CN107298875A - A kind of economic and environment-friendly type disperse dyes - Google Patents
A kind of economic and environment-friendly type disperse dyes Download PDFInfo
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- CN107298875A CN107298875A CN201710554594.4A CN201710554594A CN107298875A CN 107298875 A CN107298875 A CN 107298875A CN 201710554594 A CN201710554594 A CN 201710554594A CN 107298875 A CN107298875 A CN 107298875A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0041—Blends of pigments; Mixtured crystals; Solid solutions mixtures containing one azo dye
- C09B67/0042—Mixtures containing two reactive dyes one of them being an azo dye
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
- C09B67/008—Preparations of disperse dyes or solvent dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0041—Blends of pigments; Mixtured crystals; Solid solutions mixtures containing one azo dye
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
- C09B67/0079—Azoic dyestuff preparations
Abstract
A kind of economic and environment-friendly type disperse dyes, are related to a kind of composite disperse dye, including several dispersion dyes monomers and neutral inorganic monomer.Compared with prior art, anionic auxiliary agent is replaced by using substantial amounts of inorganic salts, so that the discharge of dyeing and printing sewage is greatly reduced, it ensure that disperse dyes, in coloured light and the reliability and stability of tint applications aspect of performance, had so not only saved production cost but also reduced the discharge in dyeing waste-water simultaneously.
Description
Technical field
The present invention relates to a kind of composite disperse dye, especially a kind of environmentally friendly disperse dyes.
Background technology
China is disperse dyes manufacturing nation maximum in the world, and its production needs to use anionic dispersing agent, consumption
More than 250,000 tons/year.At present, the anionic dispersing agent used mainly condensation compound of methyl naphthalene sulfonic acid and formaldehyde, such as dispersant
MF, molecular structural formula is as follows:
Naphthalene sulfonic acid-formaldehyde condensation product, such as dispersant NNO, molecular structural formula are as follows;
Benzyl naphthalene sulfonic acid-formaldehyde condensation product, such as dispersing agent C NF, molecular structural formula are as follows:
These dispersants circulate into dyeing waste water again after printing and dyeing, because these dispersants are difficult to decompose in nature,
Long-term use will necessarily cause greatly negative effect to environment;Dyeing is the important composition portion in textile industry industrial chain
Point, it is the crucial industry and bottleneck for lifting clothes, household textile quality and added value.Since 2000, textile and dyeing industry
While developing rapidly, environmental issue is also more protruded.The dyeing waste water of textile printing and dyeing industry discharge is China's industrial system
One of middle major polluting sources.According to statistics, the dyeing waste water of dyeing discharge accounts for 80% left side of national textile industrial discharge total amount
It is right.The problem of there is energy consumption in China's textile industry particularly printing and dyeing industry, water consume is high.Energy-saving and emission-reduction turn into DYE PRODUCTION enterprise
Middle frequency of use highest noun, the management objectives as governments at all levels and industry, dye industry faces unprecedented pressure.Cause
This, how " energy-conservation, emission reduction, consumption reduction, synergy ", be that each dyestuff manufactory is worth the long-standing problem of thinking, it is suitable to develop
Economic and environment-friendly type disperse dyes are also needed for dyestuff factory meets printing and dyeing mill's survival and development.
The content of the invention
The present invention is for of the prior art not enough there is provided a kind of economic and environment-friendly type disperse dyes, by using a large amount of
Inorganic salts replace anionic auxiliary agent so that the discharge of dyeing and printing sewage is greatly reduced, while ensure that disperse dyes in color
The reliability and stability of light and tint applications aspect of performance, had so not only saved production cost but also had reduced the row in dyeing waste-water
Put.
In order to solve the above-mentioned technical problem, the present invention is addressed by following technical proposals:A kind of economic and environment-friendly type point
Dissipate dyestuff, it is characterised in that including several dispersion dyes monomers and neutral inorganic monomer.
In above-mentioned technical proposal, it is preferred that also including auxiliary agent.
In above-mentioned technical proposal, it is preferred that described neutral inorganic monomer is sodium sulphate, potassium sulfate, sodium chloride or chlorine
Change the one of which of potassium.
