CN107325848B - Coke oven gas transmission system and coke oven gas purification system - Google Patents

Coke oven gas transmission system and coke oven gas purification system Download PDF

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Publication number
CN107325848B
CN107325848B CN201710555538.2A CN201710555538A CN107325848B CN 107325848 B CN107325848 B CN 107325848B CN 201710555538 A CN201710555538 A CN 201710555538A CN 107325848 B CN107325848 B CN 107325848B
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China
Prior art keywords
gas
coke oven
pipe
oven gas
outlet
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CN107325848A (en
Inventor
马科伟
张美玲
姜士敏
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Huatai Yongchuang Beijing Technology Co ltd
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Huatai Yongchuang Beijing Technology Co ltd
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • C10K1/04Purifying combustible gases containing carbon monoxide by cooling to condense non-gaseous materials
    • C10K1/06Purifying combustible gases containing carbon monoxide by cooling to condense non-gaseous materials combined with spraying with water
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • C10K1/04Purifying combustible gases containing carbon monoxide by cooling to condense non-gaseous materials
    • C10K1/046Reducing the tar content

Abstract

The embodiment of the invention provides a coke oven gas transmission system and a coke oven gas purification system, wherein the coke oven gas transmission system comprises: the gas pipe is used for communicating the coke oven and the purifying device, and an oil slag outlet is formed in the gas pipe; the spraying device is arranged in the air inlet end of the air conveying pipe and is used for spraying liquid to raw gas entering the air conveying pipe; the scraping plate device is arranged in the gas pipe and used for scraping tar residues deposited in the gas pipe; the baffle is arranged on the gas pipe and used for shielding an oil slag outlet of the gas pipe and reserving a gap for the outflow of tar slag. According to the scheme provided by the invention, dust in raw coke oven gas generated by the coke oven can be removed in the process of passing through the coke oven gas transmission system, so that the dust is prevented from entering the purification device along with the raw coke oven gas, and the pipeline in the purification device is prevented from being blocked, and the normal production of the subsequent purification device can be ensured.

