CN1072978A - A kind of preparation method of antistatic wallpaper - Google Patents
A kind of preparation method of antistatic wallpaper Download PDFInfo
- Publication number
- CN1072978A CN1072978A CN 91107547 CN91107547A CN1072978A CN 1072978 A CN1072978 A CN 1072978A CN 91107547 CN91107547 CN 91107547 CN 91107547 A CN91107547 A CN 91107547A CN 1072978 A CN1072978 A CN 1072978A
- Authority
- CN
- China
- Prior art keywords
- antistatic
- wallpaper
- coating material
- pvc
- dop
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 239000011248 coating agent Substances 0.000 claims abstract description 16
- 238000000576 coating method Methods 0.000 claims abstract description 16
- 239000000463 material Substances 0.000 claims abstract description 15
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 13
- 239000000654 additive Substances 0.000 claims abstract description 12
- 230000000996 additive effect Effects 0.000 claims abstract description 12
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 8
- 239000000758 substrate Substances 0.000 claims abstract description 7
- 238000005187 foaming Methods 0.000 claims abstract description 6
- 239000002131 composite material Substances 0.000 claims abstract description 5
- 239000003381 stabilizer Substances 0.000 claims abstract description 5
- 238000004049 embossing Methods 0.000 claims abstract description 4
- 239000011701 zinc Substances 0.000 claims abstract description 4
- IHBCFWWEZXPPLG-UHFFFAOYSA-N [Ca].[Zn] Chemical compound [Ca].[Zn] IHBCFWWEZXPPLG-UHFFFAOYSA-N 0.000 claims abstract description 3
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims description 19
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims description 18
- 239000002002 slurry Substances 0.000 claims description 17
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 9
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 5
- NBOCQTNZUPTTEI-UHFFFAOYSA-N 4-[4-(hydrazinesulfonyl)phenoxy]benzenesulfonohydrazide Chemical compound C1=CC(S(=O)(=O)NN)=CC=C1OC1=CC=C(S(=O)(=O)NN)C=C1 NBOCQTNZUPTTEI-UHFFFAOYSA-N 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 125000006487 butyl benzyl group Chemical group 0.000 claims description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 239000011575 calcium Substances 0.000 claims 1
- 229910000019 calcium carbonate Inorganic materials 0.000 claims 1
- -1 dioctyl ester Chemical class 0.000 claims 1
- 239000011591 potassium Substances 0.000 claims 1
- 229910052700 potassium Inorganic materials 0.000 claims 1
- 239000004014 plasticizer Substances 0.000 abstract description 6
- 239000004604 Blowing Agent Substances 0.000 abstract description 4
- 239000003795 chemical substances by application Substances 0.000 abstract description 4
- 238000004040 coloring Methods 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract description 4
- 230000003068 static effect Effects 0.000 abstract description 3
- 238000005034 decoration Methods 0.000 abstract description 2
- 239000011342 resin composition Substances 0.000 abstract 1
- 238000003756 stirring Methods 0.000 description 4
- 239000011787 zinc oxide Substances 0.000 description 3
- 229910010413 TiO 2 Inorganic materials 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000005749 Copper compound Substances 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 229920002522 Wood fibre Polymers 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 150000001880 copper compounds Chemical class 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- HTMIBDQKFHUPSX-UHFFFAOYSA-N methdilazine Chemical group C1N(C)CCC1CN1C2=CC=CC=C2SC2=CC=CC=C21 HTMIBDQKFHUPSX-UHFFFAOYSA-N 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
Abstract
A kind of preparation method of antistatic wallpaper.
This method is the PVC coating material that contains antistatic additive that contains amide-type (HOA) antistatic additive, plasticizer (DOP and BBP), blowing agent (AC), calcium-zinc composite stabilizing agent (CZ-2, Ca/Zn), colouring agent, stuffing and polyvinyl chloride (PVC) paste resin composition by a kind of.The PVC coating material is evenly coated on the paper substrate,,, promptly be can be made into antistatic wallpaper, as on coating surface, carrying out embossing, then can be made into having the antistatic wallpaper of decoration function through plasticizing, foaming through 160～220 ℃ temperature.
Because antistatic wallpaper not only has good antistatic behaviour, and has higher resistive performance, and can the static that gather be leaked easily, therefore, is applicable to the antistatic computer floor that has higher requirements, electric panel room etc.
Description
The present invention relates to antistatic manufacture method with wallpaper.
