CN107325770A - A kind of 3D printing powder binding agent and its application - Google Patents
A kind of 3D printing powder binding agent and its application Download PDFInfo
- Publication number
- CN107325770A CN107325770A CN201710386098.2A CN201710386098A CN107325770A CN 107325770 A CN107325770 A CN 107325770A CN 201710386098 A CN201710386098 A CN 201710386098A CN 107325770 A CN107325770 A CN 107325770A
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- binding agent
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- printing powder
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
Abstract
The invention belongs to binding agent field, and in particular to a kind of 3D printing powder binding agent and its application.3D printing powder binding agent, the binding agent is resinoid bond, and for the rapid shaping of 3D printing dusty material, rapid curing, overall with powder particle Adhesion formation in a heated state, and high-temperature post-treatment obtains product, and its each component is calculated as by weight：40 60 parts of bisphenol A type epoxy resin, 5 10 parts of curing agent, 38 parts of toughener, 15 parts of accelerator, 10 20 parts of filler, 35 parts of coupling agent, diluent surplus.Binding agent use condition prepared by the present invention is simple, environmental pollution is small, good product performance, and precision is high, and adhesive speed is fast, and mechanical property is good, it is adaptable to the 3D printing shaping of ceramic powders and metal dust；Raw material of the present invention obtains in extensive range, and preparation method is simple and easy to apply, and cost is low, is conducive to the popularization of the marketization.
Description
Technical field
The invention belongs to binding agent field, and in particular to a kind of 3D printing powder binding agent and its application.
Background technology
3D printing is a kind of rapid shaping technique, and it combines computer graphical processing, digital information and control, laser
The advantage of the multinomial technology such as technology, mechanical ＆ electrical technology and material technology, can pass through modeling software or three-dimensional by the physical form of product
Scanner is converted into 3-dimensional digital three-dimensional model, with delamination software that this model is discrete in Z axis, forms a series of with specific thickness
The thin layer of degree, then using various methods by this series of thin layers successively heap come, eventually pass appropriate post-processing approach,
Obtain required product.This forming method does not need mould, eliminates the processes such as mold design, manufacture and matched moulds, the demoulding,
Research and development and manufacturing cycle are significantly shorten, the cost of product is reduced.With the development and application of 3D printing technique, material turns into
One of key factor of 3D printing technique future trend is limited, to a certain extent, the development of material decides that can 3D printing
There is wider application.At present, 3D printing material mainly include engineering plastics, photosensitive resin, rubber type of material, metal material and
Ceramic material etc., in addition, the food such as coloured plaster material, artificial bone meal, cell biological raw material, wood materials and granulated sugar
Material is also applied in 3D printing field.
The exploitation of numerous 3D printing materials and use, the application of 3D printing technique has not only been expanded, while also promoting
The exploitation and production of more auxiliary materials, such as：Binding agent.Binding agent as most important auxiliary material in 3D printing technique it
One requires it is necessary to have adhesion strength is high, curing rate is fast, environmentally friendly, easy to use etc..As increasing dusty material is used
In 3D printing, the 3D that the performance and feature that dusty material possesses cause current binding agent largely to cannot be used for dusty material is beaten
Type, and popularization and application with 3D printing technique in daily life are printed as, condition of molding and environmental issue turn into new
Restraining factors, thus the binding agent that a kind of use condition of invention is simple, health environment-friendly, adhesion strength are high, curing rate is fast is to 3D
Printing is widely used in the significant of life.
The content of the invention
In order to solve the above problems, the invention discloses a kind of use condition is simple, environmental pollution is small, good product performance,
Precision is high, the fast 3D printing powder binding agent of shaping speed.
To realize the purpose of the present invention, the present invention is adopted the following technical scheme that：
A kind of 3D printing powder binding agent, the binding agent is resinoid bond, for the fast of 3D printing dusty material
Rapid-result type, rapid curing, overall with powder particle Adhesion formation in a heated state, and high-temperature post-treatment obtains product, its each group
Divide and be calculated as by weight：
40-60 parts of bisphenol A type epoxy resin, 5-10 parts of curing agent, 3-8 parts of toughener, 1-5 parts of accelerator, filler 10-
20 parts, 3-5 parts of coupling agent, diluent surplus.
