CN107298947A - A kind of SGP films and preparation method thereof - Google Patents
A kind of SGP films and preparation method thereof Download PDFInfo
- Publication number
- CN107298947A CN107298947A CN201710674868.3A CN201710674868A CN107298947A CN 107298947 A CN107298947 A CN 107298947A CN 201710674868 A CN201710674868 A CN 201710674868A CN 107298947 A CN107298947 A CN 107298947A
- Authority
- CN
- China
- Prior art keywords
- parts
- sgp films
- hydrolysis
- ultra
- resisting agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/04—Homopolymers or copolymers of ethene
- C09J123/08—Copolymers of ethene
- C09J123/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C09J123/0869—Acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J183/00—Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Adhesives based on derivatives of such polymers
- C09J183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
- C09J2301/408—Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the adhesive layer
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2423/00—Presence of polyolefin
- C09J2423/04—Presence of homo or copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2483/00—Presence of polysiloxane
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Laminated Bodies (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of SGP films and preparation method thereof, the SGP films include according to the raw material of parts by weight：10 50 parts of ethylene methyl acrylate copolymer, 10 50 parts of organic siliconresin, 5 30 parts of terpene resin, 0.1 10 parts of tetrabutyl titanate, 1 10 parts of aliphatic amine polyoxyethylene ether, 0.1 12 parts of organotin, 2 15 parts of antioxidant, 0.05 8 parts of hydrolysis-resisting agent, 0.05 8 parts of ultra-violet absorber.Ball milling is carried out to tetrabutyl titanate, aliphatic amine polyoxyethylene ether, organotin, hydrolysis-resisting agent with ball mill, then emulsification pretreatment machine, mixed processing, standing are added with antioxidant, ultra-violet absorber；Then Twin screw extruder extrusion is added with other raw materials and produces SGP films.SGP films produced by the present invention, end properties are stable, and anti-uv-ray is strong, and preferably, tensile strength and shading coefficient are high for infrared resistant ability.The raw material that the present invention is used is easy to get, and preparation technology is simple, and easy to operate, production cost is low, suitable for industrialized production.
Description
Technical field
The present invention relates to glass material field, specifically a kind of SGP films and preparation method thereof.
Background technology
Glass is due to its good optical property, rigid and cheap cost, in fields such as decorating building decoration, automobiles
In be increasingly widely applied.But monolithic glass haves the shortcomings that frangible, shock resistance is poor, easily hinders after glass breaking
People.In order to keep the high transparency of glass visual, while improving the impact strength of glass, laminated glass arises at the historic moment.Interlayer
Glass be using intermediate coat by two panels or divided glass be bonded together formed by compound glass, because glass is by external impacts
Still sticked together, thus human body will not be damaged by intermediate coat after rupture, while intermediate coat can greatly improve glass
Impact strength.It is also increasing as the film demand of middle membrane material with the extensive use of laminated glass.General glue
Piece is PVB films or EVA films.But the problem of film existence and stability that is produced under conventional art is poor, infrared ray stops difference.
The content of the invention
It is an object of the invention to provide a kind of SGP films and preparation method thereof, to solve to propose in above-mentioned background technology
The problem of.
To achieve the above object, the present invention provides following technical scheme：
A kind of SGP films, include according to the raw material of parts by weight：0-50 parts of ethylene-methyl acrylate copolymer 1, organosilicon tree
10-50 parts of fat, 5-30 parts of terpene resin, 0.1-10 parts of tetrabutyl titanate, 1-10 parts of aliphatic amine polyoxyethylene ether, organotin 0.1-
12 parts, 2-15 parts of antioxidant, 0.05-8 parts of hydrolysis-resisting agent, 0.05-8 parts of ultra-violet absorber.
It is used as further scheme of the invention：The hydrolysis-resisting agent is N, N'- DICs, dicyclohexyl carbon
One kind in diimine.
It is used as further scheme of the invention：The hydrolysis-resisting agent is dicyclohexylcarbodiimide.
