 50 parts by weight of hydrogenated nitrile-butadiene rubber rubber compound, 30 parts by weight of modified organic silicone resin, 15 parts by weight of feldspar, 6 weight of beryllium oxide
Measure part, 3 parts by weight of di-n-octyl phthalate, 0.6 parts by weight of methacryloxypropyl trimethoxy silane.
Wherein, the preparation method of modified organic silicone resin, includes the following steps:
(1) 20g trichloroethyl silane, 10g phenyl trichlorosilane and 50mL propyl alcohol are added in there-necked flask, have been placed in ice
In the water-bath of block, magnetic stirrer after sixty minutes, adds the chloro- 3- chloropropyl silane of 18g bis-, 12g dichlorodiethyl
Base silane continues stirring 20 minutes, obtains chlorosilane mixture；
(2) 80mL toluene, 15mL acetone and 220mL distilled water are added into another there-necked flask, step is then slowly added dropwise
(1) chlorosilane mixture obtained is heated to 55 DEG C, stirs 3 hours, and after standing 2 hours at normal temperature, removal supernatant is used
NaCl obtains organic-silicone prepolymer solution after washing to neutrality；
(3) under the conditions of 18 DEG C, sequentially add what 120mL toluene, 14g diatomite and step (2) obtained in there-necked flask
Organosilicon prepolymer solution stirs 10 minutes, then increases oil bath temperature to 120 DEG C, after toluene distillation is gone out, is warming up to
It 190 DEG C, reacts 3.5 hours, finally distills out other solution and obtain modified organic silicone resin.
A kind of preparation method of the sealant of alkaline zinc-manganese dioxide cell sealing ring, comprising the following steps:
(1) successively by 30 part by weight modified organic siliconresins, 50 parts by weight of hydrogenated nitrile rubber rubber compounds, 0.6 parts by weight
Methacryloxypropyl trimethoxy silane, 15 parts by weight feldspars, 6 parts by weight beryllium oxide, 3 parts by weight phthalic acids two
N-octyl is added in reaction kettle；
(2) control temperature of reaction kettle is 50 DEG C, is then stirred, and control mixing speed is 400 revs/min, and stirring 7 is small
When after obtain sealant mixture.
Comparative example 1
Sealant is by 45 parts by weight of hydrogenated nitrile-butadiene rubber rubber compound, 13 parts by weight of feldspar, 5 parts by weight of beryllium oxide, adjacent benzene two
1.6 parts by weight of formic acid di-n-octyl, 0.4 parts by weight of methacryloxypropyl trimethoxy silane are prepared.
Comparative example 2
Sealant is by 45 parts by weight of hydrogenated nitrile-butadiene rubber rubber compound, 1.6 parts by weight of di-n-octyl phthalate, methyl-prop
0.4 parts by weight of alkene acryloxypropylethoxysilane trimethoxy silane are prepared.
The performance parameter for testing sealant is as shown in the table:
The above described is only a preferred embodiment of the present invention, be not intended to limit the present invention in any form, though
So the present invention has been disclosed as a preferred embodiment, and however, it is not intended to limit the invention, any technology people for being familiar with this profession
Member, without departing from the scope of the present invention, when the technology contents using the disclosure above make a little change or modification
It is right according to the technical essence of the invention for the equivalent embodiment of equivalent variations, but without departing from the technical solutions of the present invention
Any simple modification, equivalent change and modification made by above embodiments, all of which are still within the scope of the technical scheme of the invention.
