CN107297127A - A kind of VOCs waste gas processing methods - Google Patents

A kind of VOCs waste gas processing methods Download PDF

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Publication number
CN107297127A
CN107297127A CN201710477947.5A CN201710477947A CN107297127A CN 107297127 A CN107297127 A CN 107297127A CN 201710477947 A CN201710477947 A CN 201710477947A CN 107297127 A CN107297127 A CN 107297127A
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waste gas
vocs
vocs waste
plasma
gas
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CN107297127B (en
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王守国
卞忠华
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JIANGSU CHUNSHENTANG PHARMACEUTICAL Co.,Ltd.
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JIANGSU KANGYIDA MEDICAL TECHNOLOGY Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/18Absorbing units; Liquid distributors therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/007Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by irradiation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1406Multiple stage absorption
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1487Removing organic compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/32Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by electrical effects other than those provided for in group B01D61/00
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/38Removing components of undefined structure
    • B01D53/44Organic components
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/72Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2256/00Main component in the product gas stream after treatment
    • B01D2256/22Carbon dioxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/702Hydrocarbons
    • B01D2257/7027Aromatic hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708Volatile organic compounds V.O.C.'s
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/80Employing electric, magnetic, electromagnetic or wave energy, or particle radiation
    • B01D2259/818Employing electrical discharges or the generation of a plasma

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Abstract

The invention discloses a kind of VOCs waste gas processing methods, the VOCs waste gas processing methods include water curtain sprinkling processing, atomizing spray processing, gas-liquid separation processing, corona treatment and the infrared absorption particulate process step carried out successively;The clearance that the present invention realizes VOCs waste gas can reach more than 90%, solves the discharge standard requirement that existing waste gas pollution control and treatment technology is difficult to reach continuous improvement, eliminates exhaust emission of the VOCs waste gas to environment;Whole processing procedure is simple to operation, treatment effeciency is high, required equipment is few, and equipment energy consumption is low, and modern enterprise is met well to energy-saving and emission-reduction, the requirement of raising productivity effect, cost is reduced to economizing on resources and is significant.

Description

A kind of VOCs waste gas processing methods
Technical field
The invention belongs to environmental protection technical field, and in particular to a kind of VOCs waste gas processing methods.
Background technology
In recent years, the whole nation there occurs more serious air pollution episode more, and this causes people to air quality increasingly It is concerned about, while governments at all levels and environmental administration have put into effect multinomial special policy for this phenomenon so that waste gas pollution control and treatment industry is obtained To flourish.Wherein VOCs(Volatile organic matter)Waste gas pollution control and treatment industry is more using low technical content, high operation due to early stage The active carbon adsorption development of cost is slower.After various regions environmental protection carries mark, have VOCs discharge and it is untreated or processing after it is below standard Enterprise need carry out VOCs processing.
Current VOCs waste gas pollution control and treatment technologies are mainly absorption method(Spray, charcoal absorption), absorption method(Condensation, spray) With direct removal method(Low temperature plasma, photochemical catalytic oxidation, condensed combustion).Combustion method, mainly there is condensed combustion, flame combustion With catalysis burning;Condensed combustion method is all flammable using the big multicomponent of organic exhaust gas, and high concentration VOCs is further concentrated, and is improved The method directly burnt after concentration;Flame combustion is the method by the fuel such as natural gas and VOCs mixing after-combustions;Catalysis burning Relatively low temperature is acted on by catalyst(250℃-450℃)The lower method by VOCs complete oxidations.Absorb(Reclaim) Method, is mainly reclaimed including solvent absorption, Electrostatic Absorption and condensation;Solvent absorption is using the similar principle that mixes, by organic molten Agent carries out separation recycling after VOCs is absorbed;Condensation reclaims then different using VOCs different components boiling point, passes through cooling down Reclaim some components;Electrostatic Absorption is mainly used in the processing of oil-containing waste gas, makes adsorption recovery after small fuel carrying charges using electrostatic field. Absorption method, mainly using charcoal absorption, activated carbon mainly by the Van der Waals for of micro-porous adsorption and surface lack of equilibrium and Chemical bond force comes adsorption particle thing or gas molecule, reaches the purpose for removing VOCs.Decomposition method, mainly including photocatalysis, red Outer absorption microparticle technologies and low temperature plasma method;Photocatalysis is that have extremely strong oxygen under ultraviolet light based on photochemical catalyst The principle for the property changed, will adsorb the VOCs gas molecule oxidation Decompositions on surface;Low temperature plasma method is utilized in plasma VOCs is resolved into CO by high energy particle and free radical2With the method for water.And conventional method is in the presence of low to difficult waste gas clearance (Such as spray, low temperature plasma, charcoal absorption), operating cost it is high(Such as charcoal absorption, condensed combustion, photochemical catalytic oxidation) The problems such as.Such as charcoal absorption, on the one hand because operating cost is high, the active carbon adsorption equipment of many producers is in stop for a long time Fortune, is only used in green audit;On the other hand, activated carbon need to be handled according to hazardous chemical after use, and practicality is significantly Reduce, and for example traditional Low Temperature Plasma Treating technology, it uses frequency high voltage power supply or DC high-voltage power supply, passes through electricity The forms such as corona remove VOCs, but particle can not interrupt the chemical bond of some big bond energys in the plasma of its generation, make It is obtained to some VOCs clearances undergrounds, small molecule is broken into even for macromolecular, VOCs is dense after benzene type organic is processed Degree is higher than before processing 1-2 times on the contrary.
