CN107254092A - Snow defence smell show and colour - Google Patents

Snow defence smell show and colour Download PDF

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Publication number
CN107254092A
CN107254092A CN201710533360.1A CN201710533360A CN107254092A CN 107254092 A CN107254092 A CN 107254092A CN 201710533360 A CN201710533360 A CN 201710533360A CN 107254092 A CN107254092 A CN 107254092A
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CN
China
Prior art keywords
weight
parts
mixed
colour
snow defence
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710533360.1A
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Chinese (zh)
Inventor
梅霖陶
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Sichuan Mark Vision Network Technology Co Ltd
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Sichuan Mark Vision Network Technology Co Ltd
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Priority to CN201710533360.1A priority Critical patent/CN107254092A/en
Publication of CN107254092A publication Critical patent/CN107254092A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/141—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene
    • C08J2323/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2433/24—Homopolymers or copolymers of amides or imides
    • C08J2433/26—Homopolymers or copolymers of acrylamide or methacrylamide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/16—Halogen-containing compounds
    • C08K2003/162—Calcium, strontium or barium halides, e.g. calcium, strontium or barium chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/14—Applications used for foams
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The present invention relates to a kind of snow defence smell show and colour, belong to technical field of advertisement.The snow defence smell show and colour of the present invention includes：The parts by weight of polyethylene 80~86, the parts by weight of product essence 10~25, the parts by weight of sustained release agent 10~30, the parts by weight of calcium carbonate 5~10, the parts by weight of polyacrylamide 3~5, the parts by weight of ethyl cellulose 3~5, the parts by weight of antifreeze 1~5, the parts by weight of foaming agent 0.5~1.8, the parts by weight of paraffin 5~10, the parts by weight of acetic acid 5~8, the parts by weight of attapulgite 2~4, the parts by weight of graphite 2~4, the parts by weight of potassium nitrate 2~4, the parts by weight of ice crystal sand 5~10, the parts by weight of calcium chloride 3~6.The snow defence smell show and colour of the present invention is shined upon, and the heat storage phase-changing material in snow defence smell show and colour absorbs heat energy and stored, and under conditions of no daylight, heat storage phase-changing material releases energy.So as to play the anti-freeze effect of snow defence.

