A kind of energy-efficient fuel oil additive and preparation method thereof for improving power
Technical field
The invention belongs to fuel oil additive technical fields, and in particular to a kind of energy-efficient fuel oil additive for improving power
And preparation method thereof.
Background technique
Energy-saving and emission-reduction are the task of top priority of world today's energy shortages, and the efficiency of combustion of fuel oil directly affects energy conservation and subtracts
The effect of row, fuel oil additive can improve oil, promote fuel oil full combustion, improve efficiency of combustion, save fuel oil;It can mention
Its high atomization quality, reduces fuel oil full combustion by noxious gas emission, achieves energy-saving and emission reduction purposes.
In field of internal combustion engine, in order to improve fuel economy, increase output power, reduction oil consumption, decarbonizing reduction
Noxious gas emission, main at present there are two technological approaches: first is that addition or reforming equipment, second is that putting into additive to fuel oil.
First approach investment is big, program is cumbersome, also increases car and boat self weight and maintenance difficulty, so second approach more people is connect
By.But current fuel oil additive has the disadvantage in that 1, saving fuel oil, the effect of promotion power are undesirable mostly, has
Power performance is also reduced, this is that current fuel oil additive cannot be the generally accepted main cause of users;2, it is easy to make
At " secondary pollution ", some drawn may be generated while playing efficiency by the additive that chemical reaction is worked
Attention or public hazards object not yet arousing attention, being more difficult natural degradation are played, to become the hidden danger of businessman and the public, such as famous
Additive MTBE (methyl tertiary butyl ether(MTBE)), being found it after the U.S. passes unimpeded 20 years will increase oxynitride discharge, especially
The serious is the permanent polluted sources of meeting, thus are used by limitation;3, efficiency is unstable: since the component of fuel oil is extremely complex,
The same label fuel oil technique in process of production and adding ingredient of different manufacturers production are different or even same producers
Same label product, since the raw material sources difference of different batches will also result in the difference of product composition, just because of it is this not
Certainty, which to rely primarily on the additive that chemical agent works, cannot often stablize performance efficiency, and be easy to produce " two
The adverse consequences such as secondary pollution " and parts corrosion.Therefore, developing one kind can energy-efficient raising power and generation
The fuel oil additive of " secondary pollution " is extremely necessary.
Summary of the invention
The present invention provides a kind of energy-efficient fuel oil additives for improving power, solve the addition of prior art intermediate fuel oil
The problem of agent saving fuel oil, the effect for promoting power are undesirable and are easy to produce secondary pollution.
The first purpose of the invention is to provide a kind of energy-efficient fuel oil additive for improving power, prepare raw material by
The group of following parts by weight is grouped as: 20~40 parts of lauroyl isopropanolamine, 10~15 parts of polyisobutene sulphur phosphatization barium salt, gather it is different
5~10 parts of the more succimides of butylene, 0.5~1 part of organo-silicon compound, vulcanization 0.5~1 part of plant fat acid esters, octyl
0.5~1 part of glucosides, 10~25 parts of petroleum ether, 5~15 parts of combustion adjuvant, 0.1~0.2 part of surfactant;
Wherein, the combustion adjuvant is mixed by methyl ferrocene methanol, polyvinylmethyl ethers according to the weight ratio of 1:1~3
It arrives.
Preferably, the energy-efficient fuel oil additive for improving power prepares raw material by the component of following parts by weight
Composition: 30 parts of lauroyl isopropanolamine, 12 parts of polyisobutene sulphur phosphatization barium salt, 8 parts of the more succimides of polyisobutene, organosilicon
0.5 part of compound, vulcanization 1 part of plant fat acid esters, 1 part of octyl glucosides, 20 parts of petroleum ether, 10 parts of combustion adjuvant, surface-active
0.1 part of agent;
Wherein, the combustion adjuvant is mixed to get by methyl ferrocene methanol, polyvinylmethyl ethers according to the weight ratio of 1:1.5
's.
