CN107290495A - Evaluation of river water quality method based on multi-parameter index - Google Patents

Evaluation of river water quality method based on multi-parameter index Download PDF

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CN107290495A
CN107290495A CN201710563026.0A CN201710563026A CN107290495A CN 107290495 A CN107290495 A CN 107290495A CN 201710563026 A CN201710563026 A CN 201710563026A CN 107290495 A CN107290495 A CN 107290495A
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wqi
mrow
index
water quality
river
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吴召仕
王昌辉
王晓龙
蔡永久
张磊
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Nanjing Institute of Geography and Limnology of CAS
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Abstract

The invention discloses a kind of evaluation of river water quality method based on multi-parameter index.This method is with WQIminAs index, based on water quality index (WQI), water quality of river is evaluated and grade classification.Present invention discover that by ammoniacal nitrogen (NH4N), permanganate index (CODMn), nitrate (NO3N), the WQI of dissolved oxygen (DO) and turbidity (tur) compositionminIt is in notable positive correlation with WQI indexes, therefore the WQI built by ammoniacal nitrogen, permanganate index, nitrate, dissolved oxygen and turbidity can be usedminIndex substitution needs the numerous parameters determined to calculate obtained WQI indexes originally, you can realize the Fast Evaluation and Type division of water quality of river.Operation is simple for the inventive method, with low cost, it is easy to promotes, and its advantage is fairly obvious.

Description

Evaluation of river water quality method based on multi-parameter index
Technical field
The present invention relates to environmental science and monitoring technical field, it is related to a kind of quality evaluation method, is then specifically development one Plant and be based on by ammoniacal nitrogen (NH4- N), permanganate index (CODMn), nitrate (NO3- N), dissolved oxygen (DO) and turbidity (tur) WQI of compositionminCarry out the method for water quality of river Fast Evaluation and water quality category division.
Background technology
Because natural process, mankind's activity and water resource are using reasons such as increases, deteriorating water quality turns into the world today The most important environmental pollution problem faced, causes the extensive concern of domestic and international scientist and administrative department.It is worth noting that, Following freshwater resources can be more rare, so as to jeopardize utilization of the mankind to water resource, particularly its drinking water function and its Important function in economic development.The World Health Organization finds that the drinking water of global about 1,100,000,000 populations can not obtain effective guarantee. It can be seen that, the protection to Freshwater ecosystems water resource is particularly important, and numerous countries and regions are carried out in this aspect Extensive work.River ecosystem plays an important role in terms of human health and economic development, simultaneously as taking The waste water such as band life and industry, its water quality is highly prone to pollution.
Water quality assessment is particularly important to contamination control and resource management.On the one hand, by water quality assessment, we can be with Fresh water water resource water quality condition and its variation tendency are grasped, scientific basis is provided for water resources management.On the other hand, water quality is carried out Appraisal, contributes to major pollutants and its contribution to water quality change in time and space in identification water body, so that what manager had Arrow is put, water resource is preferably managed.In addition, the acquisition based on water quality condition, the public can more energetically participate in environment Work is protected, is conducive to the smooth implementation of environmental practice.
Therefore, efficiently and quickly evaluating water quality situation be carry out water pollution preventing and treating and groundwater optimal management premise and It is crucial.Domestic quality evaluation method conventional at present is single factor evaluation method, biological assessment method etc..Because evaluation result is depended on Worst index, single factor evaluation method can not concentrated expression water quality situation.Biological assessment is wasted time and energy, and evaluation result compared with according to Rely the identification level in analyst.At present, evaluation of river water quality is generally carried out using water quality index (WQI) in the world, it is integrated Numerous environmental index, and a single numerical value is effectively translated into, to reflect water quality condition, solve each factor evaluation knot The problem of fruit differs, is conducive to manager to carry out relevant Decision.But, this method needs to carry out the survey of a large amount of water quality parameters It is fixed, it is with high costs, and a large amount of chemical reagent used in water quality parameter continuous mode also have harm to water environment.In order to enter one Step promotes China's present status and trend monitoring and prevents and treats the research of theory, in the urgent need to a kind of accurate, simplicity of development, quickly, just Preferably with the evaluation of river water quality method of of low pollution.
