CN107325721A - A kind of anti-ultraviolet paint for building and its preparation technology - Google Patents
A kind of anti-ultraviolet paint for building and its preparation technology Download PDFInfo
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- CN107325721A CN107325721A CN201710660547.8A CN201710660547A CN107325721A CN 107325721 A CN107325721 A CN 107325721A CN 201710660547 A CN201710660547 A CN 201710660547A CN 107325721 A CN107325721 A CN 107325721A
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- uvioresistant
- bentonite
- silicone oil
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of anti-ultraviolet paint for building and its preparation technology, coating components include 10 18 parts of epoxy acrylic resin by weight, 10 20 parts of hydroxy propyl methacrylate, 5 15 parts of barium sulfate, 30 50 parts of emulsion, 10 25 parts of glass fibre, 4 12 parts of nano titanium oxide, 38 parts of hydroxyethyl cellulose, 10 18 parts of VTES, 5 12 parts of bentonite, 3 10 parts of alumina silicate fibre, 20 30 parts of uvioresistant organic silicone oil, preparation technology of the present invention is simple, asepsis environment-protecting, obtained coating has excellent anti-ultraviolet function, energy consumption can be reduced in process of production simultaneously, improve production efficiency.
Description
Technical field
The present invention relates to technical field of paint preparation, specially a kind of anti-ultraviolet paint for building and its preparation technology.
Background technology
In recent years, with the high speed development of modern science and technology, anti-ultraviolet paint goes out as a kind of new curing technology coating
The with rapid changepl. never-ending changes and improvements, good momentum of fast development is showed.Anti-ultraviolet paint has curing rate is fast (to complete within 0.1-10 seconds because of it
Solidification), save the energy 1/5-1/10 of heat curing coating (power consumption be about) and coating performance it is excellent (such as high glaze,
High rigidity, chemical proofing are good etc.) the advantages of and be widely used in construction material, sports goods, telecommunications, packaging
The different field such as material and automobile component.However, to there is stability poor, not environmentally and anti-for existing ultraviolet photo-curing coating
The shortcoming of ultraviolet poor performance, so as to limit its application to a certain extent.
The content of the invention
It is an object of the invention to provide a kind of anti-ultraviolet paint for building and its preparation technology, to solve above-mentioned background
The problem of being proposed in technology.
To achieve the above object, the present invention provides following technical scheme：A kind of anti-ultraviolet paint for building, coating components
Include 10-18 parts of epoxy acrylic resin, 10-20 parts of hydroxy propyl methacrylate, 5-15 parts of barium sulfate, emulsion by weight
30-50 parts, 10-25 parts of glass fibre, 4-12 parts of nano titanium oxide, 3-8 parts of hydroxyethyl cellulose, vinyl triethoxyl silicon
10-18 parts of alkane, 5-12 parts of bentonite, 3-10 parts of alumina silicate fibre, 20-30 parts of uvioresistant organic silicone oil.
It is preferred that, the preferred composition proportion of coating components is：14 parts of epoxy acrylic resin, hydroxy propyl methacrylate 15
Part, 10 parts of barium sulfate, 40 parts of emulsion, 18 parts of glass fibre, 8 parts of nano titanium oxide, 5 parts of hydroxyethyl cellulose, vinyl three
14 parts of Ethoxysilane, 9 parts of bentonite, 7 parts of alumina silicate fibre, 25 parts of uvioresistant organic silicone oil.
It is preferred that, its preparation technology comprises the following steps：
A, will epoxy acrylic resin, hydroxy propyl methacrylate, VTES, emulsion mix after add stirring
High low speed mixing is carried out in container, high-speed stirred is first carried out, speed is 3000 revs/min, and the time is 5min；Carry out afterwards low
Speed stirring, speed is 400 revs/min, and the time is 10min, and standing obtains mixture A；
B, by barium sulfate, glass fibre, nano titanium oxide, hydroxyethyl cellulose, bentonite, alumina silicate fibre, uvioresistant
Added after organic silicone oil mixing and heating response is carried out in reactor, temperature is 90 DEG C -120 DEG C, and the time is 15min-25min, it
After be cooled to after room temperature, obtain mixture B；
C, mixture B added in mixture A, be mixed evenly, when being ground to 70-90 μm, that is, obtain uvioresistant painting
Material.
Compared with prior art, the beneficial effects of the invention are as follows：Preparation technology of the present invention is simple, and asepsis environment-protecting is obtained
Coating has excellent anti-ultraviolet function, while can reduce energy consumption in process of production, improve production efficiency；In the present invention
Barium sulfate, bentonite, the alumina silicate fibre of addition, it is possible to increase the resistance to elevated temperatures of coating；The glass fibre of addition, nanometer two
Titanium oxide, it is possible to increase the antiseptic property of coating；The uvioresistant organic silicone oil of addition can further improve the anti-purple of coating
Outside line effect；In addition, the process of preparing that the present invention is used is simple, it can be ensured that each component is sufficiently mixed, and improves coating
Comprehensive utilization ratio.
