CN107290771A - A kind of method for packing of scintillation crystal array and scintillation crystal array - Google Patents

A kind of method for packing of scintillation crystal array and scintillation crystal array Download PDF

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Publication number
CN107290771A
CN107290771A CN201710632551.3A CN201710632551A CN107290771A CN 107290771 A CN107290771 A CN 107290771A CN 201710632551 A CN201710632551 A CN 201710632551A CN 107290771 A CN107290771 A CN 107290771A
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CN
China
Prior art keywords
scintillation crystal
crystal bar
transparency carrier
array
bar
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Pending
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CN201710632551.3A
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Chinese (zh)
Inventor
魏建德
郑熠
吴少凡
苏伟平
叶宁
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Xiamen Shuo Photoelectric Technology Co Ltd
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Xiamen Shuo Photoelectric Technology Co Ltd
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Priority to CN201710632551.3A priority Critical patent/CN107290771A/en
Publication of CN107290771A publication Critical patent/CN107290771A/en
Pending legal-status Critical Current

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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01TMEASUREMENT OF NUCLEAR OR X-RADIATION
    • G01T1/00Measuring X-radiation, gamma radiation, corpuscular radiation, or cosmic radiation
    • G01T1/16Measuring radiation intensity
    • G01T1/20Measuring radiation intensity with scintillation detectors
    • G01T1/202Measuring radiation intensity with scintillation detectors the detector being a crystal

Abstract

The embodiment of the invention discloses a kind of scintillation crystal array and the method for packing of scintillation crystal array, methods described is included in the lateral surface plating high reflection film plating layer of scintillation crystal bar, in the end face plating anti-reflection coating layer of scintillation crystal bar;Transparency carrier one side offer can accommodate under each scintillation crystal bar end face groove;Each scintillation crystal bar is bonded in the respective slot on transparency carrier by colloid;The space between scintillation crystal bar will be packed into every light mixture, obtains scintillation crystal block, scintillation crystal block lateral surface even spread every light mixture, dry every light mixture;Scintillation crystal block side even spread every light mixture is installed in array case, with the gap between light mixture closed array shell and transparency carrier.The embodiment of the present invention protects it from the influence of moisture by carrying out effective encapsulation to scintillation crystal bar, to keep the characteristic of scintillation crystal, maintains the image resolution ratio of contrast imaging detector.

Description

A kind of method for packing of scintillation crystal array and scintillation crystal array
Technical field
The present invention relates to scintillation crystal encapsulation technology field, more particularly to a kind of scintillation crystal array and scintillation crystal array Method for packing.
Background technology
Positron emission tomography (Positron Emission Tomography, PET) technology is to utilize to detect certain A pair of gamma-rays that the negatron in positive electron and organism that isotope decay is produced is buried in oblivion and produced are planted, biology is obtained Internal this Nuclear analysis information, the 3 Dimension Image Technique of image reconstruction is completed using modern computer.Due to constituting life Basic element C, O, N etc. have the isotope of transmitting positive electron, therefore, PET in theory can be to many positions of life entity Physiological function be imaged.It can be seen that, PET is the quite distinctive instrument of life science, medical diagnosis.PET system is by visiting Survey device, data collecting system, image reconstruction and the part of image procossing three composition.Pet detector design should meet claimed below: (1) high sensitivity, the detection efficient to 511keV gamma-rays pair is high;(2) high spatial resolution, more accurately determines and buries in oblivion position Put;(3) good temporal resolution, eliminates random coincidence event;(4) good energy resolution, eliminates Compton scattering Influence;(5) it is cheap;(6) time is short;(7) stability is good.Pet detector is usually by scintillation crystal and photomultiplier (location-sensitive photomultiplier or semiconductor devices) is coupled to form.Positron e mission computed tomography, is core doctor The more advanced clinical examination image technology in field.Its substantially method is, by certain material, usually in biological life metabolism After short-life radionuclide on necessary material, mark, injection human body, by the aggregation for the material in metabolism, To reflect the situation of vital metabolic activity, so as to reach the purpose of diagnosis.Contrast imaging detector is the technological core of the technology