Specifically, the epoxide number of described epoxy resin is 0.41-0.54.
Specifically, described curing agent is ethylenediamine, hexamethylene diamine, diethylenetriamine, triethylene tetramine, lignocaine third
One or more in amine, maleic anhydride, phthalic anhydride.
Specifically, described toughener is polysulfide rubber, carboxyl LNBR, polyamide, polyvinyl alcohol uncle
One kind in butyraldehyde.
Specifically, described accelerator is one kind in phenol, chlorinated phenol, resorcinol, salicylic acid.
Specifically, described filler is aluminum oxide, graphite powder, titanium dioxide, magnetic one or more.
Specifically, described coupling agent is γ-(methacryloxypropyl) propyl trimethoxy silicane, the second of γ-aminopropyl three
One kind in TMOS 3- (2,3- the third oxygen of epoxy) propyl trimethoxy silicane.
Specifically, described diluent is that butyl glycidyl ether, BDDE, ethylene glycol two contract
One kind in water glycerin ether, 1,6- hexanediol diglycidyl ethers.
Further, a kind of described 3D printing powder binding agent, is directly used in the 3D printing rapid shaping of dusty material,
Forming step is：1) 3D printing 3-D solid structure model is designed as needed；2) by designed 3D printing 3 D stereo knot
Structure model imports 3D printer；3) binding agent of the present invention and the 3D printing needed to use are added separately to 3D with dusty material and beaten
In the hopper of print machine, and print platform is placed in 40-80 DEG C of environment；4) 3D printer is started, according to the digital mould of design
Type is printed, and printing principle is first one layer of powder of sprinkling, then sprays a layer binder, one layer of layer binder of powder one of formation
Alternating structure, so bonds to get up to form required germule in layer；5) obtained germule is put into temperature for 120-200
DEG C high temperature furnace in further solidification obtain product.
Further, described powder is one kind in metal dust, ceramic powders.
The device have the advantages that：
(1) the binding agent use condition of the invention prepared is simple, environmental pollution is small, good product performance, and precision is high, bonds speed
Degree is fast, and mechanical property is good, it is adaptable to the 3D printing shaping of ceramic powders and metal dust.
(2) raw material of the present invention obtains in extensive range, and preparation method is simple and easy to apply, and cost is low, is conducive to the popularization of the marketization.
Embodiment
Presently in connection with embodiment, the present invention is further detailed explanation.
Embodiment 1
A kind of 3D printing powder binding agent, its each component is calculated as by weight：
40 parts of bisphenol A type epoxy resin, epoxide equivalent is 0.41,8 parts of ethylenediamine, 3 parts of polysulfide rubber, 1 part of phenol, oxidation
15 parts of aluminium, γ -4 parts of (methacryloxypropyl) propyl trimethoxy silicane, butyl glycidyl ether surplus.
A kind of 3D printing powder binding agent, preparation method comprises the following steps：
(1) by 80% butyl glycidyl ether in above-mentioned formula rate and bisphenol A type epoxy resin, polysulfide rubber, oxygen
Change aluminium, γ-(methacryloxypropyl) propyl trimethoxy silicane to be uniformly mixed in the case where temperature is 40-50 DEG C；
(2) remaining 20% butyl glycidyl ether is used for miscible phenol and ethylenediamine, treats that phenol ethylenediamine is miscible
It is well mixed after uniform with the solution of step (1), 3D printing powder binding agent is made.
The application of binding agent：The binding agent of preparation is directly used in the 3D printing rapid shaping of ceramic powder material, shaping step
Suddenly it is：1) 3D printing 3-D solid structure model is designed as needed；2) by designed 3D printing 3-D solid structure model
Import 3D printer；3) binding agent of the present invention and the 3D printing needed to use are added separately to 3D printing with ceramic powder material
In the hopper of machine, and print platform is placed in 40-80 DEG C of environment；4) 3D printer is started, according to the mathematical model of design
Printed, printing principle is first one layer of powder of sprinkling, then spray a layer binder, form the friendship of one layer of layer binder of powder one
For structure, so bond to get up to form required germule in layer；5) obtained germule is put into temperature for 120-200 DEG C
High temperature furnace in further solidification obtain product.
