CN103278959A - Strain liquid crystal multifunctional dimming glass, and manufacturing method and application for strain liquid crystal multifunctional dimming glass - Google Patents

Strain liquid crystal multifunctional dimming glass, and manufacturing method and application for strain liquid crystal multifunctional dimming glass Download PDF

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Publication number
CN103278959A
CN103278959A CN2013102163259A CN201310216325A CN103278959A CN 103278959 A CN103278959 A CN 103278959A CN 2013102163259 A CN2013102163259 A CN 2013102163259A CN 201310216325 A CN201310216325 A CN 201310216325A CN 103278959 A CN103278959 A CN 103278959A
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liquid crystal
glass
dimming glass
strain
strain liquid
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范志新
冯昌喜
焦龙
戴爱华
王玲
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NANJING JINGDUO NEW MATERIAL TECHNOLOGY Co Ltd
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NANJING JINGDUO NEW MATERIAL TECHNOLOGY Co Ltd
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Abstract

The invention relates to strain liquid crystal multifunctional dimming glass. Functions of electronic-control dimming glass, functions of strain dimming glass and functions of scattering polarization glass are integrated in the strain liquid crystal multifunctional dimming glass, the strain liquid crystal multifunctional dimming glass comprises two pieces of float super-flat transparent conducting thick glass, a polymer dispersed liquid crystal thin film, a stainless steel frame and a power conducting wire, and the polymer dispersed liquid crystal thin film is sandwiched between the two pieces of float super-flat transparent conducting thick glass. The strain liquid crystal multifunctional dimming glass has a total scattering foggy appearance, is turned into a fully transparent state after voltage is applied to the strain liquid crystal multifunctional dimming glass, and is turned into a hazy and semi-transparent state when shearing stress is applied to the strain liquid crystal multifunctional dimming glass instead of electricity. The strain liquid crystal multifunctional dimming glass has the advantages that the strain liquid crystal multifunctional dimming glass has the functions of the scattering polarization glass when in the semi-transparent state, and is a transparent projection screen with an excellent rear projection imaging effect when used with a single-chip liquid crystal projector; and the strain liquid crystal multifunctional dimming glass is applicable to manufacturing products such as active doors and windows, commodity counters, art glass screens and interior finish products of modified vehicles for interior decoration for offices, shopping malls and hotels.

Description

The multi-functional dimming glass of a kind of strain liquid crystal and manufacture method and application
Technical field
Technical solution of the present invention relates to and a kind ofly possesses electric-controlled light-regulating glass, strain dimming glass and three kinds of functions of scattering spread glass in the multi-functional dimming glass product of one.
Background technology
Polymer Dispersed Liquid Crystal (PDLC) and polymer network liquid crystal (PNLC) are polymkeric substance and liquid crystal compound system, in to Polymer Dispersed Liquid Crystal and polymer network liquid crystal research, find, stress application is influential to polymerization and the Liquid Crystal Molecules Alignment state of polymkeric substance, be stress induced liquid crystal aligning effect, this research field is called strain liquid crystal (SLC).Its goods of Polymer Dispersed Liquid Crystal electric-controlled light-regulating film have frosted glass mist attitude outward appearance, apply electric field and become pellucidity, we adopt the strain liquid crystal technology to prepare pros-and-cons type strain dimming glass, scattering spread glass and trans electric-controlled light-regulating glass, the patent of obtaining the authorization " polymer dispersion liquid crystal piezo-optical effect film and manufacture method thereof and application " (200810154177.1), " Polymer Dispersed Liquid Crystal shearing effect light glass and manufacture method and application " (200910070975.0), publication " transconfiguration piezooptical effect dimming glass " (201210324128.4), " transconfiguration shearing effect privacy glass " (201210324127.X), " a kind of scattering spread glass and manufacture method and application " (201310013345.6) and obtain accepting patent " a kind of trans electric-controlled light-regulating glass and manufacture method and application " (201310135804.8) further have the experiment new discovery to produce inspiration of the present invention in product development and the industrialization process on these working foundations.