Description

Coke oven gas transmission system and coke oven gas purification system
Technical Field
The invention relates to the technical field of coke oven gas purification, in particular to a coke oven gas transmission system and a coke oven gas purification system.
Background
Coking coal is subjected to humidity adjustment or preheating treatment and then is put into a coke oven for coking, raw coke oven gas is generated in the coking process, and the raw coke oven gas enters a purification device for purification through a gas collecting pipe.
Moisture in coking coal is reduced after the conditioning or preheating treatment, so that a large amount of dust is generated when the coking coal is filled into the coke oven, and the dust enters the purifying device along with raw gas to cause pipeline blockage in the purifying device, thereby influencing the normal operation of the purifying device.
Therefore, how to remove the dust and other impurities in the coking raw gas in advance before entering the purification device, so as to ensure the normal production of the subsequent purification device is a problem to be solved by the technicians in the field.
Disclosure of Invention
The embodiment of the invention aims to provide a coke oven gas transmission system and a coke oven gas purification system, so that dust in coking raw gas is removed in advance before entering a purification device, and normal production of a subsequent purification device is ensured. The specific technical scheme is as follows:
a coke oven gas delivery system comprising:
the gas pipe is used for communicating the coke oven and the purifying device, and an oil slag outlet is formed in the gas pipe;
the spraying device is arranged in the air inlet end of the air conveying pipe and is used for spraying liquid to raw gas entering the air conveying pipe;
the scraping plate device is arranged in the gas pipe and used for scraping tar residues deposited in the gas pipe;
the baffle is arranged on the gas pipe and used for shielding gas at the upper part of the gas pipe and reserving a gap for the outflow of tar residues.
Optionally, the gas delivery pipe includes: a vertically arranged ascending pipe, a horizontally arranged gas collecting pipe and a bridge pipe communicated with the ascending pipe and the gas collecting pipe;
the rising pipe is used for being communicated with the coke oven, and the gas collecting pipe is used for being communicated with the purifying device;
the spraying device is arranged on the bridge pipe, the scraping plate device is arranged in the gas collecting pipe, and the gas collecting pipe is provided with the oil slag outlet. Optionally, an air inlet and an air outlet are formed in the side wall of the gas collecting tube, the gas collecting tube is communicated with the bridge tube through the air inlet, and is communicated with the purifying device through the air outlet.
Optionally, one port or two ports of the gas collecting tube are the oil residue outlet, and each port is inclined upwards relative to the central line of the gas collecting tube.
Optionally, the device comprises a plurality of ascending pipes and bridge pipes corresponding to the ascending pipes, wherein the ascending pipes are communicated with the gas collecting pipes through the bridge pipes corresponding to the ascending pipes.
Optionally, a liquid outlet is formed in the side wall of the gas collecting tube;
the coke oven gas transmission system further comprises: the liquid draining device comprises a self-flow pipeline and a water sealing tank, wherein one end of the self-flow pipeline is communicated with the liquid draining port, and the other end of the self-flow pipeline is inserted into liquid in the water sealing tank.
Optionally, the gas-liquid separator further comprises a washing spray pipe, wherein the washing spray pipe is arranged in the gas outlet end of the gas pipe and is used for spraying liquid to raw gas flowing out of the gas pipe.
The embodiment of the invention also provides a coke oven gas purifying system, which comprises the coke oven gas conveying system, a coke oven and a purifying device;
the coke oven gas transmission system is used for communicating the coke oven and the purifying device.
The coke oven gas transmission system and the coke oven gas purification system provided by the embodiment of the invention can remove dust in raw coke oven gas generated in a coke oven in advance in the process of passing through the coke oven gas transmission system, so that the dust is prevented from entering the purification device along with the raw coke oven gas to cause the blockage of the pipeline in the purification device, and the normal production of the subsequent purification device can be ensured.
Drawings
In order to more clearly illustrate the embodiments of the invention or the technical solutions in the prior art, the drawings that are required in the embodiments or the description of the prior art will be briefly described, it being obvious that the drawings in the following description are only some embodiments of the invention, and that other drawings may be obtained according to these drawings without inventive effort for a person skilled in the art.
FIG. 1 is a block diagram of an embodiment of a coke oven gas purification system provided by the present invention;
FIG. 2 is a schematic diagram of a coke oven gas delivery system embodiment of the present invention;
fig. 3 is a right side view of fig. 1.
The correspondence between each component name and the corresponding reference numeral in fig. 1 to 3 is:
00 coke oven gas transmission systems, 01 coke ovens and 02 purifying devices;
1 a gas pipe, 11 a gas collecting pipe, 12 bridge pipes and 13 ascending pipes;
2, a spraying device;
3 a scraper device;
4, collecting a box;
5 baffle plates;
6, a liquid outlet;
7, a self-flowing pipeline;
8, water seal grooves;
9 washing spray pipe.
Detailed Description
The following description of the embodiments of the present invention will be made clearly and completely with reference to the accompanying drawings, in which it is apparent that the embodiments described are only some embodiments of the present invention, but not all embodiments. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
The upper and lower terms in this embodiment are defined with reference to the position of the coke oven gas transmission system shown in fig. 2.
Referring to fig. 1, a coke oven gas purifying system provided in this embodiment includes: coke oven gas transmission system 00, coke oven 01 and purifying device 02.
Wherein, the air inlet end of the coke oven gas transmission system 00 is communicated with the coke oven 01, and the air outlet end of the coke oven gas transmission system 00 is communicated with the purifying device 02.
