CN107324917A - Biomass graphene trace element water-soluble fertilizer - Google Patents

Biomass graphene trace element water-soluble fertilizer Download PDF

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Publication number
CN107324917A
CN107324917A CN201710705397.8A CN201710705397A CN107324917A CN 107324917 A CN107324917 A CN 107324917A CN 201710705397 A CN201710705397 A CN 201710705397A CN 107324917 A CN107324917 A CN 107324917A
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CN
China
Prior art keywords
soluble fertilizer
graphene
water
trace element
element water
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CN201710705397.8A
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Chinese (zh)
Inventor
孟钖
王丹
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Shandong Promise Biotechnology Co Ltd
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Shandong Promise Biotechnology Co Ltd
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Priority to CN201710705397.8A priority Critical patent/CN107324917A/en
Publication of CN107324917A publication Critical patent/CN107324917A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05DINORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D9/00Other inorganic fertilisers
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00Fertilisers characterised by their form
    • C05G5/20Liquid fertilisers
    • C05G5/23Solutions

Abstract

The present invention relates to a kind of biomass graphene trace element water-soluble fertilizer, the water-soluble fertilizer is prepared from by following raw materials in parts by weight number ratio:210 310 parts of manganese sulfate monohydrate;350 450 parts of monohydrate zinc sulphate;50 150 parts of ferrous sulfate monohydrate;25 75 parts of copper sulphate;1 40 parts of graphene;1,700 1800 parts of water.The present invention extracts the oxide of biomass graphene by raw material of straw, crop self-healing ability can be activated, realize the self-regeneration mechanism of crop, the performance such as antibacterial, antibacterial is notable, microcirculation can be promoted, have remarkable result in terms of suppressing bacterium, fungi, improving crop quality, promotion crop yield, with curative booster action, with remodeling immunity function, recover effect of crop health.