It is used as further scheme of the invention：The ultra-violet absorber is 2-hydroxy-4-n-octoxybenzophenone, 2-
One kind in hydroxyl -4- oxy-octyl benzophenones.
It is used as further scheme of the invention：The SGP films, include according to the raw material of parts by weight：Ethene-metering system
12-45 parts of acid ester copolymer, 15-45 parts of organic siliconresin, 6-28 parts of terpene resin, 0.2-8 parts of tetrabutyl titanate, fatty amine gather
2-8 parts of oxygen vinethene, 0.5-10 parts of organotin, 3-12 parts of antioxidant, 0.08-6 parts of hydrolysis-resisting agent, ultra-violet absorber 0.08-6
Part.
It is used as further scheme of the invention：The SGP films, include according to the raw material of parts by weight：Ethene-metering system
12-40 parts of acid ester copolymer, 18-40 parts of organic siliconresin, 8-25 parts of terpene resin, 0.5-5 parts of tetrabutyl titanate, fatty amine gather
3-7 parts of oxygen vinethene, 1-8 parts of organotin, 5-10 parts of antioxidant, 0.1-5 parts of hydrolysis-resisting agent, 0.1-5 parts of ultra-violet absorber.
The preparation method of the SGP films, comprises the following steps：
1）Ball milling is carried out to tetrabutyl titanate, aliphatic amine polyoxyethylene ether, organotin, hydrolysis-resisting agent with ball mill, mixing is made
Thing A；
2）Said mixture A and antioxidant, ultra-violet absorber are added into emulsification pretreatment machine, mixed processing 40-70min is stood
1-5h, is made mixture B；
3）Ethylene-methyl acrylate copolymer, organic siliconresin, terpene resin and mixture B are added into Twin screw extruder,
Extrusion produces SGP films after blended, plasticizing, exhaust.
It is used as further scheme of the invention：Step 1）In, Ball-milling Time is 1-5h.
It is used as further scheme of the invention：Step 1）In, in ball mill, based on kg/L, ratio of grinding media to material is（1-6）：10.
Compared with prior art, the beneficial effects of the invention are as follows：
The present invention is using SGP films made from above-mentioned raw materials and preparation technology, and end properties are stable, and anti-uv-ray is strong, resist
Preferably, tensile strength and shading coefficient are high for infrared capable.The raw material that the present invention is used is easy to get, and preparation technology is simple, easy to operate,
Production cost is low, suitable for industrialized production.
Embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described,
Obviously, described embodiment is only a part of embodiment of the invention, rather than whole embodiments.Based in the present invention
Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all
Belong to the scope of protection of the invention.
Embodiment 1
In the embodiment of the present invention, a kind of SGP films, including following raw material：It is ethylene-methyl acrylate copolymer 1 0kg, organic
Silicones 10kg, terpene resin 5kg, tetrabutyl titanate 0.1kg, aliphatic amine polyoxyethylene ether 1kg, organotin 0.1kg, antioxidant
2kg, hydrolysis-resisting agent 0.05kg, ultra-violet absorber 0.05kg.
The hydrolysis-resisting agent is N, N'- DICs.The ultra-violet absorber is the just pungent oxygen of 2- hydroxyls -4-
Base benzophenone.
The preparation method of the SGP films, comprises the following steps：
1）Ball milling 1h, ball mill are carried out to tetrabutyl titanate, aliphatic amine polyoxyethylene ether, organotin, hydrolysis-resisting agent with ball mill
In, based on kg/L, ratio of grinding media to material is 1：10, mixture A is made.
2）Said mixture A and antioxidant, ultra-violet absorber are added into emulsification pretreatment machine, mixed processing 40min is stood
1h, is made mixture B.
3）Ethylene-methyl acrylate copolymer, organic siliconresin, terpene resin and mixture B addition double helix are squeezed
Go out machine, extrusion produces SGP films after blended, plasticizing, exhaust.
Embodiment 2
In the embodiment of the present invention, a kind of SGP films, including following raw material：It is ethylene-methyl acrylate copolymer 50kg, organic
Silicones 50kg, terpene resin 30kg, tetrabutyl titanate 10kg, aliphatic amine polyoxyethylene ether 10kg, organotin 12kg, antioxidant
15kg, hydrolysis-resisting agent 8kg, ultra-violet absorber 8kg.