Summary of the invention
Technical matters to be solved by this invention is: a kind of dimming glass has both electric-controlled light-regulating glass, strain dimming glass and three kinds of functions of scattering spread glass, goods were not in total scattering mist attitude when added electric field did not add shear stress yet, apply the electric field goods and become full clear state between transparent conducting glass; Added electric field is not pulled handle and two sheet glass are applied the shear stress goods is in dim translucent attitude; Goods have scattering spread glass function when translucent attitude, light transmission shaft vertical shear direction.
The present invention solves this technical problem the technical scheme that adopts: the multi-functional dimming glass of strain liquid crystal is made of the laminated glass articles of being with stainless steel frame and welding lead two super flat electrically conducting transparent heavy sheet glass and intermediate course polymer dispersed liquid-crystal film.The polymer dispersion liquid crystal material that the present invention uses is mixed by uv curable oligomer and nematic liquid crystal material, and prepolymer and nematic liquid crystal material are formed with about 1: 1 mass ratio.Described prepolymer is made up of 15~25% alkoxy nonyl phenyl acrylate, 65~75% trimethylolpropane triacrylate, 3~5% toughner nitrile rubber, 3~5% chain-transferring agent 2 mercapto ethanol and 3~5% light trigger 1173, described number percent is mass percent, and refractive index can be roughly n after the prepolymer cures p~1.5.The dielectric anisotropy of described nematic liquid crystal material is about Δ ε>4, and ordinary refraction index is roughly n o~1.5, very optical index is roughly n e~1.7, the birefringence rate variance is Δ n~more than 0.2.The used phase detachment technique of the multi-functional dimming glass of strain liquid crystal of the present invention adopts the ultraviolet light polymerization phase detachment technique, wherein the formation of polymer dispersed liquid-crystal film comprises that also diameter is the gasket material plastic microsphere of 10~30 μ m, and its consumption calculates less than 100/cm with the glassware area 2Wherein said transparent conducting glass is the dull and stereotyped heavy sheet glass plating tin oxide of super flat float glass process or oxidation Indium tin nesa coating, and resistance per square 40~60 Ω, its thickness of glass are 3~5mm, thickness 10~30 μ m of wherein said polymer dispersed liquid-crystal film.
The manufacturing of the multi-functional dimming glass of strain liquid crystal need be carried out at dust proof workshop, and preparation method's basic step is:
The first step, the preparation prepolymer, alkoxy nonyl phenyl acrylate with 15~25%, 65~75% trimethylolpropane triacrylate, 1~3% toughner nitrile rubber, 3~5% chain-transferring agent 2 mercapto ethanol and 3~5% light trigger 1173 preparation prepolymers stir potpourri at ambient temperature and fully to mix in 2 minutes.
Second step, preparation liquid crystal glue, the prepolymer that the first step is prepared mixes with the mass ratio of nematic liquid crystal material with 1: 1, with the stirrer stirring it is fully mixed under the room temperature and forms liquid crystal glue, and liquid crystal glue is the water white transparency state, and viscosity is less.
In the 3rd step, the cleaning glass substrate cuts into the transparent conducting glass of thickness 3~5mm the size that needs, adding detersive in the deionization pure water cleans glass substrate, make the clean no dirt of glass surface, clean with purified rinse water, remove water stain with the dustless dried cloth wiping of cleaning again.
The 4th step, the spreading wadding, in sprayer, inject diluting solvent solvent adhesive (converting anhydrous alcohol or butyl acetate reagent as 502 instantaneous adhesives), the wadding microballoon powder that adds 10~30 μ m in the solvent, to a slice this solvent of an amount of sprinkling on glass, treat that solvent evaporates falls, the wadding plastic microsphere is bonded in glass surface.
The 5th step, the combined glass glass, at the wet method spreading a slice another sheet glass that closes on glass of wadding, tilt to be put in the special-purpose enamel tray groove pond, clamp with the stainless steel and iron clip in side the lower end, syringe needle is injected in the upper end, makes the wedge gap that forms in the middle of two sheet glass as thin as a wafer, and two sheet glass are reserved welding lead and conveniently applied the dislocation of shear stress.
