CN107321119A - A kind of liquid waste incineration flue gas purifying equipment - Google Patents

A kind of liquid waste incineration flue gas purifying equipment Download PDF

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Publication number
CN107321119A
CN107321119A CN201710728348.6A CN201710728348A CN107321119A CN 107321119 A CN107321119 A CN 107321119A CN 201710728348 A CN201710728348 A CN 201710728348A CN 107321119 A CN107321119 A CN 107321119A
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CN
China
Prior art keywords
flue gas
air
ceramic
gas
temperature
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Pending
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CN201710728348.6A
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Chinese (zh)
Inventor
张峰
仲兆祥
许志龙
韩峰
魏巍
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Jiangsu Jiulang High-Tech Co Ltd
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Jiangsu Jiulang High-Tech Co Ltd
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Priority to CN201710728348.6A priority Critical patent/CN107321119A/en
Publication of CN107321119A publication Critical patent/CN107321119A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D50/00Combinations of methods or devices for separating particles from gases or vapours
    • B01D50/20Combinations of devices covered by groups B01D45/00 and B01D46/00

Abstract

The present invention provides a kind of liquid waste incineration flue gas purifying equipment, mainly including gas mixer, cyclone dust collectors, ceramic membrane integrated filter, Pulse anti-blow device and air-purifying chamber.High-temperature flue gas and air are subjected to hybrid cooling in gas mixer, the solid salt particles in high-temperature flue gas are separated out.Gaseous mixture containing salt particle dust first passes through cyclone dust collectors and removes a part of particle, and another part then enters ceramic film dust-remover, carries out secondary separation purification.Present device compact conformation, dedusting precision is high, and high temperature resistant, acid and alkali-resistance, service life are long, can effectively prevent salt in the adhesion of equipment surface, to have very strong applicability to organic waste liquid burning gas cleaning, it can also be used to the processing of other high-temperature flue gas purifications.