The content of the invention
The present invention seeks to set up a kind of side that water quality of river Fast Evaluation and classification are carried out based on multi-parameter water quality index Method, it is adaptable to different quality classification, the river of different type (mountain area, Plain), while survey needed for enormously simplify water quality assessment Fixed numerous indexs, with low cost, operating method is easy, it is easy to promotion and application.
Above-mentioned purpose of the present invention is achieved through the following technical solutions:
A kind of evaluation of river water quality method based on multi-parameter index, comprises the following steps:
(1) the water body ammoniacal nitrogen in river to be evaluated, permanganate index, nitrate, dissolved oxygen and turbidity concentration are determined;
(2) the parameter measured value determined based on step (1) calculates its standardized value, and calculates river according to standard parameter value Flow WQIminIndex, its calculation formula is as follows:
In formula:CiIt is the standardized value of i-th kind of parameter, PiIt is the weight of i-th kind of parameter;
(3) WQI is usedminWater quality division is carried out to river:
WQImin≤ 25 be V class;25<WQImin≤ 50 be IV class;50<WQImin≤ 70 be III class;70<WQImin≤ 90 are II class;90<WQImin≤ 100 be I class.
The method of the present invention, in the step (1), the concentration of nitrate is by determining water body nitrate, and by nitre State nitrogen concentration is converted into nitrate concentration acquisition.
In the method for the present invention, the step (1), ammoniacal nitrogen is determined using Na's colorimetry, and permanganate index is used Permanganate index acid process is determined, and nitrate nitrogen is determined using disulfonic acid phenol;Dissolved oxygen and turbidity concentration use multi-parameter water Matter tacheometer is determined.
In the method for the present invention, the step (2), standard parameter method uses point system.
The method of the present invention, in the step (2), water body ammoniacal nitrogen, permanganate index, nitrate, dissolved oxygen and The weight of turbidity parameter is followed successively by 3,3,2,4 and 2.
In the method for the present invention, the step (3), water quality category division mode is obtained based on WQI indexes.
The method of the present invention, in addition to, according to WQI exponent pairs WQIminIndex computational accuracy verified, percentage error PE calculation formula are as follows:
Wherein, n is water body number of samples, and P is the WQI of i-th of water body sampleminCalculated value, O is i-th of water body sample WQI。
Advantages of the present invention and beneficial effect:
(1) water quality of river category division is carried out with single index in traditional utilization GB3838-2002 different, the present invention Method is effectively translated into a single numerical value based on water quality index method generally popular in the world, to reflect water quality shape Condition, solves the problem of each factor evaluation result differs, and is conducive to manager to carry out relevant Decision.
(2) on the basis of comprehensive 15 environmental index, it is proposed that the WQI being made up of 5 kinds of key factorsmin.Therefore reduce Unnecessary environmental factor measurement experiment process it is cumbersome the step such as clear up, drastically reduce the area testing cost, save chemistry examination Agent is used, and reduces pollutant emission, protects environment.
(3) present invention is abundant and has developed the computational methods of water quality of river index, can be widely applied to different type river The monitoring and appraisal of stream, will deepen basic theory and the Control Technology research of river evaluation.
With reference to specific implementation case, the present invention will be described in detail.Protection scope of the present invention is not with specific real The mode of applying is limited, but is defined in the claims.
Brief description of the drawings
Fig. 1 is the minimum water quality index (WQI based on different water systems and different type Taihu Lake basin river structuremin) with containing The relation of the water quality index (WQI) of 15 environmental index of lid.
Embodiment
Below using the different water system river results of study of Taihu Lake basin as example, this method is described further.