Because antistatic wallpaper has good antistatic behaviour, be the existing higher resistive performance of this kind wallpaper, can static leaked easily again, therefore, can be applicable to computer floor, automated workshop that static is had higher requirements, the indoor use of electric panel room etc.The preparation method of existing antistatic wallpaper is introduced by Japanese clear 58-5374 and clear 61-201100 patent, before a kind of be with adsorption of metal ions on tacryl, be cut into the conductive fiber material of suitable length, mix with water and synthetic resin again, the conductive fiber material mixture is coated on the metope, with its evaporation, drying, can play antistatic property; The paper shape thing layer that a kind of conducting fibre that is the impregnation copper compound is bonded in back is manufactured is sticking to be posted on the ply of paper.Above-mentioned two kinds of method technologies are complicated, are difficult for making.
The objective of the invention is to adopt a kind of relatively more easy method of making antistatic wallpaper.
This method is to be uniformly coated on the paper substrate with the pvc coating material that contains a kind of antistatic additive, through heating, plasticizing, foaming, makes antistatic wallpaper.The coating material of antistatic additive is by amide-type antistatic additive (HOA), polyvinyl chloride (PVC), plasticizer phthalic acid dioctyl ester (DOP) and butyl benzyl (BBP), stuffing (CaCO
3), blowing agent Celogen Az (AC), colouring agent titanium dioxide (TiO
2) and zinc oxide (ZnO) and Ca-Zn liquid composite stabilizing agent (CZ-2) etc. formulated.Its concrete preparation steps is to prepare three kinds of slurries respectively: (1) Celogen Az (AC) blowing agent slurry, AC blowing agent and dioctyl phthalate (DOP) plasticizer are pressed 1: 1 ratio, and be mixed with slurry through fully stirring; (2) titanium dioxide (TiO
2) the colouring agent slurry: with TiO
2Powder and DOP plasticizer are pressed 1: 2 ratio, are mixed with slurry through fully stirring; (3) ZnO colouring agent slurry: ZnO powder and DOP plasticizer are pressed 1: 2 ratio, make slurry through fully stirring.When the above-mentioned three kinds of slurries of preparation, material all needs grind through grinder.And then preparation polyvinyl chloride (PVC) coating material, its step is that raw materials such as polyvinyl chloride resin, AC foaming slurry, titanium dioxide slurry, zinc oxide slurry, plasticizer (DOP, BBP), Ca-Zn liquid composite stabilizing agent, amide-type antistatic additive and stuffing are made the antistatic coating material that mixes through mixing, grind, pulverizing.This coating material is evenly coated on the paper substrate, the THICKNESS CONTROL of coating material is in the scope of 0.35 ± 0.02mm again.Then, the paper substrate that the is stained with coating material temperature through 160～220 ℃ is plastified, foams, just make wallpaper, compress and give fixed pattern, promptly become antistatic wallpaper with decoration function with antistatic property.
After tested, the electrification voltage of antistatic wallpaper is 102～108V, and the surface insulation resistance value is 7.1 * 10
6～1.5 * 10
7Ω.
Embodiment:
Account for 75% at wood fibre, cotton fibre accounts for that (its index: weight is 100g/m on 25% the paper substrate
2, thickness is 0.15mm), evenly be coated with a kind of dope layer, polyvinyl chloride (PVC) dope layer that this kind contains antistatic property is by with in polyvinyl chloride resin, calcium-zinc composite stabilizing agent (CZ-2) and amide-type antistatic additive (HOA), the dioctyl phthalate (DOP), adds TiO
2Slurry (ratio is 1: 1) and fourth benzyl fat (BBP) and CaCO with slurry (ratio is 1: 2), Celogen Az and the DOP of slurry (ratio is 1: 2), ZnO and the DOP of DOP
3Deng, make through mixing, stir and grind, disperseing.The coating material coating thickness is 0.35 ± 0.02mm, through promptly plastifying after 205 ℃ of heating and foaming, presses difform pattern (being embossing) again on this antistatic wallpaper, promptly can be made into the antistatic wallpaper with decorative pattern.After measured, its surface insulation point resistance value is (7.1～15) * 10
6Ω.
Claims (4)
1, a kind of preparation method of antistatic wallpaper is characterized in that, evenly coat on the paper substrate with a kind of pvc coating material that contains antistatic additive, and through heating plasticizing, foaming, embossing, and the wallpaper that acquisition has antistatic behaviour.
2, antistatic wallpaper according to claim 1, it is characterized in that, this kind contains polyvinyl chloride (the being PVC) coating material of antistatic additive, is by Celogen Az (AC) and the mixed uniformly slurry of dioctyl phthalate (DOP) (ratio is 1: 1), titanium dioxide (TiO
2) add through mixed uniformly calcium-zinc composite stabilizing agent (CZ-2, i.e. Ca/Zn), amide-type antistatic additive (HOA), dioctyl phthalate (DOP), butyl benzyl (BBP) and the calcium carbonate (CaCO of containing respectively with the mixed uniformly slurry of o-2 potassium acid dioctyl ester (DOP) (ratio is 1: 2), zinc oxide (ZnO) and the mixed uniformly slurry of dioctyl phthalate (DOP) (ratio is 1: 2) etc.