The hydrolysis-resisting agent is N, N'- DICs.The ultra-violet absorber is the just pungent oxygen of 2- hydroxyls -4-
Base benzophenone.
The preparation method of the SGP films, comprises the following steps：
1）Ball milling 5h, ball mill are carried out to tetrabutyl titanate, aliphatic amine polyoxyethylene ether, organotin, hydrolysis-resisting agent with ball mill
In, based on kg/L, ratio of grinding media to material is 6：10, mixture A is made.
2）Said mixture A and antioxidant, ultra-violet absorber are added into emulsification pretreatment machine, mixed processing 70min is stood
5h, is made mixture B.
3）Ethylene-methyl acrylate copolymer, organic siliconresin, terpene resin and mixture B addition double helix are squeezed
Go out machine, extrusion produces SGP films after blended, plasticizing, exhaust.
Embodiment 3
In the embodiment of the present invention, a kind of SGP films, including following raw material：It is ethylene-methyl acrylate copolymer 1 2kg, organic
Silicones 15kg, terpene resin 6kg, tetrabutyl titanate 0.2kg, aliphatic amine polyoxyethylene ether 2kg, organotin 0.5kg, antioxidant
3kg, hydrolysis-resisting agent 0.08kg, ultra-violet absorber 0.08kg.
The hydrolysis-resisting agent is dicyclohexylcarbodiimide.The ultra-violet absorber is 2- hydroxyl -4- n-octyloxies two
Benzophenone.
The preparation method of the SGP films, comprises the following steps：
1）Ball milling 2h, ball mill are carried out to tetrabutyl titanate, aliphatic amine polyoxyethylene ether, organotin, hydrolysis-resisting agent with ball mill
In, based on kg/L, ratio of grinding media to material is 2：10, mixture A is made.
2）Said mixture A and antioxidant, ultra-violet absorber are added into emulsification pretreatment machine, mixed processing 50min is stood
2h, is made mixture B.
3）Ethylene-methyl acrylate copolymer, organic siliconresin, terpene resin and mixture B addition double helix are squeezed
Go out machine, extrusion produces SGP films after blended, plasticizing, exhaust.
Embodiment 4
In the embodiment of the present invention, a kind of SGP films, including following raw material：It is ethylene-methyl acrylate copolymer 45kg, organic
Silicones 45kg, terpene resin 28kg, tetrabutyl titanate 8kg, aliphatic amine polyoxyethylene ether 8kg, organotin 10kg, antioxidant
12kg, hydrolysis-resisting agent 6kg, ultra-violet absorber 6kg.
The hydrolysis-resisting agent is dicyclohexylcarbodiimide.The ultra-violet absorber is 2- hydroxyl -4- n-octyloxies two
Benzophenone.
The preparation method of the SGP films, comprises the following steps：
1）Ball milling 4h, ball mill are carried out to tetrabutyl titanate, aliphatic amine polyoxyethylene ether, organotin, hydrolysis-resisting agent with ball mill
In, based on kg/L, ratio of grinding media to material is 5：10, mixture A is made.
2）Said mixture A and antioxidant, ultra-violet absorber are added into emulsification pretreatment machine, mixed processing 60min is stood
4h, is made mixture B.
3）Ethylene-methyl acrylate copolymer, organic siliconresin, terpene resin and mixture B addition double helix are squeezed
Go out machine, extrusion produces SGP films after blended, plasticizing, exhaust.
Embodiment 5
In the embodiment of the present invention, a kind of SGP films, including following raw material：It is ethylene-methyl acrylate copolymer 1 2kg, organic
Silicones 18kg, terpene resin 8kg, tetrabutyl titanate 0.5kg, aliphatic amine polyoxyethylene ether 3kg, organotin 1kg, antioxidant
5kg, hydrolysis-resisting agent 0.1kg, ultra-violet absorber 0.1kg.