In above-mentioned technical proposal, it is preferred that described auxiliary agent includes condensation compound of methyl naphthalene sulfonic acid and formaldehyde, naphthalenesulfonateformaldehyde formaldehyde and contracted
Compound, benzyl naphthalene sulfonic acid-formaldehyde condensation product, the one or more of lignosulfonates.
In above-mentioned technical proposal, it is preferred that by weight percentage, including the disperse dyes list described in 3%-65%
The inorganic salt monomer of body, 20%-56%, the auxiliary agent described in 15%-50%.
In above-mentioned technical proposal, it is preferred that by weight percentage, including the disperse dyes list described in 15%-30%
The inorganic salt monomer of body, 30%-50%, the auxiliary agent described in 20%-40%.
In above-mentioned technical proposal, it is preferred that described dispersion dyes monomer includes:
One or more.
The present invention relates to the dyestuffs such as quinolines, monoazo class and neutral inorganic composition, it mainly includes disperse dyes
Monomer, inorganic salt monomer and auxiliary agent.The present invention in dye formulation by neutral inorganic can make in dye bath dyestuff fiber with
Balance between water shifts to machine direction.With neutral inorganic substitute part of auxiliary (predominantly dispersant) can both reduce dyestuff into
This, can reduce quinoline, formaldehyde, the COD dyed in residual night, reduce environmental pollution again.Disperse dyes of the present invention are applied to
Polyester material and the dyeing of vinegar fiber material are contaminated, especially passes through dyes in one bath with reactive dye, direct dyes when printing and dyeing polyester-cotton fabric
Color, had not only saved accelerant but also had reduced the usage amount of dispersing aid, and two kinds of dyestuff one-bath processes realize what is promoted dye and disperse
Balance.Light color in dye is especially suitable for, coloured light, application performance are stable when contaminating shallow middle color, favorable reproducibility.
Compared with prior art, anionic auxiliary agent is replaced by using substantial amounts of inorganic salts so that the row of dyeing and printing sewage
Great reduction is put, while ensure that disperse dyes, in coloured light and the reliability and stability of tint applications aspect of performance, are so both saved
About production cost again reduces the discharge in dyeing waste-water.
Embodiment
The present invention is described in further detail with reference to embodiment.
A kind of economic and environment-friendly type disperse dyes of the present invention can be prepared as follows:The disperse dyes list of ratio will be measured
After body A, dispersion dyes monomer B, auxiliary agent, water or the mixing of other wetting agent, it is ground scattered, is then spray-dried with grinder,
Gone out finished product is uniform with inorganic salt monomer blending again.Wherein dispersion dyes monomer A is
Dispersion dyes monomer B isOn
The commercially available C.I. disperse yellows in commercially available prod can be respectively adopted in dispersion dyes monomer A, dispersion dyes monomer B, the inorganic salt monomer stated
54 former dyestuffs, the former dyestuff of C.I. disperse orange 25s, the glauber salt of content >=98%.
Such a dyestuff can be also prepared as follows:First by C.I. points of dispersion dyes monomer A and auxiliary agent finished product dyestuff
Huang 54 is dissipated, then by dispersion dyes monomer B and auxiliary agent finished product dyestuff C.I. disperse orange 25s, then by above-mentioned each finished product dyestuff and help
Agent adds water after blending, grinding distribution, then sprays again dry etc. dry, goes out finished product uniform with inorganic salt monomer blending again;Or control
Inorganic salt monomer is directly sprayed to dry mixture by inorganic salts content of monomer processed in 10%-15% or so;Can also will be upper
State a kind of or two kinds and above finished product dyestuff and directly carry out blending with inorganic salt monomer, auxiliary agent, be ground to and be uniformly dispersed.Equally,
Commercially available prod can be respectively adopted in above-mentioned several raw materials.
It is golden yellow by dye colour made from dispersion dyes monomer A and dispersion dyes monomer B, its specific proportioning is being implemented
Example 1 to embodiment 10 is described.