3) and the slurries of polyvinyl chloride (PVC) paste resin in, through evenly mixing.
According to claim 1 and 2 described antistatic wallpapers, it is characterized in that 3, the above-mentioned PVC coating material that contains antistatic additive need evenly be coated on the paper substrate, its thickness requirement is 0.35 ± 0.02mm.
4, according to the described antistatic wallpaper of claim 1 to 3, it is characterized in that, be coated with the PVC coating material of antistatic additive, need to make through 160～220 ℃ temperature heating, plasticizing, foaming, embossing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 91107547 CN1072978A (en) | 1991-12-03 | 1991-12-03 | A kind of preparation method of antistatic wallpaper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 91107547 CN1072978A (en) | 1991-12-03 | 1991-12-03 | A kind of preparation method of antistatic wallpaper |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1072978A true CN1072978A (en) | 1993-06-09 |
Family
ID=4908882
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 91107547 Pending CN1072978A (en) | 1991-12-03 | 1991-12-03 | A kind of preparation method of antistatic wallpaper |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1072978A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101100831B (en) * | 2007-07-23 | 2010-12-01 | 深圳现代彩印有限公司 | Wallpaper processing method |
| CN102516689A (en) * | 2011-12-27 | 2012-06-27 | 浙江博泰塑胶有限公司 | Conductive film for coal mine ventilation tube |
| CN101235666B (en) * | 2007-01-30 | 2012-07-04 | Lg化学株式会社 | Decorative wall paper and its production method |
| CN102839564A (en) * | 2012-08-02 | 2012-12-26 | 杭州嘉力丰化工有限公司 | Nano-silver mouldproof wallpaper coating and preparation method thereof |
| CN102924846A (en) * | 2012-10-26 | 2013-02-13 | 方少彬 | Wallpaper paste material capable of removing peculiar smell and preparation method thereof |
| CN103388283A (en) * | 2013-08-13 | 2013-11-13 | 福建圣莉雅环保壁纸有限公司 | Method for producing wallpaper from low-gram-weight materials instead of high-gram-weight materials |
| CN104818650A (en) * | 2015-04-29 | 2015-08-05 | 福建圣莉雅环保壁纸有限公司 | Ultra-hard size and production method and applications thereof |
| CN108914605A (en) * | 2018-07-11 | 2018-11-30 | 刘永 | A kind of environmental protection flame retardant PVC wallpaper material |
-
1991
- 1991-12-03 CN CN 91107547 patent/CN1072978A/en active Pending
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101235666B (en) * | 2007-01-30 | 2012-07-04 | Lg化学株式会社 | Decorative wall paper and its production method |
| CN101100831B (en) * | 2007-07-23 | 2010-12-01 | 深圳现代彩印有限公司 | Wallpaper processing method |
| CN102516689A (en) * | 2011-12-27 | 2012-06-27 | 浙江博泰塑胶有限公司 | Conductive film for coal mine ventilation tube |
| CN102516689B (en) * | 2011-12-27 | 2013-09-18 | 浙江博泰塑胶有限公司 | Conductive film for coal mine ventilation tube |
| CN102839564A (en) * | 2012-08-02 | 2012-12-26 | 杭州嘉力丰化工有限公司 | Nano-silver mouldproof wallpaper coating and preparation method thereof |
| CN102924846A (en) * | 2012-10-26 | 2013-02-13 | 方少彬 | Wallpaper paste material capable of removing peculiar smell and preparation method thereof |
| CN102924846B (en) * | 2012-10-26 | 2014-11-05 | 方少彬 | Wallpaper paste material capable of removing peculiar smell and preparation method thereof |
| CN103388283A (en) * | 2013-08-13 | 2013-11-13 | 福建圣莉雅环保壁纸有限公司 | Method for producing wallpaper from low-gram-weight materials instead of high-gram-weight materials |
| CN103388283B (en) * | 2013-08-13 | 2016-03-16 | 福建圣莉雅环保壁纸有限公司 | The method of high grammes per square metre manufacture of materials wallpaper is replaced with low grammes per square metre material |
| CN104818650A (en) * | 2015-04-29 | 2015-08-05 | 福建圣莉雅环保壁纸有限公司 | Ultra-hard size and production method and applications thereof |
| CN108914605A (en) * | 2018-07-11 | 2018-11-30 | 刘永 | A kind of environmental protection flame retardant PVC wallpaper material |
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