CN107298828A - A kind of pipeline high intensity, corrosion-resistant ABS composite material and preparation method thereof - Google Patents
A kind of pipeline high intensity, corrosion-resistant ABS composite material and preparation method thereof Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/9258—Velocity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/262—Alkali metal carbonates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/18—Applications used for pipes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The present invention provides a kind of pipeline high intensity, corrosion-resistant ABS composite material and preparation method thereof, is related to technical field of polymer materials.Inventive pipeline is made up with high intensity, corrosion-resistant ABS composite material of following raw material：ABS resin, epoxy propane butyl ether, high brilliant activated carbon nano fiber material, diallyl phthalate, plant ash, reinforcing fiber, hollow silica ball, compatilizer, lubricant, antioxidant, toughener.Inventive pipeline is difficult breed bacteria, non-scaling with high intensity, corrosion-resistant ABS composite material；The pipeline material prepared using material of the present invention has high intensity, good corrosion resistance, and compression strength is high.
Description
Technical field
The present invention relates to technical field of polymer materials, and in particular to a kind of pipeline high intensity, corrosion-resistant ABS composite woods
Material and preparation method thereof.
Background technology
ABS be 1940s occur a kind of new high polymer material, not only with impact resistance, high rigidity,
Oil resistivity, mechanical strength and excellent electrical properties, phase excellent mechanical property, and with preferable chemical-resistant resistance in a balanced way
The advantages of property, dimensional stability, surface gloss, low temperature tolerance characteristicses, tinctorial property and processing flowability.It is that a kind of performance is excellent
Good, relative low price thermoplastic engineering plastic.With the requirement more and more higher to engineering plastics performance, with good sexual valence
The development attention of the long fiber reinforced ABS composite material of ratio, has a extensive future, and is widely used in automobile, electronic apparatus,
Light industry, building etc. industry.
Although ABS turns into one of current most popular high polymer material with its remarkable performance, it is being molded and is making
During, the influence for the external force such as ABS is easily stretched, bent, impacting.Some plastic conduits, such as running water pipe, combustion gas
Pipeline often has higher humidity, thus pipeline material is required for having well corrosion-resistant, high temperature resistant and weather resistance
Energy.
Widely, existing tubing is generally that homogenous material is processed to tubing purposes, and tubing needs in use
Certain pressure is born, tubing is laid on ground bottom, trouble is changed if there is damaging, easy knot inside traditional tubing
Structure, is blocked, particularly water transferring line, the easy breed bacteria of inside pipe fitting to tubing, influences the quality of water.
Therefore, design a with corrosion resistance, compression strength is high, and service life is long, is difficult breed bacteria, non-scaling
A kind of pipeline is particularly important with ABS composite material.
The content of the invention
In view of the shortcomings of the prior art, the present invention provides a kind of pipeline high intensity, corrosion-resistant ABS composite material and its preparation
Method, solves the low technical problem of the easy fouling of prior art pipeline ABS composite material, perishable, compression strength.
To realize object above, technical scheme is achieved by the following technical programs：
A kind of pipeline high intensity, corrosion-resistant ABS composite material, the pipeline high intensity, corrosion-resistant ABS composite material
It is made up of the raw material of following parts by weight：50-90 parts of ABS resin, 8-16 parts of epoxy propane butyl ether, high brilliant activated carbon nano fiber
6-13 parts of material, 5-15 parts of diallyl phthalate, 10-15 parts of plant ash, 7-16 parts of reinforcing fiber, silicon dioxide hollow
5-15 parts of ball, 1-5 parts of compatilizer, 3-6 parts of lubricant, 3-6 parts of antioxidant, 0.5-3 parts of toughener.
It is preferred that, the reinforcing fiber is at least one of short fiber/glass fiber, carbon fiber, boron fibre.
It is preferred that, the relative density of the ABS resin is 1.06-1.10%, and acrylonitrile content 10-15%, butadiene contains
Measure as 10-15%, styrene-content is 70-80%, and transmissivity is 88%-90%.
It is preferred that, the average grain diameter of the hollow silica ball is 0.5-1.5 μm.
It is preferred that, the lubricant is one kind in vinyl bis-stearamides, zinc stearate, calcium stearate.
It is preferred that, the compatilizer is MBS terpolymer, acrylic acid-Malaysia
In acid anhydrides-styrene copolymer, ethylene-methyl acrylate-glyceryl methacrylate random terpolymer extremely
Few one kind.
It is preferred that, the toughener is at least one in high glue powder class, acrylic ester elastomer, phenylethylene toughener
Kind.