Embodiment 1, by 55 grams of dispersion dyes monomers A, 15 grams of dispersion dyes monomer B, 10 grams of inorganic salt monomers, 68 grams of diffusions
Agent CNF adds after 222 grams of water blendings, and scattered, the economic and environment-friendly type point of obtained the application after spray drying is ground with grinder
Dissipate dyestuff.
Embodiment 2, by 50 grams of dispersion dyes monomers A, 13 grams of dispersion dyes monomer B, 15 grams of inorganic salt monomers, 65 grams of diffusions
Agent NNO adds after 215 grams of water blendings, and scattered, the economic and environment-friendly type point of obtained the application after spray drying is ground with grinder
Dissipate dyestuff.
Embodiment 3, by 45 grams of dispersion dyes monomer A, 17 grams of dispersion dyes monomer B, 18 grams of inorganic salt monomers, 43 grams are disperseed
Agent MF, 15 grams of dispersing agent CNFs add after 207 grams of water blendings, and scattered, obtained the application after drying such as spraying is ground with grinder
Economic and environment-friendly type disperse dyes.
Embodiment 4, by 42 grams of dispersion dyes monomer A, 11 grams of dispersion dyes monomer B, 20 grams of inorganic salt monomers, 45 grams are disperseed
After agent MF, 17 grams of sodium lignin sulfonates, plus 202 grams of water blendings, scattered, this obtained Shen after spray drying is ground with grinder
Economic and environment-friendly type disperse dyes please.
Table 1 is that embodiment 1 to embodiment 4 matches table
According to continuous data shown in table 1, in embodiment 1 into embodiment 4, by dispersion dyes monomer A, dispersion dyes monomer
B, inorganic salt monomer, auxiliary agent are added water after blending, and scattered, the drying such as spraying is ground with grinder.Wherein auxiliary agent is to divide
Powder MF (condensation compound of methyl naphthalene sulfonic acid and formaldehyde), dispersing agent CNF (benzyl naphthalene sulfonic acid-formaldehyde condensation product), dispersing agent NNO (naphthalene sulfonic acids
Formaldehyde condensation products), the one or more in sodium lignin sulfonate, inorganic salt monomer be mainly sodium sulphate, potassium sulfate, sodium chloride or
Potassium chloride.
Embodiment 5, by 90 grams of C.I. disperse yellows, 54,30 grams of C.I. disperse orange 25s, 36 grams of glauber salt directly carry out blending, ground
It is milled to the economic and environment-friendly type disperse dyes for the obtained the application that is uniformly dispersed.
Embodiment 6, by 62 grams of C.I. disperse yellows, 54,25 grams of C.I. disperse orange 25s, 100 grams of glauber salt, 9 grams of Dispersant MFs, 1
Gram dispersing agent CNF directly carries out blending, is ground to the economic and environment-friendly type disperse dyes for the obtained the application that is uniformly dispersed.
Embodiment 7, by 109 grams of C.I. disperse yellows, 54,33 grams of C.I. disperse orange 25s, 110 grams of glauber salt directly carry out blending,
It is ground to the economic and environment-friendly type disperse dyes for the obtained the application that is uniformly dispersed.
Embodiment 8, by 72 grams of C.I. disperse yellows, 54,27 grams of C.I. disperse orange 25s, 52 grams of glauber salt, 77 grams of Dispersant MFs are straight
Row blending is tapped into, the economic and environment-friendly type disperse dyes for the obtained the application that is uniformly dispersed are ground to.
Embodiment 9, by 71.2 grams of C.I. disperse yellows, 54,25.1 grams of C.I. disperse orange 25s, 31 grams of glauber salt, 69.2 grams are disperseed
Agent MF, 1 gram of dispersing agent NNO directly carries out blending, is ground to the economic and environment-friendly type disperse dyes for the obtained the application that is uniformly dispersed.
Embodiment 10, by 52 grams of C.I. disperse yellows, 54,15 grams of C.I. disperse orange 25s, 30 grams of glauber salt directly carry out blending,
It is ground to the economic and environment-friendly type disperse dyes for the obtained the application that is uniformly dispersed.