The hydrolysis-resisting agent is dicyclohexylcarbodiimide.
The ultra-violet absorber is 2-hydroxy-4-n-octoxybenzophenone.
The preparation method of the SGP films, comprises the following steps：
1）Ball milling 3h, ball mill are carried out to tetrabutyl titanate, aliphatic amine polyoxyethylene ether, organotin, hydrolysis-resisting agent with ball mill
In, based on kg/L, ratio of grinding media to material is 3：10, mixture A is made.
2）Said mixture A and antioxidant, ultra-violet absorber are added into emulsification pretreatment machine, mixed processing 50min is stood
3h, is made mixture B.
3）Ethylene-methyl acrylate copolymer, organic siliconresin, terpene resin and mixture B addition double helix are squeezed
Go out machine, extrusion produces SGP films after blended, plasticizing, exhaust.
Embodiment 6
In the embodiment of the present invention, a kind of SGP films, including following raw material：It is ethylene-methyl acrylate copolymer 40kg, organic
Silicones 40kg, terpene resin 25kg, tetrabutyl titanate 5kg, aliphatic amine polyoxyethylene ether 7kg, organotin 8kg, antioxidant
10kg, hydrolysis-resisting agent 5kg, ultra-violet absorber 5kg.
The hydrolysis-resisting agent is dicyclohexylcarbodiimide.The ultra-violet absorber is 2- hydroxyl -4- n-octyloxies two
Benzophenone.
The preparation method of the SGP films, comprises the following steps：
1）Ball milling 2.5h, ball milling are carried out to tetrabutyl titanate, aliphatic amine polyoxyethylene ether, organotin, hydrolysis-resisting agent with ball mill
In machine, based on kg/L, ratio of grinding media to material is 3：10, mixture A is made.
2）Said mixture A and antioxidant, ultra-violet absorber are added into emulsification pretreatment machine, mixed processing 55min is stood
3.5, mixture B is made.
3）Ethylene-methyl acrylate copolymer, organic siliconresin, terpene resin and mixture B addition double helix are squeezed
Go out machine, extrusion produces SGP films after blended, plasticizing, exhaust.
The performance test of 1-6 products of the embodiment of the present invention is as described below, as a result as shown in table 1-2：
（1）Physical property is evaluated and tested according to ISO system certifications.
（2）Test condition is：Room temperature is 10-25 degrees Celsius, humidity 10-30%.
Table 1
| Performance indications | Tensile strength/MPa | Acid number/（mgKOH/g） |
| Standard items | 60.5 | 4.0 |
| Embodiment 1 | 81.5 | 4.4 |
| Embodiment 2 | 81.8 | 4.4 |
| Embodiment 3 | 82.5 | 4.5 |
| Embodiment 4 | 82.7 | 4.5 |
| Embodiment 5 | 83.9 | 4.5 |
| Embodiment 6 | 84.1 | 4.5 |
Table 2
| Performance indications | Ultraviolet isolating rate/% | Infrared ray rejection rate/% | Visible light transmissivity/% | Shading coefficient |
| Standard items | 56.5 | 80 | 80 | 0.72 |
| Embodiment 1 | 98.5 | 82 | 78 | 0.74 |
| Embodiment 2 | 99.2 | 83 | 79 | 0.74 |
| Embodiment 3 | 100 | 85 | 74 | 0.75 |
| Embodiment 4 | 100 | 86 | 75 | 0.76 |
| Embodiment 5 | 100 | 88 | 72 | 0.76 |
| Embodiment 6 | 100 | 89 | 72 | 0.77 |
From experimental data, embodiment 1-6 properties are superior to standard items.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power
Profit is required rather than described above is limited, it is intended that all in the implication and scope of the equivalency of claim by falling
Change is included in the present invention.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each embodiment is only wrapped
Containing an independent technical scheme, this narrating mode of specification is only that for clarity, those skilled in the art should
Using specification as an entirety, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
It may be appreciated other embodiment.
