CN107299546B - Method for repairing abnormal color marks and color flowers of nylon cloth - Google Patents
Method for repairing abnormal color marks and color flowers of nylon cloth Download PDFInfo
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- CN107299546B CN107299546B CN201710699906.0A CN201710699906A CN107299546B CN 107299546 B CN107299546 B CN 107299546B CN 201710699906 A CN201710699906 A CN 201710699906A CN 107299546 B CN107299546 B CN 107299546B
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
- D06P5/08—After-treatment with organic compounds macromolecular
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B15/00—Removing liquids, gases or vapours from textile materials in association with treatment of the materials by liquids, gases or vapours
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
- D06B3/10—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06C—FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
- D06C7/00—Heating or cooling textile fabrics
- D06C7/02—Setting
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/24—Polyamides; Polyurethanes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/10—After-treatment with compounds containing metal
Abstract
The invention relates to a method for repairing abnormal color marks and color flowers of nylon cloth, belonging to the technical field of nylon cloth dyeing processing. The method for repairing the abnormal color traces and the abnormal color flowers of the nylon cloth comprises the following steps: rewinding abnormal nylon grey cloth → color correction → color fixation → dehydration → drying middle process → sizing process. Compared with the traditional color repairing process, the repairing method can complete color repairing only by one-time dip dyeing treatment under the condition of no need of color fading, saves a large amount of dyeing water, and has small influence on the quality of cloth; the secondary bleaching and dyeing process after stripping is omitted, the color repairing time is greatly shortened, the using amount and the using types of chemical reagents such as dye, auxiliary agent and the like are reduced, and the sewage discharge amount is reduced; effectively shortens the procedures of repairing the color marks and the color flowers of the prior nylon cloth, obviously reduces the production cost and can be popularized and applied in the field.
Description
Technical Field
The invention belongs to the technical field of nylon cloth dyeing processing, and particularly relates to a method for repairing abnormal color marks and color flowers of nylon cloth.
Background
During printing and dyeing of nylon cloth, problems of competitive dyeing, dyeing defects, color spots, color marks and the like may occur due to the problems of dye property difference, poor adaptability of equipment to dyes, improper setting of process parameters and the like, and printing and dyeing defects need to be repaired.
The traditional color repair process generally comprises the following steps: cloth preparation → stripping → secondary bleaching and dyeing → dehydration → drying in-process → sizing, namely the color of the abnormal cloth needs to be faded out (stripping), and then the required color is bleached and dyed again, the specific procedures include: cloth preparation: rewinding the abnormal cloth and distributing the abnormal cloth to a cloth vehicle; stripping: fading the color of the abnormal cloth; secondary bleaching and dyeing: re-coloring; dehydrating, drying, detecting and confirming bleaching and dyeing quality; and (6) shaping. Wherein, the secondary bleaching and dyeing process is the same as the bleaching and dyeing process, and the used reagents during stripping comprise the following components in percentage by mass: 1-3% of NaOH, 15-20% of peregal O and 5-8% of synthetic detergent, and sequentially adding the reagents into a stripping tank, wherein the bath ratio is 1: 25-30, the temperature is 98 ℃, and the stripping treatment is carried out for 20-30 min until all colors are faded; gradually cooling after stripping, washing with water, placing the cloth in 0.5ml/L acetic acid, treating at 30 deg.C for 10min, neutralizing residual alkali solution, and washing with clear water. In order to improve the color fastness of the cloth, the color fixing treatment can be carried out after the secondary bleaching and dyeing.
Although the traditional color repair process can achieve the repair treatment of abnormal grey cloth, the main defects exist: if the dyeing process is carried out for one time due to the errors of bleaching and dyeing, all colors are bleached out and then bleached and dyed again, so that the bleaching and dyeing working hours are prolonged, the treatment procedures and the use amount of chemical auxiliaries are increased, multiple times of bleaching and dyeing sewage can be generated, and the quality of cloth obtained by secondary bleaching and dyeing is not as good as that of initial bleaching and dyeing.
In the prior art related to the color correction of the cloth, a method for repairing the abnormal color mark of the nylon cloth after the color is patterned is not found. For example, the chinese patent application with the application number of "200910099745.7" entitled "method for fixing color of cotton knitted fabric on forming machine" discloses a method for fixing color of cotton knitted fabric on forming machine, which mainly comprises the following steps: preparing a repairing liquid, preparing grey cloth, padding the repairing liquid, baking by a setting machine, washing, drying, napping and setting, wherein the repairing liquid is mainly used for repairing colors of cotton knitted grey cloth; for example, the application number is '201610452953.0', the invention is named as a dyeing method for preventing cloth cover color spots, white spots and floating colors of light and thin fabrics, and the dyeing method is mainly used for preventing the light and thin fabrics from having color spots, white spots and floating colors, and provides a dyeing scheme capable of preventing the light and thin fabrics from having slight defects, and the scheme has an unsatisfactory prevention effect on fabrics with medium density or above or with large dyeing defects and is not suitable for repairing the color defects of nylon cloth.
