CN107326690A - A kind of preparation method of Amber Alerts garment material - Google Patents
A kind of preparation method of Amber Alerts garment material Download PDFInfo
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- CN107326690A CN107326690A CN201710596304.2A CN201710596304A CN107326690A CN 107326690 A CN107326690 A CN 107326690A CN 201710596304 A CN201710596304 A CN 201710596304A CN 107326690 A CN107326690 A CN 107326690A
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- China
- Prior art keywords
- fluorescein
- preparation
- garment material
- amber alerts
- powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/042—Acrylic polymers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0006—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using woven fabrics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0086—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
- D06N3/0088—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by directly applying the resin
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2201/00—Chemical constitution of the fibres, threads or yarns
- D06N2201/04—Vegetal fibres
- D06N2201/042—Cellulose fibres, e.g. cotton
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/08—Properties of the materials having optical properties
- D06N2209/0807—Coloured
- D06N2209/0823—Coloured within the layer by addition of a colorant, e.g. pigments, dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/12—Permeability or impermeability properties
- D06N2209/121—Permeability to gases, adsorption
- D06N2209/123—Breathable
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/16—Properties of the materials having other properties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/10—Clothing
Abstract
The invention discloses a kind of preparation method of Amber Alerts garment material, it is characterised in that fluorescein powder is prepared with the oxide containing rare earth element, with higher luminous intensity；In order to improve the stability of photoluminescence of fluorescein powder, using silane coupler film-coating technique, fluorescein powder is prepared, so as to improve the stability of fluorescein coating；Using printing technique, high visual water-fastness fluorescein coating is organized in pure cotton woven, the Amber Alerts garment material of preparation with good sucting wet air permeability, and can meet 30 washing requirements.
Description
Technical field：
The present invention relates to a kind of preparation method of fabric, more particularly to a kind of preparation side of Amber Alerts garment material
Method.
Background technology：
At present, warning clothes are commonly used main based on the common fluorescent paint coatings polyester fabric of Chinese red, quality ginseng
Difference is uneven, the problems such as generally existing not enough base material fabric fluorescence, low luminance factor and visual poor reflective materials,
Even if the visual performance of novel clothes reaches requirement, but because study and work property relation, children and environmental sanitation personnel often change
Wash more diligent, and the shortcomings of the reflectance of traditional fluorescent paint generally existing is poor, not washable, sucting wet air permeability is poor, cause it to warn
Show effect reduction, even without alarming effect, so as to be easily caused the generation of traffic accident, after tested：In Normal Wash 15~20
After secondary, the warning function at its night will be reduced substantially；After washing 30 times, warning function will be almost lost.In addition, using common painting
The warning clothes that layer and polyester fabric are made, often because its hygroscopicity is poor, airtight, Boardy Feeling, and add user's
Physiology and psychological burden, wearing comfortable are poor.
The content of the invention：
It is an object of the invention to provide a kind of good warning effect, while having good comfort (water-fastness, hygroscopicity concurrently
Good, good permeability) Amber Alerts garment material preparation method.
