CN107298529A - A kind of high-heat-resisting glass glass and preparation method thereof - Google Patents

A kind of high-heat-resisting glass glass and preparation method thereof Download PDF

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Publication number
CN107298529A
CN107298529A CN201710475999.9A CN201710475999A CN107298529A CN 107298529 A CN107298529 A CN 107298529A CN 201710475999 A CN201710475999 A CN 201710475999A CN 107298529 A CN107298529 A CN 107298529A
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China
Prior art keywords
parts
powder
glass
heat
resisting
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CN201710475999.9A
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Chinese (zh)
Inventor
张锐
张鹏
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Friends Of City Of Chuzhou Precision Manufacturing Co Ltd
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Friends Of City Of Chuzhou Precision Manufacturing Co Ltd
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Priority to CN201710475999.9A priority Critical patent/CN107298529A/en
Publication of CN107298529A publication Critical patent/CN107298529A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • C03C1/002Use of waste materials, e.g. slags
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B13/00Rolling molten glass, i.e. where the molten glass is shaped by rolling
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Glass Compositions (AREA)

Abstract

The invention discloses a kind of high-heat-resisting glass glass and preparation method thereof, the parts by weight of each component are as follows during it is formulated:50 60 parts of haloflex, 10 25 parts of neoprene, 15 30 parts of thermoplastic ethylene's resinoid, 6 10 parts of paraffin, 24 parts of silicon fire retardant, 13 parts of glass fibre, 56 parts of zinc oxide, 13 parts of magnesium stearate, 15 parts of plasticizer octyl ester of epoxy fatty acid, 39 parts of antioxidant, 8 12 parts of inorganic filler.High-heat-resisting glass glass of the present invention has good intensity and heat endurance, uniform wall thickness, and ageing-resistant performance is excellent, cheap, can meet it is various in the case of use environment change demand.