One of, the scintillation crystal array reflectivity of existing contrast imaging detector is not good, photon collection performance is bad, cause resolution ratio compared with It is low, it is impossible to carry out high accuracy, high-resolution imaging, difficulty is caused to doctor's read tablet.Therefore, the material property of scintillation crystal, Volume, shape etc. are very big to the performance impact of detector, and scintillator is used as part essential in X-ray detector, one The crystalline substance of the scintillator of a little excellent performances, the either crystal such as former NaI, CsI, still La emerging in recent years (lanthanum) system composition The scintillator that the problems such as in body due to easy deliquescence itself, such as rare earth halogen system constitute, this crystalloid is more sensitive to WGR, holds very much Easy deliquescence, and it is greatly reduced or even loses original effect to the performance of scintillation crystal after deliquescence.And for example, more commonly use at present It is lanthanum bromide scintillator, this kind of scintillator has the advantages that high brightness, high-resolution.Mix the bromination langasite single crystal (LaBr3 of cerium:Ce3 +) be even more excellent performance scintillator material, with than the more excellent scintillation properties such as sodium iodide, Ce-doped lanthanum oxide.But due to Lanthanum bromide is hygroscopic materials, exposure in atmosphere can due to absorbing moisture and deliquescence, so that the characteristic of its scintillator can be reduced, This will cause image resolution ratio to be greatly lowered.Therefore, how scintillation crystal is effectively encapsulated, so that it is not by moisture Influence, it appears particularly important.
The content of the invention
In view of the above problems, the present invention provides a kind of sudden strain of a muscle for overcoming above mentioned problem or solving the above problems at least in part The method for packing of bright crystal array and scintillation crystal array, to prevent easy deliquescence scintillation crystal array because of deliquescence problem to flicker The performance of crystal is impacted.
One aspect of the present invention there is provided a kind of scintillation crystal array, including:Transparency carrier and the transparency carrier Seal the array case installed and be placed in the sealing space formed by the transparency carrier and array case at least one Individual scintillation crystal bar;
The one side of the transparency carrier is provided with the groove for placing each scintillation crystal bar end face, each scintillation crystal The colloid that bar is in by refractive index between transparency carrier and scintillation crystal bar is bonded in the respective slot on the transparency carrier In, the end face being placed in the respective slot of each scintillation crystal bar is coated with anti-reflection coating layer, and each scintillation crystal bar Lateral surface is coated with high reflection film plating layer, and the gap between each scintillation crystal bar is filled with every light mixture, to be formed Scintillation crystal block, has described every light mixture in the side even spread of the scintillation crystal block.
Wherein, the array case is the rectangular aluminum box of one end open, the rectangular aluminum box opening size and transparency carrier Size is consistent.
Wherein, the groove is to be equidistantly spaced between rectangular recess, the rectangular recess.
Wherein, it is described every the mixture that light mixture is anhydrous glue and barium sulfate.
Wherein, the anhydrous glue is anhydrous epoxy resin.
Wherein, the scintillation crystal bar is the scintillation crystal bar of size identical square, cuboid or cylinder.
Wherein, the thickness of the high reflection film plating layer is 1.5-2.5 microns.
Wherein, described high reflection film plating layer is total reflection plated film, and the reflectivity of high reflection film plating layer is more than 99.9%.
Another aspect of the present invention includes there is provided a kind of method for packing of scintillation crystal array, methods described:
High reflection film plating layer is plated in the lateral surface of scintillation crystal bar, anti-reflection plating is plated in an end face of the scintillation crystal bar Film layer;
The groove of the end face for placing each scintillation crystal bar is opened up in the one side of transparency carrier;
The colloid each scintillation crystal bar being in by refractive index between transparency carrier and scintillation crystal bar is bonded in institute State in the respective slot on transparency carrier;
Using the space filled every light mixture between the scintillation crystal bar, scintillation crystal block is obtained, in the flicker Every light mixture described in the lateral surface even spread of crystal block, drying is described every light mixture;
There is the scintillation crystal block every light mixture to install in array case side even spread, with described The gap between the array case and the transparency carrier is closed every light mixture.
