CN107326416A - A kind of generating means of negative electrodes for lithium batteries collector - Google Patents

A kind of generating means of negative electrodes for lithium batteries collector Download PDF

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Publication number
CN107326416A
CN107326416A CN201710462230.3A CN201710462230A CN107326416A CN 107326416 A CN107326416 A CN 107326416A CN 201710462230 A CN201710462230 A CN 201710462230A CN 107326416 A CN107326416 A CN 107326416A
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CN
China
Prior art keywords
titanium roller
titanium
copper foil
roller
flap
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Application number
CN201710462230.3A
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Chinese (zh)
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CN107326416B (en
Inventor
许开华
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GEM Co Ltd China
Jingmen GEM New Material Co Ltd
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GEM Co Ltd China
Jingmen GEM New Material Co Ltd
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Priority to CN201710462230.3A priority Critical patent/CN107326416B/en
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D7/00Electroplating characterised by the article coated
    • C25D7/06Wires; Strips; Foils
    • C25D7/0614Strips or foils
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/058Construction or manufacture
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/64Carriers or collectors
    • H01M4/66Selection of materials
    • H01M4/661Metal or alloys, e.g. alloy coatings
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Cell Electrode Carriers And Collectors (AREA)

Abstract

The present invention is applied to lithium battery production technical field, a kind of generating means of negative electrodes for lithium batteries collector are provided, in the present apparatus, corrosion resistant rubber ring is closely cased with the middle of titanium roller, titanium roller two ends are also cased between serum cap, two suspension rods of door-shaped hanging bracket being fixed with a slide bar, and the present apparatus also includes two cleaning parts, the circular arc cleaning brush of part is swept, is close to the titanium roller surface between rubber ring and serum cap.In the present invention, titanium roller is divided into two sections by rubber ring, and every section and electrolyte contacts can carry out the copper foil generation of two groups of width simultaneously, be produced for the copper foil of different size, the titanium roller without changing different length reduces cost;In addition, setting rubber disc at titanium roller two ends, copper foil edge can be avoided to generate burr;In addition, being also provided with cleaning part, realize and the surface of two sections of titanium rollers is uninterruptedly cleaned with water, keep titanium roller surface clean and tidy, it is to avoid impurity occurs in copper foil surface.