Description

A kind of high-heat-resisting glass glass and preparation method thereof
Technical field
The present invention relates to a kind of high-heat-resisting glass glass and preparation method thereof, belong to glassmaking art.
Background technology
With the fast development of China's building decoration and science and technology, glassware is widely used in every field, glass The purposes of glass product also comes more by being intended to of developing of people, and heat resistant glass refers to containing the strong boric acid of heat resistance, silicic acid component, energy Enough bear the special glass of cold and hot fusion difference variation.Thermal coefficient of expansion is smaller, is not easy to crush under dramatic temperature change, This heat endurance has obtained being also that more demand is also carried out in market.
But in existing glass technology in be difficult to have and accomplish that glassware can have good high-fire resistance, can have again Excellent ageing-resistant performance, so a kind of new high-heat-resisting glass glass of invention is particularly important.
The content of the invention
Present invention aims at providing a kind of high-heat-resisting glass glass and preparation method thereof, with heat endurance is good, fire resistance, Ageing-resistant performance is excellent.
The solution of the present invention is as follows:
A kind of high-heat-resisting glass glass, is made up of according to parts by weight the following raw material:25-40 parts of quartz sand powder, feldspar powder 15-25 Part, 10-15 parts of graphene powder, 11-16 parts of calcite powder, 6-10 parts of soda ash, 5-12 parts of zinc oxide, 8-13 parts of sodium nitrate, 1-3 parts of high borosilicate 5-8 parts, 3-7 parts of chrome ore slag, 6-10 parts of charcoal, 3-5 parts of manganese powder, 1-3 parts of binding agent and antiager.
A kind of above-mentioned high-heat-resisting glass glass, is made up of according to parts by weight the following raw material:34-40 parts of quartz sand powder, length 20-25 parts of stone powder, 13-15 parts of graphene powder, 13-16 parts of calcite powder, 8-10 parts of soda ash, 7-12 parts of zinc oxide, nitre Sour sodium 10-13 parts, high borosilicate 6-8 parts, 5-7 parts of chrome ore slag, 8-10 parts of charcoal, 4-5 parts of manganese powder, 2-3 parts of binding agent and ageing-resistant 2-3 parts of agent.
A kind of above-mentioned high-heat-resisting glass glass, is made up of according to parts by weight the following raw material:34 parts of quartz sand powder, feldspar powder End 20 parts, 13 parts of graphene powder, 13 parts of calcite powder, 8 parts of soda ash, 7 parts of zinc oxide, 10 parts of sodium nitrate, 6 parts of high borosilicate, 2 parts of 5 parts of chrome ore slag, 8 parts of charcoal, 4 parts of manganese powder, 2 parts of binding agent and antiager.
A kind of preparation method of above-mentioned high-heat-resisting glass glass is as follows:
(1)Dispensing:Quartz sand powder, feldspar powder, graphene powder, calcite powder, soda ash, oxidation are taken according to part by weight Zinc, sodium nitrate, high borosilicate, chrome ore slag, charcoal, manganese powder, are poured into grinder, and mixed grinding is into powder, after then mixing Raw material be put into homogenizer with 1000-1400r/min speed stirring mixing 0.5-1h;
(2)Found:It will be put into through the mixed raw material of high-speed stirred, binding agent and antiager in molten cellar for storing things and refine into molten State, smelting temperature is controlled at 1450-1500 DEG C, and the time is 0.5-1h;
(3)Shaping:Molten mass is rapidly injected in calender and rolled, required shape is obtained, forming temperature is 1200-1300 DEG C;
(4)Annealing:Glass after shaping is made annealing treatment, annealing temperature is 540 DEG C, cooling produces high heat-resisting after stepping back Glass.
Beneficial effects of the present invention:
High-heat-resisting glass glass of the present invention has good intensity and heat endurance, uniform wall thickness, and ageing-resistant performance is excellent, price It is cheap, can meet it is various in the case of use environment change demand.
Embodiment
With reference to embodiment, the present invention will be further described.
Embodiment 1
A kind of high-heat-resisting glass glass, is made up of according to parts by weight the following raw material:25 parts of quartz sand powder, 15 parts of feldspar powder, stone Black 10 parts of alkene powder, 11 parts of calcite powder, 6 parts of soda ash, 5 parts of zinc oxide, 8 parts of sodium nitrate, 5 parts of high borosilicate, 3 parts of chrome ore slag, 1 part of 6 parts of charcoal, 3 parts of manganese powder, 1 part of binding agent and antiager.
A kind of preparation method of above-mentioned high-heat-resisting glass glass is as follows:
(1)Dispensing:Quartz sand powder, feldspar powder, graphene powder, calcite powder, soda ash, oxidation are taken according to part by weight Zinc, sodium nitrate, high borosilicate, chrome ore slag, charcoal, manganese powder, are poured into grinder, and mixed grinding is into powder, after then mixing Raw material be put into homogenizer with 1200r/min speed stirring mixing 0.5h;
(2)Found:It will be put into through the mixed raw material of high-speed stirred, binding agent and antiager in molten cellar for storing things and refine into molten State, smelting temperature is controlled at 1450 DEG C, and the time is 45min;
(3)Shaping:Molten mass is rapidly injected in calender and rolled, required shape is obtained, forming temperature is 1200 DEG C;
(4)Annealing:Glass after shaping is made annealing treatment, annealing temperature is 540 DEG C, cooling produces high heat-resisting after annealing Glass.
Embodiment 2
A kind of high-heat-resisting glass glass, is made up of according to parts by weight the following raw material:40 parts of quartz sand powder, 25 parts of feldspar powder, stone Black 15 parts of alkene powder, 16 parts of calcite powder, 10 parts of soda ash, 12 parts of zinc oxide, 13 parts of sodium nitrate, 8 parts of high borosilicate, chrome ore slag 7 Part, 10 parts of charcoal, 5 parts of manganese powder, 3 parts of binding agent and 3 parts of antiager.
A kind of preparation method of above-mentioned high-heat-resisting glass glass is as follows:
(1)Dispensing:Quartz sand powder, feldspar powder, graphene powder, calcite powder, soda ash, oxidation are taken according to part by weight Zinc, sodium nitrate, high borosilicate, chrome ore slag, charcoal, manganese powder, are poured into grinder, and mixed grinding is into powder, after then mixing Raw material be put into homogenizer with 1200r/min speed stirring mixing 0.5h;
(2)Found:It will be put into through the mixed raw material of high-speed stirred, binding agent and antiager in molten cellar for storing things and refine into molten State, smelting temperature is controlled at 1450 DEG C, and the time is 45min;
(3)Shaping:Molten mass is rapidly injected in calender and rolled, required shape is obtained, forming temperature is 1200 DEG C;
(4)Annealing:Glass after shaping is made annealing treatment, annealing temperature is 540 DEG C, cooling produces high heat-resisting after annealing Glass.
Embodiment 3
A kind of high-heat-resisting glass glass, is made up of according to parts by weight the following raw material:34 parts of quartz sand powder, 20 parts of feldspar powder, stone Black 13 parts of alkene powder, 13 parts of calcite powder, 8 parts of soda ash, 7 parts of zinc oxide, 10 parts of sodium nitrate, 6 parts of high borosilicate, 5 parts of chrome ore slag, 2 parts of 8 parts of charcoal, 4 parts of manganese powder, 2 parts of binding agent and antiager.
A kind of preparation method of above-mentioned above-mentioned high-heat-resisting glass glass is as follows:
(1)Dispensing:Quartz sand powder, feldspar powder, graphene powder, calcite powder, soda ash, oxidation are taken according to part by weight Zinc, sodium nitrate, high borosilicate, chrome ore slag, charcoal, manganese powder, are poured into grinder, and mixed grinding is into powder, after then mixing Raw material be put into homogenizer with 1200r/min speed stirring mixing 0.5h;
(2)Found:It will be put into through the mixed raw material of high-speed stirred, binding agent and antiager in molten cellar for storing things and refine into molten State, smelting temperature is controlled at 1450 DEG C, and the time is 45min;
(3)Shaping:Molten mass is rapidly injected in calender and rolled, required shape is obtained, forming temperature is 1200 DEG C;
(4)Annealing:Glass after shaping is made annealing treatment, annealing temperature is 540 DEG C, cooling produces high heat-resisting after annealing Glass.
High-heat-resisting glass glass of the present invention has good intensity and heat endurance, uniform wall thickness, and ageing-resistant performance is excellent, It is cheap, can meet it is various in the case of use environment change demand.
Although the embodiment to the present invention gives detailed description and illustrated above, it should be noted that We can carry out various equivalent changes and modification according to the conception of the present invention to above-mentioned embodiment, and the function produced by it is made , all should be within protection scope of the present invention during with the spirit still covered without departing from specification.