Referring to fig. 2 and 3, the coke oven gas transmission system 00 includes: the device comprises a gas pipe 1, a spraying device 2, a scraping plate device 3, a collecting box 4 and a baffle plate 5.
The gas pipe 1 is used for communicating the coke oven 01 and the purifying device 02, and the gas pipe 1 is provided with an oil slag outlet; the spraying device 2 is arranged in the air inlet end of the air conveying pipe 1 and is used for spraying liquid to raw gas entering the air conveying pipe 1; the scraping plate device 3 is arranged in the gas pipe 1 and is used for scraping tar residues deposited in the gas pipe 1; and the baffle plate 5 is arranged on the gas pipe 1 and used for shielding gas at the upper part of the gas pipe 1 and reserving a gap for scraping tar residues.
Preferably, the coke oven gas transmission system 00 further comprises a collecting box 4, which is arranged at the oil residue outlet of the gas transmission pipe 1 and is used for collecting the tar residue.
In practical application, raw gas generated by the coke oven 01 passes through the coke oven gas transmission system 00 and then enters the purification device 02 for purification. In the process, the spraying device 2 arranged at the air inlet end of the air conveying pipe 1 sprays liquid on the raw coke oven gas entering the air conveying pipe 1, the sprayed liquid reduces the temperature of the raw coke oven gas, and then most of dust and other impurities entering the air conveying pipe 1 along with the raw coke oven gas are condensed and washed, for example, the raw coke oven gas is continuously sprayed by using circulating ammonia water, and the temperature of the raw coke oven gas is reduced from 650 degrees to 82 degrees after the circulating ammonia water is sprayed. Then, the washed dust and other impurities enter the gas pipe 1 and settle to form tar slag. The scraper means 3 then scrapes the deposited tar residue into a collecting tank 4.
In order to ensure that raw gas does not leak from the oil and slag outlet of the gas pipe 1, a baffle plate 5 is arranged at the oil and slag outlet of the gas pipe 1, and a gap for the outflow of tar slag is reserved between the baffle plate 5 and the gas pipe 1 so that the tar slag can flow out from the oil and slag outlet. For example, to ensure that the baffle 5 is effective against the raw gas, the baffle 5 may be inserted at least 40mm into the liquid in the gas delivery pipe 1, but the baffle 5 is not connected to the bottom of the gas delivery pipe 1.
By the scheme provided by the embodiment of the invention, dust in raw coke oven gas generated by the coke oven 01 can be removed in the process of passing through the coke oven gas transmission system 00, so that the dust is prevented from entering the purification device 02 along with the raw coke oven gas, the pipeline in the purification device 02 is prevented from being blocked, and the normal production of the subsequent purification device 02 can be ensured.
Specifically, please continue to combine fig. 2 and 3, in practical application, the gas pipe 1 includes: a vertically arranged riser 13, a horizontally arranged header 11, and a bridge pipe 12 communicating the riser 13 and the header 11.
Wherein, the ascending pipe 13 is used for communicating with the coke oven 01, and the gas collecting pipe 11 is used for communicating with the purifying device 02;
specifically, the spraying device 2 is mounted on the bridge pipe 12, and is used for spraying liquid to raw gas passing through the bridge pipe 12. The scraper device 3 is arranged in the gas collecting tube 11 and is used for scraping tar residues deposited in the gas collecting tube 11. The gas collecting tube 11 is provided with an oil residue outlet, and the collecting box 4 is arranged at the oil residue outlet of the gas collecting tube 11 and is used for collecting tar residue in the gas collecting tube 11. The baffle 5 is arranged on the gas collecting tube 11 and is used for shielding a notch reserved for the outflow of tar residues at the oil residue outlet of the gas collecting tube 11.
In practical application, raw gas generated by the coke oven 01 sequentially passes through the riser 13, the bridge pipe 12 and the gas collecting pipe 11, and enters the purifying device 02 for purification. After the raw gas passing through the bridge pipe 12 is sprayed with liquid by the spraying device 2, impurities such as dust entering the ascending pipe 13 along with the raw gas are condensed and washed. The washed dust and other impurities enter the gas collecting pipe 11 and settle to form tar slag. The scraper means 3 then scrapes the deposited tar residue into a collecting tank 4.
The baffle plate 5 arranged in the gas collecting tube 11 is inserted into the liquid in the gas collecting tube 11, and a gap for the outflow of tar residue is reserved so as to ensure that raw gas does not leak from the oil residue outlet of the gas collecting tube 11, and the tar residue can flow out from the oil residue outlet.
It will be appreciated that during installation of the spraying device 2, the spraying direction of the spraying device 2 may be the same as the flow direction of the raw gas, i.e. the spraying device 2 is installed along the raw gas flow. The spraying direction of the spraying device 2 can be opposite to or perpendicular to the flow direction of the raw gas, namely, the spraying device 2 is installed against the raw gas flow or is installed perpendicular to the raw gas flow.
Specifically, in order to improve the washing and condensing effects of the spraying device 2 on dust in raw gas, there may be a plurality of spraying devices 2 on the bridge pipe 12.
Preferably, an air inlet and an air outlet are formed in the side wall of the air collecting pipe 11, the air collecting pipe 11 is communicated with the bridge pipe 12 through the air inlet, and is communicated with the purifying device 02 through the air outlet.
Referring to fig. 2, in one implementation, two ports of the gas collecting tube 11 are oil residue outlets, and each port is inclined upward from the center line of the gas collecting tube 11.
In order to reduce the size of the cross section of the port of the gas collecting tube 11 and prevent raw gas in the gas collecting tube 11 from leaking from the port, the two ports of the gas collecting tube 11 can have a certain gradient and tilt, that is, the two ports of the gas collecting tube 11 are inclined upwards relative to the central line of the gas collecting tube 11. In practical applications, the inclination angle of the port of the gas collecting tube 11 may be determined according to practical experience or practical working conditions, for example, the upward inclination angle of the port of the gas collecting tube 11 may be 45 ° or 30 °.
