CN107298784A - Antifreeze smell show and colour - Google Patents

Antifreeze smell show and colour Download PDF

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Publication number
CN107298784A
CN107298784A CN201710525632.3A CN201710525632A CN107298784A CN 107298784 A CN107298784 A CN 107298784A CN 201710525632 A CN201710525632 A CN 201710525632A CN 107298784 A CN107298784 A CN 107298784A
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CN
China
Prior art keywords
antifreeze
weight
parts
colour
smell
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710525632.3A
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Chinese (zh)
Inventor
梅霖陶
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sichuan Mark Vision Network Technology Co Ltd
Original Assignee
Sichuan Mark Vision Network Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Priority to CN201710525632.3A priority Critical patent/CN107298784A/en
Publication of CN107298784A publication Critical patent/CN107298784A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/141Hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00Foams characterized by the expanding agent
    • C08J2203/14Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04Homopolymers or copolymers of ethene
    • C08J2323/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/14Applications used for foams
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The present invention relates to a kind of antifreeze smell show and colour, belong to technical field of advertisement.The antifreeze smell show and colour of the present invention includes:The parts by weight of polyethylene 80~86;The parts by weight of product essence 10~25, the parts by weight of sustained release agent 10~30, the parts by weight of calcium carbonate 5~10, the parts by weight of polyacrylamide 3~5, the parts by weight of ethyl cellulose 3~5, the parts by weight of antifreeze 1~5, the parts by weight of foaming agent 0.5~1.8.Beneficial effect:The essence for treating advertised product is stored in release membranes by the antifreeze smell show and colour of the present invention, slow release, plays certain smell the effect of publicity, is not easy to freeze when temperature is low, can as outdoor advertising material.The antifreeze smell show and colour of the present invention is in addition to the essence for treating advertised product, and the smell of other compositions is very weak, does not influence the effect of publicity.The antifreeze smell show and colour of the present invention is easy to make, and technique is simple, is conducive to popularization and application.