Description

Snow defence smell show and colour
Technical field
The present invention relates to a kind of snow defence smell show and colour, belong to technical field of advertisement.
Background technology
Show and colour is the carrier of advertisement, and existing advertisement form is various, there is image, word, video, audio etc., wherein The advertisement of picture and text form is most common.But without the propagating advertisement in the form of smell, for the product famous with smell, Smell advertisement is used, more can intuitively be experienced to consumer, therefore it is significant to develop a kind of smell show and colour.
The advertisement of many picture and text forms, road sign are disposed in the outdoor, or even field, can usually face the extreme weathers such as snow, ice Condition.Not only block vision, and fragile show and colour, so as to reduce its service life.
Polyethylene odorless, nontoxic, with excellent resistance to low temperature, chemical stability is good, is resistant to invading for most of soda acids Erosion.Common solvent is not dissolved under normal temperature, water imbibition is small, and electrical insulating property is excellent.
The content of the invention
The invention solves the problems that first technical problem be to provide a kind of snow defence smell show and colour.
In order to solve the above technical problems, the snow defence smell show and colour of the present invention includes：The parts by weight of polyethylene 80~86, production The parts by weight of product essence 10~25, the parts by weight of sustained release agent 10~30, the parts by weight of calcium carbonate 5~10, the parts by weight of polyacrylamide 3~5, The parts by weight of ethyl cellulose 3~5, the parts by weight of antifreeze 1~5, the parts by weight of foaming agent 0.5~1.8, the parts by weight of paraffin 5~10, vinegar Sour 5~8 parts by weight, the parts by weight of attapulgite 2~4, the parts by weight of graphite 2~4, the parts by weight of potassium nitrate 2~4, the weight of ice crystal sand 5~10 Measure part, the parts by weight of calcium chloride 3~6.
Further, the sustained release agent is at least one of polyethylene glycol, hydroxymethyl cellulose, guar gum.
Further, the one kind of the foaming agent in Arcton 11, dicholorodifluoromethane, pentamethylene and isopentane Or several mixing.
Further, the antifreeze be 2,2,2- nitroso three, 0.15~0.17wt% of ethanol, sodium nitrate 0.09~ 0.12wt%, BTA 0.05~0.08wt% of amine salt, remaining is the mixture of ethylene glycol.
Further, the snow defence smell show and colour is prepared by following methods：
A. material is weighed, product essence, sustained release agent and antifreeze are mixed into obtain mixture A；
B. polyethylene and polyacrylamide are mixed；
C. calcium carbonate and ethyl cellulose are mixed；
D. by paraffin, acetic acid, attapulgite, graphite, potassium nitrate, ice crystal sand, calcium chloride is well mixed, and obtains mixture D storage Can material；
E. mixed material and antifreeze in b step and step c are mixed at 100~110 DEG C and knead 5~8 points Clock, adds mixture D and foaming agent, is kneaded 8~12 minutes at 120~140 DEG C, is cooled to 80~85 DEG C, adds mixture A, is kept for 80~85 DEG C, 0.5~0.6Mpa obtains snow defence smell show and colour in 15~20 minutes.
The invention solves the problems that second technical problem be to provide a kind of preparation method of above-mentioned snow defence smell show and colour.
To solve second technical problem of the present invention, the technique of the preparation method of snow defence smell show and colour of the invention It is as follows：
A. material is weighed, product essence, sustained release agent and antifreeze are mixed into obtain mixture A；
B. polyethylene and polyacrylamide are mixed；
C. calcium carbonate and ethyl cellulose are mixed；
D. by paraffin, acetic acid, attapulgite, graphite, potassium nitrate, ice crystal sand, calcium chloride is well mixed, and obtains mixture D storage Can material；
E. mixed material and antifreeze in b step and step c are mixed at 100~110 DEG C and knead 5~8 points Clock, adds mixture D and foaming agent, is kneaded 8~12 minutes at 120~140 DEG C, is cooled to 80~85 DEG C, adds mixture A, is kept for 80~85 DEG C, 0.5~0.6Mpa obtains snow defence smell show and colour in 15~20 minutes.
Beneficial effect：The snow defence smell show and colour of the present invention is shined upon, the storage in snow defence smell show and colour Hot phase-change material absorbs heat energy and stored, and under conditions of no daylight, heat storage phase-changing material releases energy.So as to play The anti-freeze effect of snow defence.
The essence for treating advertised product is stored in release membranes by the snow defence smell show and colour of the present invention, slow release, is risen To certain smell the effect of publicity, be not easy to when temperature is low freeze, can as outdoor advertising material.
The snow defence smell show and colour of the present invention is easy to make, and technique is simple, is conducive to popularization and application.
Embodiment
