CN107313261A - A kind of method of the plain enzyme of reinforcing fiber to bafta biopolishing effect - Google Patents

A kind of method of the plain enzyme of reinforcing fiber to bafta biopolishing effect Download PDF

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Publication number
CN107313261A
CN107313261A CN201710673067.5A CN201710673067A CN107313261A CN 107313261 A CN107313261 A CN 107313261A CN 201710673067 A CN201710673067 A CN 201710673067A CN 107313261 A CN107313261 A CN 107313261A
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CN
China
Prior art keywords
bafta
biopolishing
cellulase
mass concentration
dissolving
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710673067.5A
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Chinese (zh)
Inventor
郝龙云
王蕊
谭业强
蔡玉青
房宽峻
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Qingdao University
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Qingdao University
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Priority to CN201710673067.5A priority Critical patent/CN107313261A/en
Publication of CN107313261A publication Critical patent/CN107313261A/en
Pending legal-status Critical Current

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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D06M16/003Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with enzymes or microorganisms
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/11Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
    • D06M11/13Ammonium halides or halides of elements of Groups 1 or 11 of the Periodic Table
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/11Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
    • D06M11/155Halides of elements of Groups 2 or 12 of the Periodic Table
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/30Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with oxides of halogens, oxyacids of halogens or their salts, e.g. with perchlorates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Biochemistry (AREA)
  • Microbiology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Coloring (AREA)

Abstract

The present invention relates to a kind of plain enzyme of reinforcing fiber to the method for bafta biopolishing effect, belong to technical field of textile printing.The present invention uses following technique:(1)Potassium metaperiodate and stirring and dissolving of the mass concentration for 4 6g/L are added in water, the zinc chloride and stirring and dissolving of lithium chloride, 2g/L calcium chloride and 2g/L that mass concentration is 1g/L is then separately added into;(2)Pending bafta is put into, bath raio is controlled 1:50, solution temperature is risen to 60 DEG C and 1 hour is incubated;(3)Bafta takes out from solution after handling, and fully carries out cellulase biopolishing processing after washing.The present invention improves the hydrolysis efficiency of cellulase by the way of oxidation pre-treatment is carried out to bafta, can effectively reduce the consumption of cellulase while biopolishing effect is ensured, reduce biopolishing processing cost.