Embodiment 2
A kind of 3D printing powder binding agent, its each component is calculated as by weight：
50 parts of bisphenol A type epoxy resin, epoxide equivalent be 0.45,5 parts of diethylenetriamine, 5 parts of carboxyl LNBR,
5 parts of chlorinated phenol, 10 parts of graphite powder, 3 parts of gamma-aminopropyl-triethoxy-silane, 1,4- butanediol diglycidyl ether surpluses.
A kind of 3D printing powder binding agent, preparation method comprises the following steps：
(1) by above-mentioned formula rate 80% 1,4- butanediol diglycidyl ethers and bisphenol A type epoxy resin, carboxyl
LNBR, graphite powder, gamma-aminopropyl-triethoxy-silane are uniformly mixed in the case where temperature is 40-50 DEG C；
(2) by remaining 20% butyl glycidyl ether be used for miscible chlorinated phenol and diethylenetriamine, treat chlorinated phenol and
Diethylenetriamine is miscible to be uniformly well mixed with the solution of step (1) afterwards, and 3D printing powder binding agent is made.
The application of binding agent：The binding agent of preparation is directly used in the 3D printing rapid shaping of ceramic powder material, shaping step
Suddenly it is：1) 3D printing 3-D solid structure model is designed as needed；2) by designed 3D printing 3-D solid structure model
Import 3D printer；3) binding agent of the present invention and the 3D printing needed to use are added separately to 3D printing with ceramic powder material
In the hopper of machine, and print platform is placed in 40-80 DEG C of environment；4) 3D printer is started, according to the mathematical model of design
Printed, printing principle is first one layer of powder of sprinkling, then spray a layer binder, form the friendship of one layer of layer binder of powder one
For structure, so bond to get up to form required germule in layer；5) obtained germule is put into temperature for 120-200 DEG C
High temperature furnace in further solidification obtain product.
Embodiment 3
A kind of 3D printing powder binding agent, its each component is calculated as by weight：
55 parts of bisphenol A type epoxy resin, epoxide equivalent is 0.50,10 parts of diethylaminopropylamine, polyamide 8 part,
3 parts of benzenediol, 15 parts of titanium dioxide, 3- (2,3- the third oxygen of epoxy) 5 parts of propyl trimethoxy silicane, more than ethylene glycol diglycidylether
Amount.
A kind of 3D printing powder binding agent, preparation method comprises the following steps：
(1) by 80% ethylene glycol diglycidylether in above-mentioned formula rate and bisphenol A type epoxy resin, carboxyl liquid
The stirring mixing in the case where temperature is 40-50 DEG C of polyamide, titanium dioxide, 3- (2,3- the third oxygen of epoxy) propyl trimethoxy silicanes is equal
It is even；
(2) remaining 20% ethylene glycol diglycidylether is used for miscible resorcinol and diethylaminopropylamine, treated
Resorcinol and diethylaminopropylamine it is miscible it is uniform after be well mixed with the solution of step (1), obtained 3D printing powder bonding
Agent.
The application of binding agent：The binding agent of preparation is directly used in the 3D printing rapid shaping of metal powder material, shaping step
Suddenly it is：1) 3D printing 3-D solid structure model is designed as needed；2) by designed 3D printing 3-D solid structure model
Import 3D printer；3) binding agent of the present invention and the 3D printing needed to use are added separately to 3D printing with metal powder material
In the hopper of machine, and print platform is placed in 40-80 DEG C of environment；4) 3D printer is started, according to the mathematical model of design
Printed, printing principle is first one layer of powder of sprinkling, then spray a layer binder, form the friendship of one layer of layer binder of powder one
For structure, so bond to get up to form required germule in layer；5) obtained germule is put into temperature for 120-200 DEG C
High temperature furnace in further solidification obtain product.