Embodiment
The technical scheme in the embodiment of the present invention is clearly and completely described below, it is clear that described embodiment
Only a part of embodiment of the invention, rather than whole embodiments.Based on the embodiment in the present invention, the common skill in this area
The every other embodiment that art personnel are obtained under the premise of creative work is not made, belongs to the model that the present invention is protected
Enclose.
The present invention provides following technical scheme：A kind of anti-ultraviolet paint for building, coating components include by weight
10-18 parts of epoxy acrylic resin, 10-20 parts of hydroxy propyl methacrylate, 5-15 parts of barium sulfate, 30-50 parts of emulsion, glass fibers
10-25 parts of dimension, 4-12 parts of nano titanium oxide, 3-8 parts of hydroxyethyl cellulose, 10-18 parts of VTES, swelling
Native 5-12 parts, 3-10 parts of alumina silicate fibre, 20-30 parts of uvioresistant organic silicone oil.
Embodiment one：
Coating components by weight include 10 parts of epoxy acrylic resin, 10 parts of hydroxy propyl methacrylate, 5 parts of barium sulfate,
30 parts of emulsion, 10 parts of glass fibre, 4 parts of nano titanium oxide, 3 parts of hydroxyethyl cellulose, 10 parts of VTES,
5 parts of bentonite, 3 parts of alumina silicate fibre, 20 parts of uvioresistant organic silicone oil.
The preparation technology of the present embodiment comprises the following steps：
A, will epoxy acrylic resin, hydroxy propyl methacrylate, VTES, emulsion mix after add stirring
High low speed mixing is carried out in container, high-speed stirred is first carried out, speed is 3000 revs/min, and the time is 5min；Carry out afterwards low
Speed stirring, speed is 400 revs/min, and the time is 10min, and standing obtains mixture A；
B, by barium sulfate, glass fibre, nano titanium oxide, hydroxyethyl cellulose, bentonite, alumina silicate fibre, uvioresistant
Added after organic silicone oil mixing and heating response is carried out in reactor, temperature is 90 DEG C, and the time is 15min, and room temperature is cooled to afterwards
Afterwards, mixture B is obtained；
C, mixture B added in mixture A, be mixed evenly, when being ground to 70 μm, that is, obtain anti-ultraviolet paint.
Embodiment two：
Coating components by weight include 18 parts of epoxy acrylic resin, 20 parts of hydroxy propyl methacrylate, 15 parts of barium sulfate,
50 parts of emulsion, 25 parts of glass fibre, 12 parts of nano titanium oxide, 8 parts of hydroxyethyl cellulose, VTES 18
Part, 12 parts of bentonite, 10 parts of alumina silicate fibre, 30 parts of uvioresistant organic silicone oil.
The preparation technology of the present embodiment comprises the following steps：
A, will epoxy acrylic resin, hydroxy propyl methacrylate, VTES, emulsion mix after add stirring
High low speed mixing is carried out in container, high-speed stirred is first carried out, speed is 3000 revs/min, and the time is 5min；Carry out afterwards low
Speed stirring, speed is 400 revs/min, and the time is 10min, and standing obtains mixture A；
B, by barium sulfate, glass fibre, nano titanium oxide, hydroxyethyl cellulose, bentonite, alumina silicate fibre, uvioresistant
Added after organic silicone oil mixing and heating response is carried out in reactor, temperature is 120 DEG C, and the time is 25min, and room temperature is cooled to afterwards
Afterwards, mixture B is obtained；
C, mixture B added in mixture A, be mixed evenly, when being ground to 90 μm, that is, obtain anti-ultraviolet paint.
Embodiment three：
Coating components by weight include 11 parts of epoxy acrylic resin, 12 parts of hydroxy propyl methacrylate, 6 parts of barium sulfate,
35 parts of emulsion, 13 parts of glass fibre, 5 parts of nano titanium oxide, 4 parts of hydroxyethyl cellulose, 11 parts of VTES,
7 parts of bentonite, 4 parts of alumina silicate fibre, 23 parts of uvioresistant organic silicone oil.