Preferably, the organo-silicon compound are one of hydroxy silicon oil, methyl-silicone oil or silicone oil of carboxyl.
Preferably, the surfactant is one in glycerin monostearate, fatty acid sorbitan or vegetable oil acid
Kind.
A second object of the present invention is to provide a kind of preparation method of energy-efficient fuel oil additive for improving power, tools
Body follows the steps below to implement:
Step 1, methyl ferrocene methanol and polyvinylmethyl ethers are weighed according to the weight ratio of 1:1~3, then by it in room
The lower mixing of temperature, and 30min is stirred in the case where blender revolving speed is 1000r/min, stirring finishes to obtain combustion adjuvant, spare;
Step 2,20~40 parts of lauroyl isopropanolamine, 10~15 parts of polyisobutene sulphur phosphatization barium salt, polyisobutene are weighed
5~10 parts of more succimides, 0.5~1 part of organo-silicon compound, vulcanization 0.5~1 part of plant fat acid esters, octyl glucosides
0.5~1 part, 10~25 parts of petroleum ether, 5~15 parts of combustion adjuvant, 0.1~0.2 part of surfactant made from step 1, it is spare;
Step 3, the more succimides of lauroyl isopropanolamine, polyisobutene, the organosilicon compound that will claim in step 2
Object, surfactant, petroleum ether are placed in reaction kettle, and under the mixing speed of 1500r/min, 2h is stirred at 60 DEG C, stirring
Ultrasonic mixing 30min is finished, intermediate blend is obtained;
Step 4, polyisobutene sulphur phosphatization barium salt is added into the intermediate blend of step 3, vulcanizes plant fat acid esters, is pungent
Alkyl glycosides and combustion adjuvant stir 30min under the mixing speed of 2000r/min at 80 DEG C, are then cooled to 50 DEG C again
30min is stirred, stirring finishes ultrasonic mixing 20min to get the energy-efficient fuel oil additive for improving power is arrived.
Fuel oil additive of the invention is made of gas chromatography, and many components have for fuel oil Main Components
Smaller molecule can be dissolved completely in liquid fuel after mixing with fuel oil, these components are sent out in correct ratio group cost
Bright fuel oil additive improves fuel oil and draws in internal combustion engine by mixing a small amount of fuel oil additive of the invention with fuel oil
The burning in combustion chamber is held up, fuel oil more completely burned is promoted, enhances fuel combustion efficiency, has reached energy-efficient purpose, improved
Air pollution caused by the discharge of fuel economy and reduction hydrocarbon or combustion intermediate product.
Lauroyl isopropanolamine is added in the present invention can be improved the vapo(u)rability of fuel oil and the spatter property of atomizer, main
Effect is that engine interior is made to keep cleaning, makes the insoluble substance generated in colloidal suspension state, is not to be further formed
Carbon deposit, paint film or greasy filth, and the paint film being adsorbed on parts surface and carbon deposit can be washed, dispersion in the oil, makes
Engine and metal surface keep cleaning.
The more succimides of polyisobutene can remove the deposit of atomizer and intake valve etc., have as detersive
Excellent low temperature dispersity and high-order stability and lauroyl isopropanolamine are used cooperatively, and it is preferably clear to can guarantee that gasoline has
Net dispersion effect.
Polyisobutene sulphur phosphatization barium salt can be such that the ignition temperature of fuel oil reduces, and burning velocity is speeded, and promotes fuel burning
Completely, the mechanism of action is that polyisobutene sulphur phosphatization barium salt generates new metallic compound in burning, anti-to combustion oxidation
It should play catalyst.
On the one hand organo-silicon compound can be improved the frost resistance of fuel oil, on the other hand play thickening, the anti-shearing, row of reduction
Cigarette improves the lubricity effect of gasoline.Octyl glucosides not only has preferable inoxidizability and from detergent power, but also overcomes
Oil reservoir emulsifies this defect.Surfactant can significantly reduce the surface tension of the interface of oil and gas, make atomizing fuel oil, thus
Make fuel oil full combustion.