It is preferred that, the antioxidant is triethylene glycol double -3- (3- tertiary butyl-4-hydroxy -5- aminomethyl phenyls) acrylonitrile, three
(2,4- di-tert-butylphenol) phosphite ester, four [3- (3,5- di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol esters, phosphorous acid
One kind in three (2,4- 6- di-tert-butyl phenyl esters).
A kind of pipeline high intensity, the preparation method of corrosion-resistant ABS composite material, comprise the following steps：
S1, according to parts by weight weigh each raw material；
S2, by ABS resin, high brilliant activated carbon nano fiber material, plant ash, reinforcing fiber, hollow silica ball, phase
Hold in agent, lubricant, antioxidant input mixer and be well mixed, add progress mixing 15-20min in two-roll mill, mix
It is 200-230 DEG C to refine temperature, obtains mixed material；
S3, by mixed material from main spout add double screw extruder in, by diallyl phthalate, epoxy third
Alkane butyl ether, toughener side loading mouthful are added in double screw extruder, shear, extrude through twin-screw, tie rod, cooling, granulation, i.e.,
Can.
It is preferred that, area's temperature of the double screw extruder is 170-200 DEG C, and two area's temperature are 180-210 DEG C, 3rd area
Temperature is 190-220 DEG C, and four area's temperature are 200-230 DEG C, and five area's temperature are 200-220 DEG C, and head temperature is 200-210 DEG C,
Rate of feeding is 230-300/min, and screw speed is 550-650r/min.
The present invention provides a kind of pipeline high intensity, corrosion-resistant ABS composite material and preparation method thereof, with prior art phase
It is than advantage：
Inventive pipeline high intensity, corrosion-resistant ABS composite material are using high brilliant activated carbon nano fiber material, vegetation
Ash, reinforcing fiber, hollow silica ball and other raw materials, enhance the improvement surface between ABS resin and other raw materials
Adhesion, can preferably be merged, and improved the overall performance of material, enhanced antibacterial ability, the mobility of material, use the material
Material is difficult breed bacteria, non-scaling；The pipeline material prepared using material of the present invention has high intensity, good corrosion resistance, resistance to compression
Intensity is high, and current frictional resistance is small, and conveyance power of water is strong, reduces energy consumption, the rigidity with more than common plastics tube, impact resistance；
The tubing that inventive pipeline is prepared with high intensity, corrosion-resistant ABS composite material is not easily blocked, non-scaling, antibiotic property
By force, breed bacteria is difficult, water quality is good during for aqueduct, lightweight, loads and unloads convenient transportation, the traditional plastic conduit of customer service
Quick stress cracking phenomenon, wear resistance is good, and service life is long, the number of turnover more than 100 times, and product can repeat to reclaim
Utilize, energy-conserving and environment-protective, to mould Dai Mu, are widely used in pipeline field.
Embodiment
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, with reference to the embodiment of the present invention pair
Technical scheme in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is a part of the invention
Embodiment, rather than whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art are not making wound
The every other embodiment obtained under the premise of the property made work, belongs to the scope of protection of the invention.
Embodiment 1：
The present embodiment pipeline is made up with high intensity, corrosion-resistant ABS composite material of the raw material of following parts by weight：ABS resin
50 parts, 8 parts of epoxy propane butyl ether, high brilliant 6 parts of activated carbon nano fiber material, 5 parts of diallyl phthalate, plant ash
10 parts, 7 parts of reinforcing fiber, 5 parts of hollow silica ball, 1 part of compatilizer, 3 parts of lubricant, 3 parts of antioxidant, 0.5 part of toughener；
Wherein, reinforcing fiber is short fiber/glass fiber；The relative density of ABS resin be 1.06-1.10%, acrylonitrile content 10-15%,
Butadiene content is 10-15%, and styrene-content is 70-80%, and transmissivity is 88%-90%；Hollow silica ball it is flat
Equal particle diameter is 0.5 μm；Lubricant is vinyl bis-stearamides；Compatilizer is MBS three
Membered copolymer；Toughener is high glue powder class；Antioxidant is double -3- (3- tertiary butyl-4-hydroxy -5- aminomethyl phenyls) propylene of triethylene glycol
Nitrile；
The present embodiment pipeline high intensity, the preparation method of corrosion-resistant ABS composite material, comprise the following steps：
S1, according to parts by weight weigh each raw material；
S2, by ABS resin, high brilliant activated carbon nano fiber material, plant ash, reinforcing fiber, hollow silica ball, phase
Hold in agent, lubricant, antioxidant input mixer and be well mixed, add progress mixing 15min in two-roll mill, mixing temperature
Spend for 200 DEG C, obtain mixed material；
S3, by mixed material from main spout add double screw extruder in, by diallyl phthalate, epoxy third
Alkane butyl ether, toughener side loading mouthful are added in double screw extruder, shear, extrude through twin-screw, tie rod, cooling, granulation, i.e.,
Can, area's temperature of double screw extruder is 170 DEG C, and two area's temperature are 180 DEG C, and three area's temperature are 190 DEG C, and four area's temperature are
200 DEG C, five area's temperature are 200 DEG C, and head temperature is 200 DEG C, and rate of feeding is 230/min, and screw speed is 550r/min.