Wherein, the lateral surface in scintillation crystal bar plates high reflection film plating layer, at an end of the scintillation crystal bar Before face plating anti-reflection coating layer, in addition to:
The raw material of scintillation crystal are cut, scintillation crystal bar is obtained.
The technical scheme provided in the embodiment of the present application, has the following technical effect that or advantage:
The method for packing of scintillation crystal array and scintillation crystal array provided in an embodiment of the present invention, by scintillation crystal Bar is effectively encapsulated, and protects it from the influence of moisture, to prevent easy deliquescence scintillation crystal brilliant to flicker because of deliquescence problem The performance of body is impacted, and keeps the characteristic of scintillation crystal, maintains the image resolution ratio of contrast imaging detector.
Described above is only the general introduction of technical solution of the present invention, in order to better understand the technological means of the present invention, And can be practiced according to the content of specification, and in order to allow above and other objects of the present invention, feature and advantage can Become apparent, below especially exemplified by the embodiment of the present invention.
Brief description of the drawings
By reading the detailed description of hereafter preferred embodiment, various other advantages and benefit is common for this area Technical staff will be clear understanding.Accompanying drawing is only used for showing the purpose of preferred embodiment, and is not considered as to the present invention Limitation.And in whole accompanying drawing, identical part is denoted by the same reference numerals.In the accompanying drawings:
Fig. 1 is a kind of structured flowchart for scintillation crystal array that the embodiment of the present invention is proposed;
A kind of flow chart of the method for packing for scintillation crystal array that Fig. 2 embodiment of the present invention is proposed.
Embodiment
The exemplary embodiment of the disclosure is more fully described below with reference to accompanying drawings.Although showing the disclosure in accompanying drawing Exemplary embodiment, it being understood, however, that may be realized in various forms the disclosure without should be by embodiments set forth here Limited.On the contrary, these embodiments are provided to facilitate a more thoroughly understanding of the present invention, and can be by the scope of the present disclosure Complete conveys to those skilled in the art.
Fig. 1 diagrammatically illustrates a kind of scintillation crystal array of one embodiment of the invention offer.Reference picture 1, the present invention Embodiment is specifically included:Transparency carrier 4, with the transparency carrier 4 seal install array case 5 and be placed in by described transparent At least one scintillation crystal bar 1 in the sealing space that substrate 4 is formed with the array case 5.In the present embodiment, flicker is brilliant Body bar 1 can be size identical square, cuboid or cylinder.
Wherein, the one side of transparency carrier 4 is provided with the groove for placing each end face of scintillation crystal bar 1, each flicker The colloid that crystal bar 1 is in by refractive index between transparency carrier 4 and scintillation crystal bar 1 is bonded on the transparency carrier 4 In respective slot, the end face being placed in the respective slot of each scintillation crystal bar 1 is coated with anti-reflection coating layer, and each flicker The lateral surface of crystal bar 1 is coated with high reflection film plating layer 2, and the gap between each scintillation crystal bar 1 is filled with mixed every light Compound 3, to form scintillation crystal block, has described every light mixture 3 in the side even spread of the scintillation crystal block.Wherein, The space between full scintillation crystal bar 1 is filled every light mixture 3, to reach every light effect.Be filled in each scintillation crystal bar 1 it Between every light mixture 3 and the side for being coated on scintillation crystal block every the formation scintillation crystal array of light mixture 3 every photosphere. In the embodiment of the present invention, by carrying out effective encapsulation to scintillation crystal bar, the influence of moisture is protected it from, to keep flicker brilliant The flicker bulk properties of body, maintains the image resolution ratio of contrast imaging detector.