Petroleum ether, on the one hand can be miscible at an entirety by each component as a kind of organic solvent, on the other hand can mention
The volatility of fuel oil is risen, to improve the burning of fuel oil in a combustion chamber, petroleum ether not only contributes to improve the rate of economizing gasoline of fuel oil
(MPG raising) can also improve the starting of engine and increase engine power, these improve relatively low for engine efficiency outmoded
Vehicle it is more significant.
Methyl ferrocene methanol mixes use, methyl ferrocene methanol energy as combustion adjuvant with polyvinylmethyl ethers
Enough promote polyvinylmethyl ethers to decomposite more methoxy free radicals, the charcoal chain of fuel oil is accelerated to be broken, promotes oxidizing fire.Phase
Than can preferably accelerate the ignition rate and burning velocity of fuel oil for common combustion adjuvant, combustion adjuvant is dissolved with fuel oil
Enter cylinder body afterwards, a large amount of fuel gas is generated at a high temperature of engine chamber, provides more oxygen for fuel burning
Gas, enables fuel oil full combustion, largely reduces Vehicular exhaust pollution, and substantially increase the power performance of engine.
Various components are combined and are prepared for environmental-friendly fuel oil additive by the present invention, pass through the type and quantity of additive
Control to reach the balance between each performance, rather than the corresponding additive of simple selection for a certain performance, and adding
Add and avoid the negative influence generated between each other in the selection of the type and type of agent as far as possible, therefore it is better to obtain performance
The energy-efficient fuel oil additive for improving power.
Compared with prior art, the beneficial effects of the present invention are:
1) fuel oil additive of the invention can significantly improve the efficiency of combustion of fuel oil, keep fuel burning more complete, improve
Engine power reduces fuel consumption.
2) fuel oil additive of the invention can clear carbon decontamination, improve the economy of fuel oil, and therefore reduce HC in air,
CO、NOxAnd the discharge of other exhaust gas, the effect of having reached energy-saving and emission-reduction, further, since having clear carbon decontamination and oil-saving discharging-reducing
Effect reduces maintenance expense, extends service life of aeroengine to reduce corrosion.
3) fuel oil additive preparation method of the invention is simple, and normal temperature and pressure operation, additive amount is small, and additive amount is only fuel oil
0.1% (mass ratio), application prospect is boundless.
Specific embodiment
In order to enable those skilled in the art to more fully understand, technical solution of the present invention is practiced, below with reference to specific
The invention will be further described for embodiment, but illustrated embodiment is not as a limitation of the invention.
The test method of actual conditions is not specified in following embodiments, according to conventional methods in the art with condition into
Row, if material used is commercially available without specified otherwise.
Embodiment 1
A kind of energy-efficient fuel oil additive for improving power, prepares raw material and is composed of the following parts by weight:
20 parts of lauroyl isopropanolamine, 15 parts of polyisobutene sulphur phosphatization barium salt, 10 parts of the more succimides of polyisobutene, hydroxy silicon oil
0.5 part, vulcanization 0.6 part of plant fat acid esters, 0.8 part of octyl glucosides, 10 parts of petroleum ether, 5 parts of combustion adjuvant, glycerol monostearate
0.1 part of ester;
Wherein, combustion adjuvant is mixed to get by methyl ferrocene methanol, polyvinylmethyl ethers according to the weight ratio of 1:1.
