CN107300797A - A kind of application type dimming glass and its manufacturing process - Google Patents

A kind of application type dimming glass and its manufacturing process Download PDF

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Publication number
CN107300797A
CN107300797A CN201710517181.9A CN201710517181A CN107300797A CN 107300797 A CN107300797 A CN 107300797A CN 201710517181 A CN201710517181 A CN 201710517181A CN 107300797 A CN107300797 A CN 107300797A
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China
Prior art keywords
layer
coating layer
coating
application type
dimming glass
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Pending
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CN201710517181.9A
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Chinese (zh)
Inventor
韩忠美
张斌
邓景月
张强
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Suzhou Bai Xin Mstar Technology Ltd
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Suzhou Bai Xin Mstar Technology Ltd
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Priority to CN201710517181.9A priority Critical patent/CN107300797A/en
Publication of CN107300797A publication Critical patent/CN107300797A/en
Pending legal-status Critical Current

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    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods

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  • Physics & Mathematics (AREA)
  • Nonlinear Science (AREA)
  • Mathematical Physics (AREA)
  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Electrochromic Elements, Electrophoresis, Or Variable Reflection Or Absorption Elements (AREA)
  • Liquid Crystal (AREA)

Abstract

The invention discloses a kind of application type dimming glass and its manufacturing process, including basalis, basalis upper surface is equipped with the second coating layer, second coating layer upper surface is equipped with light modulation layer, light modulation layer upper surface is equipped with the first coating layer, first coating layer upper surface is equipped with protective coating, first coating layer and the second coating layer connection electrode connector, its manufacturing process is first to be coated with the first coating layer on the base layer first, start coating light modulation layer after solidification detection while attaching mesh support, pass through ultra-violet curing light modulation layer, it is coated with the second coating layer, after solidification detection, electrode connecting parts are bound with anisotropic conductive tape, be powered test, it is coated with protective coating and ultra-violet curing, complete element manufacturing, the present invention is simple in construction, simplify existing product structure, light transmittance is higher, visual angle is bigger, reduce raw material loss, technique is simpler, processing is more flexible, process and the use more more energy efficient environmental protection of process simultaneously.