The 6th step, perfusion liquid crystal glue, the liquid crystal glue that an amount of aforementioned arrangements is good is filled in the space of two sheet glass with syringe, treat that liquid crystal glue is left to the glass below, extract syringe needle gradually out, close up glass, take off agrafe, make liquid crystal glue evenly be full of the glass space.
The 7th step, press box, doubling glass taken out from the groove pond be put on the horizontal table top that is covered with heavy sheet glass, place two heavy sheet glass weights and liquid crystal glue is exerted pressure extrude unnecessary liquid crystal glue and make liquid crystal glue thickness even on glass, and clean unnecessary liquid crystal glue with clean dust-free paper.
In the 8th step, uv-exposure exposes aforementioned two sheet glass that poured into liquid crystal glue under ultraviolet lamp, the potpourri of prepolymer and nematic liquid crystal is separated, and ultraviolet lamp intensity is moderate (as light intensity flux 400W/m 2), about 1 minute of time shutter, the prepolymer polymerization reaction take place, nematic liquid crystal is separated out from polymkeric substance, forms diameter less than the liquid crystal droplet of 1 μ m, and products appearance is the stray mist attitude.
The 9th step, welding lead, copper-foil conducting electricity adhesive tape on compacting is pasted on the dislocation limit of reserving, both sides welds upper conductor at the copper-foil conducting electricity adhesive tape.
The tenth step, frame is installed, wrap plastic strip at the glass dual-side of pasting copper-foil conducting electricity, inject in the window frame that the Stainless Steel U slot welding with 0.8~1.5mm wall thickness is connected into, be processed with hole in the middle of one side of window frame, hole can inject flat cam handle, is pasting steel plate on one side flat cam pushes up, rubber skin buffering dottle pin is arranged between steel plate and the glass side, make thus by the band stainless steel frame of two transparent conducting glass laminated polymer dispersed liquid-crystal films and the multi-functional dimming glass of lead.
The multi-functional dimming glass of above-mentioned strain liquid crystal, normality is the stray mist attitude, become full clear state after applying electric field, do not power up and apply shear stress and become dim translucent attitude, by applying and removing bright and translucent three states conversion of scattering, full impregnated that voltage or shear stress can be realized dimming glass, have electric-controlled light-regulating glass, strain dimming glass and three kinds of functions of scattering spread glass.
Used starting material are known commodity on the market among the multi-functional dimming glass preparation method of above-mentioned strain liquid crystal, and related stirrer, sprayer, ultraviolet lamp and glass cutting machine are known tool equipment.Related ultraviolet lamp exposure desk device is that particular design is installed, and liquid crystal glue is special formulation.
Beneficial effect of the present invention: described multi-functional dimming glass is the stray mist attitude under normal conditions, liquid crystal droplet is spherical droplet, liquid crystal molecule does not have consistent the orientation, the optical property of liquid crystal droplet namely is not the isotropy common liq, neither the anisotropy uniaxial crystal, strong light scattering not along rectilinear propagation, again because reflection and refraction take place in the refractive index sudden change, so takes place at liquid crystal and polymer interface place in light beam in liquid crystal droplet.When polymer dispersed liquid crystal layer was applied electric field, liquid crystal molecule roughly was orientated along direction of an electric field in the liquid crystal droplet, so liquid crystal droplet shows as the character of anisotropy uniaxial crystal, and the selective polymer refractive index n pWith liquid crystal ordinary refraction index n oEquate when light vertically passes through the Polymer Dispersed Liquid Crystal thin layer, do not have birefringence effect, the light transmission, the visual angle is bad certainly, and birefringence effect has been seen in the side, and film has light mist.When polymer dispersed liquid crystal layer was applied shear stress, the liquid crystal droplet shape became inclination prolate ellipsoid shape from spheroidal, and liquid crystal molecule roughly is orientated along shear direction, and liquid crystal droplet also can be regarded as the anisotropy uniaxial crystal, is n along the shear direction refractive index eWith refractive index polymer n pUnequal and differ bigger, the vertical shear direction is refractive index n oWith refractive index polymer n pEquate.But incidence natural lights can resolve into along shear direction and two components of vertical shear direction, so along half light scattering of shear direction, along half light transmission of vertical shear direction, at this moment dimming glass just has scattering spread glass function.