Embodiment 1
Using the carry out Taihu Lake basin evaluation of river water quality of the present invention, comprise the following steps:
(1) the water body ammoniacal nitrogen in Taihu Lake basin river is determined, permanganate index, nitrate, dissolved oxygen and turbidity are dense Degree;
2014-2016 is at the big water system of Taihu Lake basin 6 (sweet potato small stream, the Nanhe River, wash one's face Gehu, riverine, Huangpu, entrance of Changjiang River and Hangzhou Wan) (table 1) has carried out the field sampling of 4 seasons, is related to 96 sampled points, 39 trunk rivers (Dong Tiaoxi, Xi Tiaoxi, Chang Xinggang, south River, room Xi He, draw small stream river, Nanxi river, Meng He, Cheng Donggang, red gold Li Caohe, Beijing-Hangzhou Grand Canal, capital Hangzhoupro Guyue Library, shoulder pole river, Wu Yi canals, Wu Jingang, Meng Jinhe, Xin Gouhe, Xi Bei canal, white Qu Gang, waterside light river, Lu Zhi Gang, Miao Jing rivers, Wusongjiang River, Huang Pujiang, Tai Puhe, Desheng river, the clear canal of tin, Zhangjiagang, Wang Yu rivers, Chang Hu rivers, Yan Tietang, clear river, Chuan Yanghe, great Ye He, Sui Tang He, Jin Huigang, salt official go to river, the long mountains and rivers, the sea salt pool), cover different water systems, different types of Taihu Lake basin river, be based on The river fast appraisement method of this data set development has universality and generalization.
Scene determines water turbidity and dissolving with Portable, multiple parameter water quality tacheometer (such as Hydrolab Datasond 5) Oxygen concentration, and water sample time experimental determination ammoniacal nitrogen, permanganate index and nitrate are gathered, and nitrate is turned Turn to nitrate concentration.
(2) the parameter measured value determined based on step (1) calculates its standardized value, and calculates river according to standard parameter value Flow WQIminIndexes Index, its calculation formula is as follows:
(in formula:CiIt is the standardized value of i-th kind of parameter, PiIt is the weight of i-th kind of parameter;Standard parameter in the present embodiment Method uses point system, span 0-100, the 0 worst water quality of expression, the 100 best water quality of expression, design parameter standardization value It is as shown in table 1 with weight value.
(3) WQI is usedminWater quality division is carried out to river:
WQImin≤ 25 be V class;25<WQImin≤ 50 be IV class;50<WQImin≤ 70 be III class;70<WQImin≤ 90 are II class;90<WQImin≤ 100 be I class.
The present embodiment builds water quality index WQI also based on 15 ambient parameters, and the evaluation method to the present invention is tested Card.
Concrete operation step is as follows:
(1) scene determines water temperature with Portable, multiple parameter water quality tacheometer (such as Hydrolab Datasond 5) (T), pH, electrical conductivity (cond), turbidity and dissolved oxygen concentration, and gather water sample time experimental determination total nitrogen (TN), ammoniacal nitrogen, nitre Hydrochlorate, nitrite (NO2- N), total phosphorus (TP), permanganate index, calcium ion (Ca), magnesium ion (Mg), chlorion (Cl), Sulfate ion (SO4) concentration.
(2) total nitrogen, ammoniacal nitrogen, nitrate, nitrite, total phosphorus, permanganate index, calcium ion, magnesium ion, chlorine are carried out Ion, sulfate ion concentration are determined:Raw water sample is cleared up by alkaline chitinase, using the anti-colour developing of molybdenum antimony, configured simultaneously Standard liquid, then determines the conversion of 210nm absorbances in ultraviolet specrophotometer and obtains total nitrogen concentration, determine 700nm absorbances Conversion obtains total phosphorus concentration;It is dense using disulfonic acid phenol, N- (1- naphthyls) ethylenediamine photometry measure nitrate nitrogen, nitrite nitrogen Degree, and it is converted into NO3-N and NO2-N concentration;Using Na's colorimetry, permanganate index acid process determine ammonia state Nitrogen, permanganate index concentration;Utilize Flame Atomic Absorption calcium, magnesium ion concentration;Using ion-chromatographic determination chlorine from Son, sulfate ion concentration.
