CN107315078A - Cryogenic natural gas concentration detection apparatus - Google Patents

Cryogenic natural gas concentration detection apparatus Download PDF

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Publication number
CN107315078A
CN107315078A CN201610408590.0A CN201610408590A CN107315078A CN 107315078 A CN107315078 A CN 107315078A CN 201610408590 A CN201610408590 A CN 201610408590A CN 107315078 A CN107315078 A CN 107315078A
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CN
China
Prior art keywords
analyzer
natural gas
detection apparatus
cryogenic natural
gas
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CN201610408590.0A
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Chinese (zh)
Inventor
王全国
鲍磊
党文义
韩中枢
凌晓东
武志峰
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China Petroleum and Chemical Corp
Sinopec Qingdao Safety Engineering Institute
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China Petroleum and Chemical Corp
Sinopec Qingdao Safety Engineering Institute
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Priority to CN201610408590.0A priority Critical patent/CN107315078A/en
Publication of CN107315078A publication Critical patent/CN107315078A/en
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/22Fuels; Explosives
    • G01N33/225Gaseous fuels, e.g. natural gas

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Food Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Sampling And Sample Adjustment (AREA)

Abstract

The present invention relates to a kind of cryogenic natural gas concentration detection apparatus, the problem of mainly solving to there is no cryogenic natural gas concentration detection apparatus in the prior art.The present invention is by using a kind of cryogenic natural gas concentration detection apparatus, including sampling unit, guidance unit and data analysis and transmission unit, sampling unit includes upsampling filter, sampling pipe, triple valve and flowmeter, guidance unit includes pressure maintaining valve, core modular components, the sampling mouth of pipe, upsampling filter, triple valve, flowmeter, methane concentration analyzer is sequentially connected with analyzer component, methane concentration analyzer is connected with data analysis with transmission unit respectively with analyzer component, core modular components are connected, and core modular components also with voltage stabilizing valve outlet, gas vent line is connected, the data analysis technical scheme including methane concentration analyzer and analyzer component that is connected with transmission unit preferably solves above mentioned problem, available in cryogenic natural gas Concentration Testing.