Therefore it provides one kind removes VOCs and clearance height, efficiency high, operating cost are low, technique is simple, applicability is wide Exhaust gas treatment technology be those skilled in the art's technical problem urgently to be resolved hurrily.
The content of the invention
The technical problems to be solved by the invention are to overcome one or more deficiencies of the prior art, a kind of by providing Water curtain sprinkling is handled, atomizing spray processing, gas-liquid separation processing, corona treatment and infrared absorption particulate process step knot The VOCs waste gas processing methods of conjunction, to realize the removal VOCs of low cost, high efficiency, safety, better people's living environment, promote society Sustainable development.
To solve above technical problem, a kind of technical scheme that the present invention takes is as follows:
A kind of VOCs waste gas processing methods, the VOCs waste gas processing methods include water curtain sprinkling processing, the atomization carried out successively Spray process, gas-liquid separation processing, corona treatment and infrared absorption particulate process step.
In certain specific embodiments of the invention, in the water curtain sprinkling process step, by VOCs waste gas from water The bottom of curtain spray column is passed through, and is flowed out after water curtain sprinkling from top, and the water curtain sprinkling processing mode is sprayed using annular, institute Stating annular spray includes multiple spray sections, and helically type is distributed multiple spray sections in the water curtain sprinkling tower.
In certain specific embodiments of the invention, in the atomizing spray process step, spray liquid includes aqueous, The aqueous is atomized by atomizer to form moisture film layer by layer, the moisture film is used to capture the fine particle in VOCs waste gas, institute Stating fine particle includes paint particle, toluene and dimethylbenzene.
In certain specific embodiments of the invention, in the gas-liquid separation process step, pass through gas-liquid separator Droplet in VOCs waste gas and/or drop are removed, the gas-liquid separator is operated at normal temperatures and pressures.
, will be through the gas-liquid point in the plasma treatment step in certain specific embodiments of the invention Electric field side of the VOCs waste gas treated from process step along the plasma-generating electrode parallel to plasma producing apparatus To passing through the plasma-generating electrode so that being produced in VOCs waste gas includes electronics, cation, neutral particle, free radical Entirety be in electroneutral plasma;And make it that the dust granule surface in VOCs waste gas is powered;Plasma and VOCs Oxygen molecule, hydrone effect in waste gas, generation H, O, OH, O with strong oxidizing property3In active particle, VOCs waste gas VOCs generates gaseous carbon dioxide and water in the presence of active particle.
In certain specific embodiments of the invention, the plasma-generating electrode include one group of high-voltage electrode and One group of grounding electrode, the high-voltage electrode is coated with dielectric, the high-voltage electrode and ground connection electricity with grounding electrode Extremely it is in linear array;The high-voltage electrode connects high voltage power supply, and the high voltage power supply is positive polarity DC high-voltage power supply, just Polar impulse high voltage power supply or one kind in the DC stacked ac high voltage source of positive polarity or its combination.
In certain specific embodiments of the invention, in the infrared absorption particulate process step, it passes through infrared Heating devices heat passes through the VOCs waste gas that the plasma treatment step is treated, so that the VOCs in waste gas absorbs infrared Energy is simultaneously further acted on, and be decomposed to form carbon dioxide and water with air-flow plasma is remained in;The infrared heating dress Put including RF transmitter, gas accommodating cavity, and the infrared absorption particulate being distributed on the accommodating cavity wall of the gas, institute State and multiple columns be provided with gas accommodating cavity, multiple columns make the serpentine-like circulation of air-flow, the RF transmitter it is defeated Go out the infrared light that wavelength is 760-850nm.