Description

A kind of generating means of negative electrodes for lithium batteries collector
Technical field
The invention belongs to the generation dress of lithium battery production technical field, more particularly to a kind of negative electrodes for lithium batteries collector Put.
Background technology
The four big major parts into lithium ion battery are positive electrode, negative material, barrier film and electrolyte.But, remove Main four are most of outer, the important component for being also lithium battery for the collector of depositing positive and negative pole material.For lithium For ion battery, usually used plus plate current-collecting body is aluminium foil, and negative current collector is copper foil, in order to ensure collector in battery Internal stability, the two purity is required more than 98%.With continuing to develop for lithium power technology, either for digital product Lithium battery or electric automobile battery, the energy density that we are intended to battery tries one's best height, and the weight of battery is more and more lighter, And main in collector this block is exactly to reduce the thickness and weight of collector, intuitively the volume and again of battery is reduced Amount.
With the electric fast development of lithium in recent years, lithium battery collector develops also quickly.Positive pole aluminium foil is by several years ago 16um is reduced to 14um, then to 12um, now many cell production companies volume production uses 10um aluminium foil, or even use To 8um.And negative pole copper foil, due to copper foil pliability itself preferably, its thickness is reduced to 10um by 12um before, then to 8um, To having significant portion battery producer volume production 6um at present, and the 5um/4um that part producer is developing is possible to use 's.Because lithium battery is high for the copper aluminium foil purity requirement used, the density of material is basic in same level, with exploitation thickness Reduction, its surface density also accordingly reduces, and the weight of battery is naturally also less and less, meets our need for lithium battery Ask.
Aluminium foil is mainly prepared from calendering process, and copper foil preparation method, mainly there is rolled copper foil and electrolytic copper foil two Kind.The early stage of battery invention, due to the limitation of copper foil preparation technology equipment and technology etc., the higher calendering copper of main use cost Paper tinsel, rolled copper foil is the former paper tinsel (being also hair paper tinsel) by rolling is repeated several times and is made by copper coin, is carried out as requested at roughening Reason.
In current copper foil electrolysis process, first copper-bath is made through dissolving in copper first, then in special electrolysis installation It is middle by copper sulfate electrolyte in the presence of direct current, electro-deposition and former paper tinsel is made, then as requested to former paper tinsel carry out surface The a series of surface treatments such as processing, refractory layer processing and anti-oxidation processing.Electrolysis installation mainly includes titanium roller and positive plate, Titanium roller segment is immersed in copper sulfate electrolyte, one layer of copper foil is generated in titanium roller surface by electrolysis process, then by follow-up Handle and wind, when Faradaic current is constant, the velocity of rotation of titanium roller determines that copper foil generates thickness.Titanium roller is continuously rotated, and is received Winding apparatus is continuously wound, and can form continuously copper foil volume.But after titanium roller works long hours, understand titanium roller surface again Leave contaminant particles or air floating layer so that impurity is distributed with the copper foil surface of generation, influence copper foil electric conductivity.It is raw in addition Into copper foil edge also have flash phenomenon.In addition, the length of titanium roller is certain, when needing to produce the titanium roller of different in width, it is necessary to The titanium roller of corresponding size length is changed, it is very inconvenient.
The content of the invention
In view of the above problems, it is an object of the invention to provide a kind of generating means of negative electrodes for lithium batteries collector, purport The copper foil surface obtained in the existing copper foil generating means of solution has impurity, there is flash and can only produce the skill of fixed dimension copper foil Art problem.
The present invention is adopted the following technical scheme that:
The generating means of the negative electrodes for lithium batteries collector, including positive plate and titanium roller, positive plate and the titanium roller it Between have a copper sulfate electrolyte, the copper foil outlet port that the titanium roller is rotated is additionally provided with copper foil processing mechanism and reversing roller, institute Stating device also includes being provided with door-shaped hanging bracket between wind-up roll, the titanium roller rear and front end face, and the titanium roller centre is closely cased with Corrosion resistant rubber ring, the titanium roller two ends are also cased with serum cap, and the door-shaped hanging bracket includes two suspension rods and one is located at A slide bar is fixed between crossbeam between at the top of two suspension rods, two suspension rods, the crossbeam is formed with T-shaped along its length Block, two cleaning parts is provided with described T-shaped piece, the cleaning part includes the groove follower being arranged on T-shaped piece, described Fixing nut is screwed with groove follower, the groove follower bottom also rotating shaft is connected with flap, flap end rotating shaft connection There is circular arc cleaning brush, one of circular arc cleaning brush is close to the titanium roller surface between rubber ring and one piece of serum cap, another Circular arc cleaning brush, which is close to below the titanium roller surface between rubber ring and another piece of serum cap, the flap, is further fixed on arc Plate, the arc is provided with deep-slotted chip breaker, and the slide bar is located in the deep-slotted chip breaker, and it is small that the arc is also equipped with one piece of connection Plate, described connection platelet one end is enclosed on the slide bar, and the other end is fixed with screw, and the screw is passed through after deep-slotted chip breaker, passed through Locking nut is locked.
Further, the flap is trapezoidal, trapezoidal sliding sleeve is cased with the flap, the flap is up-narrow and down-wide, is divided into The upper plate and lower plate of rotating shaft connection, the width of the link position of upper and lower plates is in the trapezoidal sliding sleeve upper port internal diameter and lower port Between footpath.
Further, the circular arc cleaning brush includes housing and the sponge brush being arranged in the housing.
The beneficial effects of the invention are as follows:The present invention in the middle of titanium roller by setting a rubber ring for enclosing variable-width, by titanium Roller is divided into two sections, and every section and electrolyte contacts can carry out the copper foil generation of two groups of width simultaneously, be given birth to for the copper foil of different size Production, the titanium roller without changing different length reduces cost;In addition, setting rubber disc at titanium roller two ends, copper foil edge can be avoided Generate burr;In addition, being also provided with cleaning part, realize and the surface of two sections of titanium rollers is uninterruptedly cleaned with water, keep titanium roller table Face is clean and tidy, it is to avoid impurity occurs in copper foil surface.