Description

A kind of liquid waste incineration flue gas purifying equipment
Technical field
The present invention relates to a kind of liquid waste incineration flue gas purifying equipment, more particularly to it is a kind of available for the net of high temperature saliferous flue gas Change equipment, the equipment can also be used for the purified treatment of the high-temperature flue gas such as kiln, catalyst recovery.
Background technology
Liquid waste incineration is a kind of effective method of current processing industrial wastes, is had in numerous industrial process extensive Using.The gas cleaning process that liquid waste incineration is produced mainly have of both problem, one is that heat in high-temperature flue gas needs back Receive and utilize;Two be the recovery of salt needs or removal in flue gas, makes flue gas qualified discharge.It is especially high during liquid waste incineration In the combustion process of bisulfate waste liquor, heat exchange equipment inwall is easily sticked in the salt particle of molten condition, pipe on the one hand can be caused The blocking and corrosion in road, on the other hand can cause the heated inequality of boiler, there is the danger of explosion.Although can be gone by wet sprinkling Except the particulate matter in flue gas, but the waste water formation secondary pollution produced needs to discharge after after-treatment, to being returned with height The salt of value is received, difficulty is extracted also higher.Other wet sprinkling can not be in recovered flue gas heat, cause the waste of the energy.
Recovered flue gas heat can both have been made full use of by being thus badly in need of one kind, again can salt effectively in recovered flue gas, reach flue gas Mark the efficient waste liquid flue gases purification of discharge.
Bag-type dusting especially membrane bag filter dedusting has very high efficiency of dust collection, to the removal that average grain diameter is 2.5 μm Rate can reach more than 99.99%.But it is passed through the flue-gas temperature after air cooling and still reaches 600 ~ 700 degree, ordinary filter can not be met Heatproof requirement.If will be dropped to flue-gas temperature below 260 degree of the scope of application of filter bag by heat exchanger, the salt of precipitation can not can be kept away The absorption exempted from causes a hidden trouble in heat exchanger inwall, is unfavorable for the utilization of heat.
CN105169815A discloses a kind of dust removal method of the high-temperature flue gas of high salt bearing liquid wastes incinerator, first passes through pipeline Air cooled flue gas is passed through, then realizes by inertial dust separator the separation of solid particle salt and flue gas, it is to avoid salt particle is in heat exchange Boiler surfaces are bonded.But cooled down by simple pipeline blowing air, its mixing efficiency is unfavorable for the precipitation of salt particle than relatively low. And inertial dust separator efficiency of dust collection is relatively low, having considerable amount of particle can not still be removed.
CN101520182A discloses a kind of full automatic liquid waste incinerator, and flue gas is utilized using the heat exchanger of secondary combustion chamber Waste heat, and water-cooled deduster removal part fine particle therein is first passed through, removing remaining particle by sack cleaner. Its process route is complicated, and the flue gas with particulate matter has had salt absorption in inwall when by heat exchanger cooling.In addition, water cooling The waste water that deduster is produced can cause secondary pollution problem, in addition it is also necessary to carry out purified treatment to waste water.It is wet by the flue gas of washing Degree is larger, is unfavorable for follow-up sack cleaner operation, easily causes blocking.
Because ceramic membrane is that inorganic particle sinters form at high temperature, it is possible to more than 1000 DEG C of heatproof, thus it makes It can be greatly improved with the life-span.Further, since ceramic membrane has unsymmetric structure, it can solve to breathe freely using surface filtration technology The problem of amount can not get both with dust rejection, makes equipment have the advantages that gas treatment amount is big and dust rejection is high.Ceramics Film is more and more applied in the purification of high-temperature gas, but for the liquid waste incineration flue gas especially flue gas containing fuse salt Processing has not been reported.
CN206103562 U disclose a kind of high-temperature smoke purifier, can not be handled available for common organic filter bag High-temperature flue gas field.But the flue gas device is without flue gas refrigerating function, it is impossible to be applied to during liquid waste incineration.In addition, The device is simple filtration system, the occasion larger to dust concentration, and easily causing to build bridge blocks, and causes filtration resistance anxious Play rises.
The content of the invention
Present device is provided with cyclone dust collectors below the integrated filtering area of ceramic membrane, on the one hand available for high-temperature flue gas It is that the salt particle of molten condition separates out old solid granulates with being sufficiently mixed for air;On the other hand, it can remove what is separated out in flue gas Part salt particle, reduces the dust granules concentration into ceramic membrane filter area, is conducive to reducing operation pressure and service life, Reach double effectses.