Specifically, the coke oven gas delivery system 00 provided in this embodiment includes a plurality of ascending pipes 13 and bridge pipes 12 corresponding to the ascending pipes, where each ascending pipe 13 is communicated with the gas collecting pipe 11 through the corresponding bridge pipe 12.
In practical use, raw gas generated in the coke oven 01 flows into the gas collecting pipe 11 through the plurality of rising pipes 13 and the bridge pipe 12 corresponding to each rising pipe 13. The spraying devices 2 are arranged on the bridge pipes 12, and after the raw gas passing through the bridge pipes 12 is sprayed with liquid by the spraying devices 2 arranged on the bridge pipes 12, impurities such as dust entering the bridge pipes 12 along with the raw gas are condensed and washed. The dust and other impurities washed in each bridge pipe 12 enter the gas collecting pipe 11 and settle to form tar residues. The scraper means 3 then scrapes the deposited tar residue into a collecting tank 4.
It will be appreciated that in order to enhance the scrubbing and condensing effect of the spraying device 2 on dust in raw gas, 1 or more spraying devices 2 may be provided on each bridge pipe 12.
In practical application, the raw gas sprayed by the spraying device 2 can generate an oil-water mixture. For example, it is assumed that the spraying device 2 sprays with circulating ammonia water, and the sprayed raw gas produces a tar-ammonia water mixture.
In order to timely discharge the oil-water mixture in the gas collecting tube 11 so as to avoid excessive oil-water mixture and influence on normal operation of the gas collecting tube 11, a liquid outlet 6 is formed in the side wall of the gas collecting tube 11, and the oil-water mixture generated in the gas collecting tube 11 is timely discharged.
Through the liquid outlet 6, the oil-water mixture in the gas collecting tube 11 can be discharged in time, but the raw gas in the gas collecting tube 11 can also leak from the liquid outlet 6. In order to avoid the raw gas in the gas collecting tube 11 leaking from the liquid outlet 6, the coke oven gas transmission system 00 further comprises: a gravity flow pipeline 7 and a water seal tank 8.
One end of the self-flow pipeline 7 is communicated with the liquid outlet 6, and the other end of the self-flow pipeline is inserted into the liquid in the water seal groove 8. Through the liquid outlet 6 and the self-flowing pipeline 7, the oil-water mixture generated in the gas collecting pipe 11 is discharged to the bottom of the water seal tank 8, and a certain water seal height is arranged in the water seal tank 8, so that the gas in the gas collecting pipe 11 can not enter the water seal tank 8. It should be noted that, because the space of the water seal tank 8 is limited, the water seal tank 8 can also discharge the oil-water mixture at the bottom. For example, assuming that a tar-ammonia water mixture is generated in the gas header 11, the water seal tank 8 may continuously discharge the tar-ammonia water mixture to the tar-ammonia water separation device.
Alternatively, the coke oven 01 gas delivery system 00 can include a plurality of liquid discharge ports 6. The number of the self-flow pipelines 7 and the water seal tanks 8 is the same as that of the liquid discharge ports 6. And the liquid discharge ports 6, the self-flowing pipeline 7 and the water seal tank 8 are in one-to-one correspondence. Each drain port 6 is communicated with a water seal tank 8 corresponding to the self-flow pipeline 7 through the self-flow pipeline 7 corresponding to the drain port.
The oil-water mixture in the gas collecting pipe 11 is discharged to each water seal tank 8 through each liquid outlet 6 and the gravity flow pipe 7.
Specifically, in order to improve the service life and load capacity of the scraper device 3, the scraper device 3 in this embodiment is specifically a chain type scraper device 3, and the chain type scraper device 3 is mounted at the bottom in the gas collecting pipe 11.
The chain scraper device 3 comprises a scraper part and a chain wheel, wherein the scraper part is a scraper group which is arranged continuously. The chain scraper device 3 is connected with a motor through a speed reducer. The motor drives the chain wheel to rotate through driving the speed reducer, and when the chain wheel rotates, the scraping plate group is driven to continuously and circularly operate.
Of course, the squeegee device 3 may be another type of squeegee device, and is not limited thereto.
In order to further remove dust entering the gas pipe 1 along with raw gas, the coke oven 01 gas transmission system 00 further comprises a washing spray pipe 9, wherein the washing spray pipe 9 is arranged in the gas outlet end of the gas pipe 1 and is used for spraying liquid to the raw gas flowing out of the gas pipe 1.
It will be appreciated that during the installation of the wash lance 9, the direction of the spray of the wash lance 9 may be the same as the direction of flow of the raw gas, i.e. the wash lance 9 is installed in the flow of the raw gas. The spraying direction of the washing spray pipe 9 can be opposite to or perpendicular to the flow direction of the raw gas, namely, the washing spray pipe 9 is installed against the raw gas flow or is installed perpendicular to the raw gas flow.
It is noted that relational terms such as first and second, and the like are used solely to distinguish one entity or action from another entity or action without necessarily requiring or implying any actual such relationship or order between such entities or actions. Moreover, the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus. Without further limitation, an element defined by the phrase "comprising one … …" does not exclude the presence of other like elements in a process, method, article, or apparatus that comprises the element.
In this specification, each embodiment is described in a related manner, and identical and similar parts of each embodiment are all referred to each other, and each embodiment mainly describes differences from other embodiments. In particular, for system embodiments, since they are substantially similar to method embodiments, the description is relatively simple, as relevant to see a section of the description of method embodiments.
The foregoing description is only of the preferred embodiments of the present invention and is not intended to limit the scope of the present invention. Any modification, equivalent replacement, improvement, etc. made within the spirit and principle of the present invention are included in the protection scope of the present invention.