It is specifically implemented according to the following steps:
Step 1, methyl ferrocene methanol and polyvinylmethyl ethers are weighed according to the weight ratio of 1:1, then by it in room temperature
Lower mixing, and 30min is stirred in the case where blender revolving speed is 1000r/min, stirring finishes to obtain combustion adjuvant, spare;
Step 2,20 parts of lauroyl isopropanolamine, 15 parts of polyisobutene sulphur phosphatization barium salt, the more succinyl of polyisobutene are weighed
10 parts of imines, 0.5 part of hydroxy silicon oil, vulcanization 0.6 part of plant fat acid esters, 0.8 part of octyl glucosides, 10 parts of petroleum ether, step 1
5 parts of combustion adjuvant obtained, 0.1 part of glycerin monostearate, it is spare;
Step 3, the more succimides of lauroyl isopropanolamine, polyisobutene, the hydroxy silicon oil, list that will claim in step 2
Tristerin, petroleum ether are placed in reaction kettle, under the mixing speed of 1500r/min, are stirred 2h at 60 DEG C, have been stirred
Finish ultrasonic mixing 30min, obtains intermediate blend;
Step 4, polyisobutene sulphur phosphatization barium salt is added into the intermediate blend of step 3, vulcanizes plant fat acid esters, is pungent
Alkyl glycosides and combustion adjuvant stir 30min under the mixing speed of 2000r/min at 80 DEG C, are then cooled to 50 DEG C again
30min is stirred, stirring finishes ultrasonic mixing 20min to get the energy-efficient fuel oil additive for improving power is arrived.
Embodiment 2
A kind of energy-efficient fuel oil additive for improving power, prepares raw material and is composed of the following parts by weight:
30 parts of lauroyl isopropanolamine, 12 parts of polyisobutene sulphur phosphatization barium salt, 8 parts of the more succimides of polyisobutene, methyl-silicone oil 0.5
Part, vulcanization 1 part of plant fat acid esters, 1 part of octyl glucosides, 20 parts of petroleum ether, 10 parts of combustion adjuvant, 0.1 part of fatty acid sorbitan;
Wherein, the combustion adjuvant is mixed to get by methyl ferrocene methanol, polyvinylmethyl ethers according to the weight ratio of 1:1.5
's.
The preparation method is the same as that of Example 1, and difference is that the formula for being changed to embodiment 2 will be formulated.
Embodiment 3
A kind of energy-efficient fuel oil additive for improving power, prepares raw material and is composed of the following parts by weight:
40 parts of lauroyl isopropanolamine, 10 parts of polyisobutene sulphur phosphatization barium salt, 5 parts of the more succimides of polyisobutene, silicone oil of carboxyl 1
Part, vulcanization 0.5 part of plant fat acid esters, 0.5 part of octyl glucosides, 25 parts of petroleum ether, 15 parts of combustion adjuvant, 0.2 part of vegetable oil acid;
Wherein, combustion adjuvant is mixed to get by methyl ferrocene methanol, polyvinylmethyl ethers according to the weight ratio of 1:2.
The preparation method is the same as that of Example 1, and difference is that the formula for being changed to embodiment 3 will be formulated.
Embodiment 4
A kind of energy-efficient fuel oil additive for improving power, prepares raw material and is composed of the following parts by weight:
35 parts of lauroyl isopropanolamine, 10 parts of polyisobutene sulphur phosphatization barium salt, 6 parts of the more succimides of polyisobutene, silicone oil of carboxyl 0.6
Part, vulcanization 0.8 part of plant fat acid esters, 1 part of octyl glucosides, 20 parts of petroleum ether, 12 parts of combustion adjuvant, fatty acid sorbitan 0.15
Part;
Wherein, combustion adjuvant is mixed to get by methyl ferrocene methanol, polyvinylmethyl ethers according to the weight ratio of 1:2.
The preparation method is the same as that of Example 1, and difference is that the formula for being changed to embodiment 4 will be formulated.
Embodiment 5
A kind of energy-efficient fuel oil additive for improving power, prepares raw material and is composed of the following parts by weight:
25 parts of lauroyl isopropanolamine, 15 parts of polyisobutene sulphur phosphatization barium salt, 10 parts of the more succimides of polyisobutene, methyl-silicone oil 1
Part, vulcanization 0.5 part of plant fat acid esters, 0.5 part of octyl glucosides, 10 parts of petroleum ether, 10 parts of combustion adjuvant, 0.2 part of vegetable oil acid;
Wherein, combustion adjuvant is mixed to get by methyl ferrocene methanol, polyvinylmethyl ethers according to the weight ratio of 1:2.5.