Description

Biomass graphene trace element water-soluble fertilizer
Technical field
The present invention relates to fertilizer field, and in particular to a kind of biomass graphene trace element water-soluble fertilizer.
Background technology
Fertilizer is the direct or indirect donor of nutrient needed for plant growth, and with improved soil performance, produce are made in raising The function of amount and quality.But common fertilizer can not be dissolved completely in water, it is impossible to directly absorbed by the root system of crop and blade face Utilize, effective absorptivity of crop is low, and fertilizer efficiency is slow.Chemical fertilizer largely or excessively is applied, not only causes soil fertility utilization rate low, is supported Point uneven, soil hardening, the problems such as soil microbial community is unbalance, and cause environmental pollution, nutrition accumulation etc. one to be Row environmental problem, the loss that chemical fertilizer is brought in terms of environmental pollution in recent years is up to 100,000,000,000 yuan.
Trace element water-soluble fertilizer, refers to the water-soluble fertilizer containing micronutrient element, contained trace element and other Composition can promptly be dissolved in the water, it is easier to be absorbed by crops, and its absorption rate is of a relatively high, coordinate macroelement Fertilizer application, it is possible to resolve the nutritional need of high-yield crop fast growing period.Tied especially in industrialized agriculture with microspray irrigation, drip irrigation etc. Close and use, with water generation fertilizer, realize water-fertilizer integral, reach that water-saving saves the efficiency of fertile saving of labor.In water resource increasingly today in short supply, Turn into one of growth of agricultural efficiency, measure of increasing peasant income using water-soluble fertilizer.
As the infringement that bacterium, fungi, mould and virus etc. are easily received in growth course, widely using for agricultural chemicals easily makes Crop autoimmunity is reduced, and pollution environment.It is very fast that existing trace element water-soluble fertilizer has nutrients release;It can not carry High crop immunity, the problems such as needing spraying pesticide.
The content of the invention
It is an object of the invention to provide a kind of biomass graphene trace element water-soluble fertilizer, crop self-healing energy can be activated Power, realizes the self-regeneration mechanism of crop, and with curative booster action, the performance such as antibacterial, antibacterial significantly, is exempted from remodeling Epidemic disease function, recovers effect of crop health.
The purpose of the present invention is to be achieved through the following technical solutions:
A kind of biomass graphene trace element water-soluble fertilizer, the water-soluble fertilizer is by following raw materials in parts by weight number ratio It is prepared from:
In preferred embodiments, the water-soluble fertilizer is prepared from by following raw materials in parts by weight number ratio:
A kind of compounding method of the trace element water-soluble fertilizer of graphene containing biomass, is carried out as steps described below:
A, the manganese sulfate monohydrate of formula ratio, monohydrate zinc sulphate, ferrous sulfate monohydrate, copper sulphate, graphene be respectively put into Crushed in pulverizer, be crushed to and be not less than 300 mesh;
B, the water for adding into retort formula ratio, are heated to after 38 degree adding the obtained manganese sulfate monohydrate powder of step A And stir, mixing speed is 150-200rpm, and mixing time is 50-55min;
C, mixing speed is transferred to 300-350rpm, adds the sulfuric acid monohydrate zinc powder that step A obtains and simultaneously stir 30- 35min;
After D, fully dissolving, add the obtained ferrous sulfate monohydrates of step A and stir 30-35min;
After E, fully dissolving, add the obtained copper sulphate powders of step A and stir 50-55min;
After F, fully dissolving, mixing speed is transferred to after 220-260rpm and adds the graphene powder that step A is obtained, and is stirred Mix 55-60min;
G, the removal of impurities after all dissolving, sieving scope are the mesh of 300 mesh -800, then filling, obtain graphene containing biomass Trace element water-soluble fertilizer.
Beneficial effects of the present invention are:
The present invention extracts the oxide of biomass graphene by raw material of straw, can activate crop self-healing ability, real The self-regeneration mechanism of existing crop, the performance such as antibacterial, antibacterial significantly, can promote microcirculation, suppressing bacterium, fungi, improving and make There is remarkable result in terms of article matter, promotion crop yield, with curative booster action, with remodeling immunity function, recover Effect of crop health.
After the present invention is absorbed by plant cell, internal water can be made to produce effectively resonance, biological cell is in Gao Zhen Kinetic energy level, and far infrared heat energy is delivered to each several part in plant, Nutrient Cycle channel is dredged, improves local microcirculation and supports Point, transfer supply Dry matter formation accumulation.
The present invention has extremely strong bacteriostasis antibiosis performance, can activated plant vivo immunization cell, accelerate plant microcirculation, Equilibrium of the plant to a variety of nutrients is promoted to absorb, enhancing metabolism improves vegetable active and vitality, improving quality is disease-resistant Degeneration-resistant, the big fruit of many results, fruit is even, promotes precocity, increases substantially yield.
Embodiment