Claims (7)

1. A coke oven gas delivery system, comprising:
the gas pipe (1) is used for communicating the coke oven and the purifying device, and the gas pipe (1) is provided with an oil slag outlet;
the spraying device (2) is arranged in the air inlet end of the air conveying pipe (1) and is used for spraying liquid to raw gas entering the air conveying pipe (1);
the scraping plate device (3) is arranged in the gas pipe (1) and is used for scraping tar residues deposited in the gas pipe (1);
the baffle (5) is arranged on the gas pipe (1) and used for shielding gas at the upper part of the gas pipe (1) and reserving a gap for the outflow of tar residues;
the gas delivery pipe (1) includes: a vertically arranged riser (13), a horizontally arranged gas collector (11), and a bridge pipe (12) communicating the riser (13) and the gas collector (11);
the rising pipe (13) is used for being communicated with the coke oven, and the gas collecting pipe (11) is used for being communicated with the purifying device;
the spraying device (2) is installed in the bridge pipe (12), the scraper device (3) is installed in the gas collecting pipe (11), and the gas collecting pipe (11) is provided with the oil slag outlet.
2. Coke oven gas delivery system according to claim 1, characterized in that one or both ports of the gas header (11) are the oil residue outlet ports, which ports are inclined upwards with respect to the centre line of the gas header (11).
3. Coke oven gas delivery system according to claim 1, characterized in that the side wall of the gas collecting pipe (11) is provided with a liquid outlet (6);
the coke oven gas transmission system further comprises: the liquid draining device comprises a self-flowing pipeline (7) and a water sealing tank (8), wherein one end of the self-flowing pipeline (7) is communicated with the liquid draining port (6), and the other end of the self-flowing pipeline is inserted into liquid in the water sealing tank (8).
4. Coke oven gas delivery system according to claim 1, characterized in that the side wall of the gas collecting pipe (11) is provided with a gas inlet and a gas outlet, the gas collecting pipe (11) is communicated with the bridge pipe (12) through the gas inlet, and is communicated with the purification device through the gas outlet.
5. Coke oven gas delivery system according to claim 1, characterized in, that it comprises a plurality of said risers (13) and said bridge pipes (12) corresponding thereto, said risers (13) being in communication with said header (11) through said bridge pipes (12) corresponding thereto.
6. Coke oven gas transfer system according to any one of claims 1 to 5, further comprising a washing lance (9), said washing lance (9) being arranged in the gas outlet end of the gas transfer pipe (1) for spraying liquid onto the raw gas flowing out of the gas transfer pipe (1).
7. Coke oven gas purification system, characterized by comprising a coke oven gas transmission system (00) according to any one of claims 1 to 6, a coke oven (01) and a purification device (02);
the coke oven gas transmission system (00) is used for communicating the coke oven (01) and the purifying device (02).
CN201710555538.2A 2017-07-10 2017-07-10 Coke oven gas transmission system and coke oven gas purification system Active CN107325848B (en)