The technical scheme that the present invention takes to achieve the above object is as follows：
A kind of preparation method of Amber Alerts garment material, it is characterised in that comprise the following steps：
(1), the preparation of fluorescein powder：
Gadolinium oxide, dysprosia nitric acid are dissolved respectively, gadolinium nitrate solution, dysprosium nitrate solution is obtained；Measure gadolinium nitrate solution,
Dysprosium nitrate solution ＆ stir is uniform；Add urea and stir 20min, continue to react 12h at 180 DEG C, be subsequently cooled to room temperature,
Water washing is distilled after filtering；Obtained product is dried into 3h in 70 DEG C of baking ovens, is subsequently placed in 900 DEG C of Muffle furnaces in lower calcining
2h, naturally cools to room temperature and obtains fluorescein powder sample；
Silane coupling reagent KH-570 and fluorescein powder sample are weighed, in pH value in 3.5~4.0 water/ethanol solution
It is fully hydrolyzed, is slowly added in round-bottomed flask, reaction 12h, suction filtration, washing is stood after 30 DEG C of stirring 30min；Then, utilize
Horizontal nanometer sand mill is ground, and filtering obtains fluorescein powder；
(2), the preparation of fluorescein coating：
Formula：Following compositions by mass percentage：
Preparation method：Acrylic resin is diluted with ethanol, fluorescein powder is added under slow stirring, at 40~50 DEG C
5~10min is incubated, room temperature is cooled to, after the pyrrolidones of addition N- methyl -2, trihydroxy aminomethane, ethylene glycol are sufficiently mixed
Fluorescein coating；
(3) Amber Alerts garment material, is prepared：
Mass fraction 50% is pressed by fluorescein coating, adhesive, with water：20%：30% mixing, adds thickener stirring equal
It is even, it is uniformly coated on using scraper on pure cotton woven, then 80 DEG C of drying 5min, then 110~150 DEG C bake 3min, that is, make
Obtain Amber Alerts garment material.
Further it is provided in：
In step (1), the volume ratio of the gadolinium nitrate solution, dysprosium nitrate solution and urea is 1:1:2.
In step (1), silane coupler and fluorescein powder, ethanol, the weight/mass percentage composition of water be 20~50%,
20%th, 15%, 15~45%.
In step (2), the proportioning of fluorescein coating is：Acrylic resin 50%, fluorescein powder 40%, the pyrrole of N- methyl -2
Pyrrolidone 5%, trihydroxy aminomethane 1%, ethylene glycol 4%.
In step (3), baking temperature is 130 DEG C.
Beneficial effects of the present invention are as follows：
Present invention improves over the formula of fluorescein coating and preparation technology, and fluorescein coating answering on bafta
With, prepared Amber Alerts garment material, with excellent water-wash resistance, fastness to soaping reaches 4~5 grades；And
With good moisture permeability.In addition, its color-values and luminance factor β can reach《Occupation high visibility warning clothing》
The requirement of yellow standard, and 30 washing requirements can be met.
Below in conjunction with embodiment, the invention will be further described.
Embodiment：
Basic embodiment：
A kind of preparation method of Amber Alerts garment material of the present invention, comprises the following steps：
(1), the preparation of fluorescein powder：
Gadolinium oxide, dysprosia nitric acid are dissolved respectively, gadolinium nitrate solution, dysprosium nitrate solution is obtained；Measure gadolinium nitrate solution,
Dysprosium nitrate solution ＆ stir is uniform；Add urea and stir 20min, continue to react 12h at 180 DEG C, be subsequently cooled to room temperature,
Water washing is distilled after filtering；Obtained product is dried into 3h in 70 DEG C of baking ovens, is subsequently placed in 900 DEG C of Muffle furnaces and calcines 2h,
Naturally cool to room temperature and obtain fluorescein powder sample；
A certain amount of Silane coupling reagent KH-570 and fluorescein powder are weighed, it is molten for 3.5~4.0 water/ethanol in pH value
It is fully hydrolyzed, is slowly added in round-bottomed flask in liquid, reaction 12h, suction filtration, washing is stood after 30 DEG C of stirring 30min；Then,
It is ground using high efficient horizontal nanometer sand mill, fluorescein powder is produced through filtering.
(2), the preparation of fluorescein coating：
Formula：Following compositions by mass percentage：
Preparation method：The acrylic resin of mass fraction 40~60% is diluted with ethanol, matter is added under slow stirring
The fluorescein powder of fraction 30~50% is measured, 5~10min is incubated at 40~50 DEG C, room temperature is cooled to, mass fraction 5%N- is added
The pyrrolidones of methyl -2, the trihydroxy aminomethane of mass fraction 1%, the ethylene glycol of mass fraction 4% be sufficiently mixed after fluorescence
Yellow coating.
(3), application of the fluorescein coating on bafta：
Mass fraction 50% is pressed by fluorescein coating, adhesive, with water：20%：30% mixing, adds appropriate thickener and stirs
Mix uniform, be uniformly coated on using scraper on pure cotton woven, then 80 DEG C of drying 5min, then 110~150 DEG C bake 3min.