Description

A kind of method of the plain enzyme of reinforcing fiber to bafta biopolishing effect
Technical field
The present invention relates to a kind of plain enzyme of reinforcing fiber to the method for bafta biopolishing effect, belong to textile printing and dyeing technology Field.
Background technology
Cellulase is catalyzing hydrolysis cellulose, the general name of glucogenic enzyme, the enzyme system being made up of multicomponent enzyme. Bafta biopolishing is gone down except the fine hair on surface using cellulase in certain mechanical power cooperation, makes that fabric face is bright and clean, hair Plumage is reduced, anti-fluffing and anti-pilling, with the special performance such as soft, fluffy.Bafta biopolishing finishing effect is protruded and to environment Pollution is small, is rapidly progressed in recent years.
Cellulase is to the catalytic efficiency of bafta and substrate structure and property, cellulase source, temperature, pH value, dense Degree, action time, mechanical external force intensity and chemical assistant etc. have substantial connection.Because the price of cellulase is higher, researcher It is directed to improving its catalytic efficiency in different ways for a long time, to which the addition of cellulase can be reduced, reduction Biopolishing cost.
The content of the invention
The present invention improves the hydrolysis efficiency of cellulase by the way of oxidation pre-treatment is carried out to bafta, is ensureing life The consumption of cellulase can be effectively reduced while thing polishing effect, biopolishing processing cost is reduced.
The present invention uses following technique:
(1)Potassium metaperiodate and stirring and dissolving of the mass concentration for 4-6g/L are added in water, being then separately added into mass concentration is The zinc chloride and stirring and dissolving of 1g/L lithium chloride, 2g/L calcium chloride and 2g/L;
(2)Pending bafta is put into, bath raio is controlled 1:50, solution temperature is risen to 60 DEG C and 1 hour is incubated;
(3)Bafta takes out from solution after handling, and fully carries out cellulase biopolishing processing after washing.
First, potassium metaperiodate and stirring and dissolving of the mass concentration for 4-6g/L are added in water, the effect of potassium metaperiodate is Bafta is aoxidized, part of hydroxyl is changed into aldehyde radical.Add mass concentration for 1g/L lithium chloride, 2g/L calcium chloride and 2g/L zinc chloride and stirring and dissolving, the addition of these materials contributes to the structure of loose cotton fiber, collaboration enhancing potassium metaperiodate Oxidation effectiveness, shorten oxidization time.Pending bafta is added, bath raio is controlled 1:50, solution temperature is risen to 60 DEG C, Preprocessing process was completed in 1 hour.Bafta after being handled through above-mentioned collaboration can make the adsorbance and water of cellulase protein Solution efficiency is all significantly improved.Finally, bafta after processing is taken out from solution, fully washes to remove various residuals Thing, biopolishing processing is carried out using weaving with polishing cellulase to the bafta after oxidation pre-treatment.
Embodiment
The present invention is further illustrated below by embodiment and comparative example.
Embodiment 1
By bafta(100g/m2)It is handled as follows:Mass concentration is added in water for 4g/L potassium metaperiodate and stirs molten Solution, is then separately added into the zinc chloride and stirring and dissolving of lithium chloride, 2g/L calcium chloride and 2g/L that mass concentration is 1g/L;Put Enter pending bafta, bath raio is controlled 1:50, solution temperature is risen to 60 DEG C and 1 hour is incubated;Will processing after bafta from Taken out in solution, fully carry out cellulase biopolishing processing after washing.
Comparative example 1
By equal bafta(100g/m2)Without oxidation pre-treatment, biopolishing processing is directly carried out, polishing cellulase is used Amount is same as Example 1, and other polishing conditions are also consistent.
After measured, the reduction rate of the gained bafta of embodiment 1 is 2.8%, and the gained bafta reduction rate of comparative example 1 is 1.9%; In addition, the gained bafta anti-fluffing and anti-pilling grade of embodiment 1 is higher half grade than the gained bafta of comparative example 1.This shows, in identical Under the conditions of biopolishing, the hydrolysis polishing effect of cellulase can be improved using the inventive method.
Embodiment 2
By bafta(100g/m2)It is handled as follows:Mass concentration is added in water for 4g/L potassium metaperiodate and stirs molten Solution, is then separately added into the zinc chloride and stirring and dissolving of lithium chloride, 2g/L calcium chloride and 2g/L that mass concentration is 1g/L;Put Enter pending bafta, bath raio is controlled 1:50, solution temperature is risen to 60 DEG C and 1 hour is incubated;Will processing after bafta from Taken out in solution, fully carry out cellulase biopolishing processing after washing.
Comparative example 2
By equal bafta(100g/m2)Without oxidation pre-treatment, biopolishing processing is directly carried out, polishing cellulase is used Amount improves 25% than embodiment 2, and other polishing conditions are consistent.
After measured, the reduction rate of the gained bafta of embodiment 2 is 2.8%, and the gained bafta reduction rate of comparative example 2 is 2.6%; In addition, the gained bafta anti-fluffing and anti-pilling grade of embodiment 2 is identical with the gained bafta of comparative example 2.This shows, is not reducing life In the case of thing polishing effect, the consumption of polishing cellulase can be reduced using the inventive method.
Embodiment 3
By bafta(320g/m2)It is handled as follows:Mass concentration is added in water for 6g/L potassium metaperiodate and stirs molten Solution, is then separately added into the zinc chloride and stirring and dissolving of lithium chloride, 2g/L calcium chloride and 2g/L that mass concentration is 1g/L;Put Enter pending bafta, bath raio is controlled 1:50, solution temperature is risen to 60 DEG C and 1 hour is incubated;Will processing after bafta from Taken out in solution, fully carry out cellulase biopolishing processing after washing.
Comparative example 3
By equal bafta(320g/m2)Without oxidation pre-treatment, biopolishing processing is directly carried out, polishing cellulase is used Amount is same as Example 3, and other polishing conditions are also consistent.
After measured, the reduction rate of the gained bafta of embodiment 3 is 3.3%, and the gained bafta reduction rate of comparative example 3 is 2.1%; In addition, the gained bafta anti-fluffing and anti-pilling grade of embodiment 3 is higher 1 grade than the gained bafta of comparative example 3.This shows, in identical Under the conditions of biopolishing, the biopolishing effect of cellulase can be improved using the inventive method.
Embodiment 4
By bafta(320g/m2)It is handled as follows:Mass concentration is added in water for 6g/L potassium metaperiodate and stirs molten Solution, is then separately added into the zinc chloride and stirring and dissolving of lithium chloride, 2g/L calcium chloride and 2g/L that mass concentration is 1g/L;Put Enter pending bafta, bath raio is controlled 1:50, solution temperature is risen to 60 DEG C and 1 hour is incubated;Will processing after bafta from Taken out in solution, fully carry out cellulase biopolishing processing after washing.
Comparative example 4
By equal bafta(320g/m2)Without oxidation pre-treatment, biopolishing processing is directly carried out, polishing cellulase is used Amount is than embodiment 4 high 30%, and other polishing conditions are consistent.
After measured, the reduction rate of the gained bafta of embodiment 4 is 3.3%, and the gained bafta reduction rate of comparative example 4 is 3.1%; In addition, the gained bafta anti-fluffing and anti-pilling grade of embodiment 4 is identical with the gained bafta of comparative example 4.This shows, is not reducing life In the case of thing polishing effect, the consumption of polishing cellulase can be reduced using the inventive method.