The present invention provides a kind of liquid waste incineration flue gas purifying equipment, and the purpose is to made not causing ventilation inwall to adsorb salt In the case of clog, the heat in flue gas is made full use of, salt that can also be effectively in recovered flue gas, and do not result in any Secondary pollution.The use of high temperature resistant and corrosion resistant ceramic membrane is filter material, to high-temperature flue gas and with good applicability, ceramics Film has the double dominant of high Air permenbility and high filtering precision.
Another free-revving engine of the present invention is fully to combine heat exchange cooling, dust removal process, on the one hand enhances and exchanged heat Journey, by providing the mixed zone of air-flow, makes the salt in flue gas effectively separate out.Another aspect cyclone structure makes the salt of generation first be gone Remove.Compact equipment, forms the efficient coupling of plurality of devices, significantly improves the operational efficiency of equipment.
Technical scheme is as follows:
A kind of liquid waste incineration flue gas purifying equipment, including gas mixer, cyclone dust collectors, ceramic membrane integrated filter, pulse Back-blowing device and air-purifying chamber;There are high-temperature flue gas import and air intlet in gas mixer side;Cyclone dust collectors and ceramic membrane collection It is connected respectively with the two ends of gas mixer into filter, is above cyclone dust collectors, gas mixer below gas mixer For ceramic membrane integrated filter;Ceramic membrane integrated filter air inlet is located at below the high-temperature flue gas import of gas mixer, pottery The air-flow rate of climb is 1.5 ~ 10m/s in porcelain film integrated filter;Air-purifying chamber is located at the top of ceramic membrane integrated filter, air-purifying chamber Side wall, which is provided with gas outlet, air-purifying chamber, is provided with Pulse anti-blow device.
Air inlet of the present invention carries air inlet valve, two imports of high-temperature flue gas import and air intlet and gas The housing of blender is oriented in a tangential direction, and high-temperature flue gas import and air intlet are located at same level height, are between two imports To distribution or angled distribution, angle is 45 ~ 180 degree;Gas mixer bottom carries temperature sensor, after detection mixing The temperature of flue gas.
Cyclone dust collectors are different according to the concentration of dust granules, particle diameter, and cyclone dust collectors sidewall slope angle is adjusted to 60 ~ 80 degree, cinder-discharging port is arranged at cyclone dust collectors bottom.
A diameter of 20 ~ the 150mm of ceramic-film tube of ceramic membrane integrated filter, length is 300 ~ 3000mm, and average pore size is 50nm~20μm;Ceramic-film tube arrangement mode is that concentric circles is arranged or triangular pitch or rectanglar arrangement, ceramic-film tube center spacing For 1.5 ~ 2.5 times of membrane tube diameter;Ceramic-film tube is sealed using high-temperature seal ring in ceramic membrane integrated filter.
High-temperature seal ring material is asbestos seal ring, carbon seal ring, ceramic fibre sealing ring or stainless steel felt seal circle.
Pulse anti-blow device is made up of pulse valve and injection tube, and the injection mouth of pipe is provided with injection mouth, injection mouth and ceramic-film tube Center it is relative, injection mouth lower end is from being 10 ~ 30cm with a distance from ceramic-film tube top.Pulse jet pressure be 0.3 ~ 0.8MPa。
Beneficial effects of the present invention:
1)Gas mixer, cyclone dust collectors and ceramic membrane integrated filter are coupled in an equipment by the present invention, on the one hand Gas mixing process is enhanced, is conducive to the precipitation of fuse salt;On the other hand the space of equipment is reduced, makes multiple processes effective Coupling.
2)Liquid waste incineration process gas cleaning is directed in the present invention, it can also be used to the high-temperature flue gas purification mistake such as kiln, boiler Journey, filter element uses resistant to elevated temperatures ceramic membrane, high with dedusting precision, and intensity height, high temperature resistant, acid and alkali-resistance, service life are long Advantage.
Brief description of the drawings
Fig. 1 is liquid waste incineration flue gas purifying equipment figure, wherein:1- high-temperature flue gas air inlets;2- Pulse anti-blow devices;3- is net Air chamber;4- ceramic membrane integrated filters;5- air intlets;6- air inlet valves, 7- ceramic membrane integrated filter air inlets;8- Temperature sensor;9- cinder-discharging ports;10- cyclone dust collectors;11- gas mixers.
Embodiment
The present invention is done with reference to embodiment and further explained.The following example is merely to illustrate the present invention, but It is not used to limit the practical range of the present invention.
A kind of liquid waste incineration flue gas purifying equipment, including gas mixer 11, cyclone dust collectors 10, the integrated filtering of ceramic membrane Device 4, Pulse anti-blow device 2 and air-purifying chamber 3;There are high-temperature flue gas import 1 and air intlet 5 in the side of gas mixer 11;Whirlwind is removed The two ends of dirt device 10 and ceramic membrane integrated filter 4 respectively with gas mixer 11 are connected, and the lower section of gas mixer 11 is whirlwind Deduster 10, the top of gas mixer 11 is ceramic membrane integrated filter 4;Ceramic membrane integrated filter air inlet 7 is located at gas The air-flow rate of climb is 1.5 ~ 10m/s in the lower section of high-temperature flue gas import 1 of blender 11, ceramic membrane integrated filter 4;Air-purifying chamber 3 are located at the top of ceramic membrane integrated filter 4, and the side wall of air-purifying chamber 3, which is provided with gas outlet, air-purifying chamber 3, is provided with Pulse anti-blow device 2.