Description

A kind of application type dimming glass and its manufacturing process
Technical field
The present invention relates to glass manufacturing area, specifically a kind of application type dimming glass and its manufacturing process.
Background technology
Glass be fused together by silica and other chemical substances formed (main production raw material is:Soda ash, stone Lime stone, quartz).Contiguous network structure is formed in melting, viscosity, which gradually increases and hardened, in cooling procedure causes what it was crystallized Silicates nonmetallic materials.The chemical composition of simple glass is Na2SiO3, CaSiO3, SiO2 or Na2OCaO6SiO2 Deng main component is silicate double salt, is a kind of non-crystalline solids of random structure.Be widely used in building, for every Wind printing opacity, belongs to mixture.It is another to have the oxide or salt that have been mixed into some metals and the coloured glass for showing color, and Pass through safety glass etc. made from the method for physics or chemistry.Sometimes some transparent plastics (such as poly-methyl methacrylates Ester) it is also referred to as lucite.
Dimming glass is as one kind of glass, and according to control device and the similarities and differences of principle, dimming glass can be by automatically controlled, temperature Control, light-operated, voltage-controlled etc. are embodied in various ways the switching of the transparent and opaque state of glass.Due to the limitation of various conditions, mesh The preceding dimming glass for realizing volume production on the market, is nearly all electronic control type dimming glass.The principle of electronic-control dimming glass is easier Understand:When electric control product closes power supply, irregular spread state can be presented in the liquid crystal molecule inside electronic-control dimming glass, make Light can not be injected, and allow automatically controlled glass that opaque outward appearance is presented;Although the price of dimming glass by just coming out when per square meter U.S. dollars up to ten thousand are down at present per square meter less than ten thousand yuans, but due to the reason, dimming glass price phase such as cost is high Still it is in a high position always for, this is also determined is positioned at high-end market its application field more.
Dimming glass be it is a liquid crystal film is combined into the middle of layer glass, through HTHP it is glued after integrally formed folder The new special photoelectric glass product of Rotating fields.User by the break-make of control electric current whether control glass it is transparent with it is impermeable Bright state.Glass not only has the characteristic of all safety glasses in itself, while being protected but also with control glass transparent whether privacy Protective function, due to the characteristic of liquid crystal film interlayer, dimming glass is also used as projection screen and used, and common curtain is substituted, in glass High definition picture image is presented on glass.
Described dimming glass is mainly PDLC technologies in the market, and other are such as suspended particulates technology (SPD), electroluminescent change Color (ECD), micro- louver (Microblinds), these all actual uses without batch.Eighties of last century late nineteen eighties, PDLC Dimming glass technology is invented by Texas, USA University of Kent and is commercialized volume production.Earliest product is exactly mainly to apply hot polymerization Close and HTHP sandwich technique produce dimming glass, and in the beginning of the nineties first Application in U.S. NASA project, this is It is also known earliest PDLC liquid crystal light modulation glass application cases.Domestic and international producer entered this industry, mesh one after another in the last few years Preceding is all HTHP production dimming glass after first UV methods production PDLC light modulation films, and a large amount of petrochemical industry plastic cement, the energy and time is lost.
In addition, mentioning the abbreviation that PDLC is English Polymer Dispersed Liquid Crystal, Chinese name here It is PDLC.PDLC (PDLC) is by low molecular weight liquid crystal (liquid crystal, be abbreviated as LC) Mixed with prepolymer, under certain condition aggregated reaction, form micron-sized liquid crystal droplet and be evenly dispersed in macromolecule In network, the dielectric anisotropy of liquid crystal molecule is recycled to obtain the material with electro-optic response characteristic, it operates mainly in scattered Penetrate between state and transparent state and with certain gray scale.Polymer dispersed liquid crystal film is that liquid crystal and polymer are combined to one obtained Plant the membrane material of excellent combination property.Liquid crystal molecule imparts the significant electro-optical characteristic of polymer dispersed liquid crystal film, make its by Extensive concern, and have broad application prospects.For conventional display device, polymer-dispersed liquid crystal is shown Utensil has many good qualities, for example, be not required to polarizer and oriented layer, and preparation technology is simple, it is easy to large area flexible display is made Deng the acquisition in terms of optical modulator, temperature-sensitive and pressure-sensitive device, automatically controlled glass, light valve, Projection Display, e-book at present Extensive use.
At present, the dimming glass product of in the market is more and more, and the overwhelming majority is with pdlc film and layer glass doubling Into this technique needs first to make pdlc film, then by the method for HTHP produces at least seven with EVA or PVB glued membranes The dimming glass of Rotating fields, the production cycle is long, and raw material loss is high, and energy consumption is also very high in production process.
The content of the invention
It is an object of the invention to provide a kind of application type dimming glass and its manufacturing process, to solve above-mentioned background technology The problem of middle proposition.
To achieve the above object, the present invention provides following technical scheme:
A kind of application type dimming glass, including basalis, the basalis upper surface are equipped with the second coating layer, the second coating Layer upper surface is equipped with light modulation layer, and light modulation layer upper surface is equipped with the first coating layer, and the first coating layer upper surface is equipped with protective coating, institute State the first coating layer and the second coating layer connection electrode connector.