In certain specific embodiments of the invention, the VOCs waste gas processing methods are carried out using following processing system Processing:
The processing system includes being sequentially connected the water curtain sprinkling tower of UNICOM, atomization spray tower, gas-liquid separator, plasma hair Generating apparatus and infrared heating device;
The water curtain sprinkling tower includes multiple spray sections, and helically type divides multiple spray sections in the water curtain sprinkling tower Cloth;The atomization spray tower includes atomizer and spray liquid, and the spray liquid passes through atomizer formation layer laminated film shape droplet;
The plasma producing apparatus includes plasma-generating electrode and high voltage power supply, the plasma-generating electrode bag One group of high-voltage electrode and one group of grounding electrode are included, the high-voltage electrode is coated with dielectric with the grounding electrode, The high-voltage electrode is in linear array with the grounding electrode;The high-voltage electrode connects the high voltage power supply, described High voltage power supply is in positive polarity DC high-voltage power supply, positive pulse high voltage power supply or the DC stacked ac high voltage source of positive polarity One kind or its combination;
The infrared heating device includes RF transmitter, gas accommodating cavity, and is distributed in the gas accommodating cavity Multiple columns are provided with infrared absorption particulate, the gas accommodating cavity, multiple columns make the serpentine-like circulation of air-flow, described red The output wavelength of outside line transmitter is 760-850nm infrared light.
Further, the plasma producing apparatus also includes pressure sensor and temperature sensor, and the pressure is passed Sensor and temperature sensor, for monitoring the pressure and temperature in the plasma producing apparatus in real time.
In the present invention, VOCs total removal rates are more than or equal to 75% in the waste gas after the VOCs waste gas processing methods processing, Wherein, in waste gas:Benzene≤17mg/m3;Toluene≤60mg/m3;Dimethylbenzene≤90mg/m3.
Due to the use of above technical scheme, the present invention has the following advantages that compared with prior art:
1st, the present invention water curtain sprinkling is handled, atomizing spray processing, gas-liquid separation processing, corona treatment and infrared absorption it is micro- Grain process step is organically combined, and each step is mutually acted synergistically, is realized VOCs qualified discharges, and handling process it is simple, Operating cost is low, applicability is wide, VOCs clearances high.
2nd, the present invention solves the problem of Conventional cryogenic plasma technique is low to difficult waste gas decomposition clearance, and the application The middle flow direction by VOCs waste gas is arranged to put down with the direction of an electric field of the plasma-generating electrode of plasma producing apparatus OK, overcome flue gas flow rate it is excessive or too small when the reduction of corona treatment effect that causes, increase flue gas and plasma The time of contact of body, contact area, to realize the efficient utilization of plasma.
3rd, the present invention is coordinated plasma treatment step, realized using unique infrared absorption particulate process step The high clearance of VOCs waste gas, and device is simple, cost is low, energy consumption is low, meets current demand, is suitably widely applied.
4th, using the VOCs waste gas processing methods of the present invention, not only invest that small, operation expense is low, occupation area of equipment Small, treatment effeciency is high, and also achieves efficient deodorizing, eliminates the unusual smell, and the waste gas after processing can fully meet various regions environmental protection The particular technique index request of office, while by adding temperature control and Stress control, it is to avoid because air draft failure or other VOCs concentration such as drastically raises at the detonation caused by security incident in short time caused by some reasons, prevents it from feeding through to car Between, the injures and deaths of staff are caused, security performance is greatly improved.
Brief description of the drawings
In order to illustrate more clearly about the embodiment of the present invention or technical scheme of the prior art, below will be to embodiment or existing There is the accompanying drawing used required in technology description to be briefly described, it should be apparent that, drawings in the following description are only this Some embodiments of invention, for those of ordinary skill in the art, on the premise of not paying creative work, can be with Other accompanying drawings are obtained according to these accompanying drawings.
Fig. 1 is the schematic flow sheet of the VOCs processing methods of the present invention;
Fig. 2 is the schematic diagram of one of embodiment of the VOCs processing methods of the present invention;
Fig. 3 is the structural representation of the plasma producing apparatus of the present invention;
Fig. 4 is the structural representation of the infrared heating device of the present invention.