Air inlet 5 of the present invention carry air inlet valve 6,5 two imports of high-temperature flue gas import 1 and air intlet with The housing of gas mixer 11 is oriented in a tangential direction, and high-temperature flue gas import 1 and air intlet 5 are located at same level height, and two are entered It is to distribution or angled distribution, angle is 45 ~ 180 degree between mouthful;The bottom of gas mixer 11 carries temperature sensor 8, The temperature of flue gas after detection mixing.
Concentration, particle diameter difference of the cyclone dust collectors 10 according to dust granules, the adjustment of the sidewall slope angle of cyclone dust collectors 10 For 60 ~ 80 degree, cinder-discharging port 9 is arranged at the bottom of cyclone dust collectors 10.
A diameter of 20 ~ the 150mm of ceramic-film tube of ceramic membrane integrated filter 4, length is 300 ~ 3000mm, and average pore size is 50nm~20μm;Ceramic-film tube arrangement mode is that concentric circles is arranged or triangular pitch or rectanglar arrangement, ceramic-film tube center spacing For 1.5 ~ 2.5 times of membrane tube diameter;Ceramic-film tube is sealed using high-temperature seal ring in ceramic membrane integrated filter 4.
High-temperature seal ring material is asbestos seal ring, carbon seal ring, ceramic fibre sealing ring or stainless steel felt seal circle. Pulse jet pressure is 0.3 ~ 0.8MPa.
The course of work of this liquid waste incineration flue gas purifying equipment is as follows:Under suction function, the height containing molten condition salt Warm flue gas enters gas mixer 11 from high-temperature flue gas air inlet 1;Air enters gas mixer 11, two strands from air intlet 5 Air-flow is sufficiently mixed in gas mixer 11, adjusts the aperture of air inlet valve 6 to control the temperature of mixed gas, high temperature Flue-gas temperature declines, the temperature of flue gas after the detection mixing of temperature sensor 8.Molten condition therein is salted out as solid granulates Salt, two bursts of air-flow mixing are moved downward, and can be removed by salt in harge granules when lower section cyclone dust collectors 10, from cinder-discharging port 9 It is discharged.After cyclone dust collectors 10, mixed air-flow is mingled with not removed salt particle, from the integrated filtering of ceramic membrane Device air inlet 7 enters ceramic membrane integrated filter 4, the ceramic-film tube dedusting of gas permeation loose structure, the flue gas after purification from Air-purifying chamber 3 is discharged.And salt particle is trapped within ceramic-film tube surface, acted on by the back draught of Pulse anti-blow device 2, ceramics The salt particle dust on membrane tube surface, which is peeled off, to be removed, and falls into lower section cyclone dust collectors 10, the particle removed with cyclone dust collectors 10 It is discharged together from cinder-discharging port 9.
Embodiment 1
The present embodiment is 20mm using external diameter, and a length of 300mm, average pore size are 50nm aluminium oxide ceramics membrane tube, high-temperature flue gas Into 45 degree of angular distributions between 5 two imports of import 1 and air intlet;Air inlet valve 6 is opened, high-temperature flue-gas is adjusted To 500 DEG C, the side inclination angle of cyclone dust collectors 10 is 75 degree, and the feed rate of the lower end of ceramic membrane integrated filter 4 is 1.5m/s, Aluminium oxide ceramics membrane tube makees sealing ring using stainless steel felt.Aluminium oxide ceramics membrane tube is arranged by triangle, and membrane tube centre distance is 50mm, equipment resistance is less than 800Pa, and efficiency of dust collection reaches 99.95%.
Embodiment 2
The present embodiment is 60mm using external diameter, and a length of 1500mm, average pore size are 5 μm of silicon carbide ceramics membrane tube, high-temperature flue gas It is distributed between 5 two imports of import 1 and air intlet into an angle of 90 degrees degree;Air inlet valve 6 is opened, high-temperature flue-gas is adjusted To 700 DEG C, the side inclination angle of cyclone dust collectors 10 is 60 degree, and the feed rate of the lower end of ceramic membrane integrated filter 4 is 5m/s, carbon SiClx ceramic-film tube makees sealing ring using ceramic fibre.Silicon carbide ceramic membrane is arranged by circular concentric, and membrane tube centre distance is 90mm.Equipment resistance is less than 1500Pa.Dust rejection is more than 99.99%.
Embodiment 3
The present embodiment is 150mm using external diameter, and a length of 3000mm, average pore size are 20 μm of ceramic fibre membrane tube, high-temperature flue gas Into 180 degree angular distribution between 5 two imports of import 1 and air intlet;Air intlet valve 6 is opened, high-temperature flue gas temperature is adjusted Spend for 500 DEG C.The side inclination angle of cyclone dust collectors 10 is 80 degree, and the feed rate of the lower end of ceramic membrane integrated filter 4 is 10m/ S, silicon carbide ceramics membrane tube makees sealing ring using asbestos seal ring.Ceramic membrane integrated filter 4 presses rectanglar arrangement, ceramic fibre film Centre distance is 230mm.Equipment resistance is less than 3000Pa, and dust rejection is more than 99.9%.