It is used as further scheme of the invention:The basalis is glass material layer or acrylic material layer or makrolon Material layer.
It is used as further scheme of the invention:First coating layer and the second coating layer are nano-silver thread dope layer or height Molecule conductive paint or carbon nano-tube coating layer.
It is used as further scheme of the invention:The light modulation layer includes a mesh support and liquid crystal polymer mixture Obturator.
It is used as further scheme of the invention:The protective coating is acrylate paint layer.
It is used as further scheme of the invention:The electrode connecting parts are compliant conductive connecting lines.
It is used as further scheme of the invention:The mesh support, thickness is 1~20UM, and interstitial hole can be six Side shape, square, rhombus, rectangle, circle, aperture are 20UM to 100UM.
It is used as further scheme of the invention:The liquid crystal polymer mixture obturator, including 30% to 80% Liquid crystal, is made up of the method for phase separation or prefabricated spheroid.
It is used as further scheme of the invention:Second coating layer is than the first small 1~10mm of coating layer area.
The manufacturing process of the application type dimming glass is:First it is coated with the first coating layer, solidification inspection on the base layer first Start coating light modulation layer after survey while attaching mesh support, by ultra-violet curing light modulation layer, be coated with the second coating layer, solidification inspection After survey, electrode connecting parts are bound with anisotropic conductive tape, be powered test, coating protective coating and ultra-violet curing complete device Part makes.
Compared with prior art, the beneficial effects of the invention are as follows:The present invention is simple in construction, simplifies existing product structure, Light transmittance is higher, and visual angle is bigger, reduces raw material loss, technique is simpler, processes more flexible, while process and making With the more more energy efficient environmental protection of process.
Brief description of the drawings
Fig. 1 is the structural representation of application type dimming glass.
In figure:1- protective coatings, the coating layers of 2- first, 3- light modulation layers, the coating layers of 4- second, 5- basalises, 6- electrodes connect Fitting.
Embodiment
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is carried out clear, complete Site preparation is described, it is clear that described embodiment is only a part of embodiment of the invention, rather than whole embodiments.It is based on Embodiment in the present invention, it is every other that those of ordinary skill in the art are obtained under the premise of creative work is not made Embodiment, belongs to the scope of protection of the invention.
Referring to Fig. 1, in the embodiment of the present invention, a kind of application type dimming glass, including basalis 5, the upper surface of basalis 5 Equipped with the second coating layer 4, the upper surface of the second coating layer 4 is equipped with light modulation layer 3, and the upper surface of light modulation layer 3 is equipped with the first coating layer 2, the The upper surface of one coating layer 2 is equipped with protective coating 1, the first coating layer 2 and the connection electrode connector 6 of the second coating layer 4, basalis 5 It is glass material layer or acrylic material layer or makrolon material layer, the first coating layer 2 and the second coating layer 4 are nano-silver threads Dope layer or conductive polymer dope layer or carbon nano-tube coating layer, light modulation layer 3 include a mesh support and liquid crystal high score Sub- mixture obturator, protective coating 1 is acrylate paint layer, and electrode connecting parts are compliant conductive connecting line, mesh-supported Body, thickness is 1~20UM, and interstitial hole can be hexagon, square, rhombus, rectangle, circle, and aperture is arrived for 20UM 100UM, liquid crystal polymer mixture obturator, includes 30% to 80% liquid crystal, passes through phase separation or the method for prefabricated spheroid It is made, the small 1~10mm of area of 4 to the first coating layer of the second coating layer 2.
The manufacturing process of application type dimming glass is:The first coating layer 4, solidification detection are first coated with basalis 5 first After start coating light modulation layer 3 and meanwhile attach mesh support, pass through ultra-violet curing light modulation layer 3, be coated with the second coating layer 2, solidification After detection, electrode connecting parts 6 are bound with anisotropic conductive tape, be powered test, coating protective coating 1 and ultra-violet curing are complete Into element manufacturing.
Embodiment 1
A kind of application type dimming glass, including basalis 5, the upper surface of basalis 5 are equipped with the second coating layer 4, the second coating 4 upper surface of layer are equipped with light modulation layer 3, and the upper surface of light modulation layer 3 is equipped with the first coating layer 2, and the upper surface of the first coating layer 2 is applied equipped with protection Layer 1, the first coating layer 2 and the connection electrode connector 6 of the second coating layer 4, basalis 5 is glass material layer, the He of the first coating layer 2 Second coating layer 4 is nano-silver thread dope layer, and light modulation layer 3 includes a mesh support and liquid crystal polymer mixture is filled Body, protective coating 1 is acrylate paint layer, and electrode connecting parts are compliant conductive connecting lines, and mesh support, thickness is 4UM, Interstitial hole can be hexagon, square, rhombus, rectangle, circle, and aperture is 20UM, liquid crystal polymer mixture obturator, Including 30% liquid crystal, it is made up of the method for phase separation or prefabricated spheroid, the second coating layer 4 to the first coating layer, 2 areas are small 2mm。
The manufacturing process of application type dimming glass is:Nano-silver thread dope layer is first coated with first in glass material layer, Gu Change and start coating light modulation layer after detection while attaching mesh support, by ultra-violet curing light modulation layer, be coated with nano-silver thread coating Layer, after solidification detection, compliant conductive connecting line is bound with anisotropic conductive tape, and be powered test, is coated with acrylate paint Layer and ultra-violet curing, complete element manufacturing.