The preparation technology of the present embodiment comprises the following steps：
A, will epoxy acrylic resin, hydroxy propyl methacrylate, VTES, emulsion mix after add stirring
High low speed mixing is carried out in container, high-speed stirred is first carried out, speed is 3000 revs/min, and the time is 5min；Carry out afterwards low
Speed stirring, speed is 400 revs/min, and the time is 10min, and standing obtains mixture A；
B, by barium sulfate, glass fibre, nano titanium oxide, hydroxyethyl cellulose, bentonite, alumina silicate fibre, uvioresistant
Added after organic silicone oil mixing and heating response is carried out in reactor, temperature is 95 DEG C, and the time is 18min, and room temperature is cooled to afterwards
Afterwards, mixture B is obtained；
C, mixture B added in mixture A, be mixed evenly, when being ground to 75 μm, that is, obtain anti-ultraviolet paint.
Example IV：
Coating components by weight include 17 parts of epoxy acrylic resin, 18 parts of hydroxy propyl methacrylate, 13 parts of barium sulfate,
45 parts of emulsion, 23 parts of glass fibre, 11 parts of nano titanium oxide, 7 parts of hydroxyethyl cellulose, VTES 17
Part, 10 parts of bentonite, 9 parts of alumina silicate fibre, 28 parts of uvioresistant organic silicone oil.
The preparation technology of the present embodiment comprises the following steps：
A, will epoxy acrylic resin, hydroxy propyl methacrylate, VTES, emulsion mix after add stirring
High low speed mixing is carried out in container, high-speed stirred is first carried out, speed is 3000 revs/min, and the time is 5min；Carry out afterwards low
Speed stirring, speed is 400 revs/min, and the time is 10min, and standing obtains mixture A；
B, by barium sulfate, glass fibre, nano titanium oxide, hydroxyethyl cellulose, bentonite, alumina silicate fibre, uvioresistant
Added after organic silicone oil mixing and heating response is carried out in reactor, temperature is 115 DEG C, and the time is 22min, and room temperature is cooled to afterwards
Afterwards, mixture B is obtained；
C, mixture B added in mixture A, be mixed evenly, when being ground to 85 μm, that is, obtain anti-ultraviolet paint.
Embodiment five：
Coating components by weight include 16 parts of epoxy acrylic resin, 16 parts of hydroxy propyl methacrylate, 12 parts of barium sulfate,
42 parts of emulsion, 22 parts of glass fibre, 10 parts of nano titanium oxide, 6 parts of hydroxyethyl cellulose, VTES 17
Part, 7 parts of bentonite, 9 parts of alumina silicate fibre, 24 parts of uvioresistant organic silicone oil.
The preparation technology of the present embodiment comprises the following steps：
A, will epoxy acrylic resin, hydroxy propyl methacrylate, VTES, emulsion mix after add stirring
High low speed mixing is carried out in container, high-speed stirred is first carried out, speed is 3000 revs/min, and the time is 5min；Carry out afterwards low
Speed stirring, speed is 400 revs/min, and the time is 10min, and standing obtains mixture A；
B, by barium sulfate, glass fibre, nano titanium oxide, hydroxyethyl cellulose, bentonite, alumina silicate fibre, uvioresistant
Added after organic silicone oil mixing and heating response is carried out in reactor, temperature is 98 DEG C, and the time is 19min, and room temperature is cooled to afterwards
Afterwards, mixture B is obtained；
C, mixture B added in mixture A, be mixed evenly, when being ground to 85 μm, that is, obtain anti-ultraviolet paint.
Embodiment six：
Coating components by weight include 14 parts of epoxy acrylic resin, 15 parts of hydroxy propyl methacrylate, 10 parts of barium sulfate,
40 parts of emulsion, 18 parts of glass fibre, 8 parts of nano titanium oxide, 5 parts of hydroxyethyl cellulose, 14 parts of VTES,
9 parts of bentonite, 7 parts of alumina silicate fibre, 25 parts of uvioresistant organic silicone oil.
The preparation technology of the present embodiment comprises the following steps：
A, will epoxy acrylic resin, hydroxy propyl methacrylate, VTES, emulsion mix after add stirring
High low speed mixing is carried out in container, high-speed stirred is first carried out, speed is 3000 revs/min, and the time is 5min；Carry out afterwards low
Speed stirring, speed is 400 revs/min, and the time is 10min, and standing obtains mixture A；
B, by barium sulfate, glass fibre, nano titanium oxide, hydroxyethyl cellulose, bentonite, alumina silicate fibre, uvioresistant
Added after organic silicone oil mixing and heating response is carried out in reactor, temperature is 105 DEG C, and the time is 20min, and room temperature is cooled to afterwards
Afterwards, mixture B is obtained；
C, mixture B added in mixture A, be mixed evenly, when being ground to 80 μm, that is, obtain anti-ultraviolet paint.