The snow defence smell show and colour of the present invention includes：The parts by weight of polyethylene 80~86, the parts by weight of product essence 10~25, The parts by weight of sustained release agent 10~30, the parts by weight of calcium carbonate 5~10, the parts by weight of polyacrylamide 3~5, the weight of ethyl cellulose 3~5 Part, the parts by weight of antifreeze 1~5, the parts by weight of foaming agent 0.5~1.8, the parts by weight of paraffin 5~10, the parts by weight of acetic acid 5~8 are concavo-convex The parts by weight of rod soil 2~4, the parts by weight of graphite 2~4, the parts by weight of potassium nitrate 2~4, the parts by weight of ice crystal sand 5~10, the weight of calcium chloride 3~6 Measure part.
Further, the sustained release agent is at least one of polyethylene glycol, hydroxymethyl cellulose, guar gum.
Further, the one kind of the foaming agent in Arcton 11, dicholorodifluoromethane, pentamethylene and isopentane Or several mixing.
Further, the antifreeze be 2,2,2- nitroso three, 0.15~0.17wt% of ethanol, sodium nitrate 0.09~ 0.12wt%, BTA 0.05~0.08wt% of amine salt, remaining is the mixture of ethylene glycol.
Further, the snow defence smell show and colour is prepared by following methods：
A. material is weighed, product essence, sustained release agent and antifreeze are mixed into obtain mixture A；
B. polyethylene and polyacrylamide are mixed；
C. calcium carbonate and ethyl cellulose are mixed；
D. by paraffin, acetic acid, attapulgite, graphite, potassium nitrate, ice crystal sand, calcium chloride is well mixed, and obtains mixture D storage Can material；
E. mixed material and antifreeze in b step and step c are mixed at 100~110 DEG C and knead 5~8 points Clock, adds mixture D and foaming agent, is kneaded 8~12 minutes at 120~140 DEG C, is cooled to 80~85 DEG C, adds mixture A, is kept for 80~85 DEG C, 0.5~0.6Mpa obtains snow defence smell show and colour in 15~20 minutes.
The technique of the preparation method of the snow defence smell show and colour of the present invention is as follows：
A. material is weighed, product essence, sustained release agent and antifreeze are mixed into obtain mixture A；
B. polyethylene and polyacrylamide are mixed；
C. calcium carbonate and ethyl cellulose are mixed；
D. by paraffin, acetic acid, attapulgite, graphite, potassium nitrate, ice crystal sand, calcium chloride is well mixed, and obtains mixture D storage Can material；
E. mixed material and antifreeze in b step and step c are mixed at 100~110 DEG C and knead 5~8 points Clock, adds mixture D and foaming agent, is kneaded 8~12 minutes at 120~140 DEG C, is cooled to 80~85 DEG C, adds mixture A, is kept for 80~85 DEG C, 0.5~0.6Mpa obtains snow defence smell show and colour in 15~20 minutes.
Embodiment 1
Take the ethanol 0.2g of 2,2,2- nitroso three, sodium nitrate 0.12g, BTA amine salt 0.08g, ethylene glycol 120g mixing Obtain antifreeze.
The parts by weight of polyethylene 80 are weighed, the parts by weight of mango essence 20, the parts by weight of polyethylene glycol 25, the parts by weight of calcium carbonate 8 are gathered The parts by weight of acrylamide 4, the parts by weight of ethyl cellulose 4, the parts by weight of antifreeze 5, the parts by weight of pentamethylene 1, the parts by weight of paraffin 6, vinegar Sour 6 parts by weight, the parts by weight of attapulgite 3, the parts by weight of graphite 3, the parts by weight of potassium nitrate 3, the parts by weight of ice crystal sand 7, the weight of calcium chloride 4 Part.
A. mango essence, polyethylene glycol and antifreeze are mixed into obtain mixture A；
B. polyethylene and polyacrylamide are mixed；
C. calcium carbonate and ethyl cellulose are mixed；
D. by paraffin, acetic acid, attapulgite, graphite, potassium nitrate, ice crystal sand, calcium chloride is well mixed, and obtains mixture D storage Can material；
E. mixed material and antifreeze in b step and step c are mixed at 100 DEG C and kneaded 7 minutes, added Mixture D and pentamethylene, are kneaded 10 minutes at 130 DEG C, are cooled to 80 DEG C, are kept for 80 DEG C, add mixture A, 0.5Mpa, 20 Minute obtains snow defence mango taste show and colour.
Embodiment 2
Take the ethanol 0.2g of 2,2,2- nitroso three, sodium nitrate 0.12g, BTA amine salt 0.08g, ethylene glycol 120g mixing Obtain antifreeze.
Weigh the parts by weight of polyethylene 85, the parts by weight of cream jasmin france 20, the parts by weight of polyethylene glycol 20, the parts by weight of guar gum 10, The parts by weight of calcium carbonate 5, the parts by weight of polyacrylamide 3, the parts by weight of ethyl cellulose 4, the parts by weight of antifreeze 5, the weight of isopentane 1 Part, the parts by weight of paraffin 8, the parts by weight of acetic acid 8, the parts by weight of attapulgite 4, the parts by weight of graphite 3, the parts by weight of potassium nitrate 4, ice crystal sand 8 Parts by weight, the parts by weight of calcium chloride 5.
A. cream jasmin france, polyethylene glycol, guar gum and antifreeze are mixed into obtain mixture A；
B. polyethylene and polyacrylamide are mixed；
C. calcium carbonate and ethyl cellulose are mixed；
D. by paraffin, acetic acid, attapulgite, graphite, potassium nitrate, ice crystal sand, calcium chloride is well mixed, and obtains mixture D storage Can material；
E. mixed material and antifreeze in b step and step c are mixed at 110 DEG C and kneaded 5 minutes, added Mixture D and isopentane, are kneaded 10 minutes at 120 DEG C, are cooled to 80 DEG C, are kept for 80 DEG C, add mixture A, 0.6Mpa, 15 Minute obtains snow defence jasmine taste show and colour.