Embodiment 2
A kind of application type dimming glass, including basalis 5, the upper surface of basalis 5 are equipped with the second coating layer 4, the second coating 4 upper surface of layer are equipped with light modulation layer 3, and the upper surface of light modulation layer 3 is equipped with the first coating layer 2, and the upper surface of the first coating layer 2 is applied equipped with protection Layer 1, the first coating layer 2 and the connection electrode connector 6 of the second coating layer 4, basalis 5 are acrylic material layer, the first coating layer 2 It is conductive polymer dope layer with the second coating layer 4, light modulation layer 3 includes a mesh support and liquid crystal polymer mixture is filled out Fill body, protective coating 1 is acrylate paint layer, electrode connecting parts are compliant conductive connecting lines, mesh support, thickness is 8UM, interstitial hole can be hexagon, square, rhombus, rectangle, circle, and aperture is 40UM, and liquid crystal polymer mixture is filled out Body is filled, includes 40% liquid crystal, is made up of the method for phase separation or prefabricated spheroid, the face of 4 to the first coating layer of the second coating layer 2 The small 4mm of product.
The manufacturing process of application type dimming glass is:First conductive polymer coating is first coated with acrylic material layer Layer, starts coating light modulation layer 3 after solidification detection while attaching mesh support, by ultra-violet curing light modulation layer 3, is coated with macromolecule Conductive paint, after solidification detection, compliant conductive connecting line is bound with anisotropic conductive tape, and be powered test, acrylate Dope layer and ultra-violet curing, complete element manufacturing.
Embodiment 3
A kind of application type dimming glass, including basalis 5, the upper surface of basalis 5 are equipped with the second coating layer 4, the second coating 4 upper surface of layer are equipped with light modulation layer 3, and the upper surface of light modulation layer 3 is equipped with the first coating layer 2, and the upper surface of the first coating layer 2 is applied equipped with protection Layer 1, the first coating layer 2 and the connection electrode connector 6 of the second coating layer 4, basalis 5 are makrolon material layer, the first coating The coating layer 4 of layer 2 and second is carbon nano-tube coating layer, and light modulation layer 3 includes a mesh support and liquid crystal polymer mixture Obturator, protective coating 1 is acrylate paint layer, and electrode connecting parts are compliant conductive connecting lines, mesh support, and thickness is 12UM, interstitial hole can be hexagon, square, rhombus, rectangle, circle, and aperture is 60UM, and liquid crystal polymer mixture is filled out Body is filled, includes 50% liquid crystal, is made up of the method for phase separation or prefabricated spheroid, the face of 4 to the first coating layer of the second coating layer 2 The small 6mm of product.
The manufacturing process of application type dimming glass is:The first carbon nanotubes coating first on makrolon material layer Layer, starts coating light modulation layer while attaching mesh support after solidification detection, passes through ultra-violet curing light modulation layer, carbon nanotubes Dope layer, after solidification detection, compliant conductive connecting line is bound with anisotropic conductive tape, and be powered test, is coated with acrylate Dope layer and ultra-violet curing, complete element manufacturing
Embodiment 4
A kind of application type dimming glass, including basalis 5, the upper surface of basalis 5 are equipped with the second coating layer 4, the second coating 4 upper surface of layer are equipped with light modulation layer 3, and the upper surface of light modulation layer 3 is equipped with the first coating layer 2, and the upper surface of the first coating layer 2 is applied equipped with protection Layer 1, the first coating layer 2 and the connection electrode connector 6 of the second coating layer 4, basalis 5 is glass material layer, the He of the first coating layer 2 Second coating layer 4 is conductive polymer dope layer, and light modulation layer 3 includes a mesh support and liquid crystal polymer mixture is filled Body, protective coating 1 is acrylate paint layer, and electrode connecting parts are compliant conductive connecting lines, mesh support, and thickness is 16UM, interstitial hole can be hexagon, square, rhombus, rectangle, circle, and aperture is 80UM, and liquid crystal polymer mixture is filled out Body is filled, includes 60% liquid crystal, is made up of the method for phase separation or prefabricated spheroid, the face of 4 to the first coating layer of the second coating layer 2 The small 8mm of product.
The manufacturing process of application type dimming glass is:Conductive polymer dope layer is first coated with first in glass material layer, Start coating light modulation layer while attaching mesh support after solidification detection, by ultra-violet curing light modulation layer, be coated with conductive polymer Dope layer, after solidification detection, compliant conductive connecting line is bound with anisotropic conductive tape, and be powered test, is coated with acrylate Dope layer and ultra-violet curing, complete element manufacturing.
The present invention is simple in construction, simplifies existing product structure, light transmittance is higher, and visual angle is bigger, reduces raw material damage Consumption, technique is simpler, processes more flexible, while process and the use more more energy efficient environmental protection of process.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power Profit is required rather than described above is limited, it is intended that all in the implication and scope of the equivalency of claim by falling Change is included in the present invention.Any reference in claim should not be considered as to the claim involved by limitation.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each embodiment is only wrapped Containing an independent technical scheme, this narrating mode of specification is only that for clarity, those skilled in the art should Using specification as an entirety, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art It may be appreciated other embodiment.