Table 2 is that embodiment 5 to embodiment 10 matches table
According to continuous data shown in table 2, in embodiment 5 into embodiment 10, the grade of C.I. disperse yellows 54 (commercial dye, point
Dissipate dye monomer A contents 56% or so), C.I. disperse orange 25s etc. (commercial dye, dispersion dyes monomer B content 42% or so),
Glauber salt and auxiliary agent directly carry out blending, are ground to and are uniformly dispersed.Wherein auxiliary agent is that (methyl naphthalene sulfonic acid and formaldehyde is condensed Dispersant MF
Thing), dispersing agent CNF (benzyl naphthalene sulfonic acid-formaldehyde condensation product), dispersing agent NNO (naphthalene sulfonic acid-formaldehyde condensation product), sodium lignin sulfonate
In one or more.
A kind of low-temperature environment-friendly economizing type composite disperse dye of the present invention can be prepared as follows:Ratio will be measured
After dispersion dyes monomer C, dispersion dyes monomer D, auxiliary agent, water or the mixing of other wetting agent, be ground with grinder it is scattered,
Then it is spray-dried, goes out finished product uniform with inorganic salt monomer C blendings again.Above-mentioned dye monomer A, dye monomer B, inorganic salts
The former dyestuff of the commercially available C.I. disperse yellows in commercially available prod 54, C.I. disperse orange 25s former dyestuffs, content 98% can be respectively adopted in monomer C
Glauber salt.
A kind of economic and environment-friendly type disperse dyes of the present invention can be prepared as follows:The disperse dyes list of ratio will be measured
After body C, dispersion dyes monomer D, auxiliary agent, water or the mixing of other wetting agent, it is ground scattered, is then sprayed dry with grinder
It is dry, go out finished product uniform with inorganic salt monomer blending again.Wherein dispersion dyes monomer C is
Dispersion dyes monomer D isAbove-mentioned disperse dyes
Monomer C, dispersion dyes monomer D, inorganic salt monomer can be respectively adopted the former dyestuff of the commercially available C.I. disperse blues in commercially available prod 354,
C.I. disperse yellow 184:1 former dyestuff, the glauber salt of content >=98%.
Such a dyestuff can be also prepared as follows:First by C.I. points of dispersion dyes monomer C and auxiliary agent finished product dyestuff
Indigo plant 354 is dissipated, then by dispersion dyes monomer D and auxiliary agent finished product dyestuff C.I. disperse yellows 184: 1, then by above-mentioned each finished product dyestuff
Added water with auxiliary agent after blending, then grinding distribution sprays dry etc. dry, go out finished product uniform with inorganic salt monomer blending again again;Or
Person controls inorganic salts content of monomer in 10%-15% or so, and inorganic salt monomer is directly sprayed to dry mixture;Can also
Above-mentioned a kind of or two kinds and above finished product dyestuff are directly subjected to blending with inorganic salt monomer, auxiliary agent, is ground to and is uniformly dispersed.Together
Commercially available prod can be respectively adopted in sample, above-mentioned several raw materials.
It is bright blue by dye colour made from dispersion dyes monomer C and dispersion dyes monomer D, its specific proportioning is being implemented
Example 11 is described.
Embodiment 11, by commercially available 100 grams of C.I. disperse blues, 354,5 grams of C.I. disperse yellows 184:1,350 gram of Dispersant MF,
556 grams of water mixing mashing, are spray-dried after being uniformly dispersed.100 grams of the dyestuff after spray drying is taken, 100 grams of glauber salt are added, mixing is equal
It is even, obtain the economic and environment-friendly type disperse dyes of the application.
A kind of economic and environment-friendly type disperse dyes of the present invention can be prepared as follows:The disperse dyes of ratio will be measured
After monomer E, dispersion dyes monomer F, auxiliary agent, water or the mixing of other wetting agent, it is ground scattered, is then sprayed with grinder
Dry, go out finished product uniform with inorganic salt monomer blending again.Wherein dispersion dyes monomer E is
Dispersion dyes monomer F isAbove-mentioned dispersion dyes monomer E,
The former dyestuff of the commercially available C.I. disperse oranges 73 in commercially available prod, C.I. disperse oranges can be respectively adopted in dispersion dyes monomer F, inorganic salt monomer
288 former dyestuffs, the glauber salt of content >=98%.