Claims (4)

1. a kind of high-heat-resisting glass glass, it is characterised in that be made up of according to parts by weight the following raw material:25-40 parts of quartz sand powder, 15-25 parts of feldspar powder, 10-15 parts of graphene powder, 11-16 parts of calcite powder, 6-10 parts of soda ash, 5-12 parts of zinc oxide, 8-13 parts of sodium nitrate, high borosilicate 5-8 parts, 3-7 parts of chrome ore slag, 6-10 parts of charcoal, 3-5 parts of manganese powder, 1-3 parts of binding agent and ageing-resistant 1-3 parts of agent.
2. a kind of high-heat-resisting glass glass according to claim 1, it is characterised in that according to parts by weight by the following raw material group Into:34-40 parts of quartz sand powder, 20-25 parts of feldspar powder, 13-15 parts of graphene powder, 13-16 parts of calcite powder, soda ash 8-10 parts, 7-12 parts of zinc oxide, 10-13 parts of sodium nitrate, high borosilicate 6-8 parts, 5-7 parts of chrome ore slag, 8-10 parts of charcoal, manganese powder 4-5 2-3 parts of part, 2-3 parts of binding agent and antiager.
3. a kind of high-heat-resisting glass glass according to claim 1, it is characterised in that according to parts by weight by the following raw material group Into:34 parts of quartz sand powder, 20 parts of feldspar powder, 13 parts of graphene powder, 13 parts of calcite powder, 8 parts of soda ash, zinc oxide 7 Part, 10 parts of sodium nitrate, 6 parts of high borosilicate, 5 parts of chrome ore slag, 8 parts of charcoal, 4 parts of manganese powder, 2 parts of binding agent and 2 parts of antiager.
4. according to a kind of any described high-heat-resisting glass glass of claims 1 to 3, its feature exists, a kind of high-heat-resisting glass glass Preparation method is as follows:
(1)Dispensing:Quartz sand powder, feldspar powder, graphene powder, calcite powder, soda ash, oxidation are taken according to part by weight Zinc, sodium nitrate, high borosilicate, chrome ore slag, charcoal, manganese powder, are poured into grinder, and mixed grinding is into powder, after then mixing Raw material be put into homogenizer with 1000-1400r/min speed stirring mixing 0.5-1h;
(2)Found:It will be put into through the mixed raw material of high-speed stirred, binding agent and antiager in molten cellar for storing things and refine into molten State, smelting temperature is controlled at 1450-1500 DEG C, and the time is 0.5-1h;
(3)Shaping:Molten mass is rapidly injected in calender and rolled, required shape is obtained, forming temperature is 1200-1300 DEG C;
(4)Annealing:Glass after shaping is made annealing treatment, annealing temperature is 540 DEG C, cooling produces high heat-resisting after annealing Glass.
CN201710475999.9A 2017-06-21 2017-06-21 A kind of high-heat-resisting glass glass and preparation method thereof Pending CN107298529A (en)

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CN201710475999.9A CN107298529A (en) 2017-06-21 2017-06-21 A kind of high-heat-resisting glass glass and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201710475999.9A CN107298529A (en) 2017-06-21 2017-06-21 A kind of high-heat-resisting glass glass and preparation method thereof

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Publication Number Publication Date
CN107298529A true CN107298529A (en) 2017-10-27

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103466952A (en) * 2013-08-23 2013-12-25 苏州艾特斯环保材料有限公司 Graphene glass and production process thereof
CN105110638A (en) * 2015-08-04 2015-12-02 芜湖新利德玻璃制品有限公司 Heat-resistant glass and preparation method therefor
CN105669032A (en) * 2016-01-20 2016-06-15 广西丛欣实业有限公司 Heat-resistant glass
CN106116167A (en) * 2016-06-15 2016-11-16 安徽有通玻璃有限公司 A kind of carafe glass with clean and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103466952A (en) * 2013-08-23 2013-12-25 苏州艾特斯环保材料有限公司 Graphene glass and production process thereof
CN105110638A (en) * 2015-08-04 2015-12-02 芜湖新利德玻璃制品有限公司 Heat-resistant glass and preparation method therefor
CN105669032A (en) * 2016-01-20 2016-06-15 广西丛欣实业有限公司 Heat-resistant glass
CN106116167A (en) * 2016-06-15 2016-11-16 安徽有通玻璃有限公司 A kind of carafe glass with clean and preparation method thereof

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Application publication date: 20171027