Therefore, research on a method for repairing abnormal color traces and color flowers of nylon cloth has become a technical problem to be solved by those skilled in the art.
Disclosure of Invention
The invention aims to solve the defects of the prior art and provide a method for repairing abnormal color traces and color flowers of nylon cloth, which can effectively shorten the repairing working hours, save water, reduce the types and the use amount of chemical additives and obviously reduce the influence of the repaired sewage on the environment.
The invention adopts the following technical scheme:
the method for repairing the abnormal color traces and the abnormal color flowers of the nylon cloth comprises the following steps: rewinding abnormal nylon grey cloth → color correction → color fixation → dehydration → drying middle process → sizing process.
Furthermore, the method for repairing the abnormal color traces and the abnormal color flowers of the nylon cloth comprises the following specific steps:
step one, rewinding abnormal nylon grey cloth: the nylon grey cloth with abnormal color traces and color flowers is rewound to a cloth vehicle;
step two, color correction treatment: sequentially adding 3-5 g/L of leveling agent and 0.2-0.3 g/L of soda ash according to the water amount to obtain color correction liquid, immersing the nylon gray fabric obtained in the step one into the color correction liquid, heating to 100-110 ℃ at a heating rate of 0.4-0.6 ℃/min according to a bath ratio of 1: 10-15, preserving heat for 30-60 min, then cooling to 50 ℃ at a cooling rate of 1-1.5 ℃/min, adjusting the pH value to 4.0-5.0, and preserving heat for 30-40 min; after the heat preservation is finished, heating to 100-110 ℃ at a heating rate of 0.4-0.6 ℃/min, and preserving the heat for 30-60 min;
step three, color fixing treatment: adding 2-4 g/L of color fixing agent according to the amount of water, and putting the gray fabric subjected to color correction treatment in the second step in a bath ratio of 1: 10-15; heating to 80-85 ℃ at a heating rate of 2 ℃/min, preserving heat for 20-30 min, and discharging and washing;
step four, dehydration treatment: dehydrating the grey cloth subjected to color fixing treatment in the third step, and rolling back to a cloth vehicle after dehydration is finished;
step five, drying the intermediate products: feeding the dehydrated grey cloth in the fourth step at a speed of 30-50m/min for drying, inspecting the printing and dyeing quality according to the product quality standard after drying, and rolling up after the product is qualified;
step six, setting treatment: and (4) sizing the grey cloth dried and detected in the fifth step at 165-185 ℃.
Preferably, the leveling agent in the second step is a fatty alcohol polyoxyethylene ether type leveling agent.
Preferably, the fixing agent in step three is an acidic fixing agent.
Furthermore, the temperature of the drying in the fifth step is 150-170 ℃.
Furthermore, the cloth feeding speed during the shaping in the sixth step is 45-55 m/min x width x (1+ overfeed rate), wherein the overfeed rate is 4-6%, and the width is 1.8-2.0 m.
Compared with the prior art, the invention has the beneficial effects that:
firstly, the method comprises the following steps: compared with the traditional color repairing process, the invention can complete color repairing only by one-time dip dyeing treatment without color fading, saves a large amount of dyeing water and has little influence on the quality of cloth;
secondly, the method comprises the following steps: the invention omits the secondary bleaching and dyeing process after stripping, greatly shortens the color repairing time, reduces the dosage and the use variety of chemical reagents such as dye, auxiliary agent and the like, and reduces the water dosage and the sewage discharge;
thirdly, the method comprises the following steps: the invention effectively shortens the procedures of repairing the color marks and the color flowers of the prior nylon cloth, obviously reduces the production cost and can be popularized and applied in the field.
Detailed Description
The present invention will be described in further detail with reference to examples.
It will be appreciated by those skilled in the art that the following examples are illustrative of the invention only and should not be taken as limiting the scope of the invention. The leveling agent used in the invention is polyoxyethylene ether leveling agent peregal O, and the reagent raw materials used in the invention can be purchased unless specially stated.