Claims (7)
1. a kind of sealant for alkaline zinc-manganese dioxide cell sealing ring, characterized in that including following component: hydrogenated nitrile-butadiene rubber
40 ~ 50 parts by weight of rubber compound, 20 ~ 30 parts by weight of modified organic silicone resin, 10 ~ 15 parts by weight of feldspar, 2 ~ 6 parts by weight of beryllium oxide,
1 ~ 3 parts by weight of di-n-octyl phthalate, 0.2 ~ 0.6 parts by weight of methacryloxypropyl trimethoxy silane；Wherein,
The preparation method of the modified organic silicone resin includes:
(1) 14 ~ 20g trichloroethyl silane, 3 ~ 10g phenyl trichlorosilane and 40 ~ 50 mL propyl alcohol are added in there-necked flask, are set
In the water-bath for having ice cube, magnetic stirrer 40 ~ after sixty minutes, add the chloro- 3- chloropropyl silane of 12 ~ 18g bis-,
4 ~ 12g dichloro-diethyl silane continues stirring 10 ~ 20 minutes, obtains chlorosilane mixture；
(2) at a certain temperature, 50 ~ 80mL toluene, 10 ~ 15mL acetone and 200 ~ 220 mL distillation are added into another there-necked flask
Then the chlorosilane mixture that step (1) obtains is slowly added dropwise in water, heating, stirs 2 ~ 3 hours, stands 1 ~ 2 hour at normal temperature
Afterwards, removal supernatant obtains organic-silicone prepolymer solution after being washed with NaCl to neutrality；
(3) the organosilicon performed polymer that 100 ~ 120mL toluene, 6 ~ 14g diatomite and step (2) obtain is sequentially added in there-necked flask
Solution stirs 5 ~ 10 minutes, then carries out heating heating for the first time, after toluene distillation is gone out, carries out second of heating heating,
It reaction a period of time, finally distills out other solvents and obtains modified organic silicone resin.
2. a kind of sealant for alkaline zinc-manganese dioxide cell sealing ring according to claim 1, characterized in that step
(2) it is added before drug in into there-necked flask, controlled at 10 ~ 18 DEG C.
3. a kind of sealant for alkaline zinc-manganese dioxide cell sealing ring according to claim 1, characterized in that step
(2) heating temperature is 50 ~ 55 DEG C in.
4. a kind of sealant for alkaline zinc-manganese dioxide cell sealing ring according to claim 1, characterized in that step
(3) 111 ~ 120 DEG C are warming up to for the first time in, is warming up to 170 ~ 190 DEG C for the second time.
5. a kind of sealant for alkaline zinc-manganese dioxide cell sealing ring according to claim 1, characterized in that step
(3) reaction time is 2 ~ 3.5 hours in.
6. a kind of system of the sealant for alkaline zinc-manganese dioxide cell sealing ring as described in claim 1 ~ 5 any claim
Preparation Method, characterized in that the following steps are included:
(a) successively by 20 ~ 30 parts by weight organic siliconresins, 40 ~ 50 parts by weight of hydrogenated nitrile rubber rubber compounds, 0.2 ~ 0.6 weight
Part methacryloxypropyl trimethoxy silane, 10 ~ 15 parts by weight feldspars, 2 ~ 6 parts by weight beryllium oxide, 1 ~ 3 parts by weight are adjacent
Phthalic acid di-n-octyl is added in reaction kettle；
(b) control temperature of reaction kettle is 40 ~ 50 DEG C, is then stirred, obtains sealant mixture.
7. a kind of preparation method of sealant for alkaline zinc-manganese dioxide cell sealing ring according to claim 6, special
Sign is that mixing speed is 350 ~ 400 revs/min in the step (b), and mixing time is 4 ~ 6 hours.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710620541.8A CN107338010B (en) | 2017-07-26 | 2017-07-26 | A kind of sealant and preparation method thereof for alkaline zinc-manganese dioxide cell sealing ring |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710620541.8A CN107338010B (en) | 2017-07-26 | 2017-07-26 | A kind of sealant and preparation method thereof for alkaline zinc-manganese dioxide cell sealing ring |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107338010A CN107338010A (en) | 2017-11-10 |
| CN107338010B true CN107338010B (en) | 2019-04-16 |
Family
ID=60216610
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710620541.8A Active CN107338010B (en) | 2017-07-26 | 2017-07-26 | A kind of sealant and preparation method thereof for alkaline zinc-manganese dioxide cell sealing ring |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107338010B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108587556A (en) * | 2017-12-29 | 2018-09-28 | 东莞市朗泰通实业有限公司 | A kind of Ni-MH battery leakproof seal glue and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104774587A (en) * | 2014-03-18 | 2015-07-15 | 岳胜武 | High-viscosity high-heat resistance modified organic silicone resin binder and preparation method thereof |