(3) water quality index is calculated:
Each factor is standardized, standardized method and parameters weighting are as shown in table 1.Water quality index calculation formula is such as Under:
The water quality parameter weight of table 1 and standardized method
Wherein T unit for DEG C, cond units be μ S cm-1, turbidity unit is NTU, and other specification unit is mg L-1; Before standardization, by NO2- N and NO3- N concentration is by mgN L-1It is converted into mg NOX L-1
(4) WQI and WQI is analyzedminBetween dependency relation:
Water quality index and minimum index water quality index based on 384, Taihu Lake basin river website, are analyzed between the two Dependency relation.Fig. 1 is the minimum water quality index (WQI based on different water systems and different type Taihu Lake basin river structuremin) with containing The relation of the water quality index (WQI) of 15 environmental index of lid.From fig. 1, it can be seen that based on water temperature, pH, electrical conductivity, turbidity, dissolved oxygen, Total nitrogen, ammoniacal nitrogen, nitrate, nitrite, total phosphorus, permanganate index, calcium ion, magnesium ion, chlorion, sulfate ion The water quality index of calculating and the minimum water quality index calculated based on ammoniacal nitrogen, permanganate index, nitrate, dissolved oxygen and turbidity In the presence of extremely notable positive correlation (R2=0.91, P<0.001), reflect and carry out Taihu Lake basin river using minimum water quality index The credibility and accuracy of water quality assessment.Therefore by ammoniacal nitrogen, permanganate index, nitrate, dissolved oxygen and turbidity index The WQI of structureminThe WQI that former 15 indexs are built, the Fast Evaluation for Taihu Lake basin water quality of river can be substituted.
According to the inventive method, water body WQI is utilizedminIndex, estimates Taihu Lake basin water quality of river state, and with basis often See that 15 environmental index are calculated and obtain water quality index WQI numeric ratios compared with (table 2).Obtained Taihu Lake stream is calculated according to the inventive method Domain river WQI, WQImin, according to WQI and WQIminThe water quality classification of division, model percentage error are as shown in table 2:
The WQI of table 2minIndex is in Taihu Lake basin applicating evaluating result
The parameter of analysis river water water quality index computational accuracy be the WQI that draws according to 15 conventional evaluation indexes with according to The WQI obtained according to ammoniacal nitrogen, permanganate index, nitrate, dissolved oxygen and turbidityminBetween percentage error PE, calculate public Formula is as follows:
(wherein, n is water body number of samples, and P is the WQI of i-th of water body sampleminCalculated value, O is i-th of water body sample WQI.
Through examining, the mean percent ratio error that the present invention is applied in 39 trunk rivers of Taihu Lake basin is 8.72%, according to According to WQIminOnly occurs inconsistent, the suitable Taihu Lake basin water quality of river of the parameter in 4 rivers with the WQI water quality classifications evaluated Index is estimated and precision is higher.

Claims (7)

1. a kind of evaluation of river water quality method based on multi-parameter index, it is characterised in that comprise the following steps:
(1) the water body ammoniacal nitrogen in river to be evaluated, permanganate index, nitrate, dissolved oxygen and turbidity concentration are determined;
(2) the parameter measured value determined based on step (1) calculates its standardized value, and calculates river according to standard parameter value WQIminIndex, its calculation formula is as follows:
<mrow> <msub> <mi>WQI</mi> <mi>min</mi> </msub> <mo>=</mo> <mfrac> <mrow> <msubsup> <mi>&amp;Sigma;</mi> <mrow> <mi>i</mi> <mo>=</mo> <mn>1</mn> </mrow> <mn>5</mn> </msubsup> <msub> <mi>C</mi> <mi>i</mi> </msub> <msub> <mi>P</mi> <mi>i</mi> </msub> </mrow> <mrow> <msubsup> <mi>&amp;Sigma;</mi> <mrow> <mi>i</mi> <mo>=</mo> <mn>1</mn> </mrow> <mn>5</mn> </msubsup> <msub> <mi>P</mi> <mi>i</mi> </msub> </mrow> </mfrac> <mo>-</mo> <mo>-</mo> <mo>-</mo> <mrow> <mo>(</mo> <mn>1</mn> <mo>)</mo> </mrow> </mrow>
In formula:CiIt is the standardized value of i-th kind of parameter, PiIt is the weight of i-th kind of parameter;
(3) WQI is usedminWater quality division is carried out to river:
WQImin≤ 25 be V class;25<WQImin≤ 50 be IV class;50<WQImin≤ 70 be III class;70<WQImin≤ 90 be II class; 90<WQImin≤ 100 be I class.
