CN207096165U - Mixed gas concentration on-line measurement device - Google Patents

Mixed gas concentration on-line measurement device Download PDF

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Publication number
CN207096165U
CN207096165U CN201720947826.8U CN201720947826U CN207096165U CN 207096165 U CN207096165 U CN 207096165U CN 201720947826 U CN201720947826 U CN 201720947826U CN 207096165 U CN207096165 U CN 207096165U
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air
mixed gas
air accumulator
gas concentration
measurement device
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CN201720947826.8U
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王迎
李勇
昝元峰
唐月明
郑华
张震
贺艳秋
王鸿韬
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Nuclear Power Institute of China
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Nuclear Power Institute of China
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Abstract

The utility model discloses mixed gas concentration on-line measurement device, the measurement accuracy for solving the problems, such as sensor of the prior art can not ensure.The utility model includes the air extractor being connected under test gas space, the mass spectrograph connected with air extractor (4);The air extractor includes the sample gas collection tube (1) connected with mixed gas under test gas space, the air accumulator (3) connected by air pump (2) with sample gas collection tube (1);The mass spectrograph (4) connects with air accumulator (3).The utility model has safety, carries out the on-line checking of mixed gas concentration in real time, and detection speed is fast, can survey the advantages that component is more.

Description

Mixed gas concentration on-line measurement device
Technical field
It the utility model is related to a kind of measurement apparatus, and in particular to mixed gas concentration on-line measurement device.
Background technology
Nuclear Safety is the most significant problems that nuclear power developing faces, although three generations's nuclear power technology inherent safety is very at present Height, but Fukushima, Japan nuclear accident illustrates that it is quick-fried that Nuclear Safety still suffers from hydrogen under many risks, especially nuclear plant severe accident Fried risk.In pressurized-water reactor nuclear power plant major accident, coolant loss will cause Core uncovering, the zircaloy fuel of heap in-core high temperature With water or vapor violent heat-producing chemical reaction will occur for involucrum, discharge substantial amounts of hydrogen and heat, these hydrogen It will be discharged by primary Ioops pressure boundary cut to containment.After the failure of post incident lower head of pressure vessel, reactor core melting The reaction of thing and concrete and the water RADIATION DECOMPOSITION of heap intracavitary can also produce substantial amounts of hydrogen.Substantial amounts of hydrogen is discharged to safety It after shell, will be mixed with the air in containment, the regional area of high hydrogen concentration formed in the short time, if do not had in containment Corresponding hydrogen management game, then the accumulation of localized hydrogen gas may cause acute combustion or fire, and produce and exceed to containment The temperature load or pressure load of its designed capacity, destroy the integrality of containment, radioactive substance is leaked into environment Cause the serious consequence of radioactive pollution.Therefore, nuclear power station design and operation must there is reliable density of hydrogen to monitor and control Means processed.
For confined space gas concentration measurement, mainly there are two kinds of metering systems at present, one kind is to put analyte sensors In in confined space, working sensor environment is probably high temperature, high pressure, high humidity, and most of measurement of concetrations are used at present Sensor can not reliably work under this adverse circumstances, still be emerged without the product of maturation.Another kind is from safety by gas Extract out in shell, by cooling, being depressured, pre-treatment, the feeding measurement apparatus such as dehumidify measure gas concentration.Compared in confined space Hot and humid environment, the gaseous vapor after cooling and dehumidifying are converted into aqueous water and are removed, and the gas component after processing occurs Significant change, causes measurement result larger error to be present, and measurement accuracy can not ensure.
Utility model content
Technical problem to be solved in the utility model is:The measurement accuracy of sensor of the prior art can not ensure The problem of, and it is an object of the present invention to provide the mixed gas concentration on-line measurement device to solve the above problems.
The utility model is achieved through the following technical solutions:
Mixed gas concentration on-line measurement device, including the air extractor being connected under test gas space, filled with pumping Put the mass spectrograph of connection;The air extractor includes the sample gas collection tube connected with mixed gas under test gas space, passes through The air accumulator that air pump connects with sample gas collection tube;The mass spectrograph connects with air accumulator.