Embodiment 4
A kind of 3D printing powder binding agent, its each component is calculated as by weight：
60 parts of bisphenol A type epoxy resin, epoxide equivalent be 0.54,6 parts of maleic anhydride, 5 parts of the tertiary butyraldehyde of polyvinyl alcohol,
5 parts of salicylic acid, 20 parts of magnetic, γ -4 parts of (methacryloxypropyl) propyl trimethoxy silicane, 1,6- hexylene glycol 2-glycidyls
Ether surplus.
A kind of 3D printing powder binding agent, preparation method comprises the following steps：
(1) by above-mentioned formula rate 80% 1,6- hexanediol diglycidyl ethers and bisphenol A type epoxy resin, poly- second
The stirring mixing in the case where temperature is 40-50 DEG C of the tertiary butyraldehyde of enol, magnetic, γ-(methacryloxypropyl) propyl trimethoxy silicane is equal
It is even；
(2) remaining 20% 1,6- hexanediol diglycidyl ethers are used for miscible salicylic acid and maleic acid
Acid anhydride, is well mixed after salicylic acid and maleic anhydride are miscible uniformly with the solution of step (1), and 3D printing powder is made and uses viscous
Tie agent.
The application of binding agent：The binding agent of preparation is directly used in the 3D printing rapid shaping of metal powder material, shaping step
Suddenly it is：1) 3D printing 3-D solid structure model is designed as needed；2) by designed 3D printing 3-D solid structure model
Import 3D printer；3) binding agent of the present invention and the 3D printing needed to use are added separately to 3D printing with metal powder material
In the hopper of machine, and print platform is placed in 40-80 DEG C of environment；4) 3D printer is started, according to the mathematical model of design
Printed, printing principle is first one layer of powder of sprinkling, then spray a layer binder, form the friendship of one layer of layer binder of powder one
For structure, so bond to get up to form required germule in layer；5) obtained germule is put into temperature for 120-200 DEG C
High temperature furnace in further solidification obtain product.
Embodiment 5
A kind of 3D printing powder binding agent, its each component is calculated as by weight：
60 parts of bisphenol A type epoxy resin, epoxide equivalent be 0.48,9 parts of phthalic anhydride, 3 parts of the tertiary butyraldehyde of polyvinyl alcohol,
5 parts of phenol, 10 parts of magnetic, γ -4 parts of (methacryloxypropyl) propyl trimethoxy silicane, 1,6- hexanediol diglycidyl ethers
Surplus.
A kind of 3D printing powder binding agent, preparation method comprises the following steps：
(1) by above-mentioned formula rate 80% 1,6- hexanediol diglycidyl ethers and bisphenol A type epoxy resin, poly- second
The stirring mixing in the case where temperature is 40-50 DEG C of the tertiary butyraldehyde of enol, magnetic, γ-(methacryloxypropyl) propyl trimethoxy silicane is equal
It is even；
(2) remaining 20% 1,6- hexanediol diglycidyl ethers are used for miscible phenol and phthalic anhydride,
It is well mixed after phenol and phthalic anhydride are miscible uniformly with the solution of step (1), 3D printing powder binding agent is made.
The application of binding agent：The binding agent of preparation is directly used in the 3D printing rapid shaping of metal powder material, shaping step
Suddenly it is：1) 3D printing 3-D solid structure model is designed as needed；2) by designed 3D printing 3-D solid structure model
Import 3D printer；3) binding agent of the present invention and the 3D printing needed to use are added separately to 3D printing with metal powder material
In the hopper of machine, and print platform is placed in 40-80 DEG C of environment；4) 3D printer is started, according to the mathematical model of design
Printed, printing principle is first one layer of powder of sprinkling, then spray a layer binder, form the friendship of one layer of layer binder of powder one
For structure, so bond to get up to form required germule in layer；5) obtained germule is put into temperature for 120-200 DEG C
High temperature furnace in further solidification obtain product.
Using the above-mentioned desirable embodiment according to the present invention as enlightenment, by above-mentioned description, relevant staff is complete
Various changes and amendments can be carried out without departing from the scope of the technological thought of the present invention' entirely.The technology of this invention
Property scope is not limited to the content on specification, it is necessary to its technical scope is determined according to right.