2. according to the method described in claim 1, it is characterised in that in the step (1), the concentration of nitrate is by determining water Body nitrate, and nitrate is converted into nitrate concentration acquisition.
3. method according to claim 2, it is characterised in that in the step (1), ammoniacal nitrogen is surveyed using Na's colorimetry Fixed, permanganate index is determined using permanganate index acid process, and nitrate nitrogen is determined using disulfonic acid phenol;Dissolved oxygen and turbid Concentration is spent to determine using multi-parameter water quality tacheometer.
4. according to the method described in claim 1, it is characterised in that in the step (2), standard parameter method is using scoring Method.
5. according to the method described in claim 1, it is characterised in that in the step (2), water body ammoniacal nitrogen, permanganate refers to The weight of number, nitrate, dissolved oxygen and turbidity parameter is followed successively by 3,3,2,4 and 2.
6. according to the method described in claim 1, it is characterised in that in the step (3), water quality category division mode is based on WQI indexes are obtained.
7. according to the method described in claim 1, it is characterised in that also include, according to WQI exponent pairs WQIminIndex calculates essence Degree is verified that percentage error PE calculation formula are as follows:
<mrow> <mi>P</mi> <mi>E</mi> <mo>=</mo> <msubsup> <mi>&amp;Sigma;</mi> <mrow> <mi>i</mi> <mo>=</mo> <mn>1</mn> </mrow> <mi>n</mi> </msubsup> <mo>|</mo> <mfrac> <mi>P</mi> <mi>O</mi> </mfrac> <mo>-</mo> <mn>1</mn> <mo>|</mo> <mo>*</mo> <mn>100</mn> <mo>/</mo> <mi>n</mi> <mo>-</mo> <mo>-</mo> <mo>-</mo> <mrow> <mo>(</mo> <mn>3</mn> <mo>)</mo> </mrow> </mrow>
Wherein, n is water body number of samples, and P is the WQI of i-th of water body sampleminCalculated value, O is the WQI of i-th of water body sample.
CN201710563026.0A 2017-07-11 2017-07-11 Evaluation of river water quality method based on multi-parameter index Pending CN107290495A (en)

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CN108562708A (en) * 2018-04-18 2018-09-21 中国科学院南京地理与湖泊研究所 Evaluation of river water quality method based on phytoplankton Perfection Index
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CN112798533A (en) * 2021-02-07 2021-05-14 深圳市中志环境科技有限公司 Multi-factor water quality monitor and multi-factor water quality monitoring method
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CN108320261A (en) * 2018-01-18 2018-07-24 北控水务(中国)投资有限公司 A kind of city river section dynamic water quality objective determines method
CN108226437A (en) * 2018-04-09 2018-06-29 山东建筑大学 A kind of method of amendment water quality monitoring result applied to lake library water body
CN108562708A (en) * 2018-04-18 2018-09-21 中国科学院南京地理与湖泊研究所 Evaluation of river water quality method based on phytoplankton Perfection Index
CN109470829A (en) * 2018-11-21 2019-03-15 武汉新烽光电股份有限公司 Water quality detection method, device, server, water-quality sampler and medium
CN109470829B (en) * 2018-11-21 2021-08-10 武汉新烽光电股份有限公司 Water quality detection method, device, server, water quality sampler and medium
CN112798533A (en) * 2021-02-07 2021-05-14 深圳市中志环境科技有限公司 Multi-factor water quality monitor and multi-factor water quality monitoring method
CN114354705A (en) * 2022-01-10 2022-04-15 中国水产科学研究院长江水产研究所 Comprehensive evaluation method for surface water quality based on multi-parameter relative weight
CN115053685A (en) * 2022-06-07 2022-09-16 舒城县农业科学研究所 Water and fertilizer management and control system for aquatic vegetable planting
CN115053685B (en) * 2022-06-07 2023-11-28 舒城县农业科学研究所 Fertilizer water management and control system for aquatic vegetable planting
CN117524339A (en) * 2024-01-04 2024-02-06 攀枝花市东区生态环境监测站 Method and system for measuring residual chlorine
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