Claims (10)

1. a kind of application type dimming glass, including basalis (5), it is characterised in that basalis (5) upper surface is equipped with second Coating layer (4), the second coating layer (4) upper surface is equipped with light modulation layer (3), and light modulation layer (3) upper surface is equipped with the first coating layer (2), First coating layer (2) upper surface is equipped with protective coating (1), and first coating layer (2) and the second coating layer (4) connection electrode connect Fitting (6).
2. application type dimming glass according to claim 1, it is characterised in that the basalis (5) is glass material layer Or acrylic material layer or makrolon material layer.
3. application type dimming glass according to claim 1, it is characterised in that first coating layer (2) and second applies Layer of cloth (4) is nano-silver thread dope layer or conductive polymer dope layer or carbon nano-tube coating layer.
4. application type dimming glass according to claim 1, it is characterised in that the light modulation layer (3) is netted including one Supporter and liquid crystal polymer mixture obturator.
5. application type dimming glass according to claim 1, it is characterised in that the protective coating (1) is acrylate Dope layer.
6. application type dimming glass according to claim 1, it is characterised in that the electrode connecting parts are that compliant conductive connects Wiring.
7. application type dimming glass according to claim 4, it is characterised in that the mesh support, thickness is 1~ 20UM, interstitial hole can be hexagon, square, rhombus, rectangle, circle, and aperture is 20UM to 100UM.
8. application type dimming glass according to claim 4, it is characterised in that the liquid crystal polymer mixture filling Body, includes 30% to 80% liquid crystal, is made up of the method for phase separation or prefabricated spheroid.
9. application type dimming glass according to claim 1, it is characterised in that second coating layer (4) applies than first Layer of cloth (2) small 1~10mm of area.
10. the manufacturing process of application type dimming glass according to claim 1, it is characterised in that first in basalis (5) It is upper to be first coated with the first coating layer (4), start coating light modulation layer (3) after solidification detection while mesh support is attached, by ultraviolet Solidify light modulation layer (3), after solidification detection, electrode connecting parts are bound with anisotropic conductive tape for the second coating layer of coating (2) (6), be powered test, coating protective coating (1) and ultra-violet curing, completes element manufacturing.
CN201710517181.9A 2017-06-29 2017-06-29 A kind of application type dimming glass and its manufacturing process Pending CN107300797A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113703206A (en) * 2021-08-25 2021-11-26 京东方科技集团股份有限公司 Light-adjusting glass and light-adjusting module

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JPH0961801A (en) * 1995-08-22 1997-03-07 Dainippon Printing Co Ltd Optical modulating element
CN103217849A (en) * 2013-04-03 2013-07-24 东南大学 Novel-structure adjustable-focus liquid crystal microlens array
CN103760695A (en) * 2014-01-09 2014-04-30 广州北峻工业材料有限公司 Smart glass using nano silver conducting layer and manufacturing method of smart glass
CN204945556U (en) * 2015-09-18 2016-01-06 南京华日触控显示科技有限公司 Utilize the intelligent glass that Polymer Dispersed Liquid Crystal makes
CN105810303A (en) * 2014-12-30 2016-07-27 北京生美鸿业科技有限公司 Graphene/ inorganic matter composite transparent conductive film-based light adjusting film
CN206848636U (en) * 2017-06-29 2018-01-05 苏州达佰新材料科技有限公司 A kind of application type dimming glass

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Publication number Priority date Publication date Assignee Title
US5469280A (en) * 1993-04-29 1995-11-21 Samsung Electronics Co., Ltd. Multi-layered liquid crystal display panel with auxiliary supports for reinforcement of injection holes
JPH0961801A (en) * 1995-08-22 1997-03-07 Dainippon Printing Co Ltd Optical modulating element
CN103217849A (en) * 2013-04-03 2013-07-24 东南大学 Novel-structure adjustable-focus liquid crystal microlens array
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113703206A (en) * 2021-08-25 2021-11-26 京东方科技集团股份有限公司 Light-adjusting glass and light-adjusting module
CN113703206B (en) * 2021-08-25 2023-10-17 京东方科技集团股份有限公司 Dimming glass and dimming module

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