| CN105885753A (en) * | 2016-04-25 | 2016-08-24 | 何凤英 | Insulation glue for lithium metal batteries and preparation method thereof |
| CN105907345A (en) * | 2016-04-19 | 2016-08-31 | 安徽亿诺新能源有限责任公司 | Seal gum specially used for low-self-discharge battery and preparation process of same |
| CN106336820A (en) * | 2016-08-29 | 2017-01-18 | 无锡市宝来电池有限公司 | Heat-resistant leakproof sealant of alkaline storage battery |
-
2017
- 2017-07-26 CN CN201710620541.8A patent/CN107338010B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104774587A (en) * | 2014-03-18 | 2015-07-15 | 岳胜武 | High-viscosity high-heat resistance modified organic silicone resin binder and preparation method thereof |
| CN105907345A (en) * | 2016-04-19 | 2016-08-31 | 安徽亿诺新能源有限责任公司 | Seal gum specially used for low-self-discharge battery and preparation process of same |
| CN105885753A (en) * | 2016-04-25 | 2016-08-24 | 何凤英 | Insulation glue for lithium metal batteries and preparation method thereof |
| CN106336820A (en) * | 2016-08-29 | 2017-01-18 | 无锡市宝来电池有限公司 | Heat-resistant leakproof sealant of alkaline storage battery |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107338010A (en) | 2017-11-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102443387B (en) | A kind of hydrophobic proppant and preparation method thereof | |
| CN102030906B (en) | Preparation of organic-inorganic hybrid resin for high temperature resistant heavy anti-corrosion paint | |
| CN107286897A (en) | A kind of Single-component low-viscosity dealcoholized type organic silicon potting adhesive and preparation method thereof | |
| CN101638519A (en) | Resin composition for encapsulating optical semiconductor element | |
| EP2119737B1 (en) | Electronic packaging | |
| CN104073215A (en) | Preparation method for nano silicon dioxide modified organic silicon sealant for packaging of light emitting diode (LED) | |
| CN103756627B (en) | The fast cured silicone seal gum of the weather-proof dealcoholizing-type of shelf-stable | |
| CN101016446A (en) | Organosilicon electronic encapsulation material | |
| CN102532482B (en) | Epoxy resin organosilicon modifier and preparation method thereof | |
| CN107338010B (en) | A kind of sealant and preparation method thereof for alkaline zinc-manganese dioxide cell sealing ring | |
| CN106700997A (en) | High temperature resistant packaging adhesive for large-power LED illuminating lamp and preparation method of high temperature resistant packaging adhesive | |
| CN103865474A (en) | Preparation method of transparent pasty alcohol type organosilicone sealant | |
| CN102516501A (en) | Photo-curing material for manufacturing light-emitting diode (LED) lens | |
| CN105086920A (en) | Preparation method of radiation-resistant organic silicon packaging adhesives | |
| CN110938406A (en) | Bi-component organic silicon pouring sealant and preparation method thereof | |
| CN106753214A (en) | A kind of resistant to elevated temperatures silicone sealants | |
| CN102432786A (en) | Phenolic resin and preparation method thereof as well as proppant and preparation method thereof | |
| CN102040842A (en) | Autocatalytic crosslinking type organic silicon-epoxy composite material and preparation method thereof | |
| CN104292465A (en) | Epoxy-modified phenyl vinyl silicon resin and preparation method thereof | |
| CN103666367B (en) | LED (light-emitting diode) organosilicon pouring sealant and application thereof | |
| CN104559913A (en) | High-transparency dealcoholized organic silicon pouring sealant, preparation method and application thereof | |
| CN110305556A (en) | A kind of preparation method of quick-drying water-repellent paint | |
| CN103467744B (en) | A kind of preparation method of vinyl silicone oil | |
| CN106380858A (en) | Low-hardness high-percentage elongation two-component addition-type rubber and production method thereof | |
| CN107573507A (en) | A kind of preparation method of big particle diameter polysiloxanes microballoon |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: The invention relates to a sealant for sealing ring of alkaline zinc manganese dry battery and a preparation method thereof Effective date of registration: 20210914 Granted publication date: 20190416 Pledgee: Dongyang Branch of China Construction Bank Co.,Ltd. Pledgor: HENGDIAN GROUP DMEGC MAGNETICS Co.,Ltd. Registration number: Y2021330001553 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20230628 Granted publication date: 20190416 Pledgee: Dongyang Branch of China Construction Bank Co.,Ltd. Pledgor: HENGDIAN GROUP DMEGC MAGNETICS Co.,Ltd. Registration number: Y2021330001553 |