Example 1
The nylon cloth with partial colored flowers on the surface is repaired, which comprises the following steps: rewinding abnormal nylon grey cloth → color correction → color fixation → dehydration → drying middle process → shaping process, which is concretely as follows:
step one, rewinding abnormal nylon grey cloth: rewinding the nylon grey cloth with abnormal color patterns to a cloth vehicle;
step two, color correction treatment: the color repairing equipment adopts a Jiangsu instrumental TMH128-220 overflow jig dyeing machine, 5g/L of peregal O (Federal Fine chemical Co., Ltd., industrial product) and 0.3g/L of soda (Federal Fine chemical Co., Ltd., industrial product) are sequentially added according to the water content to obtain a color repairing liquid, the nylon grey cloth in the step one is immersed into the color repairing liquid, the bath ratio is 1:10, the temperature is increased to 110 ℃ at the temperature increasing rate of 0.4 ℃/min, the temperature is kept for 30min, then the temperature is decreased to 50 ℃ at the temperature decreasing rate of 1 ℃/min, the pH is adjusted to 4.0 by acetic acid (Hengzhou Wei industrial chemical Co., Ltd., industrial product) and the temperature is kept for 30 min; after the heat preservation is finished, heating to 110 ℃ at the heating rate of 0.4 ℃/min, and preserving the heat for 30 min;
step three, color fixing treatment: and the color fixing equipment adopts a Jiangsu ceremony TMH128-220 overflow jig dyeing machine, 2g/L of an acidic color fixing agent O-LA type (Guangzhou Rihong chemical industry Co., Ltd., industrial product) is added according to the water amount, the gray fabric after color repairing treatment in the second step is put in, and the bath ratio is 1: 10; heating to 80 ℃ at the heating rate of 2 ℃/min, preserving the heat for 30min, and discharging and washing the cloth;
step four, dehydration treatment: dehydrating the grey cloth subjected to color fixing treatment in the third step, and rolling back to a cloth vehicle after dehydration is finished;
step five, drying the intermediate products: the drying equipment adopts a Taiwan Ligen ST82000HO setting machine, the grey cloth dehydrated in the step four is sent for drying at the speed of 30m/min, the temperature during drying is 170 ℃, the printing and dyeing quality is checked according to the product quality standard after drying, and the grey cloth is rewound after being qualified;
step six, setting treatment: the sizing equipment adopts a Taiwan Ligen ST82000HO sizing machine, the gray fabric which is dried and detected in the fifth step is sized at 185 ℃, the cloth feeding speed during sizing is (55 multiplied by 2 multiplied by 1.06) m/min, wherein the overfeed rate is 6 percent, and the width is 2.0 m.
Example 2
The nylon cloth with partial colored flowers on the surface is repaired, which comprises the following steps: rewinding abnormal nylon grey cloth → color correction → color fixation → dehydration → drying middle process → shaping process, which is concretely as follows:
step one, rewinding abnormal nylon grey cloth: rewinding the nylon grey cloth with abnormal color patterns to a cloth vehicle;
step two, color correction treatment: the color repairing equipment adopts a Jiangsu instrumental TMH128-220 overflow jig dyeing machine, 3g/L of peregal O (Federal Fine chemical Co., Ltd., industrial product) and 0.2g/L of soda (Federal Fine chemical Co., Ltd., industrial product) are sequentially added according to the water content to obtain a color repairing liquid, the nylon grey cloth in the step one is immersed into the color repairing liquid, the bath ratio is 1:15, the temperature is raised to 100 ℃ at the temperature raising rate of 0.6 ℃/min, the temperature is kept for 40min, then the temperature is lowered to 50 ℃ at the temperature lowering rate of 1.5 ℃/min, the pH is adjusted to 5.0 by acetic acid (industrial product, Shengzhou Weiyi chemical Co., Ltd., industrial product) and the temperature is kept for 40 min; after the heat preservation is finished, heating to 100 ℃ at the heating rate of 0.6 ℃/min, and preserving the heat for 60 min;
step three, color fixing treatment: and the color fixing equipment adopts a Jiangsu ceremony TMH128-220 overflow jig dyeing machine, 4g/L of an acidic color fixing agent O-LA type (Guangzhou Rihong chemical industry Co., Ltd., industrial product) is added according to the water amount, the gray fabric after color repairing treatment in the second step is put in, and the bath ratio is 1: 15; heating to 85 ℃ at the heating rate of 2 ℃/min, preserving the heat for 20min, and discharging and washing the cloth;
step four, dehydration treatment: dehydrating the grey cloth subjected to color fixing treatment in the third step, and rolling back to a cloth vehicle after dehydration is finished;
step five, drying the intermediate products: the drying equipment adopts a Taiwan Ligen ST82000HO setting machine, the grey cloth dehydrated in the step four is sent for drying at the speed of 50m/min, the temperature during drying is 150 ℃, the printing and dyeing quality is checked according to the product quality standard after drying, and the grey cloth is rewound after being qualified;
step six, setting treatment: the sizing equipment adopts a Taiwan Laiguan ST82000HO sizing machine, the gray fabric which is dried and detected in the fifth step is sized at 165 ℃, the cloth feeding speed during sizing is (45 multiplied by 1.8 multiplied by 1.04) m/min, the overfeeding rate is 4%, and the width is 1.8 m.