Claims (6)

1. a kind of liquid waste incineration flue gas purifying equipment, it is characterised in that including gas mixer(11), cyclone dust collectors(10)、 Ceramic membrane integrated filter(4), Pulse anti-blow device(2)And air-purifying chamber(3);Gas mixer(11)Side has high-temperature flue gas to enter Mouthful(1)And air intlet(5);Cyclone dust collectors(10)With ceramic membrane integrated filter(4)Respectively with gas mixer(11)'s Two ends are connected, gas mixer(11)Lower section is cyclone dust collectors(10), gas mixer(11)Top is the integrated mistake of ceramic membrane Filter(4);Ceramic membrane integrated filter air inlet(7)Positioned at gas mixer(11)High-temperature flue gas import(1)Lower section, ceramics Film integrated filter(4)The middle air-flow rate of climb is 1.5 ~ 10m/s;Air-purifying chamber(3)Positioned at ceramic membrane integrated filter(4)Top Portion, air-purifying chamber(3)Side wall is provided with gas outlet, air-purifying chamber(3)It is interior to be provided with Pulse anti-blow device(2).
2. a kind of liquid waste incineration flue gas purifying equipment according to claim 1, it is characterised in that air intlet(5)Band is free Gas air intake valve(6), high-temperature flue gas import(1)And air intlet(5)Two imports and gas mixer(11)Housing into cutting Line direction, high-temperature flue gas import(1)And air intlet(5)Positioned at same level height, be between two imports to distribution or Angled distribution, angle is 45 ~ 180 degree;Gas mixer(11)Bottom carries temperature sensor(8), cigarette after detection mixing The temperature of gas.
3. a kind of liquid waste incineration flue gas purifying equipment according to claim 1, it is characterised in that according to the dense of dust granules Degree, particle diameter are different, cyclone dust collectors(10)Sidewall slope angle is adjusted to 60 ~ 80 degree, cyclone dust collectors(10)Unload ash in bottom Mouthful(9).
4. a kind of liquid waste incineration flue gas purifying equipment according to claim 1, it is characterised in that ceramic membrane integrated filter (4)The a diameter of 20 ~ 150mm of ceramic-film tube, length be 300 ~ 3000mm, average pore size be 50nm ~ 20 μm;Ceramic-film tube is arranged Mode is that concentric circles is arranged or triangular pitch or rectanglar arrangement, and ceramic-film tube center spacing is 1.5 ~ 2.5 times of membrane tube diameter; Ceramic membrane integrated filter(4)Middle ceramic-film tube is sealed using high-temperature seal ring.
5. a kind of liquid waste incineration flue gas purifying equipment according to claim 4, it is characterised in that high-temperature seal ring material is stone Minuteness seal, carbon seal ring, ceramic fibre sealing ring or stainless steel felt seal circle.
6. a kind of liquid waste incineration flue gas purifying equipment according to claim 1, it is characterised in that Pulse anti-blow device(2)By Pulse valve and injection tube composition, injection tube are horizontally placed in air-purifying chamber, and injection tube side wall is provided with injection mouth, injection mouth and ceramics The center of membrane tube is relative, and injection mouth lower end is from being 10 ~ 30cm with a distance from ceramic-film tube top.
CN201710728348.6A 2017-08-23 2017-08-23 A kind of liquid waste incineration flue gas purifying equipment Pending CN107321119A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107648975A (en) * 2017-11-20 2018-02-02 泰安中意重型工业设备有限公司 A kind of dust removal method and device of dusty gas minimum discharge
CN108489283A (en) * 2018-03-09 2018-09-04 南京工业大学 A kind of system and method for the cooling high-temperature fume waste heat recovery containing liquid ash
CN113144787A (en) * 2021-02-23 2021-07-23 山东金城晖瑞环保科技有限公司 Method for removing dust of high-temperature salt-containing flue gas by using ceramic film dust remover
CN113877348A (en) * 2021-11-01 2022-01-04 南京工业大学 Cyclone separation and steel-ceramic composite flat membrane module high-temperature dust removal integrated device