Such a dyestuff can be also prepared as follows:First by C.I. points of dispersion dyes monomer E and auxiliary agent finished product dyestuff
Dissipate orange 73, then by dispersion dyes monomer F and auxiliary agent finished product dyestuff C.I. disperse oranges 288, then will above-mentioned each finished product dyestuff with
Auxiliary agent adds water after blending, grinding distribution, then sprays again dry etc. dry, goes out finished product uniform with inorganic salt monomer blending again;Or
Control inorganic salts content of monomer in 10%-15% or so, inorganic salt monomer is directly sprayed to dry mixture;Can also be by
Above-mentioned a kind of or two kinds and above finished product dyestuff directly carry out blending with inorganic salt monomer, auxiliary agent, are ground to and are uniformly dispersed.Together
Commercially available prod can be respectively adopted in sample, above-mentioned several raw materials.
It is orange by dye colour made from dispersion dyes monomer E and dispersion dyes monomer F, it is specifically matched in embodiment
12 narrations.
Embodiment 12, by 50 grams of 735,25 grams of C.I. disperse oranges, 288,50 grams of C.I. disperse oranges Dispersant MFs, 150 grams of water are mixed
Mashing is closed, dispersed 4-5 grades, spray drying is ground to sand mill.50 grams of the dyestuff after spray drying is taken, 25 grams of glauber salt are added,
It is well mixed, obtain the economic and environment-friendly type disperse dyes of the application.
A kind of economic and environment-friendly type disperse dyes of the present invention can be prepared as follows:The disperse dyes of ratio will be measured
After monomer G, dispersion dyes monomer H, dispersion dyes monomer I, auxiliary agent, water or other wetting agent mixing, ground with grinder
Mill is scattered, is then spray-dried, goes out finished product uniform with inorganic salt monomer blending again.Wherein dispersion dyes monomer H is
Dispersion dyes monomer G is
Dispersion dyes monomer I isAbove-mentioned scattered dye
Material list body G, dispersion dyes monomer H, dispersion dyes monomer I, inorganic salt monomer can be respectively adopted the commercially available C.I. in commercially available prod points
Dissipate red 145 former dyestuffs, the former dyestuff of C.I. Red-1 200s 53, C.I. disperse oranges 73, the glauber salt of content >=98%.
Such a dyestuff can be also prepared as follows:First by C.I. points of dispersion dyes monomer G and auxiliary agent finished product dyestuff
Dissipate red 145, then by dispersion dyes monomer H and auxiliary agent finished product dyestuff C.I. Red-1 200s 53, then by dispersion dyes monomer I and
Auxiliary agent finished product dyestuff C.I. disperse oranges 73, then above-mentioned each finished product dyestuff and auxiliary agent are added water after blending, grinding distribution, then
Spray again dry etc. dry, go out finished product uniform with inorganic salt monomer blending again;Or control inorganic salts content of monomer is in 10%-15%
Inorganic salt monomer, is directly sprayed to dry mixture by left and right;Can also be by above-mentioned a kind of or two kinds and above finished product dyestuff
Blending is directly carried out with inorganic salt monomer, auxiliary agent, is ground to and is uniformly dispersed.Equally, city can be respectively adopted in above-mentioned several raw materials
Sell product.
It is red by dye colour made from dispersion dyes monomer H and dispersion dyes monomer G, it is specifically matched in embodiment
13 narrations.
Embodiment 13, by 100 grams of 45,18 grams of C.I. Red-1 200s, 53,3 grams of C.I. Red-1 200s, 73,85 grams of C.I. disperse oranges
Dispersant MF, 255 grams of water mixing mashing, dispersed 4-5 grades, spray drying is ground to sand mill.Take the dyestuff after spray drying 50
Gram, 50 grams of glauber salt are added, is well mixed, obtains the economic and environment-friendly type disperse dyes of the application.