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, below by the embodiment of the present invention Technical scheme is clearly and completely described, it is clear that described embodiment is a part of embodiment of the invention, rather than entirely The embodiment in portion.Therefore, the detailed description of embodiments of the invention presented below is not intended to limit this claimed hair Bright scope, but it is merely representative of the selected embodiment of the present invention.Based on the embodiment in the present invention, ordinary skill people The every other embodiment that member is obtained under the premise of creative work is not made, belongs to the scope of protection of the invention.Under The present invention is further illustrated in face.
Embodiment 1
A kind of biomass graphene trace element water-soluble fertilizer, it is prepared from by following raw materials in parts by weight number ratio:
A kind of compounding method of the trace element water-soluble fertilizer of graphene containing biomass, is carried out as steps described below:
A, the manganese sulfate monohydrate of formula ratio, monohydrate zinc sulphate, ferrous sulfate monohydrate, copper sulphate, graphene be respectively put into Crushed in pulverizer, be crushed to 400 mesh;
B, the water for adding into retort formula ratio, are heated to after 38 degree adding the obtained manganese sulfate monohydrate powder of step A And stir, mixing speed is 150rpm, and mixing time is 50min;
C, mixing speed is transferred to 300rpm, adds the sulfuric acid monohydrate zinc powder that step A obtains and simultaneously stir 30min;
After D, fully dissolving, add the obtained ferrous sulfate monohydrates of step A and stir 30min;
After E, fully dissolving, add the obtained copper sulphate powders of step A and stir 50min;
After F, fully dissolving, mixing speed is transferred to after 220rpm and adds the graphene powder that step A is obtained, and is stirred 55min;
G, the removal of impurities after all dissolving, sieving scope are 300 mesh, then filling, obtain the micro of the graphene containing biomass Element Water soluble fertilizer.
Embodiment 2
A kind of biomass graphene trace element water-soluble fertilizer, it is prepared from by following raw materials in parts by weight number ratio:
A kind of compounding method of the trace element water-soluble fertilizer of graphene containing biomass, is carried out as steps described below:
A, the manganese sulfate monohydrate of formula ratio, monohydrate zinc sulphate, ferrous sulfate monohydrate, copper sulphate, graphene be respectively put into Crushed in pulverizer, be crushed to 350 mesh;
B, the water for adding into retort formula ratio, are heated to after 38 degree adding the obtained manganese sulfate monohydrate powder of step A And stir, mixing speed is 175rpm, and mixing time is 53min;
C, mixing speed is transferred to 325rpm, adds the sulfuric acid monohydrate zinc powder that step A obtains and simultaneously stir 33min;
After D, fully dissolving, add the obtained ferrous sulfate monohydrates of step A and stir 33min;
After E, fully dissolving, add the obtained copper sulphate powders of step A and stir 53min;
After F, fully dissolving, mixing speed is transferred to after 240rpm and adds the graphene powder that step A is obtained, and is stirred 55min;
G, the removal of impurities after all dissolving, sieving scope are 500 mesh, then filling, obtain the micro of the graphene containing biomass Element Water soluble fertilizer.
Embodiment 3
A kind of biomass graphene trace element water-soluble fertilizer, it is prepared from by following raw materials in parts by weight number ratio:
A kind of compounding method of the trace element water-soluble fertilizer of graphene containing biomass, is carried out as steps described below:
A, the manganese sulfate monohydrate of formula ratio, monohydrate zinc sulphate, ferrous sulfate monohydrate, copper sulphate, graphene be respectively put into Crushed in pulverizer, be crushed to 300 mesh;
B, the water for adding into retort formula ratio, are heated to after 38 degree adding the obtained manganese sulfate monohydrate powder of step A And stir, mixing speed is 200rpm, and mixing time is 55min;
C, mixing speed is transferred to 350rpm, adds the sulfuric acid monohydrate zinc powder that step A obtains and simultaneously stir 35min;
After D, fully dissolving, add the obtained ferrous sulfate monohydrates of step A and stir 35min;
After E, fully dissolving, add the obtained copper sulphate powders of step A and stir 55min;
After F, fully dissolving, mixing speed is transferred to after 260rpm and adds the graphene powder that step A is obtained, and is stirred 60min;
G, the removal of impurities after all dissolving, sieving scope are 800 mesh, then filling, obtain the micro of the graphene containing biomass Element Water soluble fertilizer.
Embodiment 4
September 7 in 2016, Henan Province Kaifeng Lankao County sprays the biomass graphite in embodiment 1 to grape trellis respectively The effect of alkene trace element water-soluble fertilizer carries out on-the-spot investigation examination.Through surveying production, scene is random respectively to take 1.5 square metres, extracts flower It is raw, pluck fruit and weigh, the peanut fresh fruit for spraying biomass graphene trace element water-soluble fertilizer weighs 3.3 jin, and the peanut not sprayed is fresh Fruit weighs 2.6 jin, and fresh fruit contrasts 0.7 jin of volume increase again, and 171.2 jin are increased production by contrasting every mu after 55% folding per mu yield.
September 4 in 2016, Xiang Gou towns Hou Liuwangzhuan villages spray the biomass graphene in embodiment 2 to peanut respectively Trace element water-soluble fertilizer is with other trace element water-soluble fertilizers (by white vitriol, manganese sulfate monohydrate, cupric sulfate pentahydrate, one It is prepared by aqueous ferrous sulfate, chelating agent) carry out survey production.It is live respectively to take 1.6 square metres at random, peanut is extracted, fruit is plucked and weighs, spray life The peanut fresh fruit of the trace element water-soluble fertilizer of material graphene weighs 4.9 jin, by 1123.5 jin of 55% folding per mu yield, sprays other micro- The peanut fresh fruit of secondary element water-soluble fertilizer weighs 4 jin, by 917 jin of 55% folding per mu yield, contrasts every mu and increases production 206.5 jin.