The utility model can carry out the on-line checking of mixed gas concentration safely, in real time by the setting of said structure, And possesses multicomponent gas concentration on-line measurement ability, detection speed is fast, it is more to survey component, to detection environment and gas component Without concrete restriction.And electromagnetic interference will not be produced to test environment, it can stablize under high temperature, high pressure, high humility adverse circumstances Work, thus measurement apparatus of the present utility model can meet the gas concentration measurement under high temperature, high pressure, high humility condition of work It is required that.
Further, the air extractor is more than one, and the mass spectrograph passes through in rotary valve and whole air extractors Air accumulator connects.
By the optimal design-aside of said structure, it is not only only capable of meeting multicomponent gas concentration on-line measurement, and can also Meet the detection of multi-measuring point.Also, it cannot be only used for nuclear power station density of hydrogen on-line checking, it can also be used to need online inspection simultaneously The occasion of multiple gases concentration of component is surveyed, effect is more notable.
In order that the structure of measurement is more accurate, the heating for air accumulator heating and thermal insulation is additionally provided with the air accumulator Thermal insulation cabinet.Connecting line between the air accumulator and under test gas space is disposed as being incubated transfer conduit.
By the setting of said structure, water vapor condensation in gaseous mixture can be effectively prevented, and then avoid water vapor condensation from leading The problem of testing result inaccuracy of cause, make Detection results more accurate.
Further, it is provided with exhaust emission pipe on the mass spectrograph and air accumulator.It is useless by what is set on mass spectrograph Gas discharge tube is advantageous to the gas after being detected in mass spectrograph and discharged, and the setting of exhaust emission pipe, not only only has on air accumulator Beneficial to the discharge of gas in air accumulator, moreover, the setting for passing through exhaust emission pipe, moreover it is possible to use sample gas before air accumulator gas storage Air accumulator is cleaned, effectively avoids other miscellaneous gas from influenceing the degree of accuracy that sample gas concentration detects in air accumulator, preferably improves detection The degree of accuracy.
Further, display storage device is also communicated with the mass spectrograph.The mass spectrograph by remote-transmission module with Show the connection of storage device signal.
Preferably, the sample gas collection tube is stainless steel pipes.
The utility model compared with prior art, has the following advantages and advantages:
1st, the utility model can carry out the on-line checking of mixed gas concentration safely, in real time, and can be in high temperature, height Steady operation under pressure, high humility adverse circumstances, possesses multicomponent gas concentration on-line measurement ability, to detection environment and gas group Divide without concrete restriction, Detection results are quick and precisely;
2nd, the utility model is not only only capable of meeting multicomponent gas concentration on-line measurement, and can also meet the inspection of multi-measuring point Survey;Also, it cannot be only used for nuclear power station density of hydrogen on-line checking, it can also be used to need on-line checking multiple gases component simultaneously The occasion of concentration;
3rd, the utility model is simple in construction, cost is low, significant effect.
Brief description of the drawings
Accompanying drawing described herein is used for providing further understanding the utility model embodiment, forms the one of the application Part, the restriction to the utility model embodiment is not formed.In the accompanying drawings:
Fig. 1 is structural representation of the present utility model.
Mark and corresponding parts title in accompanying drawing:
1- sample gas collection tubes, 2- air pumps, 3- air accumulators, 4-- mass spectrographs, 5- heating and thermal insulation cabinets, 6- exhaust emission pipes.
Embodiment
For the purpose of this utility model, technical scheme and advantage is more clearly understood, with reference to embodiment and accompanying drawing, The utility model is described in further detail, and exemplary embodiment of the present utility model and its explanation are only used for explaining this Utility model, it is not intended as to restriction of the present utility model.
Embodiment 1