Claims (9)
1. a kind of SGP films, it is characterised in that include according to the raw material of parts by weight：Ethylene-methyl acrylate copolymer 1 0-
50 parts, 10-50 parts of organic siliconresin, 5-30 parts of terpene resin, 0.1-10 parts of tetrabutyl titanate, aliphatic amine polyoxyethylene ether 1-10
Part, 0.1-12 parts of organotin, 2-15 parts of antioxidant, 0.05-8 parts of hydrolysis-resisting agent, 0.05-8 parts of ultra-violet absorber.
2. SGP films according to claim 1, it is characterised in that the hydrolysis-resisting agent is N, N'- diisopropyls carbon two is sub-
One kind in amine, dicyclohexylcarbodiimide.
3. SGP films according to claim 2, it is characterised in that the hydrolysis-resisting agent is dicyclohexylcarbodiimide.
4. SGP films according to claim 1, it is characterised in that the ultra-violet absorber is the just pungent oxygen of 2- hydroxyls -4-
One kind in base benzophenone, 2-hydroxy-4-n-octoxybenzophenone.
5. SGP films according to claim 1, it is characterised in that include according to the raw material of parts by weight：Ethene-methyl-prop
12-45 parts of olefin(e) acid ester copolymer, 15-45 parts of organic siliconresin, 6-28 parts of terpene resin, 0.2-8 parts of tetrabutyl titanate, fatty amine
2-8 parts of APEO, 0.5-10 parts of organotin, 3-12 parts of antioxidant, 0.08-6 parts of hydrolysis-resisting agent, ultra-violet absorber
0.08-6 parts.
6. SGP films according to claim 1, it is characterised in that include according to the raw material of parts by weight：Ethene-methyl-prop
12-40 parts of olefin(e) acid ester copolymer, 18-40 parts of organic siliconresin, 8-25 parts of terpene resin, 0.5-5 parts of tetrabutyl titanate, fatty amine
3-7 parts of APEO, 1-8 parts of organotin, 5-10 parts of antioxidant, 0.1-5 parts of hydrolysis-resisting agent, 0.1-5 parts of ultra-violet absorber.
7. the preparation method of a kind of SGP films as described in claim 1-6 is any, it is characterised in that comprise the following steps：
1）Ball milling is carried out to tetrabutyl titanate, aliphatic amine polyoxyethylene ether, organotin, hydrolysis-resisting agent with ball mill, mixing is made
Thing A；
2）Said mixture A and antioxidant, ultra-violet absorber are added into emulsification pretreatment machine, mixed processing 40-70min is stood
1-5h, is made mixture B；
3）Ethylene-methyl acrylate copolymer, organic siliconresin, terpene resin and mixture B are added into Twin screw extruder,
Extrusion produces SGP films after blended, plasticizing, exhaust.
8. the preparation method of SGP films according to claim 7, it is characterised in that step 1）In, Ball-milling Time is 1-
5h。
9. the preparation method of SGP films according to claim 7, it is characterised in that step 1）In, in ball mill, by kg/
L is counted, and ratio of grinding media to material is（1-6）：10.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710674868.3A CN107298947A (en) | 2017-08-09 | 2017-08-09 | A kind of SGP films and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710674868.3A CN107298947A (en) | 2017-08-09 | 2017-08-09 | A kind of SGP films and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107298947A true CN107298947A (en) | 2017-10-27 |
Family
ID=60134315
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710674868.3A Withdrawn CN107298947A (en) | 2017-08-09 | 2017-08-09 | A kind of SGP films and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107298947A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20130192673A1 (en) * | 2010-03-26 | 2013-08-01 | Lintec Corporation | Protective sheet for solar cell module, and solar cell module |
| JP2014125511A (en) * | 2012-12-25 | 2014-07-07 | Kuraray Co Ltd | Adhesive laminated body |
| CN105385387A (en) * | 2015-12-23 | 2016-03-09 | 青岛拓联信息技术有限公司 | Hot-melt adhesive |
| CN105400110A (en) * | 2015-12-21 | 2016-03-16 | 忠信（清远）光伏材料科技有限公司 | Preparation method of polyvinyl butyral (PVB) film with improved adhesion stress |