Claims (6)

1. snow defence smell show and colour, it is characterised in that the snow defence smell show and colour includes：The weight of polyethylene 80~86 Part, the parts by weight of product essence 10~25, the parts by weight of sustained release agent 10~30, the parts by weight of calcium carbonate 5~10, the weight of polyacrylamide 3~5 Measure part, the parts by weight of ethyl cellulose 3~5, the parts by weight of antifreeze 1~5, the parts by weight of foaming agent 0.5~1.8, the weight of paraffin 5~10 Part, the parts by weight of acetic acid 5~8, the parts by weight of attapulgite 2~4, the parts by weight of graphite 2~4, the parts by weight of potassium nitrate 2~4, ice crystal sand 5 ~10 parts by weight, the parts by weight of calcium chloride 3~6.
2. snow defence smell show and colour according to claim 1, it is characterised in that the sustained release agent is polyethylene glycol, hydroxyl At least one of methylcellulose, guar gum.
3. snow defence smell show and colour according to claim 1 or 2, it is characterised in that the foaming agent is selected from trichlorine fluorine One or more of mixing in methane, dicholorodifluoromethane, pentamethylene and isopentane.
4. the snow defence smell show and colour according to any one of claim 1-3, it is characterised in that the antifreeze is 2, 2,2- nitroso three, 0.15~0.17wt% of ethanol, 0.09~0.12wt% of sodium nitrate, BTA amine salt 0.05~ 0.08wt%, remaining is the mixture of ethylene glycol.
5. the snow defence smell show and colour according to any one of claim 1-4, it is characterised in that the snow defence smell is wide Material is accused to be prepared by following methods：
A. material is weighed, product essence, sustained release agent and antifreeze are mixed into obtain mixture A；
B. polyethylene and polyacrylamide are mixed；
C. calcium carbonate and ethyl cellulose are mixed；
D. by paraffin, acetic acid, attapulgite, graphite, potassium nitrate, ice crystal sand, calcium chloride is well mixed, and obtains mixture D energy storage material Material；
E. mixed material and antifreeze in b step and step c are mixed at 100~110 DEG C and kneaded 5~8 minutes, Mixture D and foaming agent are added, is kneaded 8~12 minutes at 120~140 DEG C, 80~85 DEG C are cooled to, mixture A is added, protected 80~85 DEG C are held, 0.5~0.6Mpa obtains snow defence smell show and colour in 15~20 minutes.
6. the preparation method of the snow defence smell show and colour according to any one of claim 1-5, it is characterised in that described The technique of method is as follows：
A. material is weighed, product essence, sustained release agent and antifreeze are mixed into obtain mixture A；
B. polyethylene and polyacrylamide are mixed；
C. calcium carbonate and ethyl cellulose are mixed；
D. by paraffin, acetic acid, attapulgite, graphite, potassium nitrate, ice crystal sand, calcium chloride is well mixed, and obtains mixture D energy storage material Material；
E. mixed material and antifreeze in b step and step c are mixed at 100~110 DEG C and kneaded 5~8 minutes, Mixture D and foaming agent are added, is kneaded 8~12 minutes at 120~140 DEG C, 80~85 DEG C are cooled to, mixture A is added, protected 80~85 DEG C are held, 0.5~0.6Mpa obtains snow defence smell show and colour in 15~20 minutes.
CN201710533360.1A 2017-07-03 2017-07-03 Snow defence smell show and colour Pending CN107254092A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710533360.1A CN107254092A (en) 2017-07-03 2017-07-03 Snow defence smell show and colour

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710533360.1A CN107254092A (en) 2017-07-03 2017-07-03 Snow defence smell show and colour

Publications (1)

Publication Number Publication Date
CN107254092A true CN107254092A (en) 2017-10-17

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CN201710533360.1A Pending CN107254092A (en) 2017-07-03 2017-07-03 Snow defence smell show and colour

Country Status (1)

Country Link
CN (1) CN107254092A (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102040759A (en) * 2009-10-14 2011-05-04 中国石油化工股份有限公司 Polyethylene composition with phase transition performance and preparation method thereof
CN102873944A (en) * 2012-09-14 2013-01-16 佛山佛塑科技集团股份有限公司 Preparation method for polyethylene spray-painting base materials
CN104650464A (en) * 2013-11-20 2015-05-27 晋江凯基高分子材料有限公司 Preparation method and application of modified propenyl elastomer foaming body
CN105058920A (en) * 2015-07-21 2015-11-18 上海婉静纺织科技有限公司 Fireproof aluminum-plastic panel for advertisements

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102040759A (en) * 2009-10-14 2011-05-04 中国石油化工股份有限公司 Polyethylene composition with phase transition performance and preparation method thereof
CN102873944A (en) * 2012-09-14 2013-01-16 佛山佛塑科技集团股份有限公司 Preparation method for polyethylene spray-painting base materials
CN104650464A (en) * 2013-11-20 2015-05-27 晋江凯基高分子材料有限公司 Preparation method and application of modified propenyl elastomer foaming body
CN105058920A (en) * 2015-07-21 2015-11-18 上海婉静纺织科技有限公司 Fireproof aluminum-plastic panel for advertisements

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
糜淑娥: "《广告设计项目教程》", 30 September 2009, 西安电子科技大学出版社 *

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