Mixed gas concentration on-line measurement device, as shown in figure 1, including the pumping dress being connected under test gas space Put, the mass spectrograph 4 connected with air extractor;The air extractor includes the sample gas connected with mixed gas under test gas space Collection tube 1, the air accumulator 3 connected by air pump 2 with sample gas collection tube 1.It is provided with the mass spectrograph 4 and air accumulator 3 useless Gas discharge tube 6.The quantity of the air extractor is arranged to one in the present embodiment.
The specific work process of the present embodiment is as follows:
(1) the sample gas collection tube 1 of front end uses 1/4 inch of stainless steel pipes, and one end is built under test gas space, another End is connected with air accumulator 3, and air pump 2 is set on the pipeline between air accumulator 3 and under test gas space, when detection starts, starts gas Pump 2, sample gas enter in air accumulator 3 by the road;
(2) air accumulator 3 is connected with exhaust emission pipe 6, and air accumulator is cleaned 15 seconds using sample gas;
(3) close air accumulator 3 to export, after pressure inside the tank rises to 0.15MPa, air pump 2 is closed, air accumulator 3 and mass spectrum Instrument 4 connects, and sample gas obtains testing result after mass spectrograph 4 carries out analysis detection;
(4) sample gas after the completion of detecting in mass spectrograph 4 and air accumulator 3 drains into air by exhaust emission pipe 6.
Embodiment 2
The present embodiment and the difference of embodiment 1 are that the quantity that the present embodiment optimizes air extractor is set, specific to set For:In the present embodiment, the air extractor is two or more, and the mass spectrograph 4 is connected by rotary valve with whole air extractors.
The specific work process of the present embodiment is as follows:
(1) the sample gas collection tube 1 of air extractor front end uses 1/4 inch of stainless steel pipes, and one end is built under test gas Space, the other end connect with air accumulator 3, air pump 2 are set on the pipeline between air accumulator 3 and under test gas space, detection starts When, booster air pump 2, sample gas enters in air accumulator 3 by the road;
(2) air accumulator 3 is connected with exhaust emission pipe 6, and air accumulator is cleaned 15 seconds using sample gas;
(3) close air accumulator 3 to export, after pressure inside the tank rises to 0.15MPa, air pump 2 is closed, air accumulator 3 and mass spectrum Rotary valve connection on instrument 4, the rotated valve of sample gas, which sequentially enters, carries out analysis detection in mass spectrograph 4, rotated by controlling Valve, mass spectrograph 4 can be achieved and connected from different air accumulators 3, complete multiple different measuring points gas concentration detections;
(4) sample gas after the completion of detecting in mass spectrograph 4 and air accumulator 3 drains into air by exhaust emission pipe 6.
Embodiment 3
The present embodiment and the difference of embodiment 1 or 2 are that the present embodiment optimizes the structure setting of air extractor, specifically It is arranged to:
The heating and thermal insulation cabinet 5 for the heating and thermal insulation of air accumulator 3 is additionally provided with the air accumulator 3.The air accumulator 3 is with treating The connecting line surveyed between the gas compartment is disposed as being incubated transfer conduit.
By the setting of said structure, it can effectively reach the effect of insulation, prevent water vapor condensation in sample gas, make detection Effect is more accurate.
Embodiment 4
The present embodiment is to increase a display storage device on the basis of embodiment 1 or 2, and the display storage device can be with Wired connection is directly realized by transmission line with mass spectrograph 4, remote-transmission module can also be used to realize and show storage device and matter Being wirelessly transferred between spectrometer 4.In the present embodiment preferably by the way of being wirelessly transferred.
By above-mentioned setting, after the completion of gas detection, effectively working result can be transmitted to display storage dress in real time Put middle progress real-time display and storage.Display storage device in the present embodiment can be only aobvious with data storage function Display screen or the computer with control process function.Meanwhile have when the display storage device in the present embodiment uses During the computer of control process function, remote control effectively can be carried out to rotary valve, and then realize mass spectrograph 4 and different air accumulators Connection between 3, complete multiple different measuring points gas concentration detections.
Above-described embodiment, the purpose of this utility model, technical scheme and beneficial effect are entered One step describes in detail, should be understood that and the foregoing is only specific embodiment of the present utility model, is not used to limit Determine the scope of protection of the utility model, it is all within the spirit and principles of the utility model, any modification for being made, equally replace Change, improve, should be included within the scope of protection of the utility model.