Embodiment
Technical scheme and its advantage are described in detail with reference to specific embodiment and accompanying drawing.
Embodiment 1
Sampling analysis is carried out to the VOCs waste gas of certain factory, its specific nature is as follows:
Wherein, in waste gas:Benzene 106.3mg/m3;Toluene 287.5mg/m3;Dimethylbenzene 627.5mg/m3.
As Figure 1-4, the present embodiment provides a kind of VOCs waste gas processing methods, comprises the following steps:
1)Water curtain sprinkling processing
The bottom of VOCs waste gas from water curtain sprinkling tower 1 is passed through, flowed out after water curtain sprinkling from top, the water curtain sprinkling processing Mode is sprayed using annular, and the annular spray includes multiple spray sections 11, and multiple spray sections 11 are in the water curtain sprinkling Helically type is distributed in tower 1;
2)Atomizing spray processing
Wherein, spray liquid includes aqueous, and the aqueous is atomized by atomizer 21 to form moisture film layer by layer, and the moisture film is used to catch The fine particle in VOCs waste gas is obtained, the fine particle includes paint particle, toluene and dimethylbenzene;
3)Gas-liquid separation is handled
The droplet in VOCs waste gas and/or drop are removed by gas-liquid separator 3, the gas-liquid separator 3 is in normal temperature and pressure Lower operation;
4)Corona treatment
By plasma of the VOCs waste gas edge treated through the gas-liquid separation process step parallel to plasma producing apparatus 4 Body occur electrode direction of an electric field pass through the plasma-generating electrode so that in VOCs waste gas produce include electronics, just from Son, neutral particle, the entirety of free radical are in the plasma of electroneutral;And cause the dust granule surface band in VOCs waste gas Electricity;Plasma is acted on the oxygen molecule in VOCs waste gas, hydrone, generation H, O, OH, O with strong oxidizing property3Active grain VOCs in son, VOCs waste gas generates gaseous carbon dioxide and water in the presence of active particle;The plasma occurs Electrode includes one group of high-voltage electrode 42 and one group of grounding electrode 43, and the high-voltage electrode 42 is coated with grounding electrode 43 Dielectric 41, the high-voltage electrode 42 is in linear array with grounding electrode 43;The high-voltage electrode 42 connects high pressure Power supply 46, the high voltage power supply 46 is that positive polarity DC high-voltage power supply, positive pulse high voltage power supply or positive polarity are DC stacked One kind or its combination in ac high voltage source;
In the present embodiment, the direction of an electric field of plasma is arranged to consistent with the direction of VOCs air-flows, increases VOCs gas The time of contact of stream and plasma line, contact area, to realize maximized utilization plasma line, and then can be saved Consumption can be subtracted, it is cost-effective.
5)The processing of infrared absorption particulate
It heats the VOCs waste gas treated by the plasma treatment step by infrared heating device 5, so that waste gas In VOCs absorb infrared energy and and remain in air-flow plasma and further act on, and be decomposed to form carbon dioxide and Water;The infrared heating device 5 includes RF transmitter, gas accommodating cavity 53, and is distributed in the gas accommodating cavity 53 Multiple columns 51 are provided with interior infrared absorption particulate 52, the gas accommodating cavity 53, multiple columns 51 make air-flow be in snake Shape circulates, and the output wavelength of the RF transmitter is 800nm infrared light;
Last waste gas is discharged through chimney 6.
Meanwhile, the VOCs waste gas processing methods of the present embodiment are handled using following processing system:
The processing system includes being sequentially connected water curtain sprinkling tower 1, atomization spray tower 2, gas-liquid separator 3, the plasma of UNICOM Body generating means 4 and infrared heating device 5;
The water curtain sprinkling tower 1 include multiple spray sections 11, multiple spray sections 11 in the water curtain sprinkling tower 1 helically Type is distributed;The atomization spray tower 2 includes atomizer 21 and spray liquid, and the spray liquid is formed layer by layer by the atomizer 21 Membranaceous droplet;
The plasma producing apparatus 4 includes plasma-generating electrode and high voltage power supply, the plasma-generating electrode Including one group of high-voltage electrode 42 and one group of grounding electrode 43, the high-voltage electrode 42 is coated with the grounding electrode 43 Dielectric 41, the high-voltage electrode 42 is in linear array with the grounding electrode 43;The high-voltage electrode 42 is connected The high voltage power supply 46, the high voltage power supply 46 is positive polarity DC high-voltage power supply, positive pulse high voltage power supply or positive polarity One kind or its combination in DC stacked ac high voltage source;
The infrared heating device 5 includes RF transmitter(It is not shown), gas accommodating cavity 53, and be distributed in the gas Multiple columns 51 are provided with infrared absorption particulate 52 in accommodating cavity 53, the gas accommodating cavity 53, multiple columns 51 make The serpentine-like circulation of air-flow, the output wavelength of the RF transmitter is 800nm infrared light.