Description

Cryogenic natural gas concentration detection apparatus
Technical field
The present invention relates to a kind of cryogenic natural gas concentration detection apparatus.
Background technology
Liquefied natural gas (LNG) is that natural gas is purified, compresses, is cooled to the liquid become after its boiling temperature (- 162 DEG C) Body.As a kind of energy of cleaning, liquefied natural gas is colourless, tasteless, nontoxic and non-corrosiveness, and its volume is about same amount gaseous state day The 1/600 of right air volume.Based on China huge energy breach and environmental protection pressure, in recent years, liquefied natural gas industry is in China Developed rapidly, many liquefaction plants, LNG gas stations, receiving stations etc. have built up and come into operation.
LNG has ultralow temperature and inflammable and explosive dual hazard property, because LNG temperature is extremely low (- 162 DEG C), gas-liquid expansion Than big, LNG, once leaking, a large amount of low temperature methane gas can be volatilized immediately and air forms explosivity during storage Mixture, runs into incendiary source and occurs serious fire explosion.Therefore, to after leakage LNG need take measures suppress its enter one Step diffusion, reduces evaporation rate, it is to avoid cause more serious secondary disaster.Liquefied natural gas main component is methane, is being carried out In the research process that liquefied natural gas diffusion suppresses, in order to study inhibition, it is necessary to the low temperature first of natural gas vaporization Alkane gas concentration is detected.Therefore, design is a kind of can to detect the experimental provision of low temperature concentration of methane gas.
It is general to be sampled using pump suction type and diffusion type at present when detecting Methane in Air concentration, diffusion type sampling The natural gas of 0-10%LEL concentration ranges can only be measured.Natural gas for measuring 0-100v% concentration ranges, typically using pump Suction.But the detection mode for using pump suction type to be evacuated has very high requirement to the explosion-proof performance of instrument, pump suction type methane in addition Concentration detector is generally portable instrument, is not suitable for being placed in the environment of low temperature, can not also work for a long time.
Low temperature concentration of methane gas device of the present invention is mainly used in methane concentration during natural gas vaporization diffusion (0-100v%) is monitored in real time.It can also be used for the Concentration Testing of other low temperature or normal temperature fuel gas.
Currently without the Patents being related in terms of cryogenic natural gas concentration detection apparatus.
The content of the invention
The technical problems to be solved by the invention are the problem of there is no cryogenic natural gas concentration detection apparatus in the prior art, A kind of new cryogenic natural gas concentration detection apparatus is provided.The device has available for excellent in cryogenic natural gas Concentration Testing Point.
To solve the above problems, the technical solution adopted by the present invention is as follows:A kind of cryogenic natural gas concentration detection apparatus, bag Sampling unit, guidance unit and data analysis and transmission unit are included, sampling unit includes upsampling filter, sampling pipe, triple valve And flowmeter, guidance unit include pressure maintaining valve, core modular components, sampling the mouth of pipe, upsampling filter, triple valve, flowmeter, first Alkane concentration analyzer is sequentially connected with analyzer component, and methane concentration analyzer is with analyzer component respectively with data analysis with passing Defeated unit is connected, core modular components are connected, and core modular components are also connected with voltage stabilizing valve outlet, gas vent line, number It is connected according to analysis with transmission unit including methane concentration analyzer and analyzer component, the data of generation pass through 4-20mA's respectively Signal output is given to host computer.
In above-mentioned technical proposal, it is preferable that tested gas is flowed through via the filter of sampling head is directed list after sampling pipe Member brings analyzer into.
In above-mentioned technical proposal, it is preferable that sampling pipe is Teflon material, and triple valve, which can connect sample gas, is used for first The demarcation of alkane concentration analyzer.
In above-mentioned technical proposal, it is preferable that core modular components are to be based on venturi principle, utilize nitrogen or the stream of air Measure the negative pressure produced and testing sample gas be drawn to methane concentration analyzer, after sample gas measure concentration through analyzer and Nitrogen or air are discharged into air together.
In above-mentioned technical proposal, it is preferable that each core modular components has 3 interfaces, one of interface difference It is connected with the outlet side of analyzer, one in 2 interfaces connects the nitrogen discharged via isocon external member and connect respectively in addition Mouthful, remaining interface is respectively connected to gas exhaust piping.
In above-mentioned technical proposal, it is preferable that methane concentration analyzer selects the analysis of 0-100v% (volume fraction) range Instrument, can realize real-time online measuring;Described device sets at least a set of sampling unit.