Brief description of the drawings
Fig. 1 is the side view of the generating means of negative electrodes for lithium batteries collector;
Fig. 2 is the front view of the generating means of negative electrodes for lithium batteries collector;
Fig. 3 is the location diagram of arc and connection platelet.
Embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, it is right below in conjunction with drawings and Examples The present invention is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, and It is not used in the restriction present invention.
In order to illustrate technical solutions according to the invention, illustrated below by specific embodiment.
Fig. 1 shows the side view structure of the generating means of negative electrodes for lithium batteries collector provided in an embodiment of the present invention, Fig. 2 Show that the generating means of negative electrodes for lithium batteries collector face structure, for convenience of description illustrate only and present invention implementation The related part of example.
As shown in Figure 1, 2, the generating means for the negative electrodes for lithium batteries collector that the present embodiment is provided include positive plate 1 and titanium Roller 2, there is copper sulfate electrolyte between the positive plate 1 and titanium roller 2, the copper foil outlet port that the titanium roller 2 is rotated is additionally provided with Copper foil processing mechanism 3 and reversing roller 4, the copper foil processing mechanism generally comprises acid dip pickle, water washing device, squeeze roll, dry Dry pipe etc..The present embodiment generating means also include wind-up roll 5, after energization, and the copper ion in electrolyte can be heavy in titanium roller surface Product forms copper foil, then passes through a series of processing, finally by reversing roller, finally winds on wind-up roll.In the present embodiment, institute State and door-shaped hanging bracket 6 is installed between the rear and front end face of titanium roller 2, corrosion resistant rubber ring 7, institute are closely cased with the middle of the titanium roller 2 State the two ends of titanium roller 2 and be also cased with serum cap 8, the door-shaped hanging bracket 6 includes two suspension rods 61 and one is located at the top of two suspension rods Between crossbeam 62, be fixed with a slide bar 63 between two suspension rods 62, the crossbeam is formed with T-shaped piece 64 along its length, Two cleaning parts 9 are installed, the cleaning part 9 includes the groove follower 91 being arranged on T-shaped piece on described T-shaped piece 64, Fixing nut 92 is screwed with the groove follower 91, the bottom of groove follower 91 also rotating shaft is connected with flap 93, the flap 93 end rotating shafts are connected with circular arc cleaning brush 94, circular arc cleaning brush 94 a total of two, and one of circular arc cleaning brush is close to Titanium roller surface between rubber ring and one piece of serum cap, another circular arc cleaning brush be close to rubber ring and another piece of serum cap it Between titanium roller surface.With reference to shown in Fig. 3, the lower section of flap 93 is further fixed on arc 95, and the arc is provided with deep-slotted chip breaker 96, the slide bar 63 is located in the deep-slotted chip breaker 96, and the arc 95 is also equipped with one piece of connection platelet 97, the connection platelet 97 one end are enclosed on the slide bar 63, and the other end is fixed with screw 98, and the screw 98 is passed through after deep-slotted chip breaker 96, passes through locking screw Mother is locked.
In use, selecting the rubber ring of suitable width as needed first, rubber ring is closely surrounded on titanium roller, by titanium roller It is divided into two sections, the two ends titanium roller width exposed is exactly the width of copper foil to be generated, and two sections of copper foils can be generated simultaneously.Then it is accurate Have in standby electrolytic cell, electrolytic cell and the titanium roller is placed above positive plate, positive plate.In existing apparatus, titanium roller is typically using vertical Support is fixed, and is dismounted and is moved in inconvenience, the present embodiment, and titanium roller is fixed by door-shaped hanging bracket, but also can pass through mobile door Type suspension bracket is realized roll change, assembling and repaired.
Two cleaning parts are installed on the crossbeam of door-shaped hanging bracket, specifically, the groove follower of cleaning part is through T-shaped On block, groove follower is then moved so that the circular arc cleaning brush of cleaning part is placed exactly in the surface of one section of titanium roller, then tightens Fixing nut fixes cleaning part.Rotation flap is pressed then under so that circular arc cleaning brush is affixed on titanium roller with certain pressure Surface, then tightens the locking nut on connection platelet so that connection platelet and arc are fixed as one, due to connection platelet One end is through on slide bar, therefore is fixed by connecting platelet, what arc and slide bar were just fixed as one, will not occur relative shifting It is dynamic, keep circular arc cleaning brush to the pressure of titanium roller surface, the cleaning works of titanium roller surface impurity and floating layer can be efficiently accomplished.This In embodiment, the circular arc cleaning brush includes housing and the sponge brush being arranged in the housing.
In the present embodiment, due to being divided into two sections, and the position according to rubber ring and width by setting rubber ring by titanium roller Degree so that can be designed that while two sections of copper foils of generation, without roll change, reduce cost;And the width of two sections of copper foils can be voluntarily Set, effect is far superior to existing titanium roller.And rubber disc is set at titanium roller two ends, the spacing between rubber disc and rubber ring is just It is the width for generating copper foil, and copper foil edge can be avoided to generate burr.
In the present embodiment, circular arc cleaning brush is replaceable, can be by circular arc cleaning brush disassembly, cleaning after work certain time. When installing circular arc cleaning brush, selection circular arc cleaning brush length is consistent with the titanium roller width spilt, it is ensured that clean effect.And this In structure, cleaning part is designed to bascule, is also convenient for changing the titanium roller of different-diameter.
As a kind of preferred structure, change or clean for convenience circular arc cleaning brush, the flap 93 be it is trapezoidal, it is described Trapezoidal sliding sleeve 99 is cased with flap 93, the flap 93 is up-narrow and down-wide, is divided into the upper plate and lower plate of rotating shaft connection, the company of upper and lower plates The width of position is connect between trapezoidal the sliding sleeve upper port internal diameter and lower port internal diameter.Change or cleaning circular arc cleaning brush When, sliding sleeve is pushed up, then lower plate and circular arc cleaning brush can integrally be turned, be changed or clean and be very convenient. Change or clean after finishing, lower plate is turned round, push down on sliding sleeve, sliding sleeve just covers the rotating shaft connection of upper plate and lower plate Position so that lower plate will not be rotated further by, and overall structure is very simple.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention Any modifications, equivalent substitutions and improvements made within refreshing and principle etc., should be included in the scope of the protection.