Embodiment 2：
The present embodiment pipeline is made up with high intensity, corrosion-resistant ABS composite material of the raw material of following parts by weight：ABS resin
90 parts, 16 parts of epoxy propane butyl ether, high brilliant 13 parts of activated carbon nano fiber material, 15 parts of diallyl phthalate, grass
15 parts of wood ash, 16 parts of reinforcing fiber, 15 parts of hollow silica ball, 5 parts of compatilizer, 6 parts of lubricant, 6 parts of antioxidant, toughener
3 parts；Wherein, reinforcing fiber is carbon fiber；The average grain diameter of hollow silica ball is 1.5 μm；Lubricant is zinc stearate；Phase
Appearance agent is acrylic acid-maleic acid acid anhydride-styrene copolymer；Toughener is acrylic ester elastomer；Antioxidant be three (2,
4- di-tert-butylphenols) phosphite ester；
The present embodiment pipeline high intensity, the preparation method of corrosion-resistant ABS composite material, comprise the following steps：
S1, according to parts by weight weigh each raw material；
S2, by ABS resin, high brilliant activated carbon nano fiber material, plant ash, reinforcing fiber, hollow silica ball, phase
Hold in agent, lubricant, antioxidant input mixer and be well mixed, add progress mixing 20min in two-roll mill, mixing temperature
Spend for 230 DEG C, obtain mixed material；
S3, by mixed material from main spout add double screw extruder in, by diallyl phthalate, epoxy third
Alkane butyl ether, toughener side loading mouthful are added in double screw extruder, shear, extrude through twin-screw, tie rod, cooling, granulation, i.e.,
Can, area's temperature of double screw extruder is 200 DEG C, and two area's temperature are 210 DEG C, and three area's temperature are 220 DEG C, and four area's temperature are
230 DEG C, five area's temperature are 220 DEG C, and head temperature is 210 DEG C, and rate of feeding is 300/min, and screw speed is 650r/min.
Embodiment 3：
The present embodiment pipeline is made up with high intensity, corrosion-resistant ABS composite material of the raw material of following parts by weight：ABS resin
70 parts, 12 parts of epoxy propane butyl ether, high brilliant 9 parts of activated carbon nano fiber material, 10 parts of diallyl phthalate, vegetation
13 parts of ash, 11 parts of reinforcing fiber, 10 parts of hollow silica ball, 2 parts of compatilizer, 4 parts of lubricant, 5 parts of antioxidant, toughener
1.7 part；Wherein, reinforcing fiber is boron fibre；The average grain diameter of hollow silica ball is 1 μm；Lubricant is calcium stearate；Phase
Appearance agent is ethylene-methyl acrylate-glyceryl methacrylate random terpolymer；Toughener is phenylethylene toughness reinforcing
Agent；Antioxidant is four [3- (3,5- di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol esters；
The present embodiment pipeline high intensity, the preparation method of corrosion-resistant ABS composite material, comprise the following steps：
S1, according to parts by weight weigh each raw material；
S2, by ABS resin, high brilliant activated carbon nano fiber material, plant ash, reinforcing fiber, hollow silica ball, phase
Hold in agent, lubricant, antioxidant input mixer and be well mixed, add progress mixing 18min in two-roll mill, mixing temperature
Spend for 215 DEG C, obtain mixed material；
S3, by mixed material from main spout add double screw extruder in, by diallyl phthalate, epoxy third
Alkane butyl ether, toughener side loading mouthful are added in double screw extruder, shear, extrude through twin-screw, tie rod, cooling, granulation, i.e.,
Can, area's temperature of double screw extruder is 185 DEG C, and two area's temperature are 195 DEG C, and three area's temperature are 205 DEG C, and four area's temperature are
215 DEG C, five area's temperature are 210 DEG C, and head temperature is 205 DEG C, and rate of feeding is 260/min, and screw speed is 600r/min.