Claims (1)

1. a kind of plain enzyme of reinforcing fiber is to the method for bafta biopolishing effect, it is characterised in that use following technique:
(1)Potassium metaperiodate and stirring and dissolving of the mass concentration for 4-6g/L are added in water, being then separately added into mass concentration is The zinc chloride and stirring and dissolving of 1g/L lithium chloride, 2g/L calcium chloride and 2g/L;
(2)Pending bafta is put into, bath raio is controlled 1:50, solution temperature is risen to 60 DEG C and 1 hour is incubated;
(3)Bafta takes out from solution after handling, and fully carries out cellulase biopolishing processing after washing.
CN201710673067.5A 2017-08-09 2017-08-09 A kind of method of the plain enzyme of reinforcing fiber to bafta biopolishing effect Pending CN107313261A (en)

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Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1760439A (en) * 2005-11-23 2006-04-19 北京服装学院 Crease-resist finish method for color cotton fabric
CN1912224A (en) * 2006-07-18 2007-02-14 东华大学 One-step process preprocessing technology of cotton fibric biological enzyme high-temp desizing refining and bleaching
CN101851868A (en) * 2010-03-09 2010-10-06 常州耀春格瑞纺织品有限公司 Ecological dyeing method for dyeing cotton fabric with mulberry red natural dye
CN102561058A (en) * 2012-02-16 2012-07-11 武汉纺织大学 Method for improving dyeing property of cotton fabric natural dye by using silk peptide
CN103669007A (en) * 2012-09-21 2014-03-26 青岛道合生物科技有限公司 Biological desizing/boiling-off enzyme compound antibacterial washing softener for fabrics
CN105040417A (en) * 2015-08-22 2015-11-11 苏州正业昌智能科技有限公司 Method for generating antibacterial cotton fibers in situ
CN105040436A (en) * 2015-08-22 2015-11-11 苏州正业昌智能科技有限公司 Finishing method of antibacterial cotton fabric
CN105040405A (en) * 2015-08-22 2015-11-11 苏州正业昌智能科技有限公司 Manufacture method of antibacterial cotton fabric
CN105088780A (en) * 2015-08-22 2015-11-25 苏州正业昌智能科技有限公司 Nano-silver antibacterial cotton fabric
CN105133287A (en) * 2015-08-19 2015-12-09 张家港市金陵纺织有限公司 Manufacture method for all-cotton super-soft silk-protein silk-like yarn-dyed fabric
CN105178037A (en) * 2015-10-12 2015-12-23 江南大学 Method for conducting cotton fabric polishing finishing by modifying neutral cellulase through cationization

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1760439A (en) * 2005-11-23 2006-04-19 北京服装学院 Crease-resist finish method for color cotton fabric
CN1912224A (en) * 2006-07-18 2007-02-14 东华大学 One-step process preprocessing technology of cotton fibric biological enzyme high-temp desizing refining and bleaching
CN101851868A (en) * 2010-03-09 2010-10-06 常州耀春格瑞纺织品有限公司 Ecological dyeing method for dyeing cotton fabric with mulberry red natural dye
CN102561058A (en) * 2012-02-16 2012-07-11 武汉纺织大学 Method for improving dyeing property of cotton fabric natural dye by using silk peptide
CN103669007A (en) * 2012-09-21 2014-03-26 青岛道合生物科技有限公司 Biological desizing/boiling-off enzyme compound antibacterial washing softener for fabrics
CN105133287A (en) * 2015-08-19 2015-12-09 张家港市金陵纺织有限公司 Manufacture method for all-cotton super-soft silk-protein silk-like yarn-dyed fabric
CN105040417A (en) * 2015-08-22 2015-11-11 苏州正业昌智能科技有限公司 Method for generating antibacterial cotton fibers in situ
CN105040436A (en) * 2015-08-22 2015-11-11 苏州正业昌智能科技有限公司 Finishing method of antibacterial cotton fabric
CN105040405A (en) * 2015-08-22 2015-11-11 苏州正业昌智能科技有限公司 Manufacture method of antibacterial cotton fabric
CN105088780A (en) * 2015-08-22 2015-11-25 苏州正业昌智能科技有限公司 Nano-silver antibacterial cotton fabric
CN105178037A (en) * 2015-10-12 2015-12-23 江南大学 Method for conducting cotton fabric polishing finishing by modifying neutral cellulase through cationization

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Application publication date: 20171103

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