Claims (10)
1. a kind of 3D printing powder binding agent, it is characterised in that the binding agent is resinoid bond, for 3D printing powder
The rapid shaping of material, rapid curing, overall with powder particle Adhesion formation in a heated state, high-temperature post-treatment system
Product, its each component is calculated as by weight：
40-60 parts of bisphenol A type epoxy resin, 5-10 parts of curing agent, 3-8 parts of toughener, 1-5 parts of accelerator, filler 10-20
Part, 3-5 parts of coupling agent, diluent surplus.
2. a kind of 3D printing powder binding agent as claimed in claim 1, it is characterised in that the epoxy of described epoxy resin
It is worth for 0.41-0.54.
3. a kind of 3D printing powder binding agent as claimed in claim 1, it is characterised in that described curing agent is second two
One in amine, hexamethylene diamine, diethylenetriamine, triethylene tetramine, diethylaminopropylamine, maleic anhydride, phthalic anhydride
Plant or several.
4. a kind of 3D printing powder binding agent as claimed in claim 1, it is characterised in that described toughener is polysulfide rubber
One kind in glue, carboxyl LNBR, polyamide, the tertiary butyraldehyde of polyvinyl alcohol.
5. a kind of 3D printing powder binding agent as claimed in claim 1, it is characterised in that described accelerator be phenol,
One kind in chlorinated phenol, resorcinol, salicylic acid.
6. a kind of 3D printing powder binding agent as claimed in claim 1, it is characterised in that described filler is oxidation
Aluminium, graphite powder, titanium dioxide, magnetic are one or more of.
7. a kind of 3D printing powder binding agent as claimed in claim 1, it is characterised in that described coupling agent is γ-(first
Base acryloyl-oxy) propyl trimethoxy silicane, gamma-aminopropyl-triethoxy-silane 3- (2,3- the third oxygen of epoxy) propyl trimethoxy
One kind in silane.
8. a kind of 3D printing powder binding agent as claimed in claim 1, it is characterised in that described diluent contracts for butyl
In water glycerin ether, 1,4- butanediol diglycidyl ethers, ethylene glycol diglycidylether, 1,6- hexanediol diglycidyl ethers
It is a kind of.
9. a kind of 3D printing powder binding agent as claimed in claim 1, it is characterised in that be directly used in the 3D of dusty material
Rapid shaping is printed, forming step is：1) 3D printing 3-D solid structure model is designed as needed；2) designed 3D is beaten
Print 3-D solid structure model and import 3D printer；3) by binding agent of the present invention and the 3D printing needed to use dusty material point
It is not added in the hopper of 3D printer, and print platform is placed in 40-80 DEG C of environment；4) 3D printer is started, according to
The mathematical model of design is printed, and printing principle is first one layer of powder of sprinkling, then sprays a layer binder, forms one layer of powder
The alternating structure of one layer binder, so bonds to get up to form required germule in layer；5) obtained germule is put into
Temperature is further solidification obtains product in 120-200 DEG C of high temperature furnace.
10. a kind of 3D printing powder binding agent as described in claim 1-9, it is characterised in that described powder is metal
One kind in powder, ceramic powders.