-
2017
- 2017-08-09 CN CN201710674868.3A patent/CN107298947A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20130192673A1 (en) * | 2010-03-26 | 2013-08-01 | Lintec Corporation | Protective sheet for solar cell module, and solar cell module |
| JP2014125511A (en) * | 2012-12-25 | 2014-07-07 | Kuraray Co Ltd | Adhesive laminated body |
| CN105400110A (en) * | 2015-12-21 | 2016-03-16 | 忠信（清远）光伏材料科技有限公司 | Preparation method of polyvinyl butyral (PVB) film with improved adhesion stress |
| CN105385387A (en) * | 2015-12-23 | 2016-03-09 | 青岛拓联信息技术有限公司 | Hot-melt adhesive |
Non-Patent Citations (3)
| Title |
|---|
| 国家药品监督管理局信息中心: "《新编世界精细化学品手册》", 30 April 2000, 国家药品监督管理局信息中心 * |
| 汪菊英等: "《塑料助剂品种及选用速查手册》", 31 January 2017, 文化发展出版社 * |
| 白振中等: "《工程玻璃深加工技术手册》", 30 April 2011, 中国建材工业出版社 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101626993B (en) | Laminated glass for window and glass window member | |
| US20190016096A1 (en) | High tg monolithic poly(vinyl acetal) sheet | |
| CN101374656A (en) | Thermoplastic resin compositions suitable for use in laminated safety glass | |
| CN102199375B (en) | Ultraviolet (UV) paint solidified by ultraviolet light | |
| CN103588954A (en) | OCA optical adhesive tape and making method thereof | |
| US20170197391A1 (en) | Three-layer uv protective film for decorative laminated sheets (hpl) | |
| CN108215411A (en) | A kind of polypropylene/polyvinylidene fluoride co-extrusion protective film and preparation method thereof | |
| CN106833407A (en) | A kind of IT product high-temperature resistant self-adhesive diaphragm | |
| CN103456817A (en) | Fluoride-free solar cell back panel and manufacturing method thereof | |
| CN107118481A (en) | A kind of outdoor section bar composite protection film and preparation method thereof | |
| CN107177146A (en) | A kind of weather-resistance flame-retardant high-performance glass surface protection film and preparation method thereof | |
| US20160252723A1 (en) | Laminated structure for displaying information | |
| CN107298947A (en) | A kind of SGP films and preparation method thereof | |
| CN104694028B (en) | A kind of optical cement and its production method | |
| JP4441414B2 (en) | Vinylidene fluoride resin film | |
| CN111440520A (en) | Polyurethane varnish and preparation method and application thereof | |
| CN109810433A (en) | A kind of dumb light PVC decorative film reducing product surface brightness | |
| CN105176428A (en) | High-definition EVA (ethylene vinyl acetate copolymer) laminated glass middle film and preparation method thereof | |
| CN102585715B (en) | Colored EVA (Ethylene Vinyl-Acetate copolymer) interlayer rubber sheet | |
| CN102922842A (en) | Solar cell back panel film and preparation method thereof | |
| CN108034370A (en) | A kind of ultraviolet curing EMMA optical films of absorbable blue light and preparation method thereof | |
| CN106009830A (en) | Computer advertising art design sample surface protection coating material | |
| KR101550756B1 (en) | Adhesive composition for touch screen panel and adhesive film using the same | |
| CN111959075A (en) | Multi-layer co-extrusion high-barrier film applied to vacuum insulation panel packaging | |
| CN104974704A (en) | TPU (thermoplastic polyurethane) film/fabric-compounding polyurethane adhesive and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information | ||
| CB02 | Change of applicant information |
Address after: 276805 Huifeng Road, industrial park, taoluo Town, Donggang District, Rizhao City, Shandong Province Applicant after: Fangding Technology Co.,Ltd. Address before: 276805 Huifeng Road, industrial park, taoluo Town, Donggang District, Rizhao City, Shandong Province Applicant before: SHANDONG FANGDING SAFETY GLASS TECHNOLOGY Co.,Ltd. |
|
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20171027 |