Embodiment 4：
The present embodiment pipeline is made up with high intensity, corrosion-resistant ABS composite material of the raw material of following parts by weight：ABS resin
60 parts, 10 parts of epoxy propane butyl ether, high brilliant 8 parts of activated carbon nano fiber material, 7 parts of diallyl phthalate, vegetation
11 parts of ash, 9 parts of reinforcing fiber, 7 parts of hollow silica ball, 1 part of compatilizer, 4 parts of lubricant, 4 parts of antioxidant, 1 part of toughener；
Wherein, reinforcing fiber is that short fiber/glass fiber, carbon fiber, boron fibre are mixed；The average grain diameter of hollow silica ball is
0.8μm；Lubricant is vinyl bis-stearamides；Compatilizer is MBS ternary polymerization
Thing, acrylic acid-maleic acid acid anhydride-styrene copolymer, ethylene-methyl acrylate-glyceryl methacrylate are random
At least one of terpolymer；Toughener be high glue powder class, acrylic ester elastomer, phenylethylene toughener mixing and
Into；Antioxidant is phosphorous acid three (2,4- 6- di-tert-butyl phenyl ester)；
The present embodiment pipeline high intensity, the preparation method of corrosion-resistant ABS composite material, comprise the following steps：
S1, according to parts by weight weigh each raw material；
S2, by ABS resin, high brilliant activated carbon nano fiber material, plant ash, reinforcing fiber, hollow silica ball, phase
Hold in agent, lubricant, antioxidant input mixer and be well mixed, add progress mixing 16min in two-roll mill, mixing temperature
Spend for 210 DEG C, obtain mixed material；
S3, by mixed material from main spout add double screw extruder in, by diallyl phthalate, epoxy third
Alkane butyl ether, toughener side loading mouthful are added in double screw extruder, shear, extrude through twin-screw, tie rod, cooling, granulation, i.e.,
Can, area's temperature of double screw extruder is 180 DEG C, and two area's temperature are 190 DEG C, and three area's temperature are 200 DEG C, and four area's temperature are
210 DEG C, five area's temperature are 210 DEG C, and head temperature is 203 DEG C, and rate of feeding is 250/min, and screw speed is 580r/min.
Embodiment 5：
The present embodiment pipeline is made up with high intensity, corrosion-resistant ABS composite material of the raw material of following parts by weight：ABS resin
80 parts, 15 parts of epoxy propane butyl ether, high brilliant 11 parts of activated carbon nano fiber material, 12 parts of diallyl phthalate, grass
12 parts of wood ash, 14 parts of reinforcing fiber, 12 parts of hollow silica ball, 4 parts of compatilizer, 5 parts of lubricant, 4 parts of antioxidant, toughener
2.5 part；Wherein, reinforcing fiber is carbon fiber；The relative density of ABS resin be 1.06-1.10%, acrylonitrile content 10-15%,
Butadiene content is 10-15%, and styrene-content is 70-80%, and transmissivity is 88%-90%；Hollow silica ball it is flat
Equal particle diameter is 1.2 μm；Lubricant is vinyl bis-stearamides；Compatilizer is acrylic acid-maleic acid acid anhydride-styrene terpolymer
Thing；Toughener is acrylic ester elastomer；Antioxidant is four [3- (3,5- di-tert-butyl-hydroxy phenyl) propionic acid] Ji Wusi
Alcohol ester；
The present embodiment pipeline high intensity, the preparation method of corrosion-resistant ABS composite material, comprise the following steps：
S1, according to parts by weight weigh each raw material；
S2, by ABS resin, high brilliant activated carbon nano fiber material, plant ash, reinforcing fiber, hollow silica ball, phase
Hold in agent, lubricant, antioxidant input mixer and be well mixed, add progress mixing 19min in two-roll mill, mixing temperature
Spend for 225 DEG C, obtain mixed material；
S3, by mixed material from main spout add double screw extruder in, by diallyl phthalate, epoxy third
Alkane butyl ether, toughener side loading mouthful are added in double screw extruder, shear, extrude through twin-screw, tie rod, cooling, granulation, i.e.,
Can, area's temperature of double screw extruder is 190 DEG C, and two area's temperature are 205 DEG C, and three area's temperature are 210 DEG C, and four area's temperature are
220 DEG C, five area's temperature are 210 DEG C, and head temperature is 206 DEG C, and rate of feeding is 270/min, and screw speed is 630r/min.
It should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations；Although ginseng
The present invention is described in detail according to previous embodiment, it will be understood by those within the art that：It still can be with
Technical scheme described in foregoing embodiments is modified, or equivalent substitution is carried out to which part technical characteristic；And
These modifications are replaced, and the essence of appropriate technical solution is departed from the spirit and model of various embodiments of the present invention technical scheme
Enclose.