Further, the plasma producing apparatus 4 also includes pressure sensor 45 and temperature sensor 44, the pressure Force snesor 45 and temperature sensor 44, for monitoring the pressure and temperature in the plasma producing apparatus 4 in real time.
A whole set of VOCs waste gas treatment process first tentatively catches big dust particle with water curtain sprinkling;Then by atomizing spray Fine particle in the moisture film layer by layer that spray liquid is formed by the atomization of atomizer 21 in tower 2, waste gas(Paint particle, toluene, two Toluene etc.)By the water capture in deduster, enter gas-water channel through cascade, make after the organic VOCs gases in part and atomization absorption Particulate matter by spray enter sewerage, by this step VOCs removal efficiency up to 15% or so;The He of temperature sensor 44 The setting of pressure sensor 45 can be avoided because of VOCs concentration in the short time caused by air draft failure or some other reason The drastically detonation caused by security incident such as rise feeds through to workshop;Gas-liquid separation handles the pretreatment as corona treatment Technique, which can be removed, largely sprays steam for bringing etc., it is to avoid plasma processing efficiency is affected;Plasma technique Remaining VOCs gas molecules are resolved into CO with infrared absorption microparticle technologies2And H2O, total VOCs gases resolution ratio is reached as high as To more than 90%, and peculiar smell of the tail gas without general processing method, stink.
VOCs total removal rates 92% in waste gas after the VOCs waste gas processing methods processing of the present embodiment, wherein, in waste gas: Benzene 8.5mg/m3;Toluene 23.0mg/m3;Dimethylbenzene 50.2mg/m3.
It was found from foregoing description, the beneficial effects of the present invention are:The clearance for realizing VOCs waste gas can reach More than 90%, the discharge standard requirement that existing waste gas pollution control and treatment technology is difficult to reach continuous improvement is solved, VOCs waste gas is completely eliminated To the exhaust emission of environment;Whole processing procedure is simple to operation, treatment effeciency is high, required equipment is few, and equipment energy consumption is low, very well Meet modern enterprise to energy-saving and emission-reduction, improve productivity effect requirement, to economize on resources reduce cost be significant.
Comparative example one
General Low Temperature Plasma Treating technical matters flow is:Water curtain sprinkling → Low Temperature Plasma Treating → Water spray → Discharge
Result:VOCs total removal rates are 50%, wherein, in waste gas:Benzene content is 53.1mg/m3;Toluene level is 143.3mg/m³;Xylene content is 313.8mg/m3.
Comparative example two
The basic be the same as Example 1 of this example, difference is that the processing of this example plasma uses Low Temperature Plasma Treating, and does not include The processing of infrared absorption particulate.
Technological process is:Water curtain sprinkling → atomizing spray → gas-liquid separation → Low Temperature Plasma Treating → discharge
Result:VOCs total removal rates are 60% in waste gas, wherein, in waste gas:Benzene content is 42.5mg/m3;Toluene level is 115.0mg/m³;Xylene content is 251.0mg/m3.
The above embodiments merely illustrate the technical concept and features of the present invention, and its object is to allow person skilled in the art Scholar can understand present disclosure and implement according to this, and it is not intended to limit the scope of the present invention, all according to the present invention The equivalent change or modification that Spirit Essence is made, should all be included within the scope of the present invention.

Claims (10)

1. a kind of VOCs waste gas processing methods, it is characterised in that the VOCs waste gas processing methods include the water curtain carried out successively Spray process, atomizing spray processing, gas-liquid separation processing, corona treatment and infrared absorption particulate process step.
2. VOCs waste gas processing methods according to claim 1, it is characterised in that in the water curtain sprinkling process step In, the bottom of VOCs waste gas from water curtain sprinkling tower is passed through, flowed out after water curtain sprinkling from top, the water curtain sprinkling processing side Formula is sprayed using annular, and the annular spray includes multiple spray sections, and multiple spray sections are in the water curtain sprinkling tower Screw type is distributed.