Description

Antifreeze smell show and colour
Technical field
The present invention relates to a kind of antifreeze smell show and colour, belong to technical field of advertisement.
Background technology
Show and colour is the carrier of advertisement, and existing advertisement form has image, word, video, audio etc., but without with The form propagating advertisement of smell, for the product famous with smell, smell advertisement is used, consumer's intuitively body can be more given Test, therefore it is significant to develop a kind of smell show and colour.
In addition, many advertisements, road sign are disposed in the outdoor, or even field, it can usually face cryogenic conditions.
Polyethylene odorless, nontoxic, with excellent resistance to low temperature, chemical stability is good, is resistant to invading for most of soda acids Erosion.Common solvent is not dissolved under normal temperature, water imbibition is small, and electrical insulating property is excellent.
The content of the invention
The invention solves the problems that first technical problem be to provide a kind of antifreeze smell show and colour.
In order to solve the above technical problems, the antifreeze smell show and colour of the present invention includes:The parts by weight of polyethylene 80~86;Production The parts by weight of product essence 10~25, the parts by weight of sustained release agent 10~30, the parts by weight of calcium carbonate 5~10, the parts by weight of polyacrylamide 3~5, The parts by weight of ethyl cellulose 3~5, the parts by weight of antifreeze 1~5, the parts by weight of foaming agent 0.5~1.8.
Further, the sustained release agent is at least one of polyethylene glycol, hydroxymethyl cellulose, guar gum.
Further, the one kind of the foaming agent in Arcton 11, dicholorodifluoromethane, pentamethylene and isopentane Or several mixing.
Further, the antifreeze be 2,2,2- nitroso three, 0.15~0.17wt% of ethanol, sodium nitrate 0.09~ 0.12wt%, 0.05~0.08wt% of BTA amine salt mixture, remaining is the mixture of ethylene glycol.
Further, the antifreeze smell show and colour is prepared by following methods:
A. material is weighed, product essence, sustained release agent and antifreeze are mixed into obtain mixture A;
B. polyethylene and polyacrylamide are mixed;
C. calcium carbonate and ethyl cellulose are mixed;
D. mixed material in b step and step c is mixed at 100~110 DEG C and kneaded 5~8 minutes, add foaming Agent, kneads 8~12 minutes at 120~140 DEG C, is cooled to 80~85 DEG C, adds mixture A, is kept for 80~85 DEG C, 0.5~ 0.6Mpa obtains antifreeze smell show and colour in 15~20 minutes.
The invention solves the problems that second technical problem be to provide a kind of preparation method of above-mentioned antifreeze smell show and colour.
To solve second technical problem of the present invention, the technique of the preparation method of antifreeze smell show and colour of the invention It is as follows:
A. material is weighed, product essence, sustained release agent and antifreeze are mixed into obtain mixture A;
B. polyethylene and polyacrylamide are mixed;
C. calcium carbonate and ethyl cellulose are mixed;
D. mixed material in b step and step c is mixed at 100~110 DEG C and kneaded 5~8 minutes, add foaming Agent, kneads 8~12 minutes at 120~140 DEG C, is cooled to 80~85 DEG C, adds mixture A, is kept for 80~85 DEG C, 0.5~ 0.6Mpa obtains antifreeze smell show and colour in 15~20 minutes.
Beneficial effect:The essence for treating advertised product is stored in release membranes by the antifreeze smell show and colour of the present invention, is delayed On The Drug Release, plays certain smell the effect of publicity, be not easy to when temperature is low freeze, can as outdoor advertising material.
The antifreeze smell show and colour of the present invention is in addition to the essence for treating advertised product, and the smell of other compositions is very weak, no Influence the effect of publicity.
The antifreeze smell show and colour of the present invention is easy to make, and technique is simple, is conducive to popularization and application.
Embodiment
The antifreeze smell show and colour of the present invention includes:The parts by weight of polyethylene 80~86;The parts by weight of product essence 10~25, The parts by weight of sustained release agent 10~30, the parts by weight of calcium carbonate 5~10, the parts by weight of polyacrylamide 3~5, the weight of ethyl cellulose 3~5 Part, the parts by weight of antifreeze 1~5, the parts by weight of foaming agent 0.5~1.8.
Further, the sustained release agent is at least one of polyethylene glycol, hydroxymethyl cellulose, guar gum.
Further, the one kind of the foaming agent in Arcton 11, dicholorodifluoromethane, pentamethylene and isopentane Or several mixing.
Further, the antifreeze be 2,2,2- nitroso three, 0.15~0.17wt% of ethanol, sodium nitrate 0.09~ 0.12wt%, BTA 0.05~0.08wt% of amine salt, remaining is the mixture of ethylene glycol.
Further, the antifreeze smell show and colour is prepared by following methods:
A. material is weighed, product essence, sustained release agent and antifreeze are mixed into obtain mixture A;
B. polyethylene and polyacrylamide are mixed;
C. calcium carbonate and ethyl cellulose are mixed;
D. mixed material in b step and step c is mixed at 100~110 DEG C and kneaded 5~8 minutes, add foaming Agent, kneads 8~12 minutes at 120~140 DEG C, is cooled to 80~85 DEG C, adds mixture A, is kept for 80~85 DEG C, 0.5~ 0.6Mpa obtains antifreeze smell show and colour in 15~20 minutes.
The technique of the preparation method of the antifreeze smell show and colour of the present invention is as follows:
A. material is weighed, product essence, sustained release agent and antifreeze are mixed into obtain mixture A;
B. polyethylene and polyacrylamide are mixed;
C. calcium carbonate and ethyl cellulose are mixed;
D. mixed material in b step and step c is mixed at 100~110 DEG C and kneaded 5~8 minutes, add foaming Agent, kneads 8~12 minutes at 120~140 DEG C, is cooled to 80~85 DEG C, adds mixture A, is kept for 80~85 DEG C, 0.5~ 0.6Mpa obtains antifreeze smell show and colour in 15~20 minutes.
Embodiment 1
Take the ethanol 0.2g of 2,2,2- nitroso three, sodium nitrate 0.12g, BTA amine salt 0.08g, ethylene glycol 120g mixing Obtain antifreeze.
The parts by weight of polyethylene 80 are weighed, the parts by weight of mango essence 20, the parts by weight of polyethylene glycol 25, the parts by weight of calcium carbonate 8 are gathered The parts by weight of acrylamide 4, the parts by weight of ethyl cellulose 4, the parts by weight of antifreeze 5, the parts by weight of pentamethylene 1.
A. mango essence, polyethylene glycol and antifreeze are mixed into obtain mixture A;
B. polyethylene and polyacrylamide are mixed;
C. calcium carbonate and ethyl cellulose are mixed;
D. mixed material in b step and step c is mixed at 100 DEG C and kneaded 7 minutes, pentamethylene is added, 130 Kneaded 10 minutes at DEG C, be cooled to 80 DEG C, add mixture A, kept for 80 DEG C, 0.5Mpa obtains antifreeze mango taste in 20 minutes Show and colour.
Embodiment 2
Take the ethanol 0.2g of 2,2,2- nitroso three, sodium nitrate 0.12g, BTA amine salt 0.08g, ethylene glycol 120g mixing Obtain antifreeze.
Weigh the parts by weight of polyethylene 85, the parts by weight of cream jasmin france 20, the parts by weight of polyethylene glycol 20, the parts by weight of guar gum 10, The parts by weight of calcium carbonate 5, the parts by weight of polyacrylamide 3, the parts by weight of ethyl cellulose 4, the parts by weight of antifreeze 5, the weight of isopentane 1 Part.
A. cream jasmin france, polyethylene glycol, guar gum and antifreeze are mixed into obtain mixture A;
B. polyethylene and polyacrylamide are mixed;
C. calcium carbonate and ethyl cellulose are mixed;
D. mixed material in b step and step c is mixed at 110 DEG C and kneaded 5 minutes, isopentane is added, 120 Kneaded 10 minutes at DEG C, be cooled to 80 DEG C, add mixture A, kept for 80 DEG C, 0.6Mpa obtains antifreeze jasmine taste in 18 minutes Advertisement material.