Yellow fluorescence bafta has excellent water-wash resistance after arrangement, and fastness to soaping reaches 4~5 grades；And have well
Moisture permeability.In addition, its color-values and luminance factor β can reach《Occupation high visibility warning clothing》Yellow standard will
Ask, and 30 washing requirements can be met.
Alternative embodiment 1：
The same basic embodiment of preparation method, difference is：The proportioning and preparation technology of set-up procedure (1) fluorescein powder,
And influence of the silane coupler with the quality proportioning of fluorescein powder to relative intensity of fluorescence is detected, as shown in table 1.
Influence of the quality proportioning of table 1, silane coupler and fluorescein powder to relative intensity of fluorescence
。
Alternative embodiment 2：
The same basic embodiment of preparation method, difference is：The preparation technology of set-up procedure (2) fluorescein coating, and detect
Acrylic resin and influence of the fluorescein powder to fluorescein coating property, as shown in table 2.
The influence of table 2, acrylic resin and fluorescein powder to fluorescent paint performance
。
Alternative embodiment 3：
The same basic embodiment of preparation method, difference is：Application of the fluorescein coating on bafta in set-up procedure (3)
Technique, and influence of the baking temperature to yellow fluorescence pure cotton fabric performance is detected, as shown in table 3.
The influence of table 3, baking temperature to yellow fluorescence pure cotton fabric performance
。
Summarize：
Present invention improves over the formula of fluorescein coating and preparation technology, and fluorescein coating answering on bafta
It is (water-fastness, hygroscopicity, ventilative in alarming effect, comfortableness compared with existing product with, prepared Amber Alerts garment material
Property) in terms of be obviously improved, be shown in Table shown in 4, table 5.
(1), the preparation of high visual, water-fastness fluorescein coating：Fluorescence is prepared with the inorganic oxide containing rare earth element
Bloom end, with higher luminous intensity；In order to improve the stability of photoluminescence of fluorescein powder, using silane coupler coating skill
Art, prepares fluorescein powder, so as to improve the stability of fluorescein coating.
(2), high visual application of the water-fastness fluorescein coating on bafta：, will be high visual water-fast using printing technique
Wash fluorescein coating and be organized in pure cotton woven.Yellow fluorescence bafta has good sucting wet air permeability, meets simultaneously《Occupation
Use high visibility warning clothing》The requirement of yellow standard, and 30 washing requirements can be met.
The performance detection of Amber Alerts garment material prepared by table 4, the present invention：
The performance detection of table 5, existing commercially available yellow fluorescence dacron：
。
Claims (5)
1. a kind of preparation method of Amber Alerts garment material, it is characterised in that comprise the following steps：
（1）, fluorescein powder preparation：
Gadolinium oxide, dysprosia nitric acid are dissolved respectively, gadolinium nitrate solution, dysprosium nitrate solution is obtained；Measure gadolinium nitrate solution, nitric acid
Dysprosium solution ＆ stir is uniform；Add urea and stir 20 min, continue to react 12 h at 180 DEG C, be subsequently cooled to room temperature, mistake
Water washing is distilled after filter；Obtained product is dried into 3h in 70 DEG C of baking ovens, is subsequently placed in 900 DEG C of Muffle furnaces in lower calcining
2h, naturally cools to room temperature and obtains fluorescein powder sample；
Silane coupling reagent KH-570 and fluorescein powder sample are weighed, in pH value is 3.5~4.0 water/ethanol solution fully
Hydrolysis, is slowly added in round-bottomed flask, and reaction 12h, suction filtration, washing are stood after 30 DEG C of stirring 30min；Then, using horizontal
Nanometer sand mill is ground, and filtering obtains fluorescein powder；
（2）, fluorescein coating preparation：
Formula：Following compositions by mass percentage：
Acrylic resin 40~60%
Fluorescein powder 30~50%
The pyrrolidones 5% of N- methyl -2
Trihydroxy aminomethane 1%
Ethylene glycol 4%；
Preparation method：Acrylic resin is diluted with ethanol, fluorescein powder is added under slow stirring, in 40~50 DEG C of insulations
5~10min, is cooled to room temperature, add after the pyrrolidones of N- methyl -2, trihydroxy aminomethane, ethylene glycol are sufficiently mixed
Fluorescein coating；
（3）, prepare Amber Alerts garment material：
Mass fraction 50% is pressed by fluorescein coating, adhesive, with water：20%：30% mixing, adds thickener and stirs, use
Scraper is uniformly coated on pure cotton woven, then 80 DEG C of drying 5min, then 110~150 DEG C bake 3min, that is, yellow police is made
The property shown garment material.