Claims (10)
1. a kind of pipeline high intensity, corrosion-resistant ABS composite material, it is characterised in that the pipeline high intensity, corrosion-resistant
ABS composite material is made up of the raw material of following parts by weight：50-90 parts of ABS resin, 8-16 parts of epoxy propane butyl ether, Gao Jingna
Rice 6-13 parts of activated carbon fiber material, 5-15 parts of diallyl phthalate, 10-15 parts of plant ash, 7-16 parts of reinforcing fiber,
5-15 parts of hollow silica ball, 1-5 parts of compatilizer, 3-6 parts of lubricant, 3-6 parts of antioxidant, 0.5-3 parts of toughener.
2. pipeline high intensity according to claim 1, corrosion-resistant ABS composite material, it is characterised in that：The enhancing is fine
Tie up as at least one of short fiber/glass fiber, carbon fiber, boron fibre.
3. pipeline high intensity according to claim 1, corrosion-resistant ABS composite material, it is characterised in that：The ABS trees
The relative density of fat is 1.06-1.10%, and acrylonitrile content 10-15%, butadiene content is 10-15%, and styrene-content is
70-80%, transmissivity is 88%-90%.
4. pipeline high intensity according to claim 1, corrosion-resistant ABS composite material, it is characterised in that：The titanium dioxide
The average grain diameter of silicon hollow ball is 0.5-1.5 μm.
5. pipeline high intensity according to claim 1, corrosion-resistant ABS composite material, it is characterised in that：The lubricant
For one kind in vinyl bis-stearamides, zinc stearate, calcium stearate.
6. pipeline high intensity according to claim 1, corrosion-resistant ABS composite material, it is characterised in that：The compatilizer
For MBS terpolymer, acrylic acid-maleic acid acid anhydride-styrene copolymer, second
At least one of alkene-methyl acrylate-GMA random terpolymer.
7. pipeline high intensity according to claim 1, corrosion-resistant ABS composite material, it is characterised in that：The toughener
For at least one of high glue powder class, acrylic ester elastomer, phenylethylene toughener.
8. pipeline high intensity according to claim 1, corrosion-resistant ABS composite material, it is characterised in that：The antioxidant
For triethylene glycol double -3- (3- tertiary butyl-4-hydroxy -5- aminomethyl phenyls) acrylonitrile, three (2,4- di-tert-butylphenol) phosphite esters, four
One in [3- (3,5- di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester, phosphorous acid three (2,4- 6- di-tert-butyl phenyl ester)
Kind.
9. a kind of pipeline high intensity as described in claim 1-8 is any, the preparation method of corrosion-resistant ABS composite material, it is special
Levy and be, comprise the following steps：
S1, according to parts by weight weigh each raw material；
S2, by ABS resin, high brilliant activated carbon nano fiber material, plant ash, reinforcing fiber, hollow silica ball, compatible
It is well mixed in agent, lubricant, antioxidant input mixer, adds progress mixing 15-20min in two-roll mill, mixing
Temperature is 200-230 DEG C, obtains mixed material；
S3, by mixed material from main spout add double screw extruder in, by diallyl phthalate, expoxy propane fourth
Base ether, toughener side loading mouthful are added in double screw extruder, shear, extrude through twin-screw, tie rod, cooling, granulation, you can.
10. preparation method according to claim 9, it is characterised in that：One area's temperature of the double screw extruder is
170-200 DEG C, two area's temperature are 180-210 DEG C, and three area's temperature are 190-220 DEG C, and four area's temperature are 200-230 DEG C, five area's temperature
Spend for 200-220 DEG C, head temperature is 200-210 DEG C, and rate of feeding is 230-300/min, and screw speed is 550-650r/
min。
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| CN201710563883.0A CN107298828A (en) | 2017-07-12 | 2017-07-12 | A kind of pipeline high intensity, corrosion-resistant ABS composite material and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111732811A (en) * | 2020-06-05 | 2020-10-02 | 江西塑高新材料有限公司 | Color conductive ABS plastic |
| FR3130285A1 (en) * | 2021-12-09 | 2023-06-16 | Sk Geo Centric Co., Ltd. | LOW FLUIDITY POLYMER COMPOSITION CONTAINING ABS COPOLYMER AND TERPOLYMER AND METHOD FOR REDUCING FLUIDITY OF ABS COPOLYMER |
Citations (4)
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| FR3130285A1 (en) * | 2021-12-09 | 2023-06-16 | Sk Geo Centric Co., Ltd. | LOW FLUIDITY POLYMER COMPOSITION CONTAINING ABS COPOLYMER AND TERPOLYMER AND METHOD FOR REDUCING FLUIDITY OF ABS COPOLYMER |
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Application publication date: 20171027 |