Claims (3)

1. between a kind of generating means of negative electrodes for lithium batteries collector, including positive plate and titanium roller, positive plate and the titanium roller There is copper sulfate electrolyte, the copper foil outlet port that the titanium roller is rotated is additionally provided with copper foil processing mechanism and reversing roller, described Device also includes wind-up roll, it is characterised in that be provided between the titanium roller rear and front end face in the middle of door-shaped hanging bracket, the titanium roller Closely be cased with corrosion resistant rubber ring, the titanium roller two ends are also cased with serum cap, the door-shaped hanging bracket include two suspension rods and A slide bar is fixed between a piece crossbeam between two suspension rods tops, two suspension rods, the crossbeam is along its length It is formed with T-shaped piece, described T-shaped piece and two cleaning parts is installed, the cleaning part includes the groove being arranged on T-shaped piece Fixing nut is screwed with sliding block, the groove follower, the groove follower bottom also rotating shaft is connected with flap, the flap end Rotating shaft is connected with circular arc cleaning brush, and one of circular arc cleaning brush is close to the titanium roller table between rubber ring and one piece of serum cap Face, another circular arc cleaning brush is close to also solid below the titanium roller surface between rubber ring and another piece of serum cap, the flap Surely there is arc, the arc is provided with deep-slotted chip breaker, and the slide bar is located in the deep-slotted chip breaker, and the arc is also equipped with one piece Platelet is connected, described connection platelet one end is enclosed on the slide bar, the other end is fixed with screw, the screw passes through deep-slotted chip breaker Afterwards, it is locked by locking nut.
2. the generating means of negative electrodes for lithium batteries collector as claimed in claim 1, it is characterised in that the flap be it is trapezoidal, Trapezoidal sliding sleeve is cased with the flap, the flap is up-narrow and down-wide, is divided into the upper plate and lower plate of rotating shaft connection, the connection of upper and lower plates The width of position is between trapezoidal the sliding sleeve upper port internal diameter and lower port internal diameter.
3. the generating means of negative electrodes for lithium batteries collector as claimed in claim 2, it is characterised in that the circular arc cleaning brush bag Include housing and the sponge brush being arranged in the housing.
CN201710462230.3A 2017-06-19 2017-06-19 A kind of generating means of negative electrodes for lithium batteries collector Active CN107326416B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108539128A (en) * 2018-05-21 2018-09-14 马可文 A kind of lithium battery polar plate packet is every machine

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN204589334U (en) * 2015-02-09 2015-08-26 梅州市威利邦电子科技有限公司 A kind of electrolytic copper foil foil producing machine
CN204793033U (en) * 2015-07-13 2015-11-18 深圳市信宇人科技有限公司 Preparation equipment of micropore copper foil
CN205463621U (en) * 2016-03-18 2016-08-17 邢台海裕锂能电池设备有限公司 Clean mechanism of roll for battery pole piece rolling machine
CN205950856U (en) * 2016-08-03 2017-02-15 上饶市致远环保科技有限公司 Electrolytic copper foil removes copper powder device

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN204589334U (en) * 2015-02-09 2015-08-26 梅州市威利邦电子科技有限公司 A kind of electrolytic copper foil foil producing machine
CN204793033U (en) * 2015-07-13 2015-11-18 深圳市信宇人科技有限公司 Preparation equipment of micropore copper foil
CN205463621U (en) * 2016-03-18 2016-08-17 邢台海裕锂能电池设备有限公司 Clean mechanism of roll for battery pole piece rolling machine
CN205950856U (en) * 2016-08-03 2017-02-15 上饶市致远环保科技有限公司 Electrolytic copper foil removes copper powder device

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108539128A (en) * 2018-05-21 2018-09-14 马可文 A kind of lithium battery polar plate packet is every machine
CN108539128B (en) * 2018-05-21 2020-11-06 泗县田原秸秆回收再利用有限责任公司 Lithium battery pole plate packing machine

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