Claims (7)

1. mixed gas concentration on-line measurement device, it is characterised in that:Including the air extractor being connected under test gas space, The mass spectrograph (4) connected with air extractor;
The air extractor includes the sample gas collection tube (1) that connect with mixed gas under test gas space, by air pump (2) and The air accumulator (3) of sample gas collection tube (1) connection;The mass spectrograph (4) connects with air accumulator (3);
The heating and thermal insulation cabinet (5) for air accumulator (3) heating and thermal insulation is additionally provided with the air accumulator (3).
2. mixed gas concentration on-line measurement device according to claim 1, it is characterised in that the air extractor is one More than individual, the mass spectrograph (4) is connected by rotary valve with the air accumulator (3) in whole air extractors.
3. mixed gas concentration on-line measurement device according to claim 1, it is characterised in that the air accumulator (3) with Connecting line between under test gas space is disposed as being incubated transfer conduit.
4. mixed gas concentration on-line measurement device according to claim 1, it is characterised in that the mass spectrograph (4) and Exhaust emission pipe (6) is provided with air accumulator (3).
5. mixed gas concentration on-line measurement device according to claim 1, it is characterised in that on the mass spectrograph (4) Also it is communicated with display storage device.
6. mixed gas concentration on-line measurement device according to claim 5, it is characterised in that the mass spectrograph (4) is logical Remote-transmission module is crossed to be connected with display storage device signal.
7. mixed gas concentration on-line measurement device according to claim 1, it is characterised in that the sample gas collection tube (1) it is stainless steel pipes.
CN201720947826.8U 2017-07-31 2017-07-31 Mixed gas concentration on-line measurement device Active CN207096165U (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108982583A (en) * 2018-06-20 2018-12-11 中国辐射防护研究院 The method and apparatus of Engineering Barrier Materials gas on-line testing under heat effect
CN108982227A (en) * 2018-06-20 2018-12-11 中国辐射防护研究院 Gas testing systems are used in a kind of Engineering Barrier Materials research in geological disposal near field
CN113670770A (en) * 2021-09-16 2021-11-19 湖北航天化学技术研究所 AlH-containing catalyst3Propellant thermal decomposition detection method
CN113777177A (en) * 2020-06-09 2021-12-10 中国石油天然气股份有限公司 Detection system and detection method for sulfur compounds in gas
CN116539381A (en) * 2023-07-05 2023-08-04 广东电网有限责任公司佛山供电局 Gas detection device and control method

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108982583A (en) * 2018-06-20 2018-12-11 中国辐射防护研究院 The method and apparatus of Engineering Barrier Materials gas on-line testing under heat effect
CN108982227A (en) * 2018-06-20 2018-12-11 中国辐射防护研究院 Gas testing systems are used in a kind of Engineering Barrier Materials research in geological disposal near field
CN113777177A (en) * 2020-06-09 2021-12-10 中国石油天然气股份有限公司 Detection system and detection method for sulfur compounds in gas
CN113777177B (en) * 2020-06-09 2024-03-26 中国石油天然气股份有限公司 System and method for detecting sulfur compounds in gas
CN113670770A (en) * 2021-09-16 2021-11-19 湖北航天化学技术研究所 AlH-containing catalyst3Propellant thermal decomposition detection method
CN116539381A (en) * 2023-07-05 2023-08-04 广东电网有限责任公司佛山供电局 Gas detection device and control method

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