Comparative example
Adopting a traditional color-modifying process to modify the color of the nylon cloth: cloth preparation → color stripping → secondary bleaching and dyeing → dehydration → drying and middle-checking → sizing.
The water consumption, the total process time, the dye assistant usage amount, and the amount of sewage generated after the restoration treatment in examples 1 and 2 and comparative example were compared (in the case of 500kg cloth), and the results are shown in table 1 below:
TABLE 1 comparative data sheet
It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, which are described in the specification and illustrated only to illustrate the principle of the present invention, but that various changes and modifications may be made therein without departing from the spirit and scope of the present invention, which fall within the scope of the invention as claimed. The scope of the invention is defined by the appended claims and equivalents thereof.
Claims (3)
1. The method for repairing the abnormal color traces and the abnormal color flowers of the nylon cloth comprises the following steps: the method comprises the following steps of rolling abnormal nylon grey cloth → color correction → color fixation → dehydration → drying middle detection → shaping, and is characterized in that the method comprises the following steps:
step one, rewinding abnormal nylon grey cloth: the nylon grey cloth with abnormal color traces and color flowers is rewound to a cloth vehicle;
step two, color correction treatment: sequentially adding 3-5 g/L of polyoxyethylene ether leveling agent and 0.2-0.3 g/L of soda ash according to the water amount to obtain color correction liquid, immersing the nylon grey cloth in the color correction liquid in a bath ratio of 1: 10-15, heating to 100-110 ℃ at a heating rate of 0.4-0.6 ℃/min, preserving heat for 30-60 min, then cooling to 50 ℃ at a cooling rate of 1-1.5 ℃/min, adjusting the pH value to 4.0-5.0, and preserving heat for 30-40 min; after the heat preservation is finished, heating to 100-110 ℃ at a heating rate of 0.4-0.6 ℃/min, and preserving the heat for 30-60 min;
step three, color fixing treatment: adding 2-4 g/L of acidic color fixing agent according to the amount of water, and putting the gray fabric subjected to color correction treatment in the second step in a bath ratio of 1: 10-15; heating to 80-85 ℃ at a heating rate of 2 ℃/min, preserving heat for 20-30 min, and discharging and washing;
step four, dehydration treatment: dehydrating the grey cloth subjected to color fixing treatment in the third step, and rolling back to a cloth vehicle after dehydration is finished;
step five, drying the intermediate products: feeding the dehydrated grey cloth in the fourth step at a speed of 30-50m/min for drying, inspecting the printing and dyeing quality according to the product quality standard after drying, and rolling up after the product is qualified;
step six, setting treatment: and (4) sizing the grey cloth dried and detected in the fifth step at 165-185 ℃.
2. The method for repairing the abnormal color traces and flowers of the nylon cloth according to claim 1, wherein the temperature of the drying in the fifth step is 150-170 ℃.
3. The method for repairing the abnormal color traces and flowers of the nylon cloth according to claim 1, wherein the cloth feeding speed during the setting in the sixth step is 45-55 m/min x width x (1+ overfeed rate), wherein the overfeed rate is 4-6% and the width is 1.8-2.0 m.
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CN109652974A (en) * | 2018-12-06 | 2019-04-19 | 山东玫姿蓝家纺有限公司 | A kind of Woollen blanket printing technique |
CN112080953B (en) * | 2020-05-12 | 2023-01-17 | 苏州联胜化学有限公司 | Repairing dye and preparation method and use method thereof |
CN111996818A (en) * | 2020-07-31 | 2020-11-27 | 信诚染织(福建)有限公司 | Method for repairing abnormal color marks and color flowers of nylon cloth |
CN111996822A (en) * | 2020-09-11 | 2020-11-27 | 广东德美精细化工集团股份有限公司 | Finishing method for effectively reducing dyeing difference of chinlon |
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CN101684620B (en) * | 2009-06-18 | 2011-09-14 | 浙江银河印染有限公司 | Method for color retouching of cotton knitted fabric on forming machine |
CN102953278A (en) * | 2011-08-24 | 2013-03-06 | 冯祥茂 | Production process of textile fiber color modifier |
CN104131429A (en) * | 2014-07-18 | 2014-11-05 | 晋江市龙兴隆染织实业有限公司 | Color retouching technology for correcting colored light by shaping padder through padding |
CN104328695A (en) * | 2014-11-21 | 2015-02-04 | 浙江振大纺织印染有限公司 | Migration and color-pulling treatment method for printing cloth with excessively deep color |
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