The multi-functional dimming glass of strain liquid crystal of the present invention can be realized such three kinds of functions: just can realize that by its two transparent conducting glass being applied voltage the total scattering mist attitude of dimming glass and full clear state change, just can realize that by two sheet glass being applied shear stress the total scattering mist attitude of dimming glass and dim translucent attitude change, be the scattering spread glass when being in translucent attitude, supporting with single chip liquid crystal (LCD) projector or monolithic liquid crystal over silicon (LCOS) projector, projected light polarization direction and light transmission shaft quadrature, there is not transmitted light to waste on glass, total scattering takes place, and the back projection imaging is very clear.Be that the multi-functional dimming glass of strain liquid crystal is current collection controlled dimming glass, strain dimming glass and three kinds of functions of scattering spread glass dimming glass product.
The multi-functional dimming glass of strain liquid crystal of the present invention is compared with existing tempered glass folder electric-controlled light-regulating film product, have new feature: existing electric-controlled light-regulating film manufacturing technology requires high, no matter be heat curing or ultraviolet curing process, it is pure to remove starting material electron levels such as requiring liquid crystal equally, outside ten thousand grades of purifications of workshop environmental requirement etc., its production equipment laminating machine etc. requires high precision, at first produce the film goods of electrically conducting transparent plateholder Polymer Dispersed Liquid Crystal thin layer at dust proof workshop, and then the film goods are clipped between two tempered glass, directly do electric-controlled light-regulating glass just than doing easier with the electrically conducting transparent film with transparent conducting glass.Electric-controlled light-regulating film production line investment huge (tens million of unit), the production cost height, valuable product, the thousands of units of every square meter, product can only be applied to superluxurious finishing field.The multi-functional dimming glass of strain liquid crystal of the present invention is invested little (millions of units only are the investments of dust proof workshop, and equipment is the ultraviolet lamp exposure desk of thousands of units), and technology is simple, and cost of products low (cost of raw material is lower than 480 yuan of every square meters) is widely used.The multi-functional dimming glass of strain liquid crystal need see clearly Chu Quan when transparent the user, can electric-controlled light-regulating; When the dim romance of needs is translucent, can the strain light modulation, energy-conservation not power consumption; When needing protection privacy, can total scattering mist attitude, printing opacity is opaque; Can work as transparent projection screens in translucent attitude uses, the video image of Monolithic LC D projector or the broadcast of Monolithic LC OS projector is throwed up, projected light polarization direction and light transmission shaft quadrature, just there is not the transmitted light waste, total scattering takes place, luminous energy roughly 90% preceding scattering back projection imaging is super clear, and 10% backward scattering front projection imaging is unintelligible.Though the electric-controlled light-regulating film can be by applying the transmittance that the strong and weak height of voltage changes tempered glass folder electric-controlled light-regulating film, because the interface is many, full impregnated bright (transmittance is near 70%), translucent (transmittance 70%~5% voltage is adjustable) and total scattering are arranged, and (transmittance is less than 5%, mist degree is near 95%) the electric-controlled light-regulating transmittance change, but normality is scattering states, and transparent and translucent attitude all needs consumed power.Trans electric-controlled light-regulating glass normality is clear state, applies electric field and becomes scattering states, though there is patented technology also not have practical product.The electric-controlled light-regulating film can be used as transparent projection screens in translucent attitude and use, but its effect is suitable with holographic transparent projection screens imaging effect, there is not scattering spread glass function, projected light energy roughly 50% transmissive slatterns, 30% preceding scattering back projection imaging is clear, and 20% backward scattering front projection is also more clear.Product of the present invention should not use film-transparent conductive glass, and thin glass is too soft, applies the shear stress discontinuity, and dimming effect is bad.Be subjected to transparent conducting glass flatness and area constraints, the multi-functional dimming glass of the present invention also is not suitable for making the large tracts of land product.