Scintillation crystal array provided in an embodiment of the present invention has Deliquescence-resistant, and reliability is high, albedo is high, structure is tight Gather, not light leak, it is easy to assembly the advantages of, while having extensive market prospects in image field.
In embodiments of the present invention, the transparency carrier 4 is made of clear material, concretely silica or blue precious Stone;The array case 5 can be made up of the similar material that can be penetrated such as 511keV gamma-rays.
In embodiments of the present invention, the array case 5 is the rectangular aluminum box of one end open, the rectangular aluminum box open-mouth ruler It is very little consistent with the size of transparency carrier 4.
In embodiments of the present invention, the groove is to be equidistantly spaced between rectangular recess, the rectangular recess, preferably , between the rectangular recess at intervals of 0.25 micron.
In embodiments of the present invention, it is described every the mixture that light mixture 3 is anhydrous glue and barium sulfate.It is preferred that, sulphur Sour barium is 1 with anhydrous glue water weight ratio:1, every light mixture thickness be 0.25mm.Wherein, the anhydrous glue can be anhydrous Epoxy resin.The embodiment of the present invention is resulted in by filling the mixture of anhydrous glue and barium sulfate between scintillation crystal bar Good luminous reflectanc, it is to avoid the light leakage phenomena between scintillation crystal crystal bar.
In the embodiment of the present invention, the thickness of high reflection film plating layer 2 is 1.5-2.5 microns, it is preferred that the high reflection plated film The thickness of layer is 2 microns.Further, high reflection film plating layer is total reflection plated film, and the reflectivity of high reflection film plating layer is more than 99.9%.
Fig. 2 diagrammatically illustrates a kind of flow chart of the method for packing of scintillation crystal array of proposition of the embodiment of the present invention. Reference picture 2, the method for packing of scintillation crystal array provided in an embodiment of the present invention specifically includes following steps:
S11, the lateral surface plating high reflection film plating layer in scintillation crystal bar, plate in an end face of the scintillation crystal bar and increase Saturating film plating layer;
S12, in the one side of transparency carrier open up the groove of the end face for placing each scintillation crystal bar;
S13, the colloid that each scintillation crystal bar is in by refractive index between transparency carrier and scintillation crystal are bonded in In respective slot on the transparency carrier;
S14, using the space filled every light mixture between the scintillation crystal bar, scintillation crystal block is obtained, described Every light mixture described in the lateral surface even spread of scintillation crystal block, drying is described every light mixture;
S15, there is the scintillation crystal block every light mixture to install in array case the side even spread, use The gap closed every light mixture between the array case and the transparency carrier.
In this embodiment of the present invention, by carrying out effective encapsulation to scintillation crystal bar, the shadow of moisture is protected it from Ring, to keep the flicker bulk properties of scintillation crystal, maintain the image resolution ratio of contrast imaging detector.
In another embodiment of the invention, the lateral surface in scintillation crystal bar plates high reflection film plating layer, described Before the end face plating anti-reflection coating layer of scintillation crystal bar, in addition to:
The raw material of scintillation crystal are cut, scintillation crystal bar is obtained.
Scintillation crystal array provided in an embodiment of the present invention, by plating high reflection deielectric-coating in scintillation crystal side, One end face plating anti-reflection coating layer, and the end face is attached on transparency carrier, anhydrous glue is filled between scintillation crystal bar Good luminous reflectanc is resulted in the mixture of barium sulfate, it is to avoid the light leakage phenomena between scintillation crystal crystal bar, then will dodge Bright crystal bar, which is encapsulated into shell, completes sealing, the scintillation crystal array that the embodiment of the present invention is obtained, with Deliquescence-resistant, reliably Property height, albedo height, compact conformation, not light leak, it is easy to assembly the advantages of, while before having extensive market in image field Scape.