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Publication number Priority date Publication date Assignee Title
CN103706213A (en) * 2013-12-23 2014-04-09 科林环保装备股份有限公司 Cyclone bag dust collector device
CN103983120A (en) * 2014-05-23 2014-08-13 北京首钢国际工程技术有限公司 Bonding preventing method of smoke system of rotary hearth furnace process for treating metallurgical zinc-bearing dust
CN105169815A (en) * 2015-09-06 2015-12-23 中国石油集团东北炼化工程有限公司吉林设计院 Method for dedusting high temperature flue gas of high-salt waste liquid incinerator
CN106369622A (en) * 2016-08-27 2017-02-01 中国葛洲坝集团水泥有限公司 Bypass exhaust device and treatment method for cooperative household refuse treatment of cement kiln
CN207169346U (en) * 2017-08-23 2018-04-03 江苏久朗高科技股份有限公司 A kind of liquid waste incineration flue gas purifying equipment

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103706213A (en) * 2013-12-23 2014-04-09 科林环保装备股份有限公司 Cyclone bag dust collector device
CN103983120A (en) * 2014-05-23 2014-08-13 北京首钢国际工程技术有限公司 Bonding preventing method of smoke system of rotary hearth furnace process for treating metallurgical zinc-bearing dust
CN105169815A (en) * 2015-09-06 2015-12-23 中国石油集团东北炼化工程有限公司吉林设计院 Method for dedusting high temperature flue gas of high-salt waste liquid incinerator
CN106369622A (en) * 2016-08-27 2017-02-01 中国葛洲坝集团水泥有限公司 Bypass exhaust device and treatment method for cooperative household refuse treatment of cement kiln
CN207169346U (en) * 2017-08-23 2018-04-03 江苏久朗高科技股份有限公司 A kind of liquid waste incineration flue gas purifying equipment

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107648975A (en) * 2017-11-20 2018-02-02 泰安中意重型工业设备有限公司 A kind of dust removal method and device of dusty gas minimum discharge
CN108489283A (en) * 2018-03-09 2018-09-04 南京工业大学 A kind of system and method for the cooling high-temperature fume waste heat recovery containing liquid ash
CN113144787A (en) * 2021-02-23 2021-07-23 山东金城晖瑞环保科技有限公司 Method for removing dust of high-temperature salt-containing flue gas by using ceramic film dust remover
CN113877348A (en) * 2021-11-01 2022-01-04 南京工业大学 Cyclone separation and steel-ceramic composite flat membrane module high-temperature dust removal integrated device

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Address after: 211800 No. 29 Buyue Road, Pukou Economic Development Zone, Qiaolin Street, Pukou District, Nanjing City, Jiangsu Province

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Application publication date: 20171107