The patent of invention of having declared with the inventor, comprise multinomial patents of invention such as various pros-and-cons type strain dimming glass and scattering spread glass comparatively speaking, the present invention has current collection controlled dimming glass, strain dimming glass and scattering spread glass function in the characteristic of one, has the outstanding advantage of multi-functional dimming glass.
Description of drawings
Below in conjunction with drawings and Examples the present invention is done further explanation.
The multi-functional dimming glass principle of work of Fig. 1 strain liquid crystal of the present invention synoptic diagram, Figure 101 normality stray mist attitude, liquid crystal molecule does not have consistent the orientation in the spherical liquid crystal droplet; The full clear state of Figure 102 electric-controlled light-regulating, liquid crystal molecule roughly is orientated along the direction of an electric field vertical plane in the spherical liquid crystal droplet; The translucent attitude of Figure 103 strain light modulation, liquid crystal molecule is roughly along the approximate planar orientation of shear direction in the inclination ellipsoid liquid crystal droplet.
The multi-functional dimming glass structural representation of Fig. 2 strain liquid crystal of the present invention, among Fig. 2,201 stainless steel frames, 202 transparent conducting glass folder polymer dispersed liquid crystal layer, 203 apply the flat cam of shear stress, 204 steel plates and plastic strip and rubber pad, 205 handles, 206 copper foil tapes and wire bonds.
Embodiment
Embodiment 1, and the multi-functional dimming glass of strain liquid crystal is in the dust proof workshop manufacturing, and preparation method's step is:
The first step, the preparation prepolymer, alkoxy nonyl phenyl acrylate with 20%, 70% trimethylolpropane triacrylate, 2% toughner nitrile rubber, 3% chain-transferring agent 2 mercapto ethanol and 5% light trigger 1173 preparation prepolymers, potpourri stirred at ambient temperature fully mixed in 2 minutes, refractive index is n after the prepolymer cures p=1.517.
Second step, preparation liquid crystal glue, the prepolymer of first step configuration is mixed with 1: 1 mass ratio with nematic phase positivity liquid crystal material (liquid crystal PDLC005 is provided by Luquan novel electron material factory), with the stirrer stirring it is fully mixed under the room temperature and form liquid crystal glue, liquid crystal glue is the water white transparency state, and viscosity is less.
The 3rd step, the cleaning glass substrate, the transparent conducting glass of thick resistance per square 50 Ω of 3mm (the emerging strength special glass in Jiangyin company limited provides) is cut into the size of 400X300mm, adding detersive in pure water tank cleans glass substrate, make the clean no dirt of glass surface, clean with purified rinse water, remove water stain with clean dustless dried cloth wiping again.
In the 4th step, the spreading wadding injects 502 instantaneous adhesives and converts butyl acetate reagent in sprayer, adding diameter in the solvent is the wadding plastic microsphere powder of 20 μ m, to a slice this solvent of an amount of sprinkling on glass, treat that solvent evaporates falls, the wadding plastic microsphere is bonded in glass surface.
The 5th step, the combined glass glass, at the wet method spreading a slice another sheet glass that closes on glass of wadding, tilt to be put in the special-purpose enamel tray groove pond, the lower end is clamped with the stainless steel and iron clip in side and is leaned against in the enamel tray, the upper end leans against the enamel tray edge, injects syringe needle, makes the middle wedge gap that forms as thin as a wafer of two sheet glass.
The 6th step, perfusion liquid crystal glue, with an amount of aforementioned liquid crystal glue for preparing with 20g/m 2Consumption be expelled in the space of two sheet glass, treat that the liquid crystal solation to glass below, extracts syringe needle out gradually, close up glass, take off agrafe, make liquid crystal glue evenly be full of the transparent conducting glass space, overflow from the base if any liquid crystal glue in the filling process and then drip in enamel tray and can collect.
