CN107325779A - A kind of solvent-free solid gum of furniture - Google Patents

A kind of solvent-free solid gum of furniture Download PDF

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Publication number
CN107325779A
CN107325779A CN201710586202.2A CN201710586202A CN107325779A CN 107325779 A CN107325779 A CN 107325779A CN 201710586202 A CN201710586202 A CN 201710586202A CN 107325779 A CN107325779 A CN 107325779A
Authority
CN
China
Prior art keywords
furniture
acrylate
solvent
mercaptan
parts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710586202.2A
Other languages
Chinese (zh)
Inventor
毛文宇
郭忠泉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nantong Lianheng New Material Co Ltd
Original Assignee
Nantong Lianheng New Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nantong Lianheng New Material Co Ltd filed Critical Nantong Lianheng New Material Co Ltd
Priority to CN201710586202.2A priority Critical patent/CN107325779A/en
Publication of CN107325779A publication Critical patent/CN107325779A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04Polyurethanes
    • C09J175/14Polyurethanes having carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/38Boron-containing compounds
    • C08K2003/387Borates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The present invention relates to chemical field, specifically related to a kind of solvent-free solid gum of furniture, a kind of solvent-free solid gum of furniture, it includes aliphatic urethane acrylate 35%, acrylate monomer 25%~30%, mercaptan 15%~25%, tackifying resin 10%~15%, stearic acid 5%, borax 10%, ethylene glycol 8%, levelling agent 0.5%, defoamer 0.5%, preservative 0.2%, 4 8wt% other auxiliary agents, it is an advantage of the invention that:The adhesive property and water resistance of solid glue of the present invention are improved, and binding speed is fast, and cohesive force is strong, and ageing-resistant, good weatherability should not be hardened.

Description

A kind of solvent-free solid gum of furniture
Technical field
The present invention relates to chemical field, and in particular to a kind of solvent-free solid gum of furniture.
Background technology
The solid glue slow drying speed of prior art, mobility is bad, and standing time length, solid gum will be dried, So as to fail, storage time is short.
The content of the invention
In order to solve the above problems, the present invention proposes a kind of solvent-free solid gum of furniture, with short production cycle, production Product are stable.
A kind of solvent-free solid gum of furniture, it includes aliphatic urethane acrylate 35%, acrylate monomer 25% ~30%, mercaptan 15%~25%, tackifying resin 10%~15%, stearic acid 5%, borax 10%, ethylene glycol 8%, levelling agent 0.5%, froth breaking Agent 0.5%, preservative 0.2%, 4-8wt% other auxiliary agents.
Described aliphatic urethane acrylate refers to the aliphatic urethane acrylate of 1~3 degree of functionality, aliphatic poly Urethane acrylate refers to Sartomer CN704, CN965NS, CN8004, CN9002, CN966J75NS, CNUVE151NS, Changxing 6113rd, 615-100, at least one of 641.
Described acrylate monomer is at least one of acrylate or methacrylate, and mercaptan is knot containing ethers The mercaptan of structure.
Described auxiliary agent is as follows:0.5wt% polyacrylamides, 2wt% essence hydrogen, 5wt% sodium oxide molybdenas.
It is an advantage of the invention that:The adhesive property and water resistance of solid glue of the present invention are improved, binding speed It hurry up, cohesive force is strong, and ageing-resistant, good weatherability should not be hardened.
Specific embodiment
A kind of solvent-free solid gum of furniture, it includes aliphatic urethane acrylate 35%, acrylate monomer 25% ~30%, mercaptan 15%~25%, tackifying resin 10%~15%, stearic acid 5%, borax 10%, ethylene glycol 8%, levelling agent 0.5%, froth breaking Agent 0.5%, preservative 0.2%, 4-8wt% other auxiliary agents.
First water, aliphatic urethane acrylate, acrylate monomer, mercaptan are entered with 60~80 revs/min of speed Row stirring 6~10 minutes, then adding tackifying resin, stearic acid stirring makes it be uniformly dispersed in 15~30 minutes, sequentially adds Defoamer, borax, ethylene glycol, levelling agent and other auxiliary agents are sequentially added, rotating speed is 40~50 revs/min of stirrings 30~40 Minute, preservative is eventually adding, is stirred 30~40 minutes.
Embodiment 1
A kind of solid glue, by weight, is prepared from by following raw material components:45 parts of aliphatic urethane acrylate, 35 parts of acrylate monomer, 1.8 parts of stearic acid, 7 parts of borax, 1 part of sodium hydroxide, 9 parts of catalyst, 4.5 parts of ethylene glycol, thickening tree 6 parts of fat, 0.3 part of essence, 0.2 part of polyacrylamide, 0.5 part of levelling agent, 0.5 part of defoamer, 110 parts of water.
Embodiment 2
A kind of solid glue, by weight, is prepared from by following raw material components:40 parts of aliphatic urethane acrylate, 30 parts of acrylate monomer, 0.2 part of stearic acid, 4 parts of borax, 0.5 part of sodium hydroxide, 6 parts of catalyst, 3 parts of ethylene glycol, thickening tree 4 parts of fat, 0.01 part of essence, 0.1 part of polyacrylamide, 0.3 part of levelling agent, 0.3 part of defoamer, 100 parts of water.
Embodiment 3
A kind of solid glue, by weight, is prepared from by following raw material components:50 parts of aliphatic urethane acrylate, 40 parts of acrylate monomer, 3 parts of stearic acid, 10 parts of borax, 1.5 parts of sodium hydroxide, 12 parts of catalyst, 6 parts of ethylene glycol, thickening tree 8 parts of fat, 0.5 part of essence, 0.3 part of polyacrylamide, 1 part of levelling agent, 1 part of defoamer, 120 parts of water.