3. VOCs waste gas processing methods according to claim 1, it is characterised in that in the atomizing spray process step In, spray liquid includes aqueous, and the aqueous is atomized by atomizer to form moisture film layer by layer, and the moisture film gives up for capturing VOCs Fine particle in gas, the fine particle includes paint particle, toluene and dimethylbenzene.
4. VOCs waste gas processing methods according to claim 1, it is characterised in that in the gas-liquid separation process step In, the droplet in VOCs waste gas and/or drop are removed by gas-liquid separator, the gas-liquid separator is grasped at normal temperatures and pressures Make.
5. VOCs waste gas processing methods according to claim 1, it is characterised in that in the plasma treatment step In, by plasma of the VOCs waste gas edge treated through the gas-liquid separation process step parallel to plasma producing apparatus Occur electrode direction of an electric field pass through the plasma-generating electrode so that in VOCs waste gas produce include electronics, cation, Neutral particle, the entirety of free radical are in the plasma of electroneutral;And make it that the dust granule surface in VOCs waste gas is powered; Plasma is acted on the oxygen molecule in VOCs waste gas, hydrone, generation H, O, OH, O with strong oxidizing property3Active particle, VOCs in VOCs waste gas generates gaseous carbon dioxide and water in the presence of active particle.
6. VOCs waste gas processing methods according to claim 5, it is characterised in that the plasma-generating electrode includes One group of high-voltage electrode and one group of grounding electrode, the high-voltage electrode are coated with dielectric, the height with grounding electrode Voltage electrode is in linear array with grounding electrode;The high-voltage electrode connects high voltage power supply, and the high voltage power supply is positive pole Property DC high-voltage power supply, positive pulse high voltage power supply or one kind or its group in the DC stacked ac high voltage source of positive polarity Close.
7. VOCs waste gas processing methods according to claim 1, it is characterised in that walked in infrared absorption particulate processing In rapid, it heats the VOCs waste gas treated by the plasma treatment step by infrared heating device, so that waste gas In VOCs absorb infrared energy and and remain in air-flow plasma and further act on, and be decomposed to form carbon dioxide and Water;The infrared heating device includes RF transmitter, gas accommodating cavity, and is distributed in red in the gas accommodating cavity Multiple columns are provided with outer absorption particulate, the gas accommodating cavity, multiple columns make the serpentine-like circulation of air-flow, described infrared The output wavelength of line transmitter is 760-850nm infrared light.
8. the VOCs waste gas processing methods according to any one of claim 1-7 claim, it is characterised in that the VOCs Waste gas processing method is handled using following processing system:
The processing system includes being sequentially connected the water curtain sprinkling tower of UNICOM, atomization spray tower, gas-liquid separator, plasma hair Generating apparatus and infrared heating device;
The water curtain sprinkling tower includes multiple spray sections, and helically type divides multiple spray sections in the water curtain sprinkling tower Cloth;The atomization spray tower includes atomizer and spray liquid, and the spray liquid passes through atomizer formation layer laminated film shape droplet;
The plasma producing apparatus includes plasma-generating electrode and high voltage power supply, the plasma-generating electrode bag One group of high-voltage electrode and one group of grounding electrode are included, the high-voltage electrode is coated with dielectric with the grounding electrode, The high-voltage electrode is in linear array with the grounding electrode;The high-voltage electrode connects the high voltage power supply, described High voltage power supply is in positive polarity DC high-voltage power supply, positive pulse high voltage power supply or the DC stacked ac high voltage source of positive polarity One kind or its combination;
The infrared heating device includes RF transmitter, gas accommodating cavity, and is distributed in the accommodating cavity wall of the gas On infrared absorption particulate, multiple columns are provided with the gas accommodating cavity, multiple columns make the serpentine-like circulation of air-flow, institute The output wavelength for stating RF transmitter is 760-850nm infrared light.
9. VOCs waste gas processing methods according to claim 8, it is characterised in that the plasma producing apparatus is also wrapped Pressure sensor and temperature sensor are included, the pressure sensor, temperature sensor are used to monitor the plasma hair in real time Pressure and temperature in generating apparatus.
10. VOCs waste gas processing methods according to claim 1, it is characterised in that at the VOCs waste gas processing methods VOCs total removal rates are more than or equal to 75% in waste gas after reason, wherein, in waste gas:Benzene≤17mg/m3;Toluene≤60mg/m3;Two Toluene≤90mg/m3.
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