The 7th step, press box, doubling glass to be taken off to lie in from enamel tray spreading on the heavy sheet glass desktop, stack on glass is put other two glass weights and is pressed box to make liquid crystal glue even, and cleans the unnecessary liquid crystal glue of extruding with clean dust-free paper.
In the 8th step, uv-exposure leaves the wide dislocation of 5mm with aforementioned two glass that poured into liquid crystal glue, so that the welding conductive lead wire exposes under ultraviolet lamp, the potpourri of prepolymer and nematic liquid crystal is separated, ultraviolet lamp luminous flux 400W/m 2, 1 minute time shutter, goods are by the transparent stray mist attitude that becomes.
The 9th step, welding lead, copper-foil conducting electricity adhesive tape on compacting is pasted on the dislocation limit of reserving, both sides welds upper conductor at the copper-foil conducting electricity adhesive tape, and lead is connected on the power-supply controller of electric.
The tenth step, frame is installed, wrap plastic strip at the glass dual-side of pasting copper-foil conducting electricity, inject in the window frame that the Stainless Steel U slot welding with the 1mm wall thickness is connected into, U-lag window frame inwall spacing 10mm, groove depth 20mm, be processed with φ shape hole in the middle of one side, hole diameter 8mm, the long 12mm of gap can inject flat φ shape cam, cam and handle one, flat cam pushes up on one side and is pasting steel plate, between steel plate and the glass side yielding rubber leather packing and plastic strip is arranged, and makes thus by the band stainless steel frame of two transparent conducting glass laminated polymer dispersed liquid-crystal films and the multi-functional dimming glass of lead.

Claims (9)

1. multi-functional dimming glass of strain liquid crystal is characterized in that it is the band stainless steel frame that is made of two electrically conducting transparent heavy sheet glass folder polymer dispersed liquid crystal layers and the laminated glass articles of power lead.
2. the multi-functional dimming glass of strain liquid crystal according to claim 1 is characterized in that polymer dispersed liquid crystal layer is to make through ultraviolet light polymerization after potpourri by prepolymer and liquid crystal mixes with about 1: 1 mass ratio under certain condition.
3. the multi-functional dimming glass preparation process of strain liquid crystal according to claim 1 is: the potpourri of prepolymer and nematic liquid crystal is filled between two electrically conducting transparent heavy sheet glass, is separated through ultraviolet photoetching, products appearance is the stray mist attitude.
4. polymer dispersed liquid crystal layer according to claim 2, it is characterized in that prepolymer is by polymerisable monomer propoxyl group nonyl phenyl acrylate 15~25%, trimethylolpropane triacrylate 65~75%, chain-transferring agent decanedioic acid 3~5%, 3~5% toughner nitrile rubber, light trigger 1173 is 3~5%, and described number percent is mass percent, and refractive index roughly is n after the prepolymer cures p=1.5.
5. polymer dispersed liquid crystal layer according to claim 2 is characterized in that described liquid crystal material is the positivity nematic liquid crystal, and ordinary refraction index is about n o=1.5, very optical index is about n eMore than=1.7, the birefringence rate variance is between 0.2~0.25.
6. the multi-functional dimming glass of strain liquid crystal according to claim 1, its goods are characterised in that the transparent conducting glass welding lead source that Connects Power, dimming glass is applied electric field, liquid crystal molecule in the polymer dispersed liquid-crystal film is arranged along direction of an electric field, and dimming glass becomes full clear state under electric field action.
7. the multi-functional dimming glass of strain liquid crystal according to claim 1, its goods are characterised in that on the stainless steel frame handle apparatus are installed, pull handle dimming glass is applied shear stress, liquid crystal molecule in the polymer dispersed liquid-crystal film is arranged along shear direction, and dimming glass becomes translucent attitude under shear stress.
8. the translucent attitude of dimming glass according to claim 7 has scattering spread glass function, light transmission shaft vertical shear direction, natural light incident, half light transmission, half light scattering.