In the specific embodiment of the present invention, the fixed substrate is made up of silica, and size is 10x10x2mm, by two 10x10 mirror polish of the fixed substrate, one of 10x10 faces use plasma etching method system 1x1x0.5mm shrinkage pool array is had, shrinkage pool is prepared at intervals of 0.25mm, altogether there are 49 shrinkage pools, 49 pieces of 1x1x10mm's of processing Lanthanum bromide crystal bar, four 1x10mm faces of lanthanum bromide crystal bar and a 1x1 face carry out optical polish, and using vacuum evaporation Four 1x10mm faces of lanthanum bromide crystal bar are coated with high reflection film plating layer by the mode of plated film, and 1x1 faces are coated with anti-reflection coating layer, its The 1x1 coated surfaces refractive index of lanthanum bromide crystal bar is in transparency carrier 4 by anti-reflection film transmissivity > 99.9%, preparation after finishing Colloid between scintillation crystal is bonded in the shrinkage pool of scintillation crystal fixation substrate and ensures that crystal bar is disposed vertically, crystal bar Between spacing be 0.25mm, 20g barium sulfate powder is mixed in the anhydrous epoxy glues of 20g and is packed into crystalline substance after stirring afterwards Among the space of body bar, array case 5 is covered, with the gap between the above-mentioned mixture closed substrate being mixed to get and shell, Dry the encapsulation that array is completed after said mixture.
For embodiment of the method, in order to be briefly described, therefore it is all expressed as to a series of combination of actions, but this area Technical staff should know that the embodiment of the present invention is not limited by described sequence of movement, because according to present invention implementation Example, some steps can be carried out sequentially or simultaneously using other.Secondly, those skilled in the art should also know, specification Described in embodiment belong to necessary to preferred embodiment, the involved action not necessarily embodiment of the present invention.
In the specification that this place is provided, numerous specific details are set forth.It is to be appreciated, however, that the implementation of the present invention Example can be put into practice in the case of these no details.In some instances, known method, structure is not been shown in detail And technology, so as not to obscure the understanding of this description.
Similarly, it will be appreciated that in order to simplify the disclosure and help to understand one or more of each inventive aspect, exist Above in the description of the exemplary embodiment of the present invention, each feature of the invention is grouped together into single implementation sometimes In example, figure or descriptions thereof.However, the method for the disclosure should be construed to reflect following intention:It is i.e. required to protect The application claims of shield features more more than the feature being expressly recited in each claim.More precisely, such as following Claims reflect as, inventive aspect is all features less than single embodiment disclosed above.Therefore, Thus the claims for following embodiment are expressly incorporated in the embodiment, wherein each claim is in itself All as the separate embodiments of the present invention.
Although in addition, it will be appreciated by those of skill in the art that some embodiments in this include institute in other embodiments Including some features rather than further feature, but not the combination of the feature of be the same as Example mean be in the scope of the present invention Within and form different embodiments.For example, in the following claims, embodiment claimed it is any it One mode can use in any combination.
It should be noted that the present invention will be described rather than limits the invention for above-described embodiment, and ability Field technique personnel can design alternative embodiment without departing from the scope of the appended claims.In the claims, Any reference symbol between bracket should not be configured to limitations on claims.Word "comprising" is not excluded the presence of not Element or step listed in the claims.Word "a" or "an" before element does not exclude the presence of multiple such Element.The use of word first, second, and third does not indicate that any order.These words can be construed to title.

Claims (10)

1. a kind of scintillation crystal array, it is characterised in that including:Transparency carrier, the array installed with transparency carrier sealing Shell and at least one the scintillation crystal bar being placed in the sealing space formed by the transparency carrier and array case;
The one side of the transparency carrier is provided with the groove for placing each scintillation crystal bar end face, and each scintillation crystal bar leads to The colloid that superrefraction rate is between transparency carrier and scintillation crystal bar is bonded in the respective slot on the transparency carrier, often The end face being placed in the respective slot of one scintillation crystal bar is coated with anti-reflection coating layer, and the lateral surface of each scintillation crystal bar High reflection film plating layer is coated with, the gap between each scintillation crystal bar is filled with every light mixture, it is brilliant to form flicker Body block, has described every light mixture in the side even spread of the scintillation crystal block.