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Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108148636A (en) * 2018-02-05 2018-06-12 陕西冶金设计研究院有限公司 A kind of raw coke oven gas pneumatic trough

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1050921A (en) * 1973-08-30 1979-03-20 Walter E. Carbone Treatment of coke oven gas
CN102268269A (en) * 2011-07-06 2011-12-07 中冶焦耐(大连)工程技术有限公司 Method for drawing raw coal gas out of coke oven
CN203400909U (en) * 2013-06-17 2014-01-22 马钢(集团)控股有限公司 Coke oven raw-gas pipeline cleaning device
CN103614148A (en) * 2013-09-27 2014-03-05 王利民 Coke oven coal charging smoke elimination and dust removal equipment
CN106147803A (en) * 2016-08-11 2016-11-23 中冶焦耐(大连)工程技术有限公司 A kind of coke oven coking chamber pressure adjusting means and control method
CN207108936U (en) * 2017-07-10 2018-03-16 北京华泰焦化工程技术有限公司 A kind of coke-stove gas gas transmission system and coke oven gas purification system

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1050921A (en) * 1973-08-30 1979-03-20 Walter E. Carbone Treatment of coke oven gas
CN102268269A (en) * 2011-07-06 2011-12-07 中冶焦耐(大连)工程技术有限公司 Method for drawing raw coal gas out of coke oven
CN203400909U (en) * 2013-06-17 2014-01-22 马钢(集团)控股有限公司 Coke oven raw-gas pipeline cleaning device
CN103614148A (en) * 2013-09-27 2014-03-05 王利民 Coke oven coal charging smoke elimination and dust removal equipment
CN106147803A (en) * 2016-08-11 2016-11-23 中冶焦耐(大连)工程技术有限公司 A kind of coke oven coking chamber pressure adjusting means and control method
CN207108936U (en) * 2017-07-10 2018-03-16 北京华泰焦化工程技术有限公司 A kind of coke-stove gas gas transmission system and coke oven gas purification system

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