September 7 in 2016, Shangqiu City Suixian County, Henan Province Dong Dianxiang Wanglou villages, the spraying in embodiment 3 respectively to peanut The trace element water-soluble fertilizer of biomass graphene and other trace element water-soluble fertilizers (by white vitriol, manganese sulfate monohydrate, Prepared by cupric sulfate pentahydrate, ferrous sulfate monohydrate, chelating agent).It is live respectively to take 2.3 square metres at random, peanut is extracted, fruit is plucked and weighs, The peanut fresh fruit for spraying biomass graphene trace element water-soluble fertilizer weighs 6.5 jin, sprays other trace element water-soluble fertilizers Peanut fresh fruit weighs 4.5 jin, and fresh fruit contrasts 2 jin of volume increase again, and 290 jin are increased production by contrasting every mu after 50% folding per mu yield.
September 7 in 2016, Shangqiu City Suixian County, Henan Province Dong Dianxiang Wanglou villages, is sprayed in embodiment 1 respectively to capsicum Biomass graphene trace element water-soluble fertilizer is with other trace element water-soluble fertilizers (by white vitriol, manganese sulfate monohydrate, five Prepared by brochanite, ferrous sulfate monohydrate, chelating agent).It is live respectively to take 1.2 square metres at random, capsicum is extracted, fruit is plucked and weighs, spray The capsicum fresh fruit for applying the trace element water-soluble fertilizer of biomass graphene weighs 4.2 jin, sprays other trace element water-soluble fertilizers Capsicum fresh fruit weighs 2.7 jin, and fresh fruit contrasts 1.5 jin of volume increase again, and 208.4 jin are increased production by contrasting every mu after 25% folding per mu yield.
5 mu of capsicum annum fasciculatums have been sprayed in 3 mu of embodiments 2 by September 2 in 2016, Si Mazhen Zhou Gudui villages of Jinxiang County of Shandong Province Biomass graphene trace element water-soluble fertilizer, remaining 2 mu of controls.Scene respectively takes 2.2 square metres at random, plucks fresh green pepper and claims Weight, the capsicum fresh fruit for spraying the trace element water-soluble fertilizer of biomass graphene weighs 9.5 jin, and 2880.2 jin of per mu yield sprays other The capsicum fresh fruit of trace element water-soluble fertilizer weighs 8.6 jin, and 2607.3 jin of per mu yield contrasts every mu of fresh 305.2 jin of green pepper of every mu of volume increase.
August 22 in 2016, big Xieji Zhen Dong the Yellow River village of Juye County, respectively to having sprayed the biomass stone in embodiment 3 Black alkene trace element water-soluble fertilizer is with other trace element water-soluble fertilizers (by white vitriol, manganese sulfate monohydrate, five water sulfuric acid Copper, ferrous sulfate monohydrate, chelating agent prepare) sweet potato carry out survey production.Scene respectively takes 2.4 square metres at random, digs out sweet potato, clearly Reason is clean, and scene is weighed, and the sweet potato fresh fruit for having sprayed the trace element water-soluble fertilizer of biomass graphene weighs 28.6 jin, per mu yield 7948.3 jin, the sweet potato fresh fruit for spraying other trace element water-soluble fertilizers weighs 16.4 jin, and 4557.8 jin of per mu yield contrasts every mu of volume increase 3390.5 jin, and the former potato wedge is big, even, many, commodity potato is more, and potato face is smooth, quality better.
On May 24th, 2017, Dezhou City Shandong Province Xiajin County Lei Ji Zhenkangs temple village, to having sprayed the biology in embodiment 2 The wheat paddock of matter graphene trace element water-soluble fertilizer carries out survey production.Scene respectively takes 1 square, has sprayed biomass graphene micro- The fringe of mu spike number 40.4 ten thousand of secondary element water-soluble fertilizer, grain number per spike 31.4, mass of 1000 kernel is by 42 grams of calculating, theoretical yield 1065.6 Jin, by 905.3 jin of 85% folding per mu yield.The control fringe of field spike number 33.6 ten thousand, grain number per spike 25.4, theoretical yield 716.9 are not sprayed Jin, by 609.4 jin of 85% folding per mu yield, contrasts every mu and increases production 295.9 jin.
Anhui Province Xiao County Yan market town Kong Lou villages, to having sprayed the fertilizer of the biomass graphene trace element water-soluble in embodiment 3 5 mu of wheat paddocks of material carry out survey production.Scene respectively takes 1 square, has sprayed the mu of biomass graphene trace element water-soluble fertilizer The fringe of spike number 43.5 ten thousand, grain number per spike 45.3, mass of 1000 kernel is by 42 grams of calculating, 1655.3 jin of theoretical yield, by 85% folding per mu yield 1407.0 jin.The control fringe of field spike number 33.3 ten thousand, grain number per spike 47.4,1325.8 jin of theoretical yield, by 85% folding mu are not sprayed 1127.0 jin of production, contrasts every mu and increases production 280.0 jin.
Conclusion, according to above-mentioned contrast experiment, can be derived that the content of graphene in embodiment 1-3 gradually increases, and with The content of graphene gradually increases, and its effect of increasing production also gradually increases.
Finally it should be noted that:Above-described embodiments are merely to illustrate the technical scheme, rather than to it Limitation;Although the present invention is described in detail with reference to the foregoing embodiments, it will be understood by those within the art that: It can still modify to the technical scheme described in previous embodiment, or which part or all technical characteristic are entered Row equivalent substitution;And these modifications or substitutions, the essence of appropriate technical solution is departed from various embodiments of the present invention skill.