2. scintillation crystal array according to claim 1, it is characterised in that the array case is the rectangle of one end open Aluminium box, the rectangular aluminum box opening size is consistent with transparency carrier size.
3. scintillation crystal array according to claim 1, it is characterised in that the groove is rectangular recess, the rectangle It is equidistantly spaced between groove.
4. scintillation crystal array according to claim 3, it is characterised in that it is described every light mixture be anhydrous glue and sulphur The mixture of sour barium.
5. scintillation crystal array according to claim 4, it is characterised in that the anhydrous glue is anhydrous epoxy resin.
6. scintillation crystal array according to claim 1, it is characterised in that the scintillation crystal bar be size identical just The scintillation crystal bar of cube, cuboid or cylinder.
7. scintillation crystal array according to claim 1, it is characterised in that the thickness of the high reflection film plating layer is 1.5- 2.5 micron.
8. scintillation crystal array according to claim 1, it is characterised in that described high reflection film plating layer plates for total reflection Film, the reflectivity of high reflection film plating layer is more than 99.9%.
9. a kind of method for packing of scintillation crystal array, it is characterised in that methods described includes:
High reflection film plating layer is plated in the lateral surface of scintillation crystal bar, anti-reflection coating is plated in an end face of the scintillation crystal bar Layer;
The groove of the end face for placing each scintillation crystal bar is opened up in the one side of transparency carrier;
The colloid each scintillation crystal bar being in by refractive index between transparency carrier and scintillation crystal bar is bonded in described In respective slot on bright substrate;
Using the space filled every light mixture between the scintillation crystal bar, scintillation crystal block is obtained, in the scintillation crystal Every light mixture described in the lateral surface even spread of block, drying is described every light mixture;
There is the scintillation crystal block every light mixture to install in array case side even spread, with described every light Mixture closes the gap between the array case and the transparency carrier.
10. the method for packing of scintillation crystal array according to claim 9, it is characterised in that described in scintillation crystal bar Lateral surface plating high reflection film plating layer, the scintillation crystal bar an end face plating anti-reflection coating layer before, in addition to:
The raw material of scintillation crystal are cut, scintillation crystal bar is obtained.
CN201710632551.3A 2017-07-28 2017-07-28 A kind of method for packing of scintillation crystal array and scintillation crystal array Pending CN107290771A (en)

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CN108107463A (en) * 2017-12-12 2018-06-01 宁波虔东科浩光电科技有限公司 A kind of scintillating ceramic array and preparation method thereof
CN109459782B (en) * 2018-12-29 2020-06-16 厦门中烁光电科技有限公司 Scintillation crystal packaging method, scintillation crystal packaging structure and application thereof
CN109459782A (en) * 2018-12-29 2019-03-12 厦门中烁光电科技有限公司 Scintillation crystal packaging method, scintillation crystal encapsulating structure and its application
CN110368014A (en) * 2019-07-19 2019-10-25 东软医疗系统股份有限公司 For the crystal array of pet detector, detector rings and pet detector
CN110368014B (en) * 2019-07-19 2023-10-31 沈阳智核医疗科技有限公司 Crystal array for a PET detector, detector ring and PET detector
CN110687579A (en) * 2019-11-29 2020-01-14 刘娟 Yttrium lutetium silicate scintillation crystal radiation detector with high light extraction rate
CN110687578A (en) * 2019-11-29 2020-01-14 刘娟 Thallium-doped cesium iodide scintillation crystal radiation detector with high light extraction rate
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CN110687575A (en) * 2019-11-29 2020-01-14 刘娟 Radiation detector with high light-emitting rate for cerium-doped gadolinium silicate scintillation crystal
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Application publication date: 20171024