The technical problems to be solved by the invention are to devise one kind to detect cryogenic natural gas concentration (0-100v%) Experimental provision, the low temperature concentration of methane gas that can be come out by the device to natural gas vaporization detects, specifically The evaporation and diffusion Inhibition test of liquefied natural gas is can be applied to, is studied by detecting the change of methane concentration to liquefied natural gas Inhibition, can be used for other low temperature of real-time online measuring or normal temperature hydrocarbon gas concentration, achieve preferable technology Effect.
Brief description of the drawings
Fig. 1 cryogenic natural gas concentration detection apparatus schematic diagrames.
In Fig. 1, the 1 sampling mouth of pipe, 2 upsampling filters, 3 triple valves, 4 flowmeters, 5 methane concentration analyzers and analyzer group Part, 6 core modular components, 7 nitrogen or air, 8 pressure maintaining valves, 9 sample gases, 10 gas vent lines;11 data analyses are with passing It is defeated.
Below by embodiment, the invention will be further elaborated, but is not limited only to the present embodiment.
Embodiment
【Embodiment 1】
The present invention proposes a kind of device detected applied to low temperature concentration of methane gas, as shown in figure 1, its technical scheme It is as follows:
(1) low temperature concentration of methane gas detection means of the present invention includes three units:Sampling unit, guidance unit and On-line analysis and data transmission unit.
(2) low temperature methane sampling unit of the present invention includes upsampling filter, sampling pipe, the portion such as triple valve and flowmeter It is grouped into;Tested gas is flowed through via the filter of sampling head to be directed unit and brings analyzer into after sampling pipe.Sampling pipe is spy Fluorine dragon material.Triple valve, which can connect sample gas, is used for the demarcation of methane concentration analyzer.
According to the length of sampling pipe and the temperature range of gas concentration analyzer requirement, to avoid cryogenic gas from entering concentration Analyzer damages equipment, it is contemplated that set heating apparatus.
(3) nitrogen or air guidance unit of the present invention includes guiding pressure maintaining valve, core modular components, shunting pipe sleeve Part, gas extraction system and nitrogen cylinder group or air-compressor set into;Guiding core modular components therein are to be based on venturi principle, profit Testing sample gas is drawn to methane concentration analyzer by the negative pressure produced with the flow of nitrogen or air, and sample gas is through analysis Instrument has measured and has been discharged into air together with nitrogen or air after concentration;
Guiding gas is provided by nitrogen cylinder group, if concentration analyzer is antiknock device, the sky that can also be provided with air compressor machine Gas is used as guiding gas.
Each guiding core modular components of the system have 3 interfaces.One of interface goes out with analyzer respectively Gas end is connected, and one in 2 interfaces connects the nitrogen interface discharged via isocon external member, remaining interface respectively in addition It is respectively connected to gas exhaust piping.
(4) data analysis of the present invention includes methane concentration analyzer and analyzer component with transmission unit.Methane is dense The analyzer that analyzer selects 0-100v% ranges is spent, real-time online measuring can be realized;
In-line analyzer and data transmission unit main function are being collected in each position of front end via sampling unit The gas come over by analyzer detect after generate some groups of data respectively, the data of generation are defeated by 4-20mA signal respectively again Go out to be given to host computer.
(5) device of the present invention can set a pipeline to realize the methane concentration measurement of a point, may also set up many Realize that multiple spot methane concentration is measured with pipeline.
(6)CH4The upper end of instrument cabinet is arranged on Deng combustible gas leak alarm instrument, to ensure analyzer in experimentation The safety on periphery.
(7) according to the model and function of gas analyzer, device of the present invention can also be used for the dense of other hydrocarbon gas Degree detection.
Specific measuring method is as follows:
The nitrogen or air 7 that nitrogen cylinder group or air engine are produced enter guidance unit after decompression by the voltage stabilizing of pressure maintaining valve 8 Core modular components 6, gas is flowed after the negative pressure produced filters under test gas 1 by gas piping filter 2 through triple valve 3rd, flowmeter 4 enters methane concentration analyzer 5, methane concentration analyzer 5 measure after methane concentration data are uploaded to it is upper Machine, the gas after measurement is discharged into air with guiding gas.
【Comparative example】
It is pump suction type device to put forward measurement apparatus corresponding with the present invention, if measuring natural gas using pump suction type device Concentration for this patent with respect to having significant limitation.First, pump suction type is unable to direct measurement cryogenic natural gas concentration, it is impossible to Applied to the low temperature environment described in patent of the present invention, otherwise equipment can be caused damage.Second, because natural gas is combustible gas Body, pump suction type device must be explosion-proof instrument, it is necessary to which the equipment that can be applied to flammability hazard place for meeting national regulation is explosion-proof It is required that, investment is thus considerably increased, it is not possessed practical value.3rd, pump suction type methane concentration detector is not suitable for The environment of low temperature is placed in, can not also be worked for a long time.