Claims (6)

1. antifreeze smell show and colour, it is characterised in that the antifreeze smell show and colour includes:The weight of polyethylene 80~86 Part;The parts by weight of product essence 10~25, the parts by weight of sustained release agent 10~30, the parts by weight of calcium carbonate 5~10, the weight of polyacrylamide 3~5 Measure part, the parts by weight of ethyl cellulose 3~5, the parts by weight of antifreeze 1~5, the parts by weight of foaming agent 0.5~1.8.
2. antifreeze smell show and colour according to claim 1, it is characterised in that the sustained release agent is polyethylene glycol, hydroxyl At least one of methylcellulose, guar gum.
3. antifreeze smell show and colour according to claim 1 or 2, it is characterised in that the foaming agent is selected from trichlorine fluorine One or more of mixing in methane, dicholorodifluoromethane, pentamethylene and isopentane.
4. antifreeze smell show and colour according to claim 1 or 2, it is characterised in that the antifreeze is 2,2,2- sub- 0.15~0.17wt% of nitrotrimethylolmethane ethanol, 0.09~0.12wt% of sodium nitrate, BTA 0.05~0.08wt% of amine salt, remaining For the mixture of ethylene glycol.
5. the antifreeze smell show and colour according to any one of claim 1-4, it is characterised in that the antifreeze smell is wide Material is accused to be prepared by following methods:
A. material is weighed, product essence, sustained release agent and antifreeze are mixed into obtain mixture A;
B. polyethylene and polyacrylamide are mixed;
C. calcium carbonate and ethyl cellulose are mixed;
D. mixed material in b step and step c is mixed at 100~110 DEG C and kneaded 5~8 minutes, add foaming agent, Kneaded 8~12 minutes at 120~140 DEG C, be cooled to 80~85 DEG C, add mixture A, kept for 80~85 DEG C, 0.5~ 0.6Mpa obtains antifreeze smell show and colour in 15~20 minutes.
6. the preparation method of the antifreeze smell show and colour according to any one of claim 1-5, it is characterised in that described The technique of method is as follows:
A. material is weighed, product essence, sustained release agent and antifreeze are mixed into obtain mixture A;
B. polyethylene and polyacrylamide are mixed;
C. calcium carbonate and ethyl cellulose are mixed;
D. mixed material in b step and step c is mixed at 100~110 DEG C and kneaded 5~8 minutes, add foaming agent, Kneaded 8~12 minutes at 120~140 DEG C, be cooled to 80~85 DEG C, add mixture A, kept for 80~85 DEG C, 0.5~ 0.6Mpa obtains antifreeze smell show and colour in 15~20 minutes.
CN201710525632.3A 2017-06-30 2017-06-30 Antifreeze smell show and colour Pending CN107298784A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710525632.3A CN107298784A (en) 2017-06-30 2017-06-30 Antifreeze smell show and colour

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710525632.3A CN107298784A (en) 2017-06-30 2017-06-30 Antifreeze smell show and colour

Publications (1)

Publication Number Publication Date
CN107298784A true CN107298784A (en) 2017-10-27

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Family Applications (1)

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CN201710525632.3A Pending CN107298784A (en) 2017-06-30 2017-06-30 Antifreeze smell show and colour

Country Status (1)

Country Link
CN (1) CN107298784A (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102040759A (en) * 2009-10-14 2011-05-04 中国石油化工股份有限公司 Polyethylene composition with phase transition performance and preparation method thereof
CN102873944A (en) * 2012-09-14 2013-01-16 佛山佛塑科技集团股份有限公司 Preparation method for polyethylene spray-painting base materials
CN104650464A (en) * 2013-11-20 2015-05-27 晋江凯基高分子材料有限公司 Preparation method and application of modified propenyl elastomer foaming body
CN105058920A (en) * 2015-07-21 2015-11-18 上海婉静纺织科技有限公司 Fireproof aluminum-plastic panel for advertisements

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102040759A (en) * 2009-10-14 2011-05-04 中国石油化工股份有限公司 Polyethylene composition with phase transition performance and preparation method thereof
CN102873944A (en) * 2012-09-14 2013-01-16 佛山佛塑科技集团股份有限公司 Preparation method for polyethylene spray-painting base materials
CN104650464A (en) * 2013-11-20 2015-05-27 晋江凯基高分子材料有限公司 Preparation method and application of modified propenyl elastomer foaming body
CN105058920A (en) * 2015-07-21 2015-11-18 上海婉静纺织科技有限公司 Fireproof aluminum-plastic panel for advertisements

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
糜淑娥: "《广告设计项目教程》", 30 September 2009, 西安电子科技大学出版社 *

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Application publication date: 20171027