In order to carry out performance comparison, change the inorganic salts in above-described embodiment 1- embodiments 13 into Dispersant MF, using with
Comparative example 1- comparative examples 13 are made in correspondence embodiment identical processing method.Respectively according to GB/T 5540-2007, GB/T
Method specified in 5541-2007, GB/T 27597-2011 determines the warp of the obtained the application into embodiment 13 of embodiment 1
Dispersion stabilization, High Temperature Dispersion Stability and the diffusion of Ji environmental-friendly disperse dye and corresponding comparative example dyestuff.
Table 3 is the test result table of 13 embodiments and 13 comparative example dyestuff performances
As can be seen from Table 3, the dye stabilizer performance and diffusion of embodiment and comparative example are basically identical.
The economic and environment-friendly type disperse dyes and corresponding comparative example dyestuff of the obtained the application into embodiment 13 of Example 1
Each 0.5 gram is dispersed in 500 milliliters of water, is mixed after drawing 20 milliliters with 60 milliliters of water.Dye bath PH=5, heating are adjusted with acetic acid
2 grams of polyester fibers are put into 70 DEG C simultaneously to be dyed, 130 DEG C are risen to by 70 DEG C in temperature in 30 minutes, are incubated 30 minutes, it is cold
Dried after taking out cloth specimen, reduction cleaning when but to 90 DEG C, it is standby.0.5 gram of comparative example addition MF disperse dyes are taken to carry out simultaneously
Above-mentioned steps, are obtained 26 groups of dyestuffs to be tested.This 26 groups of dyestuffs are tested, test 1 is to watch its color;Testing 2 is
Embodiment 1-13 and comparative example 1-13 dyestuffs and Disperse Blue 2BLN and Disperse Red 3B colorant match, observe itself and low temperature disperse dyes
Compatibility;Test 3 is the total color difference of embodiment and comparative example, and test 4 is to use national standard GB/T3921-1997, GB/T3920-
1997th, GB/T8427-1998, GB/T5718-1997. test its fastness respectively.
Table 4 is the dyeability test result table of 13 embodiments and 13 comparative example dyestuffs
Can be drawn in table 4, in the economic and environment-friendly type disperse dyes of the application inorganic salts to dyeing performance without obvious
Influence, golden yellow dyestuff and Disperse Blue 2BLN, Disperse Red 3B compatibility it is good, it is resistance to soap, antifriction scrape along sub-limation fastness it is real
Apply example and comparative example indifference.
Inorganic salts ratio is different in the economic and environment-friendly type disperse dyes of invention, quinoline, content of formaldehyde in dyestuff
Difference, respectively according to GB/T23973-2009《The measure of formaldehyde in dye product》And GB/T31531-2015《Dyestuff and weaving
The measure of quinoline in dyeing and finishing auxiliaries product》Specified in the method formaldehyde and quinoline that test in the inorganic salt dyestuff of different proportion contain
Amount.Test the COD of dyeing residual liquid according to the methods below simultaneously:New Example 14 is to embodiment 23, embodiment 14 to reality
The specific proportioning for applying example 23 is shown in Table 5, is disperseed by the economic and environment-friendly type of invention made from embodiment 14 to embodiment 23
Dyestuff and each 1.0 grams of comparative example are dispersed in 250 milliliters of water, are mixed after drawing 25 milliliters with 55 ml deionized waters.Use vinegar
Acid adjusts dye bath PH=5, is warming up to 70 DEG C and is dyed while being put into 2 grams of polyester fibers, is risen in temperature in 30 minutes by 70 DEG C
130 DEG C, 30 minutes are incubated, dye sample is taken out when being cooled to 90 DEG C, dyeing residual liquid is moved into 100 milliliters of volumetric flasks, with 20 milliliters
Deionization washing dye sample, wash water is moved into corresponding volumetric flask, plus deionized water adjusts solution to 100 milliliters.According to HJ/T
399-2007《The measure rapid-digestion AAS of water chemical oxygen demand》In relevant regulations determine COD contents.