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| CN201710386098.2A CN107325770A (en) | 2017-05-26 | 2017-05-26 | A kind of 3D printing powder binding agent and its application |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107722909A (en) * | 2017-11-17 | 2018-02-23 | 武汉三迪创为科技有限公司 | It is a kind of suitable for colourless adhesive glue of full-color 3D printer and preparation method thereof |
| CN107868644A (en) * | 2017-12-12 | 2018-04-03 | 成都育芽科技有限公司 | A kind of 3D printing is with processing and forming bonding agent |
| CN108658587A (en) * | 2018-07-09 | 2018-10-16 | 天津大学 | A kind of increasing material manufacturing method of aluminium oxide ceramics |
| CN108724431A (en) * | 2018-07-09 | 2018-11-02 | 天津大学 | A kind of ceramic powders bonding printer |
| CN108793975A (en) * | 2018-07-09 | 2018-11-13 | 天津大学 | A kind of increasing material manufacturing method of ferrite ceramics |
| CN108863392A (en) * | 2018-07-09 | 2018-11-23 | 天津大学 | A kind of increasing material manufacturing method of silicon carbide ceramics |
| CN108947494A (en) * | 2018-07-09 | 2018-12-07 | 天津大学 | A kind of ceramic material increasing material manufacturing method |
| CN110372982A (en) * | 2019-08-02 | 2019-10-25 | 广州金磁实业有限公司 | A kind of the printing slurry and production technology of solid micro-current film cloth |
| CN111634144A (en) * | 2020-06-02 | 2020-09-08 | 湖州衡鼎产品检测中心 | Wooden floor surface coating method based on 3D printing technology |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102181252A (en) * | 2011-05-30 | 2011-09-14 | 烟台德邦科技有限公司 | Low-halogen single-component flame-retardant epoxy adhesive |
| CN103709983A (en) * | 2013-12-23 | 2014-04-09 | 东莞市亚聚电子材料有限公司 | High temperature resisting bottom filler glue and preparation method thereof |
| CN105778423A (en) * | 2016-04-09 | 2016-07-20 | 余若冰 | Novel thermosetting 3D printing material |
| CN105907043A (en) * | 2016-04-09 | 2016-08-31 | 余若冰 | Thermosetting non-photocureable 3D printing material and printing method thereof |
| CN106084656A (en) * | 2016-06-13 | 2016-11-09 | 广西医科大学 | A kind of new modified materials printed for 3D |
-
2017
- 2017-05-26 CN CN201710386098.2A patent/CN107325770A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102181252A (en) * | 2011-05-30 | 2011-09-14 | 烟台德邦科技有限公司 | Low-halogen single-component flame-retardant epoxy adhesive |
| CN103709983A (en) * | 2013-12-23 | 2014-04-09 | 东莞市亚聚电子材料有限公司 | High temperature resisting bottom filler glue and preparation method thereof |
| CN105778423A (en) * | 2016-04-09 | 2016-07-20 | 余若冰 | Novel thermosetting 3D printing material |
| CN105907043A (en) * | 2016-04-09 | 2016-08-31 | 余若冰 | Thermosetting non-photocureable 3D printing material and printing method thereof |
| CN106084656A (en) * | 2016-06-13 | 2016-11-09 | 广西医科大学 | A kind of new modified materials printed for 3D |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107722909A (en) * | 2017-11-17 | 2018-02-23 | 武汉三迪创为科技有限公司 | It is a kind of suitable for colourless adhesive glue of full-color 3D printer and preparation method thereof |
| CN107722909B (en) * | 2017-11-17 | 2020-12-25 | 武汉三迪创为科技有限公司 | Colorless adhesive glue suitable for full-color 3D printer and preparation method thereof |
| CN107868644A (en) * | 2017-12-12 | 2018-04-03 | 成都育芽科技有限公司 | A kind of 3D printing is with processing and forming bonding agent |
| CN108658587A (en) * | 2018-07-09 | 2018-10-16 | 天津大学 | A kind of increasing material manufacturing method of aluminium oxide ceramics |
| CN108724431A (en) * | 2018-07-09 | 2018-11-02 | 天津大学 | A kind of ceramic powders bonding printer |
| CN108793975A (en) * | 2018-07-09 | 2018-11-13 | 天津大学 | A kind of increasing material manufacturing method of ferrite ceramics |
| CN108863392A (en) * | 2018-07-09 | 2018-11-23 | 天津大学 | A kind of increasing material manufacturing method of silicon carbide ceramics |
| CN108947494A (en) * | 2018-07-09 | 2018-12-07 | 天津大学 | A kind of ceramic material increasing material manufacturing method |
| CN110372982A (en) * | 2019-08-02 | 2019-10-25 | 广州金磁实业有限公司 | A kind of the printing slurry and production technology of solid micro-current film cloth |
| CN111634144A (en) * | 2020-06-02 | 2020-09-08 | 湖州衡鼎产品检测中心 | Wooden floor surface coating method based on 3D printing technology |
| CN111634144B (en) * | 2020-06-02 | 2021-10-15 | 湖州衡鼎产品检测中心 | Wooden floor surface coating method based on 3D printing technology |
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Application publication date: 20171107 |