Claims (3)

1. a kind of biomass graphene trace element water-soluble fertilizer, it is characterised in that the water-soluble fertilizer be by following raw materials by Ratio of weight and number is prepared from:
2. biomass graphene trace element water-soluble fertilizer according to claim 1, it is characterised in that the water-soluble fertilizer It is to be prepared from by following raw materials in parts by weight number ratio:
3. a kind of compounding method of the trace element water-soluble fertilizer of the graphene containing biomass described in claim 1 or 2, its feature exists In carrying out as steps described below:
A, the manganese sulfate monohydrate of formula ratio, monohydrate zinc sulphate, ferrous sulfate monohydrate, copper sulphate, graphene be respectively put into crushing Crushed in machine, be crushed to and be not less than 300 mesh;
B, the water for adding into retort formula ratio, are heated to adding the obtained manganese sulfate monohydrate powder of step A after 38 degree and stir Mix, mixing speed is 150-200rpm, mixing time is 50-55min;
C, mixing speed is transferred to 300-350rpm, adds the sulfuric acid monohydrate zinc powder that step A obtains and simultaneously stir 30-35min;
After D, fully dissolving, add the obtained ferrous sulfate monohydrates of step A and stir 30-35min;
After E, fully dissolving, add the obtained copper sulphate powders of step A and stir 50-55min;
After F, fully dissolving, mixing speed is transferred to after 220-260rpm and adds the graphene powder that step A is obtained, and is stirred 55-60min;
G, the removal of impurities after all dissolving, sieving scope are the mesh of 300 mesh -800, then filling, obtain the micro- of the graphene containing biomass Secondary element Water soluble fertilizer.
CN201710705397.8A 2017-08-17 2017-08-17 Biomass graphene trace element water-soluble fertilizer Pending CN107324917A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108410471A (en) * 2018-01-16 2018-08-17 湖南国盛石墨科技有限公司 A kind of graphene soil-repairing agent
CN112079672A (en) * 2020-08-24 2020-12-15 广西清鹿新材料科技有限责任公司 Application of graphene aqueous dispersion in farmland water retention, fertilizer retention and bacteriostasis

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106380301A (en) * 2016-08-31 2017-02-08 罗城仫佬族自治县宝玉制丝有限责任公司 Fruit trace element-containing water soluble fertilizer
CN106577644A (en) * 2016-11-25 2017-04-26 广西田园生化股份有限公司 Medical fertilizer containing graphene nano material and preparation method of medical fertilizer
CN106747954A (en) * 2016-11-25 2017-05-31 广西田园生化股份有限公司 A kind of foliar fertilizer of graphene-containing nano material
CN106986707A (en) * 2017-05-16 2017-07-28 东北农业大学 A kind of liquid level fertilizer and preparation method containing modified graphene oxide

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106380301A (en) * 2016-08-31 2017-02-08 罗城仫佬族自治县宝玉制丝有限责任公司 Fruit trace element-containing water soluble fertilizer
CN106577644A (en) * 2016-11-25 2017-04-26 广西田园生化股份有限公司 Medical fertilizer containing graphene nano material and preparation method of medical fertilizer
CN106747954A (en) * 2016-11-25 2017-05-31 广西田园生化股份有限公司 A kind of foliar fertilizer of graphene-containing nano material
CN106986707A (en) * 2017-05-16 2017-07-28 东北农业大学 A kind of liquid level fertilizer and preparation method containing modified graphene oxide

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108410471A (en) * 2018-01-16 2018-08-17 湖南国盛石墨科技有限公司 A kind of graphene soil-repairing agent
CN112079672A (en) * 2020-08-24 2020-12-15 广西清鹿新材料科技有限责任公司 Application of graphene aqueous dispersion in farmland water retention, fertilizer retention and bacteriostasis

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Application publication date: 20171107