Table 5 is different glauber salt amounts to content of formaldehyde, isoquinoline level, dyeing residual liquid COD amounts and cost in dyestuff
The environmental-protecting performance that the present invention can improve dyestuff is not limited solely to above-described embodiment 14-23 dyestuff, in embodiment
During 11-13 other color divergence dyestuff blendings, due to reducing dispersant dosage, good environmental-protecting performance equally can obtain.
In principle, on the premise of disperse dyes coloured light and application performance is not influenceed, the present invention is adapted to all disperse dyes drop intensity
Blending is produced.
Claims (7)
1. a kind of economic and environment-friendly type disperse dyes, it is characterised in that including several dispersion dyes monomers and neutral inorganic list
Body.
2. a kind of economic and environment-friendly type disperse dyes according to claim 1, it is characterised in that also including auxiliary agent.
3. a kind of economic and environment-friendly type disperse dyes according to claim 1, it is characterised in that described neutral inorganic list
Body is the one of which of sodium sulphate, potassium sulfate, sodium chloride or potassium chloride.
4. a kind of economic and environment-friendly type disperse dyes according to claim 2, it is characterised in that described auxiliary agent includes methyl
Naphthalene sulfonic acid-formaldehyde condensation product, naphthalene sulfonic acid-formaldehyde condensation product, benzyl naphthalene sulfonic acid-formaldehyde condensation product, one kind of lignosulfonates or many
Kind.
5. a kind of economic and environment-friendly type disperse dyes according to claim 2, it is characterised in that by weight percentage, bag
Include 3%-65% described dispersion dyes monomer, 20%-56% inorganic salt monomer, the auxiliary agent described in 15%-50%.
6. a kind of economic and environment-friendly type disperse dyes according to claim 5, it is characterised in that by weight percentage, bag
Include 15%-30% described dispersion dyes monomer, 30%-50% inorganic salt monomer, the auxiliary agent described in 20%-40%.
7. according to a kind of any described economic and environment-friendly type disperse dyes of claim 1 to 6, it is characterised in that described is scattered
Dye monomer includes:
One or more.
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CN115612312A (en) * | 2022-11-08 | 2023-01-17 | 浙江天浩新材料股份有限公司 | High-stability nano-cellulose dye dispersion liquid and preparation method thereof |
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CN106752085A (en) * | 2017-01-23 | 2017-05-31 | 宁波托澳贸易有限公司 | A kind of low-temperature environment-friendly economizing type composite disperse dye |
CN107868488B (en) * | 2017-12-04 | 2019-11-29 | 浙江龙盛化工研究有限公司 | A kind of yellow disperse dye composition and dye preparations |
Citations (3)
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CN104530760A (en) * | 2014-12-31 | 2015-04-22 | 浙江闰土股份有限公司 | Red liquid disperse dye and preparation method and application thereof |
CN106675092A (en) * | 2016-12-31 | 2017-05-17 | 浙江博澳染料工业有限公司 | Environment-friendly type composite disperse dye and preparation method and application thereof |
CN106752085A (en) * | 2017-01-23 | 2017-05-31 | 宁波托澳贸易有限公司 | A kind of low-temperature environment-friendly economizing type composite disperse dye |
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CN104530760A (en) * | 2014-12-31 | 2015-04-22 | 浙江闰土股份有限公司 | Red liquid disperse dye and preparation method and application thereof |
CN106675092A (en) * | 2016-12-31 | 2017-05-17 | 浙江博澳染料工业有限公司 | Environment-friendly type composite disperse dye and preparation method and application thereof |
CN106752085A (en) * | 2017-01-23 | 2017-05-31 | 宁波托澳贸易有限公司 | A kind of low-temperature environment-friendly economizing type composite disperse dye |
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CN115612312A (en) * | 2022-11-08 | 2023-01-17 | 浙江天浩新材料股份有限公司 | High-stability nano-cellulose dye dispersion liquid and preparation method thereof |
CN115612312B (en) * | 2022-11-08 | 2024-01-09 | 浙江天浩新材料股份有限公司 | High-stability nano cellulose dye dispersion liquid and preparation method thereof |
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