Claims (6)

1. a kind of cryogenic natural gas concentration detection apparatus, including sampling unit, guidance unit and data analysis and transmission unit, are adopted Sample unit includes upsampling filter, sampling pipe, triple valve and flowmeter, and guidance unit includes pressure maintaining valve, core modular components, adopted The sample mouth of pipe, upsampling filter, triple valve, flowmeter, methane concentration analyzer and analyzer component are sequentially connected, methane concentration point Analyzer is connected with data analysis with transmission unit respectively with analyzer component, core modular components are connected, and core modular components Also it is connected with voltage stabilizing valve outlet, gas vent line, data analysis is connected including methane concentration analyzer with transmission unit with dividing Analyzer component, the data of generation are given to host computer by 4-20mA signal output respectively.
2. cryogenic natural gas concentration detection apparatus according to claim 1, it is characterised in that tested gas is via sampling head Filter, which is flowed through, to be directed unit and brings analyzer into after sampling pipe.
3. cryogenic natural gas concentration detection apparatus according to claim 1, it is characterised in that sampling pipe is Teflon material, three Port valve, which can connect sample gas, is used for the demarcation of methane concentration analyzer.
4. cryogenic natural gas concentration detection apparatus according to claim 1, it is characterised in that core modular components are based on text Testing sample gas is drawn to methane concentration analyzer, sample by principle in mound, the negative pressure produced using the flow of nitrogen or air Product gas is discharged into air after having measured concentration through analyzer together with nitrogen or air.
5. cryogenic natural gas concentration detection apparatus according to claim 1, it is characterised in that each core modular components is total to There are 3 interfaces, one of interface is connected with the outlet side of analyzer respectively, one in 2 interfaces connects warp respectively in addition The nitrogen interface discharged by isocon external member, remaining interface is respectively connected to gas exhaust piping.
6. cryogenic natural gas concentration detection apparatus according to claim 1, it is characterised in that methane concentration analyzer from 0- The analyzer of 100v% ranges, can realize real-time online measuring;Described device sets at least a set of sampling unit.
CN201610408590.0A 2016-06-12 2016-06-12 Cryogenic natural gas concentration detection apparatus Pending CN107315078A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610408590.0A CN107315078A (en) 2016-06-12 2016-06-12 Cryogenic natural gas concentration detection apparatus

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610408590.0A CN107315078A (en) 2016-06-12 2016-06-12 Cryogenic natural gas concentration detection apparatus

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090193884A1 (en) * 2008-02-01 2009-08-06 Pearl Field Services, Llc Mobile vacuum sampling system
CN103472179A (en) * 2013-09-29 2013-12-25 中国寰球工程公司 System for sampling and component analysis of truck loaded finished liquefied natural gas
CN204664883U (en) * 2015-02-05 2015-09-23 北京理工大学 Combustion gas on-line monitoring system in multichannel air sampling type inspection shaft
CN204882516U (en) * 2015-08-19 2015-12-16 上海莱帝科技有限公司 Novel gaseous detecting system of formula of breathing in
CN105158419A (en) * 2015-08-25 2015-12-16 江苏远望仪器有限公司 Pumping type gas sampling monitoring device
CN204882538U (en) * 2015-07-17 2015-12-16 上海国纪电子有限公司 Detection apparatus for combustible gas concentration
CN204989134U (en) * 2015-04-30 2016-01-20 中国石油天然气股份有限公司 Air foam flooding oil output online detection device

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090193884A1 (en) * 2008-02-01 2009-08-06 Pearl Field Services, Llc Mobile vacuum sampling system
CN103472179A (en) * 2013-09-29 2013-12-25 中国寰球工程公司 System for sampling and component analysis of truck loaded finished liquefied natural gas
CN204664883U (en) * 2015-02-05 2015-09-23 北京理工大学 Combustion gas on-line monitoring system in multichannel air sampling type inspection shaft
CN204989134U (en) * 2015-04-30 2016-01-20 中国石油天然气股份有限公司 Air foam flooding oil output online detection device
CN204882538U (en) * 2015-07-17 2015-12-16 上海国纪电子有限公司 Detection apparatus for combustible gas concentration
CN204882516U (en) * 2015-08-19 2015-12-16 上海莱帝科技有限公司 Novel gaseous detecting system of formula of breathing in
CN105158419A (en) * 2015-08-25 2015-12-16 江苏远望仪器有限公司 Pumping type gas sampling monitoring device

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Application publication date: 20171103

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