Preparation technology of the present invention is simple, and asepsis environment-protecting, obtained coating has excellent anti-ultraviolet function, while can be
Energy consumption is reduced in production process, production efficiency is improved；Barium sulfate, bentonite, the alumina silicate fibre added in the present invention, can
Improve the resistance to elevated temperatures of coating；Glass fibre, the nano titanium oxide of addition, it is possible to increase the antiseptic property of coating；Addition
Uvioresistant organic silicone oil can further improve the uvioresistant effect of coating；Obtained through overtesting, traditional coating its
High temperature resistant is 48 DEG C, and inflammable, and the coating high temperature resistant of the present invention reaches 80 DEG C, and nonflammable；In addition, the system that the present invention is used
Standby process is simple, by first stirring, and rear heating mixing, finally ground order, it can be ensured that each component is sufficiently mixed is carried
The high comprehensive utilization ratio of coating.
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of changes, modification can be carried out to these embodiments, replace without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (3)
1. a kind of anti-ultraviolet paint for building, it is characterised in that：Coating components include epoxy acrylic resin by weight
10-18 parts, 10-20 parts of hydroxy propyl methacrylate, 5-15 parts of barium sulfate, 30-50 parts of emulsion, 10-25 parts of glass fibre, nanometer
4-12 parts of titanium dioxide, 3-8 parts of hydroxyethyl cellulose, 10-18 parts of VTES, 5-12 parts of bentonite, silicic acid
3-10 parts of aluminum fiber, 20-30 parts of uvioresistant organic silicone oil.
2. a kind of anti-ultraviolet paint for building according to claim 1, it is characterised in that：The preferred composition of coating components
Match and be：14 parts of epoxy acrylic resin, 15 parts of hydroxy propyl methacrylate, 10 parts of barium sulfate, 40 parts of emulsion, glass fibre 18
Part, 8 parts of nano titanium oxide, 5 parts of hydroxyethyl cellulose, 14 parts of VTES, 9 parts of bentonite, aluminium silicate fiber
Tie up 7 parts, 25 parts of uvioresistant organic silicone oil.
3. realize a kind of preparation technology of anti-ultraviolet paint for building described in claim 1, it is characterised in that：It prepares work
Skill comprises the following steps：
A, will epoxy acrylic resin, hydroxy propyl methacrylate, VTES, emulsion mix after add stirring
High low speed mixing is carried out in container, high-speed stirred is first carried out, speed is 3000 revs/min, and the time is 5min；Carry out afterwards low
Speed stirring, speed is 400 revs/min, and the time is 10min, and standing obtains mixture A；
B, by barium sulfate, glass fibre, nano titanium oxide, hydroxyethyl cellulose, bentonite, alumina silicate fibre, uvioresistant
Added after organic silicone oil mixing and heating response is carried out in reactor, temperature is 90 DEG C -120 DEG C, and the time is 15min-25min, it
After be cooled to after room temperature, obtain mixture B；
C, mixture B added in mixture A, be mixed evenly, when being ground to 70-90 μm, that is, obtain uvioresistant painting
Material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710660547.8A CN107325721A (en) | 2017-08-04 | 2017-08-04 | A kind of anti-ultraviolet paint for building and its preparation technology |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710660547.8A CN107325721A (en) | 2017-08-04 | 2017-08-04 | A kind of anti-ultraviolet paint for building and its preparation technology |
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| Publication Number | Publication Date |
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| CN107325721A true CN107325721A (en) | 2017-11-07 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201710660547.8A Withdrawn CN107325721A (en) | 2017-08-04 | 2017-08-04 | A kind of anti-ultraviolet paint for building and its preparation technology |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108841260A (en) * | 2018-07-13 | 2018-11-20 | 芜湖多辉建设有限公司 | A kind of modified interior wall coating of environment-friendly insulating |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104893465A (en) * | 2015-05-26 | 2015-09-09 | 康圣科 | Ultraviolet-proof fiber coating material |
| CN105949842A (en) * | 2016-05-03 | 2016-09-21 | 梁冬 | Waterproof and ultraviolet resistant paint for building exterior walls |
| CN105949921A (en) * | 2016-05-03 | 2016-09-21 | 梁冬 | Modified epoxy acrylate heatproof and ultraviolet resistant paint for building exterior walls |
-
2017
- 2017-08-04 CN CN201710660547.8A patent/CN107325721A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104893465A (en) * | 2015-05-26 | 2015-09-09 | 康圣科 | Ultraviolet-proof fiber coating material |
| CN105949842A (en) * | 2016-05-03 | 2016-09-21 | 梁冬 | Waterproof and ultraviolet resistant paint for building exterior walls |
| CN105949921A (en) * | 2016-05-03 | 2016-09-21 | 梁冬 | Modified epoxy acrylate heatproof and ultraviolet resistant paint for building exterior walls |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108841260A (en) * | 2018-07-13 | 2018-11-20 | 芜湖多辉建设有限公司 | A kind of modified interior wall coating of environment-friendly insulating |
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Application publication date: 20171107 |
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