2. a kind of preparation method of Amber Alerts garment material according to claim 1, it is characterised in that：Step（1）
In, the volume ratio of the gadolinium nitrate solution, dysprosium nitrate solution and urea is 1:1:2.
3. a kind of preparation method of Amber Alerts garment material according to claim 1, it is characterised in that：Step（1）
In, the weight/mass percentage composition of silane coupler and fluorescein powder, ethanol, water is 20~50%, 20%, 15%, 15~45%.
4. a kind of preparation method of Amber Alerts garment material according to claim 1, it is characterised in that：Step（2）
In, the proportioning of fluorescein coating is：Acrylic resin 50%, fluorescein powder 40%, the pyrrolidones 5% of N- methyl -2, trihydroxy ammonia
Methylmethane 1%, ethylene glycol 4%.
5. a kind of preparation method of Amber Alerts garment material according to claim 1, it is characterised in that：Step（3）
In, baking temperature is 130 DEG C.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710596304.2A CN107326690B (en) | 2017-07-20 | 2017-07-20 | A kind of preparation method of Amber Alerts garment material |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710596304.2A CN107326690B (en) | 2017-07-20 | 2017-07-20 | A kind of preparation method of Amber Alerts garment material |
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| Publication Number | Publication Date |
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| CN107326690A true CN107326690A (en) | 2017-11-07 |
| CN107326690B CN107326690B (en) | 2019-06-25 |
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| CN201710596304.2A Active CN107326690B (en) | 2017-07-20 | 2017-07-20 | A kind of preparation method of Amber Alerts garment material |
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| CN106012069A (en) * | 2016-06-28 | 2016-10-12 | 江南大学 | Preparation method of yellow luminescent fiber |
| CN106436369A (en) * | 2016-09-02 | 2017-02-22 | 北京优威科技有限公司 | Multi-color-point and fluorescent color fiber making method |
| KR20170051919A (en) * | 2015-11-03 | 2017-05-12 | 주식회사 녹스 | Cotton and digital textile printing method for printing a fluorescent paint |
-
2017
- 2017-07-20 CN CN201710596304.2A patent/CN107326690B/en active Active
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| CN1484691A (en) * | 2001-01-10 | 2004-03-24 | �����ﰲ�ز���(Bvi)����˾ | Optical brighteners compositions their production and their use |
| CN102182076A (en) * | 2011-04-06 | 2011-09-14 | 东华大学 | Preparation of temperature and pH value double-stimulation responsive intelligent clothing fabric |
| CN102993867A (en) * | 2012-11-26 | 2013-03-27 | 安徽西格尔涂料科技有限公司 | Preparation method for waterborne environment-friendly color-changing coating of vacuum cups |
| KR20170051919A (en) * | 2015-11-03 | 2017-05-12 | 주식회사 녹스 | Cotton and digital textile printing method for printing a fluorescent paint |
| CN105238400A (en) * | 2015-11-20 | 2016-01-13 | 济南大学 | Novel mono-dispersed spherical rare earth oxide fluorescent powder ad preparation method thereof |
| CN106012069A (en) * | 2016-06-28 | 2016-10-12 | 江南大学 | Preparation method of yellow luminescent fiber |
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