Claims (4)

1. a kind of solvent-free solid gum of furniture, it include aliphatic urethane acrylate 35%, acrylate monomer 25%~ 30%th, mercaptan 15%~25%, tackifying resin 10%~15%, stearic acid 5%, borax 10%, ethylene glycol 8%, levelling agent 0.5%, defoamer 0.5%th, preservative 0.2%, 4-8wt% other auxiliary agents.
2. a kind of furniture according to claim 1 is with without solution solids glue, it is characterised in that described aliphatic polyurethane Acrylate refers to the aliphatic urethane acrylate of 1~3 degree of functionality, aliphatic urethane acrylate refer to Sartomer CN704, CN965NS, CN8004, CN9002, CN966J75NS, CNUVE151NS, Changxing 6113,615-100, at least one of 641.
3. a kind of furniture according to claim 1 is with without solution solids glue, it is characterised in that described acrylate monomer For at least one of acrylate or methacrylate, mercaptan is the mercaptan of the structure containing ethers.
4. a kind of furniture according to claim 1 is with without solution solids glue, it is characterised in that described auxiliary agent is as follows:0. 5wt% polyacrylamides, 2wt% essence hydrogen, 5wt% sodium oxide molybdenas.
CN201710586202.2A 2017-07-18 2017-07-18 A kind of solvent-free solid gum of furniture Pending CN107325779A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710586202.2A CN107325779A (en) 2017-07-18 2017-07-18 A kind of solvent-free solid gum of furniture

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710586202.2A CN107325779A (en) 2017-07-18 2017-07-18 A kind of solvent-free solid gum of furniture

Publications (1)

Publication Number Publication Date
CN107325779A true CN107325779A (en) 2017-11-07

Family

ID=60226496

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710586202.2A Pending CN107325779A (en) 2017-07-18 2017-07-18 A kind of solvent-free solid gum of furniture

Country Status (1)

Country Link
CN (1) CN107325779A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107880821A (en) * 2017-12-12 2018-04-06 佛山早稻田环保节能科技有限公司 A kind of Environment-friendlysolid solid glue

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103602292A (en) * 2013-10-20 2014-02-26 安徽嘉木橡塑工业有限公司 Solid glue
CN103725245A (en) * 2013-12-20 2014-04-16 广州慧谷工程材料有限公司 Solvent-free UV (ultraviolet) curing glue for optical transparent adhesive tape and preparation method and application thereof
CN106118549A (en) * 2016-07-21 2016-11-16 柳州市五源科技有限公司 Solid gum

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103602292A (en) * 2013-10-20 2014-02-26 安徽嘉木橡塑工业有限公司 Solid glue
CN103725245A (en) * 2013-12-20 2014-04-16 广州慧谷工程材料有限公司 Solvent-free UV (ultraviolet) curing glue for optical transparent adhesive tape and preparation method and application thereof
CN106118549A (en) * 2016-07-21 2016-11-16 柳州市五源科技有限公司 Solid gum

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107880821A (en) * 2017-12-12 2018-04-06 佛山早稻田环保节能科技有限公司 A kind of Environment-friendlysolid solid glue

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Application publication date: 20171107