9. the multi-functional dimming glass of strain liquid crystal according to claim 1, its application is that it is a kind of current collection controlled dimming glass, strain dimming glass and three kinds of functions of scattering spread glass product, the scattering states mist degree is more than 90%, the full clear state transmittance of electric-controlled light-regulating is near 80%, the dim translucent attitude not consuming electric power of strain light modulation, transmittance is near 40%; Scattering spread glass state has the transparent projection screens function, single chip liquid crystal projector projected light polarization direction and light transmission shaft quadrature, and total scattering takes place in no transmitted light loss, and the back projection imaging is super clear.
CN2013102163259A 2013-06-04 2013-06-04 Strain liquid crystal multifunctional dimming glass, and manufacturing method and application for strain liquid crystal multifunctional dimming glass Pending CN103278959A (en)

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CN103602338A (en) * 2013-11-20 2014-02-26 华映视讯(吴江)有限公司 Manufacture method of polymer dispersing type liquid crystal
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CN103760713A (en) * 2013-12-25 2014-04-30 无锡科技职业学院 Strain liquid crystal dimming display glassware and manufacturing method thereof
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US9284489B2 (en) 2013-11-07 2016-03-15 Chunghwa Picture Tubes, Ltd. Method of manufacturing polymer dispersed liquid crystal
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CN103617776A (en) * 2013-11-27 2014-03-05 广东威创视讯科技股份有限公司 Method and system for adjusting display screen luminance uniformity
CN103617776B (en) * 2013-11-27 2016-04-13 广东威创视讯科技股份有限公司 Brightness of display screen uniformity adjusting method and system
CN103760713B (en) * 2013-12-25 2016-04-20 无锡科技职业学院 A kind of strain liquid crystal light modulation display glassware and preparation method thereof
CN103760713A (en) * 2013-12-25 2014-04-30 无锡科技职业学院 Strain liquid crystal dimming display glassware and manufacturing method thereof
CN105275334A (en) * 2014-06-25 2016-01-27 南京晶多新材料科技有限公司 Structure and application of strain light modulation window
CN105298084A (en) * 2014-06-25 2016-02-03 南京晶多新材料科技有限公司 Structure and application of stressed dimming glass floor
CN105319754A (en) * 2014-06-25 2016-02-10 南京晶多新材料科技有限公司 Construction and application of strain light modulation organic glass product
CN104090323A (en) * 2014-07-01 2014-10-08 深圳市三利谱光电科技股份有限公司 Construction and application of electrically controlled scattering Polaroid
CN105487157A (en) * 2014-08-13 2016-04-13 南京晶多新材料科技有限公司 Construction and application of electric control light modulation film serving as scattering polaroid
CN105717734A (en) * 2014-08-13 2016-06-29 南京晶多新材料科技有限公司 Structure and application of scattering polarized glass transparent projection screen
CN106773434A (en) * 2017-03-29 2017-05-31 常州大学怀德学院 A kind of dimming glass layer and its overpass road surface control system for constituting
CN106773434B (en) * 2017-03-29 2023-08-11 常州大学怀德学院 Dimming glass layer and overpass pavement control system formed by same
CN108628080A (en) * 2018-05-16 2018-10-09 张家港康得新光电材料有限公司 A kind of line holographic projections film and its preparation method and application
CN109432571A (en) * 2018-12-25 2019-03-08 河北化工医药职业技术学院 A kind of psychology hypnosis teaching aid
CN109621155A (en) * 2018-12-25 2019-04-16 河北化工医药职业技术学院 A kind of psychology hypnosis teaching aid
CN109621155B (en) * 2018-12-25 2022-04-05 河北化工医药职业技术学院 Psychology teaching aid that hypnotizes
CN109709704A (en) * 2019-02-28 2019-05-03 京东方科技集团股份有限公司 Dimming glass and preparation method thereof
CN110568689A (en) * 2019-09-05 2019-12-13 浙江大学 Method for regulating orientation of liquid crystal element in colloidal liquid crystal

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