The preparation method is the same as that of Example 1, and difference is that the formula for being changed to embodiment 5 will be formulated.
Embodiment 6
A kind of energy-efficient fuel oil additive for improving power, prepares raw material and is composed of the following parts by weight:
30 parts of lauroyl isopropanolamine, 10 parts of polyisobutene sulphur phosphatization barium salt, 5 parts of the more succimides of polyisobutene, hydroxy silicon oil 0.8
Part, vulcanization 1 part of plant fat acid esters, 0.6 part of octyl glucosides, 15 parts of petroleum ether, 13 parts of combustion adjuvant, glycerin monostearate
0.18 part;
Wherein, combustion adjuvant is mixed to get by methyl ferrocene methanol, polyvinylmethyl ethers according to the weight ratio of 1:3.
The preparation method is the same as that of Example 1, and difference is that the formula for being changed to embodiment 6 will be formulated.
Examples 1 to 6 has prepared the energy-efficient fuel oil additive for improving power of good performance, is set forth below one
The experimental data of a little application aspects, to illustrate the effect of Examples 1 to 6.
In experimentation, fuel oil additive obtained above is directly appended to 93# commodity according to the 0.1% of fuel weight
It is used in gasoline.Effect in order to further illustrate the present invention, using the 93# merchantable gasoline of any additive of no addition as pair
It is tested as usual.
It should be noted that test is to drive a vehicle result with Santana Vista will person of outstanding talent 1.8L to be illustrated, wherein idling
Stabilization idling after referring to 2 minutes;Average fuel consumption refers to that automobile with 60 kilometers of speed per hour travelings hourly, adds driver to have altogether
200 kilograms of load-carrying, the average fuel consumption of 20 kilometers of traveling;Noise is accelerated to refer to measuring in driver's cabin and making an uproar in kilometer accelerator
Sound is tested using GB1496-79 " motor vehicles noise measuring method ";Oil consumption is accelerated to refer to that 0~60 kilometer accelerated
Cheng Zhong, average oil consumption.Specific test result is shown in Table 1.
1 test result of table
From table 1 it follows that the embodiment of the present invention 1~6 is compared in -10 DEG C of starting times for reference examples
Ratio shortens half, illustrates after adding fuel oil additive of the invention, fuel anti-freezing property is more preferable, and power obtains mentioning greatly very much
It is high;The amount of deposit is 0.8mg or so in inlet valve deposits, and comparative example is then up to 4.2mg, illustrates that the present invention prepares
Fuel oil additive goes carbon remover ability strong;The idling of Examples 1 to 6 shows to add using fuel oil of the invention compared with comparative example height
Facilitate to increase automobile power after agent;The average fuel consumption of Examples 1 to 6 and acceleration oil consumption are below comparative example, illustrate the present invention
Fuel oil additive has the function of energy-saving;After fuel oil additive of the invention, HC, CO, NO in the tail gas of dischargex's
Content is many compared with comparative example decline, therefore will not only bring secondary pollution using fuel oil additive of the invention, moreover it is possible to subtract
The discharge of few original pollutant;Accelerate to make an uproar in running car in addition, showing that the use of fuel oil additive of the present invention also has to reduce
The effect of sound.
It should be noted that involved in claims of the present invention when numberical range, it is thus understood that each numberical range
Any one numerical value can be selected between two endpoints and two endpoints, due to step method and the Examples 1 to 6 phase of use
Together, it repeats in order to prevent, description of the invention preferred embodiment, once a person skilled in the art knows basic
Creative concept, then additional changes and modifications may be made to these embodiments.It is wrapped so the following claims are intended to be interpreted as
It includes preferred embodiment and falls into all change and modification of the scope of the invention.
Obviously, various changes and modifications can be made to the invention without departing from essence of the invention by those skilled in the art
Mind and range.In this way, if these modifications and changes of the present invention belongs to the range of the claims in the present invention and its equivalent technologies
Within, then the present invention is also intended to include these modifications and variations.